• Title/Summary/Keyword: oxide reduction

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A Study on the Current Kink Effect in NMOSFET SOI Device with the Varying Gate Oxide Thickness (NMOSFET SOI 소자에서 부분적 게이트 산화막 두께 변화에 의한 돌연 전류 효과 고찰)

  • 한명석;이충근홍신남
    • Proceedings of the IEEK Conference
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    • 1998.10a
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    • pp.545-548
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    • 1998
  • Thin film SOI(Silicon-On-Insulator) devices exhibit floating body effect. In this paper, SOI NMOSFET is proposed to solve this problem. Some part of gate oxide was considered to be 30nm~80nm thicker than the other normal gate oxide and simulated with TSUPREM-4. The I-V characteristics were simulated with 2D MEDICI mesh. Since part of gate oxide has different oxide thickness in proposed device, the gate electric field strength is not the same throught the gate and consequently the reduction of current kink effect is occurred.

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The effect of Rh/Ce/Zr additives on the redox cycling of iron oxide for hydrogen storage (산화철의 환원-산화 반응을 이용한 수소저장에 미치는 Rh/Ce/Zr의 효과)

  • Lee, Dong-Hee;Cha, Kwang-Seo;Park, Chu-Sik;Kang, Kung-Soo;Kim, Young-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.49-52
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    • 2007
  • We investigated hydrogen storage and production properties using redox system of iron oxide($Fe_{3}O_{4}$ + $4H_{2}$ ${\leftrightarrows}$ 3Fe + $4H_{2}O$) modified with rhodium, ceria and zirconia under atmospheric pressure. Reduction of iron oxide with hydrogen(hydrogen storage) and re-oxidation of reduced iron oxide with steam(hydrogen evolution) was carried out using a temperature programmed reaction(TPR) technique. On the temperature programmed studies, the effects of amounts of cerium and zirconium on the re-oxidation rate of partial reduced iron oxides were increased with increasing metal additives amount, but the rhodium amount showed little effect on the re-oxidation rate. On the thermal studies, the re-oxidation rates were enhanced with increasing temperature(300 $^{\circ}C$ < 350 $^{\circ}C$).

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The Effect of Fe-Oxide Addition on the Sintered Structure of Cast Iron Power (주철분말(鑄鐵粉末)의 소결조직(燒結組織)에 미치는 산화철(酸化鐵) 첨가(添加)의 효과(效果))

  • Kim, Hyung-Soo;Kim, Chul-Bohm;Ra, Hyung-Yong
    • Journal of Korea Foundry Society
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    • v.10 no.2
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    • pp.154-161
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    • 1990
  • The microstructures of sintered products of $Fe_2O_3$or $Fe_3O_4$-Oxide added cast iron powder was investigated. And the effects of particle size distribution was investigated too. As the result, the structures of sintered products did not related to the species of Fe-Oxide. Th porosity of sintered products was decreased in size and spherodized with increasing sintering temperature, decreasing Fe-Oxide quantity. Fe-Oxide itself did not hinder sintering of cast iron powder particularly, therefore sintering could be occurred without termination of reduction of it. And the sintered products of finer particle size distribution had finer and more spherodized porosity, and had minimized the deviation of size and shape of porosity.

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Collodial Properties and Acid Consuming Capacity of Hydrous Aluminum Oxide Suspension (제산제 알루미나수화물의 콜로이드성과 제산능)

  • 이계주;이기명
    • YAKHAK HOEJI
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    • v.35 no.4
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    • pp.277-282
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    • 1991
  • Rheological, colloidal and micromeritical properties were followed to investigate aging mechanisms of hydrous aluminum oxide suspension using Zeta-meter systems, BET adsorption apparatus, Master sizer and electronmicroscope. The results indicate that hydrous aluminum oxide suspension revealed plastic flow with thixotropy. The viscosity, thixotropy and yield value were increased with increasing concentration. During aging process, the viscosity and thixotropic index were increased by an addition of glycerin, however, sorbitol stabilized aging process of the suspension being accompanied with growth of particle size and reduction in specific surface area, pore area and pore volume, and consistency. Diminution of adsorptive power of the particles was also protected by addition of sorbitol to hydrous aluminum oxide suspension. From these results, one of aging mechanism of hydrous aluminum oxide suspension assumed growth and/or crystallization of colloidal particles in aqueous suspension.

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Characteristics of Redox Agent with Additive in Steam-Iron Process for the High Purity Hydrogen Production (고순도 수소 생성을 위한 SIP법에서 첨가제에 따른 환원 특성)

  • Jeon, Bup-Ju;Kim, Sun-Myung;Park, Ji-Hun
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.3
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    • pp.340-348
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    • 2011
  • Effects of various inorganic-metal oxide (Zr, Zn, Si, Al and Ca as promoters and stabilizers) additive on the reduction rate of iron oxide and the composition of forming hydrogen using the steam-iron cycle operation was investigated. The reduction rate of redox agent with additive was determined from weight change by TGA. The changes of weight loss and reduction rate according to redox agent with various additive affected the hydrogen purity and cycle stability of the process. The cyclic micro reactor showed that hydrogen purity exceeding 95% could be obtained by the water splitting with Si/Fe, Zn/Fe, Zr/Fe redox agents. The redox agents with these elements had an affect on redox cycle stability as a good stabilizer for forming hydrogen by the steam-iron process.

A Study on the Reduction of Nitric Oxide Molecule (NO) to Nitroxyl Anion (NO-) by Vibrational Energy (진동에너지에 의한 산화질소 분자(NO)의 음이온(NO-)으로의 환원반응에 관한 연구)

  • Cho, Seon-Woog
    • Journal of the Korean Chemical Society
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    • v.46 no.1
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    • pp.14-18
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    • 2002
  • It is shown that one-electron reduction of nitric oxide (NO) to nitroxyl anion $(NO^-)$ can be accelerated by vibrational energy. Potential energy surfaces of NO and $NO^-$ reveal that the vertical transition between them has favorable energetics for vibrationally excited molecule. Also, Franck-Condon factors between NO and $NO^-$ vibrational wave functions are calculated. It shows that the number of open channels increases with increased vibrational energy. These results mean that we can control the rate of reduction of NO to $NO^-$ by radiating an appropriate light.

A Study on the Drag Reduction Effect and Heat Transfer Enhancement of Non ionized Surfactant and Water Mixture in a Circular Pipe Flow (비이온계 계면활성제 첨가수에 대한 관내 유동저항 감소 및 열전달 촉진에 관한 연구)

  • Kim, Myoung-Jun
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.5
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    • pp.552-557
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    • 2007
  • This paper has dealt with the effect of non ionized surfactant and water mixture on drag reduction and heat transfer enhancement in a circular pipe flow with experimentally. The test section was consisted of stainless steel pipe with inside diameter of 16mm. The wire coil was used to increase heat transfer in a pipe and the on ionized surfactant(Oleyl Dihydroxyethyl Amino Oxide, ODEAO) was used to reduce the drag force of water mixture with surfactant. The main parameters of this experiment were diameter and pitch of wire coil and the ratio of test section length and horizontal wire coil length. In this experiment, the acquired results were 1) Drag reduction effect existed in this ODEAO-water mixture, 2) Friction factor and heat transfer were increased with insertion the heat transfer enhancement coil, 3) With increasing of pitch ratio, heat transfer was decreased, and 4) Heat transfer was decreased by the decreasing of inserting coil diameter.