• Title/Summary/Keyword: oxidation rate

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The Response of Nitrogen Deposition to Methane Oxidation Availability and Microbial Enzyme Activities in Forest Soils

  • Jang, In-Young;Lee, Hyoung-Min;Kang, Ho-Jeong
    • Environmental Engineering Research
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    • v.15 no.3
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    • pp.157-161
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    • 2010
  • Forest soils are often nitrogen-limited, and nitrogen input to forest soils can cause substantial changes in the structure and functions of a soil ecosystem. To determine the effects of nitrogen input on methane oxidation and the microbial enzyme activities, manipulation experiments were conducted using nitrogen addition to soil samples from Mt. Jumbong. Our findings suggested that the addition of nitrogen to the soil system of Mt. Jumbong did not affect the microbial enzyme activities. Conversely, the addition of nitrogen affected the rate of methane oxidation. Inorganic nitrogen in soils can inhibit methane oxidation via several mechanisms, such as substrate competition, toxic effects, and competition with other microbes, but the inhibitory effects are not always the same. In this research, seasonal changes were found to produce different inhibitory factors, and these different responses may be caused from differences in the methantrophic bacteria community structure.

Modeling of Piston Crevice Hydrocarbon Oxidation in SI Engines (전기점화 기관 간극 체적 내 미연탄화수소의 산화 모델링)

  • Choi, Hoi-Myung;Kim, Se-Jun;Min, Kyung-Doug
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.884-889
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    • 2001
  • Combustion chamber crevices in SI engines are identified as the largest contributor to the engine-out hydrocarbon emissions. The largest of crevice region is the piston ring pack crevice. To predict and understand the oxidation process of piston crevice hydrocarbons, a 3-dimensional numerical simulation method was developed. A engine shaped computational mesh with moving grid for piston and valve motions was constructed. And a 4-step oxidation model involving 7 species was used and the 16 coefficients in the rate expressions were optimized based on the results from a detailed chemical kinetic mechanism for the oxidation condition of engine combustion chamber. Propane was used as a fuel in order to eliminate oil layer absorption and liquid fuel effect.

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Inhibition effects of flavonoid on Oxidation of Human Low Density Lipoprotein

  • Ryu, Byeong-Ho;Kim, Min-Jeong
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.800-807
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    • 2001
  • This study was designed to investigate the antioxidative activity of a substance isolated from. The antioxidative activity of procyanidine was higher than that of dl-tocopherol and BHA on low-density lipoprotein (LDL) oxidation by thiobarbituric acid reactive substance (TBARS). Procyanidine inhibited the copper-mediated oxidation of human LDL in a dose dependent manner with almost complete inhibition at $60{\mu}g/mL$. Procyanidine at a concentration of $80{\mu}g/mL$ in hibited oxidation of LDL induced by J774. LDL oxidized by copper-mediated or cell-induced oxidation was degraded at a much greater rate than native LDL. These results suggested the importance of further research to procyanidine in the investigation of atherosclerosis and free radical-induced injury.

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A Study on Behavior of Steel Surface Oxidation with Characteristics of the Combustion (연소 특성에 따른 강판 표면 산화거동에 관한 연구)

  • KIM, SEULGI;KANG, KIJOONG;LEE, KEEMAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.4
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    • pp.392-400
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    • 2017
  • An experimental study was conducted to investigate behavior of steel surface oxidation with characteristics of the combustion. The excess entalphy combustion in porous media system was applied to implement the direct radiation heating system. The surface oxidation thickness (SOT) of fuel-lean was thicker than the SOT of fuel-rich. Also, the SOT was increased by increasing residence time. Detailed explanations were given by SEM and EDS analysis.

Oxidation Behavior of the Simulated Supent Fuel at 400-$700^{\circ}C$ (400-700 $^{\circ}C$의 온도범위에서 모의 핵연료의 산화거동)

  • 강권호
    • Journal of Powder Materials
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    • v.6 no.3
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    • pp.209-214
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    • 1999
  • The oxidation behavior of the simulated spent fuel of burn up 33 MWD/kgU was investigated to predict that of the spent fuel in the temperature ranges of 400 to $700^{\circ}C$ and was compared with those of $UO_2$. The forms of uranium oxides after the oxidation were conformed by XRD analyses. The oxidation rate at each the temperature and the activation energy were obtained. After complete oxidation, the simulated spent fuel was converted to $U_3O_8$ and pulverized to powder due to the density difference between the simulated spent fuel and uranium oxides. The activation energies were 85.35 and 30.77kJ/mol in the temperature ranges of 400$\leq$T($^{\circ}C$)$\leq$500 and 500$\leq$T($^{\circ}C$)$\leq$700, respectively.

