• Title/Summary/Keyword: oxidation time

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Oxide Layer Growth in High-Pressure Steam Oxidation (고압 수증기 내에서 산화막 형성에 관한 연구)

  • 박경희;안순의;구경완;왕진석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.735-738
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    • 2000
  • This paper shows experimentally that oxide layer on the p-type Si-substrate can grow at low temperature(500$^{\circ}C$∼600$^{\circ}C$) using high pressure water vapor system. As the result of experiment, oxide layer growth rate is about 0.19${\AA}$/min at 500$^{\circ}C$, 0.43${\AA}$/min at 550$^{\circ}C$, 1.2${\AA}$/min at 600$^{\circ}C$ respectively. So, we know oxide layer growth follows reaction-controlled mechanism in given temperature range. Consequently, granting that oxide layer growth rate increases linearly to temperature over 600$^{\circ}C$, we can expect oxide growth rate is 5.2${\AA}$/min at 1000$^{\circ}C$. High pressure oxidation of silicon is particularly attractive for the thick oxidation of power MOSFET, because thermal oxide layers can grow at relatively low temperature in run times comparable to typical high-temperature, 1 atm conditions. For higher-temperature, high-pressure oxidation, the oxidation time is reduced significantly

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Characterization of Methane Oxidation by a Methanotroph Isolated from a Landfill Cover Soil, South Korea

  • Lee, Eun-Hee;Yi, Tae-Woo;Moon, Kyung-Eun;Park, Hyun-Jung;Ryu, Hee-Wook;Cho, Kyung-Suk
    • Journal of Microbiology and Biotechnology
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    • v.21 no.7
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    • pp.753-756
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    • 2011
  • A methane-oxidizing bacterium was isolated from the enriched culture of a landfill cover soil. The closest relative of the isolate, designated M6, is Methylocystis sp. Based on a kinetic analysis, the maximum specific methane oxidation rate and saturation constant were 4.93 mmol gdry cell $weight^{-1}{\cdot}h^{-1}$ and 23${\mu}M$, respectively. This was the first time a kinetic analysis was performed using pure methanotrophic culture. The methane oxidation by M6 was investigated in the presence of aromatic (m- and pxylene and ethylbenzene) or sulfur (hydrogen sulfide, dimethyl sulfide, methanthiol) compounds. The methane oxidation was inhibited by the presence of aromatic or sulfur compounds.

The Aluminizing of Boronized Low Carbon Steel (침붕처리한 저탄소강의 알루미늄 확산처리에 관한 연구)

  • 윤영식;김한삼;김수식
    • Journal of the Korean institute of surface engineering
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    • v.29 no.2
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    • pp.120-131
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    • 1996
  • In order to improve the mechanical properties and the high temperature oxidation resistance, aluminizing was carried out at a temperature range between $850^{\circ}C$ and $1050^{\circ}C$. The pack cementation process was used to produce uniform layer. After each treatment, the microhardness and the characteristics of high temperature oxidation were tested to evaluate the properties of the aluminide layer. The aluminide layer consisted of FeAl above $1000^{\circ}C$, and $Fe_2Al_5$ below $900^{\circ}C$, and the mixed phase of FeAl and $Fe_2Al_5$ between 90$0^{\circ}C$ and $1000^{\circ}C$ in case of the mixture powder consisted of 5%Al+5%$NH_4Cl+90%AL_2O_3$. The microhardness of $Fe_2Al_5$ was obtained much as the twice as that of FeAl. As the aluminizing temperature and time increased, the thickness of aluminide increased. After aluminizing, the high temperature oxidation resistance was remarkably improved. The high temperature oxidation resistance of FeAl was superior to the resistance of high temperature oxidation of $Fe_2Al_5$.

