• Title/Summary/Keyword: oxide electrode

Search Result 1,144, Processing Time 0.031 seconds

Change of Capacitance on Maganese Dioxide Electrode for Supercapacitor by Oxidation Treatment (수퍼커패시터용 산화망간전극의 산화처리에 의한 용량 변화)

  • 김한주;홍지숙;신달우;김용철;김성호;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.07a
    • /
    • pp.946-949
    • /
    • 2000
  • Amorphous MnO$_2$$.$ nH$_2$O in 1M KOH aqueous electrolyte proves to be an excellent electrode for a faradic electrochemical capacitor cycled between -0.5 and +1.0 versus Ag/AgCl. In order to observe morphology and crystalline structure of MnO$_2$powder, we analyzed it by XRD and SEM. The effect of oxidation treatment on MnO$_2$electrode was observed by different oxidation voltages. A maximum capacitance of 364F/g was obtained by 1.1V oxidation treatment. This capacitance was attributed solely to a surface redox mechanism

  • PDF

Determination of Electrode Potential in Micro Electrochemical Machining of Nickel (니켈의 미세 전해 가공 시 전극 전위의 선정)

  • Nam H.S.;Park B.J.;Kim B.H.;Chu C.N.
    • Proceedings of the Korean Society of Precision Engineering Conference
    • /
    • 2005.10a
    • /
    • pp.585-588
    • /
    • 2005
  • The dissolution characteristic of metal shows the different tendency according to the applied electrical potential, the kind of electrolyte and pH value, etc. In the micro electrochemical machining (ECM), unfavorable oxide/passive layer formation and overall corrosion of electrodes must be prevented. The anodic polarization curve of nickel has distinct three dissolution regions, i.e. two active regions and the transpassive dissolution region. In this paper, the stable electrode potentials of workpiece and tool were determined in sulfuric acid and hydrochloric acid solution, respectively. In each solution, different machining property was shown and possible electrochemical reactions were discussed. On the basis of this experiment, the methodology to obtain the proper electrode potential was suggested.

  • PDF

Mechanically Flexible and Transparent Zinc Oxide Thin Film Transistor on Plastic Substrates (Plastic 기판 상의 투명성과 유연성을 지닌 Zinc Oxide 박막 트랜지스터)

  • Park, Kyung-Yea;Ahn, Jong-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2009.06a
    • /
    • pp.10-10
    • /
    • 2009
  • We have fabricated transparent and flexible thin film transistor(TFT) on polyethylene terephthalate(PET) substrate using Zinc Oxide (ZnO) and Indium Tin Oxide (ITO) film as active layer and electrode. The transfer printing method was used for printing the device layer on target plastic substrate at room temperature. This approach have an advantage to separate the high temperature annealing process to improve the electrical properties of ZnO TFT from the device process on plastic substrate. The resulting devices on plastic substrate presented mechanical and electrical properties similar with those on rigid substrate.

  • PDF

A Study on the Biocompatibility of Anodized Titanium (양극산화 티타늄의 생체적합성에 관한 연구)

  • 이민호;추용호
    • Journal of Biomedical Engineering Research
    • /
    • v.14 no.4
    • /
    • pp.333-340
    • /
    • 1993
  • The high biocompatibility of titanium is connected with the high corrosion resistance of the surface oxide, its high dielectric constant, and some other specific biochemical properties of the oxide. The corrosion resistance of titanium can be improved with the formation of passive film by anodic oxidation. In other to characterize the titantium oxlde film formed by anodic oxidation, titanium plates were anodized in 0.5M $H_3SO_4$ electrolyte at voltages between 5V and 100v. The oxide film was examined by an X-Ray Diffractometer(XRD) and a Scanning Electron Microscope(SEM). In addition, the corrosion resistance of oxide film was tested by dipping in physiological NaCl,5% HCI,5% $H_3PO_4$ and its biocompatability was evaluated by the fibroblast-like cell culture. The results obtained are as follows : 1. The thickness of surface oxide and micropore are increased with the increase of electrode potential and formed deeply along the grain boundary. 2. The solubilities of titanium in electrolyte solution shows that the anodized titanium has more corrosion resistance than the untreated pure titanium. 3. The biocomatibility of anodized titanium is superior to untreated pure titanium.

