• Title/Summary/Keyword: oxidation and reduction potential

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Evaluate of Electrochemical Characteristics in Electrolyzed Reduced Water

  • Park, Sung-Ho;Yun, Su-Jin;Kim, Jeong-Sik;Shin, Hyun-Su;Park, Soo-Gil
    • Journal of Electrochemical Science and Technology
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    • v.2 no.2
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    • pp.85-90
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    • 2011
  • Active oxygen species or free radicals are considered to cause extensive oxidative damage to biological macromolecules, which brings about a variety of diseases as well as aging. Electrolyzed reduced water(ERW) has been regarded as a ideal antioxidative agent in recent years. ERW is produced by passing a diluted salt solution through an electrolytic cell, within which the anode and cathode are separated by membrane. It can be produced reactive materials in ERW near the cathode during the electrolysis of water. ERW have the following advantages over other traditional cleaning agents: effective antioxidative agent, easy preparation, inexpensive, and environmentally friendly. The main advantage of ERW is its safety and antioxidative effect. ERW with strong reducing potential can be used to remove dirt and grease from items such as cutting boards and other kitchen utensils. The primary aim of this study is the activation mechanism of oxidation reduction potentials, ion conductivity, pH, and electrochemical properties with reactive materials in ERW.

Characteristics of Electricity Production by Metallic and Non-metallic Anodes Immersed in Mud Sediment Using Sediment Microbial Fuel Cell

  • Haque, Niamul;Cho, Dae-Chul;Kwon, Sung-Hyun
    • Journal of Environmental Science International
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    • v.23 no.10
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    • pp.1745-1753
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    • 2014
  • Sediment microbial fuel cell (SMFC), equipped with Zn, Al, Cu, Fe or graphite felt (GF) anode and marine sediment, was performed. Graphite felt was used as a common cathode. SMFC was single chambered and did not use any redox mediator. The aim of this work was to find efficient anodic material. Oxidation reduction potential (ORP), cell voltage, current density, power density, pH and chemical oxygen demand (COD) were measured for SMFC's performance.. The order of maximum power density was $913mWm^{-2}$ for Zn, $646mWm^{-2}$ for Fe, $387.8mWm^{-2}$ for Cu, $266mWm^{-2}$ for Al, and $127mWm^{-2}$ for graphite felt (GF). The current density over voltage was found to be strongly correlated with metal electrodes, but the graphite felt electrode, in which relatively weaker electricity was observed because of its bio-oriented mechanism. Metal corrosion reactions and/or a complicated microbial electron transfer mechanism acting around the anodic compartment may facilitate to generate electricity. We presume that more sophisticated selection of anodic material can lead to better performance in SMFC.

Study on Controlling Factors for Soil Structure in Creation of Man-made Tidal Flat (인공 간석지 창출에 있어서 토양구조를 결정하는 인자에 관한 연구)

  • 이정규;최영찬
    • Journal of Environmental Science International
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    • v.8 no.5
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    • pp.587-592
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    • 1999
  • The purpose of this study was to identify the controlling factors to construct tidal flat ecosystems having similar characteristics as natural ones. We transplanted the soil in a constructed tidal flat to a natural one and vice versa. Parameters monitored after these transplantations were silt content, organic matter, bacterial population and oxidation-reduction potential. Moreover, the relationship among silt content, organic matter and bacterial population was investigated by laboratory column experiment. The silt content, organic matter, bacterial population and vertical profile of oxidation-reduction potential in the soil transplanted from the constructed tidal flat to the natural one changed to similar values to those in the natural one. On the contrary, all the parameters for the soil transplanted from the natural tidal flat to the constructed one changed to similar values as those in the constructed one. The silt contents in thses two transplanted solis were in proportion to the organic carbon contents and bacterial population. Similarly, the bacterial population in laboratory column experiment increased with the increase in silt and organic matter contents. It seemed to be important to select a place to enhance accumulative of silt and/or to maintain the silt content by hydrodynamic control of seawater in order to construct a tidal flat having similar characteristics as natural one.

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A Study on Electrostatic Discharging in Ultrapure and Electrolyzed Waters Using Kelvin's Thunderstorm Effect (캘빈방전 효과를 이용한 초순수 및 전해이온수의 정전기 방전 연구)

  • Kim, Hyung-won;Jung, Youn-won;Choi, In-sik;Choi, Byung-sun;Choi, Donghyeon;Ryoo, Kun-kul
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.1
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    • pp.5-11
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    • 2022
  • Despite the increasing importance of manufacturing and application R&D for ultrapure deionized water and electrolyzed ion water, various and systematic studies have not been conducted until now. In this study, the electrostatic discharge (ESD) behavior of electrolyzed ion water using a proton exchange membrane(PEM) was evaluated according to the type, flow rate, and bubble of electrolyzed ion water. In addition, by observing that Oxidation Reduction Potential (ORP) value returns to the unique value of electrolyzed ion water after electrostatic discharge, the possibility of two types of ions participating in electrostatic discharge ((H2O)n+ (assumed)) and ions for maintaining the characteristics of electrolyzed water could be inferred. In order to confirm the chemical structure and characteristics of the cations, in-depth research related to water molecular orbital energy or band gap should be followed.

Evaluation of Electrolyzed Oxidizing Water as a Control Agent of Cucumber Powdery Mildew

  • Lee, Yong-Hwan;Cha, Kwang-Hong;Ko, Sook-Ju;Park, In-Jin;Park, Boung-In;Seong, Ki-Young
    • The Plant Pathology Journal
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    • v.16 no.4
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    • pp.206-210
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    • 2000
  • The effect of the electrolyzed oxidizing water on Sphaerotheca fuliginea was investigated with germination and sporulation of the fungal conidia. The sporulation was inhibited by the electrolyzed oxidizing water of pH 2.5, 3.5, and 4.5, but was not inhibited by the distilled water adjusted pH with 1N-HCL solution. However, the electrolyzed oxidizing water did not affect conidial germination. The oxidation-reduction potential at pH 2.5 and pH 3.5 of electrolyzed oxidizing water were 1130 mV and 1060 mV, respectively, but those of distilled water adjusted with HCL solution were 550 mV and 490 mV, respectively. When the electrolyzed oxidizing water of ORP over 1100 mV was sprayed on cucumplanting, the disease severities of powdery mildew were about 8.5% and 19.2%, respectively. Disease severity of a standard control (triflumizole 30% WP, $500\textrm{mg}\textrm{/L}$) was about 3.0%, while that of plants without electrolyzed oxidizing water was to 45.8%.

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Potential of combining natural-derived antioxidants for improving broiler meat shelf-life - A review

  • Andiswa Ntonhle Sithole;Vuyisa Andries Hlatini;Michael Chimonyo
    • Animal Bioscience
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    • v.36 no.9
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    • pp.1305-1313
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    • 2023
  • Synthetic antioxidants have shown adverse effects on consumers. The review, thus, aims to assess the effect of marinating broiler meat with plant leaves-derived antioxidants potential for improving shelf-life and human health. Broiler meat loss and waste due to spoilage is more than three million kg annually, thus, extending shelf-life by reducing initial microbial load and autoxidation is essential. Adding various antioxidants would reduce oxidation of protein and fatty acids improving nutritional shelf-life through synergic interactions. Antioxidant synergetic effects also improves reduction in microbiota proliferation leading to the delayed development of off flavours and deterioration of meat colour. To reduce initial microbial load and autoxidation effects, the inclusion of polyphenols and antioxidants from varying sources by mixing various antioxidants would lead to improved synergic effects.

Electrochemical Properties of Mixture Langmuir-Blogett Films of Fatty Acid containing Azobenzene and Phospholipid (아조벤젠기를 가진 지방산과 인지질 혼합 LB막의 전기화학적 특성)

  • Park, Keun-Ho;Choi, Sung-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.920-923
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    • 2004
  • We have investgated on the monolayer LB film of BASH-DMPC mixture on an ITO for the photoisomerization by light irradiation. We measured electrochemical properties by using cyclic voltammetry with a three-electrode system, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode in $NaClO_4$ solution at a variable concentration and monolayer LB films. A measuring range was reduced from initial potential to -1350mV, continuously oxidized to 1650 mV and measured to the initial point. The scan rate were 50, 100, 150 and 200 mV/s. As a results, LB films of 8A5H-DMPC appeared reversible process caused by the reduction-oxidation current from the cyclic voltammogram.

