• Title/Summary/Keyword: oxygen

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A Review of Ac-impedance Models for the Analysis of the Oxygen Reduction Reaction on the Porous Cathode Electrode for Solid Oxide Fuel Cell

  • Kim, Ju-Sik;Pyun, Su-Il
    • Journal of the Korean Electrochemical Society
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    • v.8 no.2
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    • pp.106-114
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    • 2005
  • This article covers the theoretical ac-impedance models for the analysis of oxygen reduction on the porous cathode electrode f3r solid oxide fuel cell (SOFC). Firstly, ac-impedance models were explained on the basis of the mechanism of oxygen reduction, which were classified into the rate-determining steps; (i) adsorption of oxygen atom on the electrode surface, (ii) diffusion of adsorbed oxygen atom along the electrode surface towards the three-phase (electrode/electrolyte/gas) boundaries, (iii) surface diffusion of adsorbed oxygen atom m ixed with the adsorption reaction of oxygen atom on the electrode surface and (iv) diffusion of oxygen vacancy through the electrode coupled with the charge transfer reaction at the electrode/gas interface. In each section for ac-impedance model, the representative impedance plots and the interpretation of important parameters attributed to the oxygen reduction reaction were explained. Finally, we discussed in detail the applications of the proposed theoretical ac-impedance models to the real electrode of SOFC system.

Limit-current type zirconia oxygen sensor with porous diffusion layer (다공성 확산층을 이용한 한계전류형 지르코니아 산소센서)

  • Oh, Young-Jei;Lee, Chil-Hyoung
    • Journal of Sensor Science and Technology
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    • v.17 no.5
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    • pp.329-337
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    • 2008
  • Simple, small and portable oxygen sensors were fabricated by tape casting technique. Yttria stabilized zirconia containing cordierite ceramics (YSZC) were used as a porous diffused layer of oxygen in pumping cell. Yttria stabilized zirconia (YSZ) solid electrolyte, YSZC porous diffusion layer and heater-patterned ceramic sheets were prepared by co- firing method. Limit current characteristics and the linear relationship of current to oxygen concentration were observed. Viscosity variation of the slurries both YSZ and YSZC showed a similar behavior, but micro pores in the fired sheet were increased with increasing of the cordierite amount. Molecular diffusion was dominated due to the formation of large pores in porous diffusion layer. The plateau range of limit current in porous-type oxygen sensor was narrow than the one of aperture-type oxygen sensor. However limit current curve was appeared in porous-type oxygen sensor even at the lower applied voltage. The plateau range of limit-current was widen as increasing the thickness of porous diffusion layer of the YSZ containing cordierite. Measuring temperature of $600{\sim}650^{\circ}C$ was recommended for limit-current oxygen sensor. Porous diffusion layer-type oxygen sensor showed faster response than the aperture-type one and was stable up to 30 days running without any crack at interface between the layers.

A Study on the Microfabricated Clark-type Sensor for Measuring Dissolved Oxygen (용존 산소 측정용 초소형 Clark-type 센서에 대한 연구)

  • Park, Jung-Il;Chang, Jong-Hyeon;Choi, Myung-Ki;Lee, Dong-Young;Kim, Young-Mi;Pak, Jung-Ho
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.8
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    • pp.1450-1454
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    • 2007
  • This paper presents a microfabricated Clark-type sensor which exactly can measure dissolved oxygen in the cell containing solution. We designed, fabricated, and characterized a microfabircated Clark-type oxygen sensor for measuring dissolved oxygen. The microfabricated oxygen sensor consists of 3-electrodes on a glass substrate, a FEP (Fluorinated ethylene propylene) oxygen-permeable membrane, and PDMS (Polydimethylsiloxane) reservoir for storing sample solution. Thin-film Ag/AgCl was employed as a reference electrode and its durability was verified by obtaining a stable open circuit potential for 2 hours against a commercial Ag/AgCl electrode and a stable cyclic voltammetry curve. Selectivity, response time, and linearity of the fabricated oxygen sensor were also verified well by cyclic voltammetry and amperometry depending. The fabricated oxygen sensor showed a 90% response time of 40sec and an excellent linearity with a correlation coefficient of 0.994.