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Lattice Deformation and Improvement Oxidation Resistance of Ti-6Al-4V Alloy Powders Prepared by Hydrogen Added Argon Heat Treatment (수소 첨가 열처리에 따른 Ti-6Al-4V 합금 분말의 격자 변형 및 내산화성 향상)

  • Cho, Gye-Hoon;Oh, Jung-Min;Lim, Jae-Won
    • Journal of Powder Materials
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    • v.26 no.2
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    • pp.126-131
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    • 2019
  • In the present work, a new hydrogen added argon heat treatment process that prevents the formation of hydrides and eliminates the dehydrogenation step, is developed. Dissolved hydrogen has a good effect on sintering properties such as oxidation resistance and density of greens. This process can also reduce costs and processing time. In the experiment, commercially available Ti-6Al-4V powders are used. The powders are annealed using tube furnace in an argon atmosphere at $700^{\circ}C$ and $900^{\circ}C$ for 120 min. Hydrogen was injected temporarily during argon annealing to dissolve hydrogen, and a dehydrogenation process was performed simultaneously under an argon-only atmosphere. Without hydride formation, hydrogen was dissolved in the Ti-6Al-4V powder by X-ray diffraction and gas analysis. Hydrogen is first solubilized on the beta phase and expanded the beta phases' cell volume. TGA analysis was carried out to evaluate the oxidation resistance, and it is confirmed that hydrogen-dissolved Ti-6Al-4V powders improves oxidation resistance more than raw materials.

Observation on the Ignition Delay Time of Cool and Thermal Flame of n-heptane/alcohol Blended Fuel at Low Temperature Combustion Regime (저온연소조건에서 n-heptane/alcohol 혼합연료의 냉염과 열염에 대한 착화지연 관찰)

  • Song, Jaehyeok;Kang, Kijoong;Ryu, Seunghyup;Choi, Gyungmin;Kim, Duckjool
    • Journal of the Korean Society of Combustion
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    • v.18 no.4
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    • pp.12-20
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    • 2013
  • The ignition delay time is an important factor to understand the combustion characteristics of internal combustion engine. In this study, ignition delay times of cool and thermal flame were observed separately in homogeneous charge compression ignition(HCCI) engine. This study presents numerical investigation of ignition delay time of n-heptane and alcohol(ethanol and n-butanol) binary fuel. The $O_2$ concentration in the mixture was set 9-10% to simulate high exhaust gas recirculation(EGR) rate condition. The numerical study on the ignition delay time was performed using CHEMKIN codes with various blending ratios and EGR rates. The results revealed that the ignition delay time increased with increasing the alcohol fraction in the mixture due to a decrease of oxidation of n-heptane at the low temperature. From the numerical analysis, ethanol needed more radical and higher temperature than n-butanol for oxidation. In addition, thermal ignition delay time is sharply increasing with decreasing $O_2$ fraction, but cool flame ignition delay time changes negligibly for both binary fuels. Also, in high temperature regime, the ignition delay time showed similar tendency with both blends regardless of blending ratio and EGR rate.

Cyclic Oxidation Behavior of Vacuum Plasma Sprayed NiCoCrAlY Overlay Coatings (진공 플라즈마 용사법을 통해 형성된 NiCoCrAlY 오버레이 코팅의 반복 산화 거동)

  • Yoo, Yeon Woo;Nam, Uk Hee;Park, Hunkwan;Park, Youngjin;Lee, Sunghun;Byon, Eungsun
    • Journal of the Korean institute of surface engineering
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    • v.52 no.6
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    • pp.283-288
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    • 2019
  • MCrAlY overaly coatings are used as oxidation barrier coatings to prevent degradation of the underlying substrate in high temperature and oxidizing environment of the hot section of gas turbines. Therefore, oxidation resistance in high temperature is important property of MCrAlY coatings. Also, coefficients of thermal expansion (CTE) of MCrAlY have middle value of that of Ni-based superalloys and oxides, which have the effect of preventing the delamination of the surface oxides. Cyclic oxidation test is one of the most useful methods for evaluating the high temperature durability of coatings used in gas turbines. In this study, NiCoCrAlY overlay coatings were formed on Inconel 792(IN 792) substrates by vacuum plasma spraying process. Vacuum plasma sprayed NiCoCrAlY coatings and IN 792 susbstrates were exposed to 1000℃ one-hour cyclic oxidation environment. NiCoCrAlY coatings showed lower weight gain in short-term oxidation. In long-term oxidation, IN 792 substrates showed higher weight loss due to delamination of surface oxide but NiCoCrAlY coatings showed lower weight loss. X-ray diffraction (XRD) analysis showed α-Al2O3 and NiCr2O4 was formed during the cyclic oxidation test. Through cross-section observation using scanning electron microscopy (SEM) and electron back scatter diffraction (EBSD) analysis, thermally grown oxide (TGO) layer composed of α-Al2O3 and NiCr2O4 was formed and the thickness of TGO increased during 1000℃ cyclic oxidation test. β phase in upper side of NiCoCrAlY coating was depleted due to oxidation of Al and outer beta depletion zone thickness also increased as the cyclic oxidation time increased.

