• 제목/요약/키워드: oxidation speed

검색결과 141건 처리시간 0.03초

국내 EGR과 SCR 장착 중형트럭 대기오염물질 배출 특성 (Characteristics of Air Pollutants Emission from Medium-duty Trucks Equipped EGR and SCR in Korea)

  • 손지환;김정화;정성운;유흥민;홍희경;문선희;최광호;이종태;김정수
    • 한국분무공학회지
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    • 제21권3호
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    • pp.130-136
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    • 2016
  • NOx and PM are important air pollutants as vehicle management policy aspect. Medium-duty truck is the main source of the pollutants although the vehicle market share is only 3.5%. National emission portion of NOx and PM form the mobile sourece are 14% and 16% respectively. In this study it was investigated that characteristics of air pollutants emission on medium duty truck equipped with EGR and SCR system. Vehicle's test reflected driving cycle on the chassis dynamometer, and applied test cycle was WHVC(World Harmonized Vehicle Cycle) mode. The test cycle include three segments, represent urban, rural and motorway driving. Based on the test results NOx, PM, HC were less emitted form SCR vehicle than EGR vehicle. And CO was less emitted form EGR vehicle than SCR vehicle due to CO oxidation reaction on DPF surface. And most air pollutants reduced as average vehicle speed increased. Pollutants were less emitted on motorway section than urban and rural sections. But highly NOx emission on motorway section was verified according to increased EGR ratio on fast vehicle speed. HC and CO additional emission was identified as 68%, 58% respectively during SCR vehicle's cold engine start emission test. NOx additional emission was detected by 24% on SCR vehicle's condition of engine cold start while not detected on vehicle equipped with EGR. SCR vehicle's additional NOx emission was derived from low reaction temperature during engine cold start condition. medium-duty truck emission characteristics were investigated in this study and expected to used to improve air pollutants management policy of medium-duty truck equipped with SCR & EGR.

금형 냉각이 Al-Mn계 다중압출 평판관의 압출 특성 변화에 미치는 영향 (Effects of die cooling on change of extrusion characteristics of Al-Mn-based thin-walled flat multi-port tube)

  • 신영철;하성호;강태훈;이기안;이승철
    • Design & Manufacturing
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    • 제17권4호
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    • pp.63-71
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    • 2023
  • In order to increase the extrusion production speed of aluminum, extrusion die cooling technology using liquid nitrogen has recently attracted a lot of attention. Increasing the extrusion speed increases the temperature of the bearing area of extrusion dies and the extrusion profile, which may cause defects on the surface of extruded profile. Extrusion die cooling technology is to directly inject liquid nitrogen through a cooling channel formed between the die and the backer inside the die-set. The liquid nitrogen removes heat from the die-set, and gaseous nitrogen at the exit of the channel, covers the extrusion profile of an inert atmosphere reducing the oxidation and the profile temperature. The aim of this study is to evaluate the cooling capacity by applying die cooling to extrusion of Al-Mn-based aluminum alloy flat tubes, and to investigate the effects of die cooling on the change in extrusion characteristics of flat tubes. Cooling capacity was confirmed by observing the temperature change of the extrusion profile depending on whether or not die cooling is applied. To observe changes in material characteristics due to die cooling, surface observation is conducted and microstructure and precipitate analysis are performed by FE-SEM on the surface and longitudinal cross section of the extruded flat tubes.

INVESTIGATION OF RUNNING BEHAVIORS OF AN LPG SI ENGINE WITH OXYGEN-ENRICHED AIR DURING START/WARM-UP AND HOT IDLING

  • Xiao, G.;Qiao, X.;Li, G.;Huang, Z.;Li, L.
    • International Journal of Automotive Technology
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    • 제8권4호
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    • pp.437-444
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    • 2007
  • This paper experimentally investigates the effects of oxygen-enriched air (OEA) on the running behaviors of an LPG SI engine during both start/warm-up (SW) and hot idling (HI) stages. The experiments were performed on an air-cooled, single-cylinder, 4-stroke, LPG SI engine with an electronic fuel injection system and an electrically-heated oxygen sensor. OEA containing 23% and 25% oxygen (by volume) was supplied for the experiments. The throttle position was fixed at that of idle condition. A fueling strategy was used as following: the fuel injection pulse width (FIPW) in the first cycle of injection was set 5.05 ms, and 2.6 ms in the subsequent cycles till the achieving of closed-loop control. In closed-loop mode, the FIPW was adjusted by the ECU in terms of the oxygen sensor feedback. Instantaneous engine speed, cylinder pressure, engine-out time-resolved HC, CO and NOx emissions and excess air coefficient (EAC) were measured and compared to the intake air baseline (ambient air, 21% oxygen). The results show that during SW stage, with the increase in the oxygen concentration in the intake air, the EAC of the mixture is much closer to the stoichiometric one and more oxygen is made available for oxidation, which results in evidently-improved combustion. The ignition in the first firing cycle starts earlier and peak pressure and maximum heat release rate both notably increase. The maximum engine speed is elevated and HC and CO emissions are reduced considerably. The percent reductions in HC emissions are about 48% and 68% in CO emissions about 52% and 78%; with 23% and 25% OEA, respectively, compared to ambient air. During HI stage, with OEA, the fuel amount per cycle increases due to closed-loop control, the engine speed rises, and speed stability is improved. The HC emissions notably decrease: about 60% and 80% with 23% and 25% OEA, respectively, compared to ambient air. The CO emissions remain at the same low level as with ambient air. During both SW and HI stages, intake air oxygen enrichment causes the delay of spark timing and the increased NOx emissions.