Research for the Chemical Emergency Oxygen Supply and Lighting System for Aircraft Passengers (항공기 승객용 화학적 비상산소 공급 및 조명시스템에 대한 연구)

  • Kim, Young-In
    • Journal of the Korean Society for Aviation and Aeronautics
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    • v.30 no.2
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    • pp.55-60
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    • 2022
  • A PSU (passenger service unit) is mounted on passenger seats in a cabin on an aircraft and consists of a crew call lamp, a reading lights, an information display lamp, an emergency oxygen generator, and an emergency oxygen mask. It is a safety device for providing convenience to passengers and providing oxygen to passengers in an emergency. This paper is a study on emergency oxygen supply systems and light systems of aircraft PSUs and a control device was developed to operate the system by analyzing the B767-300 aircraft's PSU circuit diagram. And the temperature generated by the B777-200ER aircraft's emergency oxygen generator was also measured by operating it directly. Through this, precautions for explaining the operation of an oxygen mask in an emergency were described and improvements were presented. Data acquired in these research processes can be used in the future to develop aircraft PSU (passenger service unit) and emergency oxygen generators.

The Influence of Oxygen on Czochralski Growth of Oxide Single Crystals

  • D. S. Chung;Park, B. H.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.06a
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    • pp.179-181
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    • 1997
  • When grown the oxide single crystal including Li-ion, optimum oxygen condition is needed. Color and crack are caused in single crystal according too the change in the condition of the oxygen. LiTaO₃ crystals grown from off-composition of congruent melt composition under oxygen deficieny condition didn't generate any crack. LiNbO₃. LiTaO₃ crystals grown from congruent melt composition under optimum oxygen condition caused pale yellow color or colorless with no crack. Color gradually became colorless and generated cracks according to Oxygen excess.

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Fabrication and characteristics of limit-current type oxygen sensor with monolith aperture structure (일체화된 Aperture 구조의 한계전류형 산소센서의 제작 및 특성)

  • Oh, Young-Jei;Lee, Deuk Yong
    • Journal of Sensor Science and Technology
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    • v.17 no.4
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    • pp.273-280
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    • 2008
  • Monolith aperture-type oxygen sensors with simple structure of YSZ(pin-hole)/Pt/ YSZ(solid electrolyte)/Pt were fabricated by co-firing technique. To enhance the yield of productivity, a couple of YSZ green sheets for diffused barrier and solid electrolyte were prepared by tape-casting and co-firing method. The limit current characteristics of the oxygen sensors were measured between 500 and $650^{\circ}C$ The heating temperature of $600^{\circ}C$ was optimum as a portable oxygen sensor in the range of oxygen concentration from 0 to 75 vol%. Linear proficiency of limit current behavior as a function of oxygen concentration was controlled by the variation of aperture dimension. The fabricated oxygen sensors showed the stable sensing output for 30 days. Gas leakage in bonding area due to warping, cracking and thermal cycling was not found in the period.

Polymer Waste Incineration by Oxygen Enriched Combustion (사업장폐기물의 순산소 소각기술)

  • Han, In-Ho;Choi, Kwang-Ho;Choung, Jin-Woo
    • 한국연소학회:학술대회논문집
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    • 2000.12a
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    • pp.132-139
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    • 2000
  • Oxygen enriched incineration can increase the incineration capacity for wastes and dramatically reduce air pollutant emissions such as CO and dioxine by the allowing complete combustion of wastes in incinerator. Furthermore, this technology is proven to have many benefits including an energy-saving, cost-effective, and versatile application for diverse wastes compared with the conventional air incineration technology. The reduced pollutant emissions in flue gas and higher incineration efficiency are also available when the oxygen enriched air is used for the high temperature incineration systems. On the basis of the experimental results the oxygen enrichment system is successfully applied to the rotary kiln incinerator for industrial wastes. The oxygen enriched incineration system could be allowed more compact design of incinerator and flue gas treatment system due to both increasing incineration capacity and reducing flue gas volume. Therefore, oxygen enriched incineration technology is becoming highlighted in the waste incinerator which strongly require more stable efficiency and environmentally friendly and safe operationPut Abstract text here.