Deterioration and Residual Life of Grease for Sealed Ball Bearing (밀봉형 볼베어링용 그리이스의 노화와 잔류수명)

  • 최인혁;김정길;김지현;손성구
    • Tribology and Lubricants
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    • v.18 no.4
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    • pp.273-278
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    • 2002
  • Grease deterioration of mineral oil type grease was investigated using sealed deep groove ball bearings (6203) and bearing life test rig. The bearing test was performed under 3,000 rpm and 245 N radial load at 120。C. Grease taken ken tested bearings was checked in using certain evaluation methods, for example, oxidation induction time (OIT), FT-IR peak intensity, leakage .ate, bleeding .ate, total acid number. (TAN) and bearing noise increase. Within these test conditions, OIT, TAN, bleeding rate were changed gradually in accordance with bearing operating time and showed useful indices for deterioration of grease.

A Study on the Bleaching Properties of Silk Fabric Using Vapor Type Ozone Treatment (기상 오존처리법을 이용한 견직물의 표백성에 관한 연구)

  • Kim, Jung-Min;Lee, Mun-Soo
    • Fashion & Textile Research Journal
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    • v.6 no.4
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    • pp.511-514
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    • 2004
  • We studied on the bleaching properties of silk fabric by vapor type ozone processing using ozone's strong oxidation instead of 28% $H_2O_2$ chemical treatment. When vapor type ozone processing was directly treated to fabrics retaining water to 50~70% pick up ratio, high concentration ozone was generated 14,000ppm(168 mg/h) approximately and finally its bleaching improved. The fabric's bleaching effect was improved because vapor type ozone generated the highest decomposition to oxidation of surface and inter molecules. The experiment revealed that fabric's bleaching was improved by change of the pick-up ratio of vapor type ozone processing. However, tensile strength and elongation were reduced by increase of time, and the time that was assumed as the most optimized time to minimize the reduction of fabric's tensile strength and elongation as well as maximizing the fabric's bleaching was 30 minutes.

Characteristics of Plasma Electrolytic Oxide Coatings on Mg-Al Alloy with Coating Time (피막처리 시간에 따른 Mg-Al 합금의 플라즈마 전해 산화 피막 특성)

  • Lee, Du-Hyung;Kim, Bo-Sik;Chang, Si-Young
    • Korean Journal of Materials Research
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    • v.18 no.5
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    • pp.241-246
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    • 2008
  • Pure Mg and Mg-6wt.%Al alloy were coated by the plasma electrolytic oxidation with various coating times and the microstructural and mechanical characteristics of the coatings were investigated. The coatings on pure Mg and Mg-6wt.%Al alloy consisted of MgO and $Mg_2SiO_4$. The surface roughness and thickness of the coatings became larger as the coating time increased. The coatings on the Mg-6wt.%Al alloy were more uniform and thicker than those on pure Mg. The microhardness and friction coefficient of the coatings increased progressively as the coating time increased. In addition, the coatings on the Mg-6wt.%Al alloy compared to pure Mg showed improved microhardness and a better friction coefficient.

The Partial Discharge Properties of Oxidized Polyethylene (산화된풀리에틸렌의 부분방전 특성)

  • 이현수;한상옥
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.41 no.7
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    • pp.802-808
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    • 1992
  • To investigate degradation procedure and life time of the oxidized PE and the unoxidized PE, alternative voltage is applied to the CIGRE Method-II (CM-II) electrode system, which is loaded artificial void, and measures the distribution of partial discharging generation. From the results, the samples etched by oxidation had wide degradation area of dielectric strength. Furthermore, discharge starting voltage was shifted to low voltage, the discharge generation frequency was high and consequently, the quantity of mean charge becomes small. Also, life time of the oxdized sample is shortened according as the oxidation time is longer.

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