• Title/Summary/Keyword: oxidation speed

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A Study on Evaluation of Diesel Oxidation Catalyst for Automotive Heavy-Duty Diesel Engine (대형자동차 디젤엔진용 산화촉매의 성능평가에 관한 연구)

  • Choi, B.C.;Jung, P.S.;Myung, K.J.;Kim, B.S.;Park, K.S.;Park, C.G.;Lee, J.H.
    • Journal of Power System Engineering
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    • v.5 no.2
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    • pp.13-21
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    • 2001
  • Diesel emission control is being addressed worldwide to help preserve the global environment. This paper mainly deals with the effects of oxidation catalysts to reduce emissions from the automotive heavy-duty diesel engine. Two types of the oxidation catalyst with different kinds of precious material were used. An 11 litter displacement diesel engine with turbocharger was operated to evaluate DOC with various engine speed, load conditions under D-13 mode cycle. We could propose the detail emission data of an automotive heavy-duty diesel engine and the characteristics of the conversion efficiency of the DOC under the D-13 mode. It was found that the mean conversion efficiencies of CO and THC were 49.7% and 61% under the D-13 mode test, respectively.

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Influence of Driving Pattern on Regeneration Performance of Continuously Regenerating Diesel Particulate Filter (연속재생 DPF의 재생 성능에 미치는 차량 운행패턴의 영향)

  • Hwang, Jin-Woo;Lee, Chang-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.5
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    • pp.358-364
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    • 2009
  • This paper is to investigate the influence of driving patterns of slow and high speed vehicles on the performance of continuously regenerating diesel particulate filter(DPF) system matched with operating conditions in field application. The DPF performance test for field application was carried out for two identical DPFs installed to slow and high speed vehicles. A slow speed vehicle was selected among local buses which have driving patterns to repeat running and stop frequently, while a high speed vehicle was prepared to have long route of high speed over 60km/h like inter-city buses. In this test, the regeneration performance on the DPF of slow speed vehicle deteriorated because of high soot load index(SLI) in spite of same balance point temperature(BPT) distribution for high speed vehicle. The DPF of slow speed vehicle melted in the end because the rapid increase of back pressure caused high temperature over $1200^{\circ}C$ in the ceramic wall of DPF. The PM components like ash collected to the filter in the DPF were analyzed in order to investigate the cause of the defect and provide an operation performance of DPF system. In the result of the analysis, high levels of lubrication oil ash(Ca, Mg, P, Zn) were detected.

Wear Behavior of Laser Modified SM45C Steel (레이저 표면개질된 SM45C강의 마멸거동)

  • 배춘익;옥철호;박흥식;전태옥
    • Tribology and Lubricants
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    • v.16 no.1
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    • pp.15-21
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    • 2000
  • Radiation of Nd-YAG laser changes and refines the surface microstructure of steels, which gives rise to enhancement of hardness and resulting wear resistance. In the present work, the effect of processing parameters during the surface modification with laser on the wear behavior of the SM45C steel was studied by means of wear testing. The counter material was alumina ceramics. The microstructure observation revealed the dependence of molten depth and width on the defocusing distance. The laser modification of steel surface give rise to improved wear resistance in the testing speed range of either <0.2 m/s or >0.9 m/s Material transfer from steel was wear observated the surface of counter material when testing speed was lower than 0.7 m/s.

Friction and Wear Behavior of Carbon/Carbon Composites for Aircraft Brake Material (항공기 브레이크 재료용 탄소/탄소 복합재료의 마찰 및 마모 거동)