초내열 합금 배기 밸브 스핀들 단조 해석 및 기계적 특성 평가 (A Forging Analysis and Mechanical Properties Evaluation of Superalloy Exhaust Valve Spindle)

  • 최성규;오중석;정호승;조종래
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2009년도 추계학술대회 논문집
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    • pp.84-88
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    • 2009
  • The nickel-based alloy Nimonic 80A possesses strength, and corrosion, creep and oxidation resistance at high temperature. The exhaust valves of low speed diesel engines are usually operated at temperature levels of 400-$600^{\circ}C$ and high pressure to enhance thermal efficiency and exposed to the corrosion atmosphere by the exhaust gas. Also, the exhaust valve is subjected to repeated thermal and mechanical loads. So, the nickel-based alloy Nimonic 80A was used for the large exhaust valve spindle. It is composed a 540mm diameter head and a 125mm diameter stem. It is developed large products by hot closed-die forging. Manufacturing process analysis of the large exhaust valve spindle was simulated by closed die forging with hydraulic press and cooled in air after forging. The preform was heated to $1080^{\circ}C$ Numerical calculation was performed by DEFORM-2D, a commercial finite element code. Heat transfer can be coupled with the deformation analysis in a non-isothermal deformation analysis. Mechanical properties of the large exhaust valve spindle were evaluated by the variety of tests, including microstructure observation, tensile, as well as hardness and fatigue tests, were conducted to evaluate the mechanical properties for head part of exhaust valve spindle.

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공정 효율 향상을 위한 연료전지전극 개발 (Manufacturing Process Improvement of Electrode for PEMFC)

  • 박석정;이재승;이기섭;노범욱
    • 한국수소및신에너지학회논문집
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    • 제26권6호
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    • pp.547-553
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    • 2015
  • For commercialization of fuel cell electric vehicles, one of the key objectives is to reduce cost of full stack assembly. Regarding Membrane Electrode Assembly, the major issue is to improve fuel cell activation process in the initial Hydrogen Oxidation Reaction and Oxygen Reduction Reaction. In this research, the VD (Vacuum Drying) process has been developed for improvement of activation process. The VD condition is developed by controlling the temperature and degree of vacuum to remove the remaining solvent of electrode. Consequently, the electrode applied to VD process showed the low characteristics such as 3.5% of remaining solvent content and the improved efficiency such as 15% of activation process speed.

전력케이블내 반도전 재료(층)의 기계적 특성 및 평활도에 관한 연구 (Mechanical Properties and Smoothness of Semiconductive Materials(Shield) in Power Cable)

  • 양종석;이용성;박대희;이경용
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제54권4호
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    • pp.154-160
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    • 2005
  • We have investigated thermal properties showed by changing the content of carbon black which is the component parts of semiconductive shield in underground power transmission cable. Specimens were made of sheet with the nine of those for measurement. Density of specimens was measured by density meter, and then stress-strain of specimens was measured by TENSOMETER 2000. A speed of measurement was 200[mm/min], ranges of stress and strain were 400(Kgf/$cm^2$) and 600[$\%$]. In addition, tests of stress-strain were progressed by aging specimens at air oven. Finally surface profile was shown in order to looking for protrusion of specimens by using smoothness tester. Density was highly measured according to increasing the content of carbon black from this experimental result, and stress was decreased, while strain was increased according to increasing the content of carbon black. And stress-strain were decreased some after aging because of oxidation reaction of chemical defect. Lastly surface of specimens smoothed generally.