  • PDF

Electrochemical Properties of Tin oxide-flyash Composite for Lithium Ion Polymer Battery (리튬 이온 폴리머 전지용 Tin oxide-flyash Composite 전극의 전기화학적 특성)

  • Kim, Jong-Uk;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2003.05c
    • /
    • pp.88-90
    • /
    • 2003
  • The purpose of this study is to research and develop tin oxide-flash composite for lithium Ion polymer battery. Tin oxide is one of the promising material as a electrode active material for lithium Ion polymer battery (LIPB). Tin-based oxides have theoretical volumetric and gravimetric capacities that are four and two times that of carbon, respectively. We investigated cyclic voltammetry and charge/discharge cycling of SnO-flyash/SPE/Li cells. The first discharge capacity of SnO-flyash composite anode was 720 mAh/g. The discharge capacity of SnO-flyash composite anode 412 and 314 mAh/g at cycle 2 and 10 at room temperature, respectively. The SnO-flyash composite anode with PVDF-PMMA-PC-EC-$LiClO_4$ electrolyte showed good capacity with cycling.

  • PDF

A Study on the Impedance Characteristics and Mechanisms of Li Intecalation on the Tin Oxide-flyash Composite Electrodes (Tin Oxide-flyash Composite 전극의 리튬 이온 Intercalation 메카니즘과 임피던스 특성에 관한 연구)

  • Gu, Hal-Bon;Kim, Jong-Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.17 no.11
    • /
    • pp.1224-1229
    • /
    • 2004
  • The purpose of this study is to research and develop tin oxide-flyash composite for lithium Ion polymer battery. Tin oxide is one of the promising material as a electrode active material for lithium Ion polymer battery (LIPB). Tin-based oxides have theoretical volumetric and gravimetric capacities that are four and two times that of carbon, respectively. We investigated cyclic voltammetry, AC impedance and charge/discharge cycling of SnO$_2$-flyash/SPE/Li cells. The first discharge capacity of SnO$_2$-flyash composite anode was 639 mAh/g. The discharge capacity of SnO$_2$-flyash composite anode was 563 and 472 mAh/g at 6th and 15th cycle, respectively. The SnO$_2$-flyash composite anode with PVDF-PMMA-PC-EC-LiClO$_4$ electrolyte showed good capacity with cycling.

The Study of Manufacturing the AAO Template and Fabrication of Carbon and Metal Oxide Nanofibers using AAO Template (AAO (Anodized Aluminium Oxide) template 제조 및 이를 이용해 제조한 탄소 및 산화 금속 나노 섬유 물질에 관한 연구)

  • Kim, Cheong;Park, Soo-Gil
    • Journal of the Korean institute of surface engineering
    • /
    • v.49 no.4
    • /
    • pp.357-362
    • /
    • 2016
  • In this study, we manufactured the anodized alumina oxide (AAO) template and fabricated the carbon nanofibers and manganese oxide nanofibers using AAO template for application to electrochemical capacitor. Pore diameters of the AAO template were increased from 50 to 90 nm by increasing the acid treatment time after two-step anodizing process. Furthermore nanofibers, which is fabricated by AAO template, showed uniform diameter and micro structure. It is suggested that the surface area is larger than commercial electrode material and it is enhancing the energy density by increasing the specific capacitance.