  • 우성택;윤재륜
    • Tribology and Lubricants
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    • v.9 no.1
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    • pp.62-69
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    • 1993
  • Friction and wear behavior of a carbon/carbon composite material for aircraft brake material was experimentally investigated. Friction and wear test setup was designed and built for the experiment. Friction and wear tests were conducted under various sliding conditions. Friction coefficients were measured and processed by a data acquisition system and amount of wear measured by a balance. Stainless steel disk was used as the counterface material. Temperature was also measured by inserting thermocouple 2.5 mm beneath the sliding surface of the carbon/carbon composite specimen. Wear surfaces were observed by SEM, and analyzed by EDAX. The experimental results showed that sliding speed and normal force did not have significant effects on friction coefficient and wear factor of the composite. Temperature increase just below the surface was not large enough to cause any thermal degradation or oxidation which occurred at higher temperature when tested by TGA. Wear film was generated both on the specimen and on the counterface at relatively low sliding speed but cracks, grooves, and wear debris were observed at high sliding speed. Friction coefficient remained almost constant when the sliding speed or normal load was varied. It is believed that the adhesive and abrasive components contributed mainly to the friction coefficient. Wear behavior at low sliding speed was governed by wear film formation and adhesive wear mechanism. At high speed, fiber orientation, ploughing by counterface asperities, and fiber breakage dominated wear of the carbon/carbon composite.

A Study on the Unidirectional Solidification of Oxygen Free Copper by the Horizontal Continuous Casting Process (수평식 연속주조법에 제조된 무산소동의 방향성 응고에 관한 연구)

  • Kim, Myung-Han;Lee, You-Jae;Jo, Hyung-Ho
    • Journal of Korea Foundry Society
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    • v.14 no.6
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    • pp.558-565
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    • 1994
  • The horizontal continuous casting process with the heated mold was applied to obtain the unidirectionally solidified rods($4{\sim}8mm$ dia.) of pure copper with good surface quality. The results could be summarized as follows. 1. The unidirectional solidification of pure copper rods with good surface(mirror surface) quality could be obtained by placing the S/L interface inside the heated mold cavity even though the cast copper rods were covered with thin copper oxide layer. 2. The casting speed for 4mm dia. rods with mirror surfaces was affected significantly by the mold-cooler distance rather than the cooling flow rate when other casting conditions were fixed. 3. The casting speed was the main factor affecting the oxidation of copper during the continuous casting and the thickness of copper oxide layer decreased almost linearly as the casting speed increased.

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Photocatalytic Degradation of Algae and its By-product using Rotating Photocatalytic Oxidation Disk Reactor

  • Son, Hee-Jong;Jung, Chul-Woo;Bae, Sang-Dae
    • Environmental Engineering Research
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    • v.14 no.3
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    • pp.170-173
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    • 2009
  • This study examined the special technique of photocatalytic degradation (RPODisk) for removal of taste and odor causing materials, algae, and algal toxin. The RPODisk was effective for removal of these troublesome contaminants. It outperformed the fixed media and the UV irradiation for geosmin removal. The RPODisk performance was comparable to the combination of the UV irradiation with TiO2. The RPODisk performance was affected by the rotating speed. The faster the speed was, the better the performance. The RPODisk was also effective for removal of algae and algal toxin. The algal activity reduced by 80% after 30 mins of the treatment. More toxic microcystin (MC)-LR was more difficult to remove than MC-RR. The times for 50% removal were 23.7 mins for MC-LR and 14.1 mins for MC-RR. Almost 100 mins of the contact time was required to completely remove MC-LR at the rotating speed of 260 rpm.

Dry sliding wear behavior of plain low carbon dual phase steel by strain hardening and oxidation (가공경화와 산화층 형성에 의한 이상조직 저탄소강의 건식 미끄럼 마멸 거동)

  • Yu, H.S.;Kim, Y.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.149-152
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    • 2006
  • Dry sliding wear behavior of low carbon dual phase steel, of which microstructure consists of hard martensite in a ductile ferrite matrix, has been investigated. The wear characteristics of the dual phase steel was compared with that of a plain carbon steel which was normalized at $950^{\circ}C$ for 30min and then air-cooled. Dry sliding wear tests were carried out using a pin-on-disk type tester at various loads of 1N to 10N under a constant sliding speed condition of 0.2m/sec against an AISI 52100 bearing steel ball at room temperature. The sliding distance was fixed as 1000m for all wear tests. The wear rate was calculated by dividing the weight loss measured to the accuracy of $10^{-5}g$ by the specific gravity and sliding distance. The worn surfaces and wear debris were analyzed by SEM, EDS and a profilomter. Micro vickers hardness values of the cross section of worn surface were measured to analyze strain hardening behavior underneath the wearing surfaces. The were rate of the dual phase steel was lower than the plain carbon steel. Oxidation on the sliding surface and strain hardening were attributed for the higher wear resistance of the dual phase steel.