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The Properties of VOCs(Benzene, Toluene) with NOx Removal in Exposed Concrete With $TiO_2$(Anatase type) Powder as Photocatalyst (이산화티탄($TiO_2$ anatase) 분말을 광촉매로 사용한 노출 콘크리트의 VOCs(Benzene, Toluene)와 질소산화물(NOx) 제거 특성 연구)

  • Kim, Kwang-Ryeon;Lee, Dong-Bum;Kim, Wha-Jung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.588-591
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    • 2004
  • Generally, $TiO_2$ powders absorb ultraviolet rays and make oxidation/reduction reactions on its surface. Hydroxide radical(OH), a product of photocatalyst reactions, has so strong oxidation/reduction electric potential that it can oxidize noxious gas like VOCs(Volatile Organic Compounds) and NOx. In this study, $TiO_2$ was substituted for exposed concrete to investigate the purifying degree of VOCs(Benzene, Toluene) and NOx. Anatase types of $TiO_2$ were used as photocatalyst. The sun rays and the ultraviolet were used as a light source. Anatase type $TiO_2$ was better than rutile type in purifying performance. The sunray showed the best purifying performance among the light sources. $3\%$ substitution of $TiO_2$ with the sunray was enough to purify VOCs(Benzene, Toluene) and NOx efficiently.

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Fabrication of Hemoglobin/Silver Nanoparticle Heterolayer for Electrochemical Signal-enhanced Bioelectronic Application

  • Lee, Taek;Yoon, Jinho;Choi, Jeong-Woo
    • Korean Chemical Engineering Research
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    • v.55 no.4
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    • pp.556-560
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    • 2017
  • A hemoglobin/silver nanoparticle heterolayer was fabricated for bioelectronic device with electrochemical signal-enhancement effect. As a device element, a hemoglobin, the metalloprotein, contained the heme group that showed the redox property was introduced for charge storage element. For electron transfer facilitation, a silver nanoparticle was introduced for electrochemical signal facilitation, the hemoglobin was immobilized onto Au substrate using chemical linker 6-mercaptohexanoic acid (6-MHA). Then, the silver nanoparticle was immobilized onto fabricated hemoglobin/6-MHA heterolayers by layer-by-layer (LbL) method. The surface morphology and surface roughness of fabricated heterolayer were investigated by atomic force microscopy (AFM). The redox property of hemoglobin/silver nanoparticle heterolayer was investigated by a cyclic voltammetry (CV) experiment for obtaining an oxidation potential and reduction potential. Moreover, for the assessing charge storage function, a chronoamperometry (CA) experiment was conducted to hemoglobin/silver nanoparticle-modified heterolayer electrode using oxidation and reduction potentials, respectively. Based on the results, the fabricated hemoglobin/silver nanoparticle heterolayer showed that an increased charge storage effect compared to hemoglobin monolayer-modified electrode.

The Reduction of Waterworks Sludge by Hydrogen Peroxide Treatment (과산화수소 산화처리에 의한 정수슬러지의 감량화)

  • Kwon, Jae-Hyun;Kim, Young-Do;Park, Ki-Young;Lee, Seock-Heon;Kim, II-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.1
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    • pp.123-130
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    • 2007
  • The effects of hydrogen peroxide treatment on the reduction of waterworks sludge were investigated in this study. Sludge treated by peroxidation $H_2O_2$ oxidation) was dewatered using a pressure filter at 3atm. It was observed that $H_2O_2$ treatment at the acidic condition significantly reduce both cake water content and specific resistance to filtration (SRF), indicating the enhancement of dewaterability and filterability. The filterability by hydrogen peroxide treatment at pH 3.5 was better than acidic treatment and became comparable with polymer conditioning. The sludge filterability evaluated by SRF was optimal at a dose 2ml $H_2O_2$/sludge($0.02g\;H_2O_2/gTS$) after adjusting of pH to 3.5. The $H_2O_2$ oxidation at pH 3.5 also produced even more dewatered cake when compared with polymer conditioning. The reduction rate of sludge mass at an optimal condition showed 34% compared with untreated sludge. The effects of peroxidation on sludge properties including zeta potential, bound water and particle size were also evaluated. Peroxidation at the acidic condition reduced both bound water and zeta potential. By $H_2O_2$ combined with sulfuric acid leached iron caused Fenton's reaction, which showed a potential to significantly reduce the amount of solids mass and to produce more compact cake with higher filterability.