• Title/Summary/Keyword: oxide electrode

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Synthesis of Ag-Pd Electrode having Oxide Additive (산화물을 첨가한 Ag-Pd 전극의 제조)

  • Lee, Jae-Seok;Lee, Dong-Yoon;Song, Jae-Sung;Kim, Myoung-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.735-738
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    • 2003
  • Downsizing electronics requires precision position control with an accuracy of sub-micron order, which demands development of ultra-fine displacive devices. Piezoelectric transducer is one of devices transferring electric field energy into mechanical energy and being capable for fine displacement control. The transducer has been widely used as fine Position control device Multilayer piezoelectric actuator, one of typical piezo-transducer, is fabricated by stacking alternatively ceramic and electrode layers several hundred times followed by cofiring process. Electrode material should be tolerable in the firing process maintaining at ceramic-sintering temperatures up to $1100{\sim}1300^{\circ}C$. Ag-Pd can be used as stable electrode material in heat treatment above $960^{\circ}C$. Besides, adding small quantity ceramic powder allow the actuator to be fabricated in a good shape by diminishing shrinkage difference between ceramic and electrode layers, resulting in avoidance of crack and delamination at and/or nearby interface between ceramic an electrode layers. This study presents synthesis of nano-oxide-added Ag/Pd powders and its feasibility to candidate material tolerable at high temperature. The powders were formed in a co-precipitation process of Ag and Pd in nano-oxide-dispersed solution where Ag and Pd precursors are melted in $HNO_3$ acid.

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Synthesis and Characterisation of Mixed Conducting Perovskite Type Oxide and Its Electrochemical Application to Electrode Material for Solid Oxide Fuel Cell

  • Kim, Yu-Mi;Pyun, Su-Il;Lee, Gyoung-Ja;Kim, Ju-Sik
    • Journal of the Korean Electrochemical Society
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    • v.10 no.2
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    • pp.116-125
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    • 2007
  • This article is concerned with synthesis, characterisation and electrochemical application of the mixed conducting perovskite type oxide to electrode materials for solid oxide fuel cell. First, this review provides a comprehensive survey of the various synthetic methods such as solid state reaction, Pechini, glycine nitrate process and sol-gel methods for the preparation of perovskite type oxide powders. Subsequently, the electrical and microstructural properties of the mixed conducting oxides were discussed in detail. Finally, as electrochemical applications of the mixed conducting perovskite type oxides to electrode materials for solid oxide fuel cell, fundamentals of theoretical ac-impedance model for porous mixed conducting electrodes were introduced. Furthermore, the ac-impedance behaviour of porous and dense mixed conducting electrodes prepared by various synthetic methods was discussed.

A Study on Energy Band Change and Stability in Photoelectrolysis by Use of Titanium Oxide Films on Ti-Bi Alloy (Ti-Bi 합금 위에 형성된 산화티타늄 피막의 광 전기분해시 에너지밴드와 안정성에 관한 연구)

  • Park, Seong-Yong;Cho, Byung-Won;Yun, Kyung-Suk
    • Journal of Hydrogen and New Energy
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    • v.5 no.1
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    • pp.41-49
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    • 1994
  • Ti-Bi alloy was prepared by arc melting of appropriate amounts of titanium and bismuth powder. The photocurrent($I_{ph}$) of Ti-Bi oxide electrode was increased with the increase of Bi content, up to 10wt%. The maximum $I_{ph}$ showed $7.6mA/cm^2$ at V=0.5V vs. SCE. The band gap energy of Ti-Bi oxide electrode was observed to 3.0~2.87eV. Surface barrier($V_s$) of Ti-10Bi oxide electrode showed maximum value(1.08V) but didn't exceed 1.23V, then it was impossible to run $H_2$ generation without any other energy sources other than the light. Ti-Bi oxide electrode was found to be quite stable under alkaline solution and showed no signs of photodecomposition.

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Characteristics of polysilicon capacitor as insulator formation method (절연막 형성 방법에 따른 다결정실리콘 캐패시터의 특성)

  • 노태문;이대우;김광수;강진영;이덕문
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.32A no.7
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    • pp.58-68
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    • 1995
  • Polysilicon capacitors with pyrogenic oxide and TEOX oxide as insulators were fabricated to develop capacitors which can be applied to analog CMOS IC, and the characteristics of the capacitors were compared with each other. The morphology of bottom polysilicon in pyrogenic oxide capacitor is degraded due to the generaged protuberances of the polysilicon grain during oxidataion. The polysilican capacitor with pyrogenic oxide of 57 nm thickness showed that the effective potential barrier height of 0.45 eV is much less than that of MOS capacitor (3.2 eV)when the top electrode is biased with a positive volgate. The morphology of the polysilicon capacitor with TEOS oxide, however, was not degraded during oxide deposition by LPCVD. The polysilicon capacitor with TEOS oxide of 54 nm thickness showed the effective potential barrier height of 1.28 eV when the top electrode is biased with a negative voltage. Therefore, it is concluded that the polysilicon capacitor with TEOS oxide is more applicable to analog CMOS IC than the pyrogenic oxide polysilicon capacitor.

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Electrochemical Immunosensor Using the Modification of an Amine-functionalized Indium Tin Oxide Electrode with Carboxylated Single-walled Carbon Nanotubes

  • Aziz, Md.Abdul;Yang, Hae-Sik
    • Bulletin of the Korean Chemical Society
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    • v.28 no.7
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    • pp.1171-1174
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    • 2007
  • We have developed an electrochemical immunosensor that combines the electrocatalytic property of carbon nanotube and the low background current of indium tin oxide (ITO) electrode. A partial monolayer of carboxylated single-walled carbon nanotube (CCNT) is covalently formed on an ITO electrode modified with amine-terminated phosphonic acid. Nonspecifically adsorbed avidin on the hydrophobic sidewalls of CCNT is used to immobilize biotinylated antibody and to reduce the nonspecific binding to CCNT. The biotinylated antimouse IgG bound on avidin and the antimouse IgG conjugated with alkaline phosphatase (ALP) sandwiches a target mouse IgG. ALP catalyzes the conversion of p-aminophenyl phosphate monohydrate into p-aminophenol, which is electrocatalytically oxidized to p-quinone imine on CCNT surface. Moderate electrocatalytic electrode obtained with the combination of CCNT and ITO allows low detection limit (0.1 ng/ mL).

New Front Plate Structure of ac-PDP using Aluminum Fence-Type Electrode Coated with Anodic Aluminum Oxide

  • Lee, Mi-yeon;Yoon, Sang-Hoon;Kim, Yong-Seog
    • Journal of Information Display
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    • v.8 no.4
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    • pp.19-22
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    • 2007
  • A new front plate structure of ac-PDP using fence-type aluminum electrode coated with anodic aluminum oxide was investigated. In this structure, ITO and glass dielectric layer were eliminated and expensive Ag BUS electrode was replaced with aluminum. Test panels were prepared using the new structure and their luminance and discharge characteristics were examined. These results indicate that the new structure provide a new way of cost reduction and enhancement of performance of ac-PDPs

An Electrochemical Detector Using Prussian Blue Electrodeposited Indium Tin Oxide Electrode (Prussian blue가 전착된 indium tin oxide 전극을 이용한 전기화학적 검출기)

  • Yi, In-Je;Kim, Ju-Ho;Kang, Chi-Jung;Kim, Yong-Sang
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.10
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    • pp.449-452
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    • 2005
  • We fabricated an electrochemical detector (ECD) to catalyze redox reaction efficiently by electrodepositing Prussian blue (PB) on the indium tin oxide (ITO) electrode. Capillary electrophoresis (CE) and amperometric method were used. We investigated the PB surface properties by topography from atomic force microscopy (AFM). Also PB film thickness calibration with respect to deposition time and voltage was used to get better PB surFace. The PB thin film of dense and smooth surface could catalyze redox reaction efficiently. Comparing with CE-ECD microchip using bare-lTO electrode, proposed CE-ECD microchip using PB deposited electrode has shown better sensitivity by determining the detected peak current from the electropherograms while the concentration of tested analyzes was maintained the same. It is verified that detection limit can be lowered for 0.01 mM of dopamine and catechol respectively.

New Front Plate Structure of ac-PDP using Aluminum Fence-type Electrode Coated with Anodic Aluminum Oxide

  • Lee, Mi-Yeon;Yoon, Sang-Hoon;Kim, Yong-Seog
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.127-130
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    • 2007
  • A new front plate structure of ac-PDP was explored using fence-type aluminum electrode coated with anodic aluminum oxide.[1] In this structure, ITO and glass dielectric layer were eliminated and expensive Ag BUS electrode was replaced with aluminum. Test panels were prepared using the new structure and their luminance and discharge characteristics were examined. These results indicate that the new structure provide a new way of cost reduction and enhancement of performance of ac-PDPs

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Improvement of Cathode Reaction of Vanadium Redox Flow Battery by Reforming Graphite Felt Electrode Using Cobalt Oxide (바나듐 레독스 흐름전지 양극 반응 향상을 위한 코발트 산화물 전극 개질법 연구)

  • Park, Jeongmok;Ko, Minseong
    • Journal of Surface Science and Engineering
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    • v.52 no.3
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    • pp.180-185
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    • 2019
  • The demands to improve the performance of the vanadium redox flow battery have attracted an intense research on modifying the carbon-based electrode. In this study, the surface of graphite felt was reformed, using cobalt oxide. The cobalt oxide was implanted into graphite felt during hydrothermal and two step heat treatments. The cobalt was deposited by hydrothermal method and the two step heat treatments made lots of holes on the graphite felt surface which is called as porous surface. The porous surface acts as an electrochemically active site for the cathodic reaction of vanadium redox flow battery. The reformed electrode shows the electrochemically improved performance compared with the pristine electrode.

Citric acid stabilized iron oxide nanoparticles for battery- type supercapacitor electrode

  • Seungil Park;C. Justin Raj;Ramu Manikandan;Byung Chul Kim;Kook Hyun Yu
    • Journal of Ceramic Processing Research
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    • v.21 no.2
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    • pp.278-283
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    • 2020
  • We report the synthesis of citrate stabilized iron oxide (C-Fe3O4) spherical nanoparticles for supercapacitor electrodes. The citrate functional group present in the surface of the Fe3O4 nanoparticles effectively controls the morphology and the surface area of the nanostructures. The C-Fe3O4 electrodes exhibited a battery-like energy storage properties with a maximum specific capacity of 146 Cg-1 (242 Fg-1) which is much higher than the specific capacity of citrate free Fe3O4 electrode (62 Cg-1; 112 Fg-1). Moreover, the C-Fe3O4 electrode showed better cyclic stability (75%) than the citrate free Fe3O4 electrode (~35%) after 1000 charge/discharge cycles.