• Title/Summary/Keyword: oxalic acid

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Free sugar, Organic acid, Hesperidin, Naringin and Inorganic elements Changes of Cheju Citrus Fruits According to Harvest Date (제주산 감귤류의 숙기에 따른 유리당, 유기산, 헤스페리딘, 나린진, 무기물 함량의 변화)

  • Song, Eun-Young;Choi, Young-Hun;Kang, Kyung-Hee;Koh, Jeong-Sam
    • Korean Journal of Food Science and Technology
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    • v.30 no.2
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    • pp.306-312
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    • 1998
  • Free sugar, organic acid, naringin, hesperidin and inorganic elements change of six varities of Cheju citrus fruits; Citrus natsudaidai, C. grandis, C. platymamma., C. sudachi, C. aurantiun and C. unshiu Marc. var. miyagawa by harvest date were investigated. