• Title/Summary/Keyword: oxidation process

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Progresses in membrane and advanced oxidation processes for water treatment

  • Khulbe, K.C.;Feng, C.Y.;Matsuura, T.;Ismail, A.F.
    • Membrane and Water Treatment
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    • v.3 no.3
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    • pp.181-200
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    • 2012
  • At present water crisis is not an issue of scarcity, but of access. There is a growing recognition of the need for increased access to clean water (drinkable, agricultural, industrial use). An encouraging number of innovative technologies, systems, components, processes are emerging for water-treatment, including new filtration and disinfectant technologies, and removal of organics from water. In the past decade many methods have been developed. The most important membrane-based water technologies include reverse osmosis (RO), ultrafiltration (UF), microfiltration (MF), and nanofiltration. Beside membrane based water-treatment processes, other techniques such as advanced oxidation process (AOP) have also been developed. Some unconventional water treatment technology such as magnetic treatment is also being developed.

Lipid Peroxidation and Its Toxicological Implications

  • Nam, Tae-Gyu
    • Toxicological Research
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    • v.27 no.1
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    • pp.1-6
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    • 2011
  • Lipid peroxidation is a free radical oxidation of polyunsaturated fatty acids such as linoleic acid or arachidonic acid. This process has been related with various pathologies and disease status mainly because of the oxidation products formed during the process. The oxidation products include reactive aldehydes such as malondialdehyde and 4-hydroxynonenal. These reactive aldehydes can form adducts with DNAs and proteins, leading to the alterations in their functions to cause various diseases. This review will provide a short summary on the implication of lipid peroxidation on cancer, atherosclerosis, and neurodegeneration as well as chemical and biochemical mechanisms by which these adducts affect the pathological conditions. In addition, select examples will be presented where antioxidants were used to counteract oxidative damage caused by lipid peroxidation. At the end, isoprostanes are discussed as a gold standard for the assessment of oxidative damages.

Degradation of 1,4-Dioxane using $O_3$/$H_2O_2$

  • Suh, Jung-Ho;Mohseni, Madjld
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.139-144
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    • 2003
  • 1, 4-dioxane is a recalcitrant pollutant found in contaminated ground waters and industrial effluents. Conventional water treatment techniques are limited to treat this compound effectively. In this study, $O_3$$H_2O_2$ oxidation process was used to eliminate 1, 4-dioxane in water and to enhance the biodegradability. Several factors affecting biodegradability enhancement were investigated. The relationship between initial oxidation rate of 1 A-dioxane and BOD enhancement rate has been determined, a kinetic model has been proposed. $H_2O_2$ concentration and pH had a proportional relation with biodegradability of 1, 4-dioxane, but in case of ozone, there was no relationship with biodegradability. 1, 4-Dioxane removal efficiencies had good agreement with the biodegradability.

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Fenton Process for Treatment of Contaminated Groundwater

  • Jung, Oh-Jin;Park, Chil-Nam
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.10 no.S_4
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    • pp.165-172
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    • 2001
  • We investigated the optimal experimental conditions and reaction kinetics for the decompositions of PCE, TCE, naphthalene, and chloroform using conventional Fenton oxidation process. Additionally, the influence of pH on the decompositions of PCE was also evaluated. The results indicated that the optimal pH value was around 3. The dosage of Fenton's reagent and the molar ratio of hydrogen peroxide to ferrous ion for an approximately complete decomposition was found to depend on the properties of the organic compound. Due to their unsaturated structures, the results show that PCE, TCE, and naphthalene could be all effectively decomposed by Fenton's reagent oxidation. Their unsaturated structures could be mostly destoyed within first 1-2 minutes at a low dosage with an certain molar ratio of hydrogen peroxide to ferrous ion. However the saturated compound such as chloroform was more difficult to decompose even with a relatively high dosage of Fenton's reagent.

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Fabrication and characterization of SILO isolation structure (SILO 구조의 제작 방법과 소자 분리 특성)

  • Choi, Soo-Han;Jang, Tae-Kyong;Kim, Byeong-Yeol
    • Proceedings of the KIEE Conference
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    • 1988.07a
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    • pp.328-331
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    • 1988
  • Sealed Interface Local Oxidation (SILO) technology has been investigated using a nitride/oxide/nitride three-layered sandwich structure. P-type silicon substrate was either nitrided by rapid thermal processing, or silicon nitride was deposited by LPCVD method. A three-layered sandwich structure was patterned either by reactive ion etch (RIE) mode or by plasma mode. Sacrificial oxidation conditions were also varied. Physical characterization such as cross-section analysis of field oxide, and electrical characterization such as gate oxide integrity, junction leakage and transistor behavior were carried out. It was found that bird's beak was nearly zero or below 0.1um, and the junction leakages in plasma mode were low compared to devices of the same geometry patterned in RIE mode, and gate oxide integrity and transistor behavior were comparable. Conclusively, SILO process is compatible with conventional local oxidation process.

