• 제목/요약/키워드: oxidation content

검색결과 1,075건 처리시간 0.031초

전기방사를 이용한 S-keratose/Nylon 6 부직포의 제조 (Preparation of S-keratose/Nylon 6 Nonwoven Webs by Electrospinning)

  • 김진원;송경근
    • 한국염색가공학회지
    • /
    • 제17권1호
    • /
    • pp.38-44
    • /
    • 2005
  • Oxidation method was used to extract S-keratose from wool. Wool was treated with performic acid and soluble fraction(S-keratose) was collected by evaporating the solvent. S-keratose and Nylon 6 were dissolved in formic acid at the ratio of 100/0, 80/20, 50/50, 20/80, and 0/100, and S-keratose/Nylon 6 web of sub-micron size was made by electro-spinning technique. SEM, EA, FT-IR, XRD, and TGA were used to characterize the properties of S-keratose/Nylon 6 solutions and electrospun fibers. As the Nylon 6 content increased, viscosity, conductivity of the electrospinning solution and the diameter of spun fiber increased. Electrospun nonwoven webs have the same S-keratose/Nylon 6 ratios of the spinning solutions. The crystalline structures of S-keratose and Nylon 6 existed separately in the electrospun webs. Thermal stability of the webs increased due to Nylon 6 content.

인진쑥 추출물의 항산화 및 항암 활성 (Antioxidant and Anticancer Activities of Extract from Artemisia capillaries)

  • 정미정;윤유;허성일;왕명현
    • 생약학회지
    • /
    • 제39권3호
    • /
    • pp.194-198
    • /
    • 2008
  • Artemisia capillaries is a major important food and medicinal resource in Korea. In order to confirm the biological activities of Artemisia capillaries, we investigated antioxidant and anticancer activities from in vitro assays. The Artemisia capillaries methanol (MeOH) extracts was used for the evaluation of DPPH scavenging, total phenolic content, total flavonoid content, hydroxyl radical (${\bullet}OH$) scavenging, reducing power assay as antioxidant activity, as well as anticancer activities as MTT assay. As a result, the Artemisia capillaries MeOH extracts showed potent antioxidative activity and anticancer activity in vitro. These results suggest that the Artemisia capillaries MeOH extracts have a potential alleviated oxidation process, cell motility activity, and tumorigenesis.

직물의 표백과 세척이 유연제 (DSDMAC) 흡착에 미치는 영향(제1보) (The Effects of Bleaching or Washing on the Absorption of Softener (DSDMAC) (part 1))

  • 박선경;유효선
    • 한국의류학회지
    • /
    • 제20권2호
    • /
    • pp.270-281
    • /
    • 1996
  • This study was carried to figure out the effect of bleaching on the cationic surfactant (DSDMAC) absorption by cotton fabrics. And physico-chemical change, static electricity, and fabric stiffness of bleached cotton fabrics were measured. Cotton fabrics bleached with sodium hypochlorite soluton and with sodium percarbonate solution were used to analyze the DADMAC absorption. The results were as follows: 1. As the number of bleaching cycles were increased, the degree of oxidation on cotton fabrics was increased. So their carboxyl content was increased and their tensile strength was decreased. 2. DSDMAC absorption by cotton fabrics was increased by bleaching and was in propor- tion to carboxyl content. Therefore, it was groved that DSDMAC absorption by cotton fabrics was motivated by ion exchange mechanism. 3. The static electricity of cotton fabrics almost no change when bleached and unbleached absorption had no effect on the static electricity of cotton fabrics. 4. DSDMAC which was absorbed by cotton fabrics acted as a lubricant. DSDMAC absorption reduced the friction coefficient of yarn, so stiffness of cotton fabric was decreased.

  • PDF

인산을 적용한 Ultra Definition 디스플레이 패널의 패턴 형성에 관한 연구 (A Study on Pattern Formation of Ultra Definition Display Panel Applying Phosphoric Acid)

  • 김민수;조을룡
    • 반도체디스플레이기술학회지
    • /
    • 제13권3호
    • /
    • pp.13-19
    • /
    • 2014
  • Phosphoric acid was used as etching agent instead of conventional peroxide - based chemicals for forming pattern of ultra definition display. Etchant was synthesized by mixing etching agent, oxidation agent, buffer solution, and additive into solvent, deionized water. Thicknesses of copper, main metal of ultra definition display, for etching, were 10,000 and $30,000{{\AA}}$. Etch stop of good low skew for proper pattern formation has been occurred at the content ratio of phosphoric acid 60 - 64%, nitric acid 4 - 5%, additive(potassium acetate) 1 - 3%. Buffer solution(acetic acid) decreased the metal contact angle $63.07^{\circ}$ to $42.49^{\circ}$ for benefiting pattern formation. Content variations on four components (phosphoric acid, nitric acid, acetic acid, potassium acetic acid) of the etchant with storage time were within 3 wt% after 24 hrs of etching work.

한국산 참깨기름과 중국산 참깨기름의 토코페롤 산화안정성 (Oxidative Stability of Tocopherols on Korean Sesame oil and chinese Sesame oil)

  • 신묘란;주광지
    • 동아시아식생활학회지
    • /
    • 제4권2호
    • /
    • pp.51-57
    • /
    • 1994
  • Six sesame oils prepared from Korean and Chinese sesame were oxidized at 40$^{\circ}C$ for 16 weeks in a dark place. Effects of oxidative stability on tocopherols of those sesame oils were studied in related to chemical changes in the oils. All oil samples showed that the rate of tocopherol reduction was increased by the storage time. The changes of peroxide value, free fatty acid, carbonyl content were not caused in direct relation to the tocopherols oxidation. The amount of total tocopherol in the Korean sesame oil ranged from 48.7-50.3mg/100g and Chinese seseame oil ranged from 42.4-44.7 mg/100g According to the three individual tocopherols remaining content after 16weeks, ${\gamma}$-,${\alpha}$-,${\beta}$- tocopherol showed 70%, 30%, 20% of initial concentrations in the oils respectively. There was no significant difference between Korean and Chinese sesame oil except the higher total amount of the tocopherol in Korean sesame oil than that of Chinese.