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Redox Reaction on Polarization Curve Variations of Polymer with Enzymes

  • Park, Chil-Nam
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.3
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    • pp.165-171
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    • 2000
  • Experiments were carried out to measure variations in the oxidation potential and current density using the polarization curves of polycarbonate. The results were then examined to identify the influences affecting the oxidation potential related to various conditions, such as temperature, pH, and oxydase(citrate and lipase). The lines representing the active anodic and cathodic dissolution shifted only slightly in the potential direction relative to temperature, pH, and the effect of the enzyme. The Tafel slope for the anodic and cathodic dissolution was determined such that the reversibility polarization was indicated as being effected by various conditions. The slope of the polarization curves describing the active-to-passive transition region shifted noticeably in their direction. Also, by varying the conditions, the optimum conditions for the most ready transform were identified, including temperature, pH, oxidation rate, and resistance of oxidation potential. The critical oxidation sensitivity(I(sub)r/I(sub)f) of the anodic current density peak and maximum passive current density was also determined, which is used in measuring the critical corrosion sensitivity of a polycarbonate.

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A Study on the Relationship between Oxidation and Sliding Wear Behavior of Ordered Fe-Al Intermetallic Alloys (규칙화된 Fe-Al 계 금속간 화합물의 산화특성과 미끄럼 마모거동과의 관계에 대한 연구)

  • 김용석
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1999.03b
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    • pp.144-148
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    • 1999
  • The relationship between oxidation and sliding wear behavior of Fe-28 at%. Al alloys with B2 ordered structure has been investigated. Sliding wear tests of the alloys have been carried out under various environmental conditions using a pin-on-disk wear tester. The wear rate of the ordered alloys in an oxygen atmoshpere was found to be much lower than in an oxygen atmosphere showed that Fe2O oxides formed on the wearing surface. The oxide layer prevented direct contact of the two mating materials and therefore improved wear resistance of the Fe-Al intermetallic alloy. It was found that the surface Al2O3 oxide layer which provides good oxidation resistance and improved mechanical properties broke down easily and didnot function properly as an oxidation barrier.

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Local Oxidation Characteristics on Implanted 4H-SiC by Atomic Force Microscopy (원자힘 현미경을 이용한 이온 주입된 4H-SiC 상의 국소 산화 특성)

  • Lee, Jung-Ho;Ahn, Jung-Joon;Koo, Sang-Mo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.4
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    • pp.294-297
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    • 2012
  • In this work, local oxidation behavior in phosphorous ion-implanted 4H-SiC has been investigated by using atomic force microscopy (AFM). The AFM-local oxidation (AFM-LO) has been performed on the implanted samples, with and without activation anneal, using an applied bias (~25 V). It has been clearly shown that the post-implantation annealing process at $1,650^{\circ}C$ has a great impact on the local oxidation rate by electrically activating the dopants and by modulating the surface roughness. In addition, the composition of resulting oxides changes depending on the doping level of SiC surfaces.

Effect of Yttria and Ceria on Mechanical Properties and Oxidation Behaviors of $\alpha$-Sialon Ceramics ($\alpha$-Sialon 세라믹스의 역학적 성질과 산화거동에 미치는 $Y_2O_3$$CeO_2$의 첨가영향)

  • 이은복;이홍림;조덕호;박원철
    • Journal of the Korean Ceramic Society
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    • v.30 no.11
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    • pp.941-948
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    • 1993
  • The powder mixture of Si3N4-AlN-Y2O3, Si3N4-AlN-CeO2 and Si3N4-AlN-Y2O3-CeO2 system was hot-pressed at 175$0^{\circ}C$ for 2h in N2 to prepare $\alpha$-Sialon ceramics. The mechanical property and oxidation behaviour of the prepared $\alpha$-Sialon ceramics were investigated. At 120$0^{\circ}C$, oxidation resistance was best for the Y2O3 added $\alpha$-Sialon ceramics and oxidation rate increased when the amount of CeO2 increased. But when the mixture of Y2O3 and CeO2 added $\alpha$-Sialon ceramics showed a good oxidation resistance. Fracture toughness of (Y2O3+CeO2) added $\alpha$-Sialon ceramics was higher than Y2O3 added $\alpha$-Sialon ceramics.

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Microstructures and Cyclic Oxidation Resistance of Aluminide Coatings for Inconel 600 (Inconel 600에 있어서 Al抗散浸透 被覆層의 微細組織과 耐反復酸化性)

  • Chung, In-Sang;Byun, Chang-Suk
    • Journal of the Korean institute of surface engineering
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    • v.20 no.2
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    • pp.60-73
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    • 1987
  • For the purpose of improving the cyclic oxidation resistance of Ni-base superalloy, Inconel 600, aluminide coating methods are studied. The formation rate of aluminide coating layers is measured as a function of time and pack composition to find out the optimum coating condition. The evaluation of cyclic oxidation is established by the change in weight, the microphotography and EPMA of cross sectional area during $200^{\circ}C\;{\leftrightarrow}\;950^{\circ}C\;and\;200^{\circ}C\;{\leftrightarrow}\;1100^{\circ}C$, respectively. The thickness of coating layer and weight gains are parabolic behavior in propotion to time and Al contents. In pack of low aluminum contents, 2 wt%, however, weight gain is decreased when activator, $NH_4Cl$ is higher than 2 wt%. The cyclic oxidation resistance of the coating carried out at 1100$^{\circ}C$ are superior to those of the coating diffusion-treated after pack cementation at 800$^{\circ}C$. Aluminide oxide, which is formed in external scale, is barrier to the cyclic oxidation.

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