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Characterizations of Thermal Compound Using CuO Particles Grown by Wet Oxidation Method (습식 산화법으로 성장된 산화구리입자를 이용한 방열 컴파운드 제조 및 특성 연구)

  • Lee, Dong Woo;Um, Chang Hyun;Chu, Jae Uk
    • Korean Journal of Materials Research
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    • v.27 no.4
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    • pp.221-228
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    • 2017
  • Various morphologies of copper oxide (CuO) have been considered to be of both fundamental and practical importance in the field of electronic materials. In this study, using Cu ($0.1{\mu}m$ and $7{\mu}m$) particles, flake-type CuO particles were grown via a wet oxidation method for 5min and 60min at $75^{\circ}C$. Using the prepared CuO, AlN, and silicone base as reagents, thermal interface material (TIM) compounds were synthesized using a high speed paste mixer. The properties of the thermal compounds prepared using the CuO particles were observed by thermal conductivity and breakdown voltage measurement. Most importantly, the volume of thermal compounds created using CuO particles grown from $0.1{\mu}m$ Cu particles increased by 192.5 % and 125 % depending on the growth time. The composition of CuO was confirmed by X-ray diffraction (XRD) analysis; cross sections of the grown CuO particles were observed using focused ion beam (FIB), field emission scanning electron microscopy (FE-SEM), and energy dispersive analysis by X-ray (EDAX). In addition, the thermal compound dispersion of the Cu and Al elements were observed by X-ray elemental mapping.

Effect of Rolling Conditions on the Sticking Phenomena of Ferritic Stainless Steel (페라이트계 스테인레스강의 Sticking 현상에 미치는 열간압연조건의 영향)

  • Jin, Won;Choi, Joem-Yong
    • Transactions of Materials Processing
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    • v.6 no.2
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    • pp.110-117
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    • 1997
  • Sticking behavior under the hot rolling conditions for ferritic stainless steels have been studied. Sticking, which is a phenomenon that the naked metal exposed to the surface by scale breakaway during hot rolling sticks to the roll surface, was affected by both high temperature tensile strength and oxidation resistance of the steels. A steel having higher tensile strength and lower oxidation resistance exhibits better resistance to the sticking. It is due to that higher tensile strength increases localized deformation resistance and lower oxidation resistance creates lower friction between steel and roll by forming thicker scale as a lubricant during hot rolling. So, the sticking tends to occur more severely in the order of 430J1L, 436L, 430 and 409L. The most sensitive temperature to the sticking was found to be 90$0^{\circ}C$ for all grade of steels. It was also found that the high speed steel(HSS) roll compared to the Hi-Cr roll was more beneficial to prevent sticking. Because higher surface hardness of HSS roll compared to that of Hi-Cr roll provides less nucleation sites for sticking such as scratch on the roll surface.

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STATIC CHARACTERISTICS OF A UREA-SCR SYSTEM FOR NOx REDUCTION IN DIESEL ENGINES

  • Nam, J.G.
    • International Journal of Automotive Technology
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    • v.8 no.3
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    • pp.283-288
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    • 2007
  • This paper presents the static characteristics of a urea-SCR system. The static characterization of the urea-SCR system was generated by sweeping urea flow rates at common engine torque/speed operating points. Several experiments were performed using engine operating points at different raw NOx emission levels, space velocities, and SCR catalyst temperatures. The recorded NOx emissions from the engine exhaust outlet and engine tailpipe are then compared. The urea-SCR static system results indicated that a $50{\sim}60%$ NOx conversion is achievable at most engine operating points using the stoichiometric $NH_3/NOx$ ratio, and a high 98% NOx conversion is possible by exceeding the stoichiometric $NH_3/NOx$ ratio. The effect of the pre-oxidation catalyst volume was also investigated and found to have a profound impact on experimental results, particularly the static NOx conversion.