Thermal Oxidative Purification of Detonation Nanodiamond in a Gas-Solid Fluidized Bed Reactor

  • Lee, Jae Hoon;Youn, Yong Suk;Lee, Dong Hyun
    • Korean Chemical Engineering Research
    • /
    • 제56권5호
    • /
    • pp.738-751
    • /
    • 2018
  • The effect of the reaction temperature and reaction time on the thermal oxidative purification quality of detonation nanodiamond (NDsoot) was investigated in a gas-solid fluidized bed reactor of a $0.10m-ID{\times}1.0m$-high stainless steel column with zirconia beads ($d_{SV}=99.2{\mu}m$). The carbon conversion increased with increasing the reaction temperature; however, when the reaction temperature was greater than 773 K, the carbon conversion did not increase. The content of $sp^3$-hybridized carbon at the reaction temperature of 703 K barely changed when the reaction time was more than 30 minutes, but at 773 K, the content decreased as preferred. At 703 K, the purification quality increased with the increasing reaction time; however, at 773 K, the purification quality increased up to 30 minutes and then decreased rapidly.

RC조 구조물의 최적 음극방식 조건 설정을 위한 함수율의 영향에 대한 평가 (Effect of Moisture on the Current Density for Optimized Cathodic Protection Condition in RC Structures)

  • 박동천;조규환;안재철
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2013년도 춘계 학술논문 발표대회
    • /
    • pp.29-30
    • /
    • 2013
  • Steel corrosion is the most serious problem in RC structures. Even though patch repair method is normally applied in repair system, the effectiveness is not enough. Cathodic protection in active repair method to deteriorated RC structures. FEM model was developed to simulate the optimized cathodic protection condition. Iro oxidation, hydrogen evolution and oxygen reduction were considered to expect current distribution. Moisture content in concrete which can affect the electrolyte conductivity was used as initial condition.

  • PDF

가속열화 실험에 의한 고분자 애자의 분해 (Degradation of Composite Insulator as Accelated Aging Test)

  • 이용희;장동욱;박영국;박정남;강성화;임기조
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
    • /
    • pp.144-147
    • /
    • 2000
  • The effect of accelerated aging test on ethylene-propylene-diene monomer(EPDM) rubber used for outdoor insulation was studied by X-ray photoelectron spectroscopy(XPS), scanning electron microscope(SEM), FFT spectrum alalysis, and electrical pulse counts using PC by oscilloscope(300 MHz). In electrical alalysis, FFT spectrum analysis indicated arcing caused a significant increase in the third harmonic content of the leakage current of polluted insulator. Also, pulse counts increased as aging time. The surface oxygen and aluminum content were found to increase and that of carbon and nitrogen were found to decrease with time. The detailed XPS analysis indicated that the concentration of carbon in C-C decreased and concentration of highly oxidized carbons increased with time, which was due to the oxidation of EPDM rubber polymer SEM analysis indicated that crack and erosion of EPDM rubber occurred with time.

  • PDF

Al(OH)3가 EPDM의 자외선 촉진열화에 미치는 전기적 특성평가 (Effect of Electrical Properties on the EPDM- $Al(OH)_3$ Composite by UV Accelerated weathering)

  • 심대섭
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
    • /
    • pp.243-247
    • /
    • 2003
  • The effect of accelerated weathering(UV) on three type of ethylene propylene diene monomer(EPDM) composite used for higher voltage insulator were investigated by weather-emoter. For weatherability of EPDM composite, surface resistance, dielectric breakdown strength, change of contact angle, surface composition were measured according to UV accelerated weathering time. From the resort of the measurement of surface resistivity, contact angle of EPDM composite decreased and showed chalking and cracking phenomenon when UV weathweing time was for 1500 h and 2000 h. The analysis of surface atomic composition indicated that surface aluminiu(Al) content was detected due to chalking phenomenon after 1500 h of UV weathering, Oxygen content of all composite increased due to the oxidation.

  • PDF

오존 처리에 의한 이태리포플러 목분의 화학적 성상 변화 (Chemical Characteristics of Ozone Treated Aspen Wood Meal)

  • 김강재;엄태진
    • 펄프종이기술
    • /
    • 제43권1호
    • /
    • pp.29-35
    • /
    • 2011
  • Since the role of lignin in the wood cell wall is to keep integrity and structure rigidity of lignocellulosic substrate, lignin of the cell wall has to be destroyed before enzymatic hydrolysis of wood polysaccharides. The aspen wood meals were delignified with ozone in acidic condition. The chemical characteristics of wood meal were investigated. The 60% of lignin and almost zero % of polysaccharides in aspen wood meal was degraded with 10min. ozone treatment. The phenolic hydroxyl groups of lignin in ozonated wood meal were increased with ozonation time. The sugar composition of ozonated wood meal showed that the hemicellulose was more susceptible to ozonation than cellulose. The yield of aldehyde was increased in some degree with 10min. ozone treatment and decreased with longer ozone treatment.