Current Status of Low-temperature TCO Electrode for Solar-cell Application: A Short Review (고효율 태양전지 적용을 위한 저온 투명전극 소재 연구현황 리뷰)

  • Park, Hyeongsik;Kim, Youngkuk;Oh, Donghyun;Pham, Duy Phong;Song, Jaechun;Yi, Junsin
    • New & Renewable Energy
    • /
    • v.17 no.1
    • /
    • pp.1-6
    • /
    • 2021
  • Transparent conducting oxide (TCO) films have been widely used in optoelectronic devices, such as OLEDs, TFTs, and solar cells. However, thin films of indium tin oxide (ITO) have few disadvantages pertaining to process parameters such as substrate temperature and sputtering power. In this study, we investigated the requirements for using TCO films in silicon-based solar cells and the best alternative TCO materials to improve their efficiency. Moreover, we discussed the current status of high-efficiency solar cells using low-temperature TCO films such as indium zinc oxide and Zr-doped indium oxide.

Modified Glassy Carbon Electrode with Silver Nanoparticles/Polyaniline/Reduced Graphene Oxide Nanocomposite for the Simultaneous Determination of Biocompounds in Biological Fluids

  • Ghanbari, Kh.;Moloudi, M.;Bonyadi, S.
    • Journal of Electrochemical Science and Technology
    • /
    • v.10 no.4
    • /
    • pp.361-372
    • /
    • 2019
  • The silver nanoparticles/polyaniline/reduced graphene oxide nanocomposite modified glassy carbon electrode (Ag/PANI/RGO/GCE) was prepared by the electrochemical method. The Ag/PANI/RGO nanocomposite was characterized by transmission electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM), Raman spectroscopy, X-ray diffraction (XRD), and electrochemical impedance spectroscopy (ESI). Two electrochemical techniques namely differential pulse voltammetry (DPV) and cyclic voltammetry (CV) were used to the electrochemical behaviors investigation of ascorbic acid (AA), dopamine (DA), and uric acid (UA). The Ag/PANI/RGO/GCE exhibited remarkable electrocatalytic activity towards the oxidation reaction of AA, DA, and UA in Britton-Robinson (BR) solution (pH=4.0). Under the optimal conditions, the determinations of AA, DA, and UA were accomplished using DPV. AA-DA and DA-UA peak potential separations were 130 and 180 mV, respectively. For simultaneous detection, the linear response ranges were in the two concentration ranges of 0.05-0.8 mM and 2.0-16.0 mM with detection limit 0.412 μM (S/N = 3) for AA, 0.7-90.0 μM and 90.0-1000.0 μM with detection limit 0.023 μM (S/N = 3) for DA, and 0.8-70.0 μM and 70.0-1000.0 μM with detection limit 0.050 μM (S/N = 3) for UA. This modified electrode showed good sensitivity, selectivity, and stability with applied to determine AA, DA, and UA in human urine and drug.

Effects of the Graphene Oxide on Glucose Oxidase Immobilization Capabilities and Sensitivities of Carbon Nanotube-based Glucose Biosensor Electrodes (그래핀 옥사이드가 탄소나노튜브기반 바이오센서 전극의 포도당 산화효소 담지능및 민감도에 미치는 영향)

  • Park, Mi-Seon;Kim, Do Young;Jung, Min-Jung;Lee, Young-Seak
    • Applied Chemistry for Engineering
    • /
    • v.26 no.1
    • /
    • pp.47-52
    • /
    • 2015
  • To improve both the GOD immobilization capability and sensitivity of MWCNTs-based biosensor electrode, the electrode was prepared by adding different quantities of GO. The addition of GO increased hydrophilicity and the surface free energy of electrodes for glucose sensing as well as the dispersion of MWCNTs. In addition, the GOD immobilization capability was enhanced and the sensitivity was improved up to $121{\mu}A\;mM^{-1}$ even though having a high $K_m$ value (0.105) when adding 0.05 g GO to 0.05 g MWCNTs. These experimental results were attributed to the fact that the improvement in dispersion stability for MWCNTs, hydrophilicity, and surface free energy of electrode surface due to the addition of GO affected GOD immobilization capability.