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Alterations in $O_2$ Uptake Following Hemorrhage and Transfusion in Rats (실혈 후 및 혈압상승 후의 소화기 조직 혈액량 및 산소 섭취량 -제 2 편 동맥 혈압하강과 산소 섭취량 감소-)

  • Yoon, Byong-Hak;Nam, Kee-Yong
    • The Korean Journal of Physiology
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    • v.2 no.1
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    • pp.17-21
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    • 1968
  • Total body oxygen uptake was measured in rats following hemorrhage (16 rats) and blood transfusion (7 rats) under light Nembutal anesthesia. Arterial blood Pressure measured on the tail artery decreased or increased following hemorrhage or transfusion. No direct relationship was observed between arterial blood pressure alteration and oxygen intake variation. Hematocrit ratio which changed after hemorrhage or transfusion showed a direct relationship with oxygen intake. Decrease in hematocrit ratio resulted in a decrease in oxygen intake of rats. The correlation coefficient between decrement of hematocrit ratio and decrement of oxygen intake was r=.56. The correlation coefficient between increment of hematocrit ratio and increment of oxygen intake was r=.86. Thus it was concluded that alteration in oxygen intake was limited by the systemic oxygen transport capacity of blood.

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Adsorption of Oxygen and Segregation of Impurity on Copper Surface(polycrystal): An AES Study (다결정 구리 표면에서 산소 흡착과 불순물 표면적출 : AES에 의한 연구)

  • Byoung Sung Han
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.25 no.8
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    • pp.966-971
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    • 1988
  • AES was used to study oxygen adsorption due to the oxygen exposure at 300\ulcorner temperature and segregation of impurities due to annealing on polycrystal copper surface. The intensity of peak of CuM2, 3VV and CuL3 VV increased with annealing time and the peak of CKLL increased after Ar ion bombardment. The effect of oxygen adsorption on copper surface at 300\ulcorner was verified by the decreased of peak of CuM2, 3VV and CuL3 VV as oxygen exposure increase. The binding energy of copper atoms gradualy shifts from 0.7eV to 1.5eV of copper atoms gradually shifts from 0.7eV to 1.5eV after a oxygen exposure. After the oxygen exposure, the width at half the height of CuM2, 3VV is larger 2V*C/S by the effect of chemical liaison of the copper aton with oxygen atom.

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Hydrogen photoproduction by the synchronously grown marine unicellular cyanobacterium Synechococcus sp. Miami BG 043511 under extremely high oxygen concentration

  • Yih, Won-Ho;Takeyama, Haruko;Mitsui, Akira
    • Journal of the korean society of oceanography
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    • v.31 no.1
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    • pp.18-22
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    • 1996
  • The effect of exogenous oxygen on hydrogen photoproduction was examined in the synchronously grown cells of marine Synechococcus sp. Miami BG 043511 under conditions of high cell density (0.6-0.8 mg chl-${\alpha}$ $ml^{-1}$) and high light intensity (1000 ${\mu}$E $m^{-2}$ $s^{-1}$). Hydrogen evolution after 20-h incubation did not decline under the initial oxygen concentrations up to 20%, but declined by half under 34% oxygen. 50% and 100% oxygen gas phase did not completely inhibit the hydrogen photoproduction during 40-h incubations. After 2-day pretreatment under 100% exogenous oxygen the hydrogen photoproduction capabilities were not irreversibly inhibited, which was demonstrated in the subsequent 9-day incubation under initial 0, 50 and even under 100% oxygen gas phase. This strain could be useful for developing a hydrogen photoproduction system under atmospheric oxygen concentration.

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