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Microstructure of Titania Layers Formed by Plasma Electrolytic Oxidation (PEO) Method

  • Ok, Myoung-Ryul;Kim, Ji Hye;Kang, Eun Young;Hong, Kyung Tae
    • Corrosion Science and Technology
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    • v.5 no.6
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    • pp.213-217
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    • 2006
  • Titania coatings were prepared on commercially pure Ti by plasma electrolytic oxidation (PEO) method with various electrolytes and process condition. Coatings were formed under galvanostatic condition with several current density values, and the change of applied voltage with process time was recorded. The microstructure of the titania coatings was observed using XRD, SEM, TEM, and the time-voltage diagrams were analyzed in terms of microstructure evolution.

Formation of $Al_2O_3$-Composites by the Melt Oxidation of an AlZnMg-alloy (AlZnMg-합금의 용융산화에 의한 $Al_2O_3$-복합재료의 형성)

  • 김일수;김상호;강정윤
    • Journal of the Korean Ceramic Society
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    • v.33 no.9
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    • pp.985-994
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    • 1996
  • The initiation and growth of $\alpha$-Al2O3/metal composites by the directed oxidation of molten commercial AlZnMg-alloy at 1223-1423K were investigated. Spontaneous bulk growth did not occur on the alloy alone. but the uniform initiation and growth of the composite were obtained by putting a thin layer of SiO2 particles on the surface of the alloy. Without SiO2 the external surface of the oxide layer was convered by MgO and MgAl2O4. But with the SiO2 reaction initiate the porous ZnO layers were found on the growth surface. The higher process temperature yielded a lower metal content. The oxidation product of $\alpha$-Al2O3 was found to be oriented with c-axis parallel to th growth direction. The growth rates increased with temperature and the apparent activation energy was 111.8 kJ/mol.

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Effect of Electrolyte Composition on Corrosion Behavior of PEO Treated AZ91 Mg Alloy

  • Park, Kyeong Jin;Lee, Jae Ho
    • Corrosion Science and Technology
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    • v.8 no.6
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    • pp.227-231
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    • 2009
  • Mg and Mg alloys have been used for lots of applications, including automobile industry, aerospace, mobile phone and computer parts owing to low density. However, Mg and Mg alloys have a restricted application because of poor corrosion properties. Thus, improved surface treatments are required to produce protective films that protect the substrate from corrosive environments. Environmental friendly Plasma Electrolytic Oxidation (PEO) has been widely investigated on magnesium alloys. PEO process combines electrochemical oxidation with plasma treatment in the aqueous solution. In this study, AZ91 Mg alloys were treated by PEO process in controlling the current with PC condition and treated time, concentration of NaF, NaOH, and $Na_2SiO_3$. The surface morphology and phase composition were analyzed using SEM, EDS and XRD. The potentiodynamic polarization tests were carried out for the analysis of corrosion properties of specimen. Additionally, salt spray tests were carried out to examine and compare the corrosion properties of the PEO treated Mg alloys.

Oxidation Resistance and Graphitization of Boron Oxide Implanted Carbon/Carbon Composites

  • Joo, Hyeok-Jong;Oh, In-Hwan;Ahn, Il-Hwan
    • Carbon letters
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    • v.5 no.3
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    • pp.127-132
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    • 2004
  • Chop molding composites and 2D carbon/carbon composites were manufactured by hot press molding method. Phenol resin of novolac type was used for matrix precursor and PAN-based carbon, PAN-based graphite and pitch-based carbon fiber were used for reinforcement and boron oxide was used for oxidation retardant. All of the composites were treated by $2000^{\circ}C$ and $2400^{\circ}C$ graphitization process, respectively. After graphitization process, amount of a boron residue in carbon/carbon composites is much according to irregularity of used raw materials. Under the presence of boron in carbon/carbon composites, catalytic effect of boron was a little at $2000^{\circ}C$ graphitization temperature. However, it was quite at $2400^{\circ}C$ graphitization.

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EFFECTS OF REACTION TIME AND pH ON FENTON'S BATCH PROCESS FOR THE TREATMENT OF LEACHATE

  • Choi, Heung-Jin;Kim, Il-Kyu
    • Journal of Korean Society on Water Environment
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    • v.18 no.2
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    • pp.169-187
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    • 2002
  • The effects of important parameters such as reaction time and pH on the Fenton's process were evaluated using a batch reactor. It was proven that organic materials and heavy metals in leachate could be successfully removed by Fenton's reagent. Favorable operation conditions were investigated. It was observed that the reaction between ferrous iron and hydrogen peroxide with the production of hydroxyl radical was almost complete in 10 minutes. That is, the oxidation of organic materials by Fenton's reagent was so fast that it was complete in 30 minutes with batch experiments. With the formation of carbonic acid, pH of the batch reactor decreased to favorable acidic conditions without acid addition. The oxidation of organic materials in the leachate showed a pH dependence and was most efficient in the pH range of 2-3.