카본블랙의 함량에 따른 송전용 반도전 재료의 기계적 특성 및 Smoothness (Mechanical Properties and Smoothness of Semiconductive Shield for Power Transmission by Carbon Black Content)

  • 이경용;양종석;이관우;최용성;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.301-307
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    • 2004
  • To improve mean-life and reliability of power cable in this paper, we have investigated stress-strain and smoothness showing by changing the content of carbon black that is semiconductive additives for underground power transmission. Specimens were made of sheet form with the three of existing resins and the nine of specimens for measurement. Stress-strain of specimens was measured by TENSOMETER 2000. A speed of measurement was 200[mm/min], ranges of stress and strain were $400(Kgf/cm^2)$ and 600[%]. In addition tests of stress-strain were progressed by aging specimens at air oven. Finally we wished to look for protrusion of specimens by using smoothness tester. According to increasing the content of carbon black from this experimental result, yield stress was increased, while strain was decreased. And stress-strain were decreased some after aging because of oxidation reaction of chemical defect. Lastly surface of specimens smoothed generally.

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오존에 의한 반응성 염료의 탈색에 관한 연구 (A Study on the Decolorization of Reactive Dyes by Using Ozone Treatment)

  • 이문수
    • 자연과학논문집
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    • 제9권1호
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    • pp.9-17
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    • 1997
  • 염색가공 폐액중의 반응성 염료에 대한 탈색효과를 검토하기 위하여 산화력이 강한 오존을 사용하여 염료의 농도, 처리용액의 pH, 처리용액의 온도조건 등을 변화시켜 가며 오존의 농도와 피로시간에 대한 염료의 탈색과정에 대하여 연구하였다. 오존의 처리 능력은 염료 폐액의 농도가 높아지면 그만큼 오존이 많이 필요하게 되므로 처리 속도도 떨어졌다. 반응성 염료의 탈색 속도는 진한 색상인 blue가 제일 늦었으며 옅은 색상일수록 빠르게 탈색이 진행되었다. 오존의 처리 시간이 경과함에 따라 반응성 염료의 색상은 중간색을 거쳐 무색으로 변하여 색상이 파괴됨을 보였다. 반응성 염료는 색상에 따라 약간의 차이는 있지만 알칼리 영역에서보다는 산성영역에서 더 빠르게 탈색이 진행되었다. 오존처리 온도가 낮을수록 탈색속도가 빠르게 나타났지만 그 차이는 적었다.

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R.F magnetron sputtering법으로 제조된 TiAlN 코팅 층의 열처리 특성 (Characterization of TiAlN Coated Layer with Heat Treatment Prepared by R.F Magnetron Sputtering)

  • 송동환;양권승;이종국
    • 열처리공학회지
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    • 제19권4호
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    • pp.225-229
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    • 2006
  • TiAlN coatings are available in various industry fields as a wear resistant coating for high-speed machining, due to its high hardness, excellent oxidation and corrosion resistance. The corrosion resistance of TiAlN multilayer coatings is better than that of single TiN coatings. Most of TiAlN coated layers were formed by heat treatment of coating layers with a non-stoichiometric $Ti_xAl_{1-x}N$. In this study, TiAlN coated layer was prepared by R.F magnetron sputtering and investigated the thermal behavior for heat treatment at various temperature in tube furnace. The formation of large particles with porous microstructure and phase change from HCP to FCC were observed on coated layer during heat treatment over $850^{\circ}C$ and it reduced the corrosion resistance of coated TiAlN layers.

Electrodes for contact electric welding of aluminium alloys

  • Bondar, M.P.;Moon, J.G.
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 1997년도 특별강연 및 추계학술발표 개요집
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    • pp.184-193
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    • 1997
  • Aluminium and aluminium alloys have the high electrical and heat conductivity. It gives rise to difficulties for a choice of electrodes material for their contact electric welding. This paper describes the investigations performed to solve the above problem. The purpose of this investigation was to obtain dispersion-hardening alloys by the internal oxidation method, to optimize their contents and treatment modes, to produce electrodes of these alloys and to test them. The strengthing effect of alloys with oxide particles depends on their size stability at high temperatures. Despite of the fact, that oxides are the most stable of all the non-metallic phases their coagulation takes place. Based on the early results, we chose two types of alloys, first No. 1 Cu - 0,4%Al and second No. 2 Cu - 0,2%Be for production of electrodes. These alloys had not additional alloying elements. These alloys were prepared as 1 mm plates and flake-formed 200 m thick, and also No. 1 as a powder of size 100 mkm (received from Korea). The large samples for electrodes were produced by three methods : explosive welding method, dynamic one including the explosion compression of electrode blank and the quasi-dynamic method including the high-speed compression of dense briquest and the further hot extrusion of a rod.

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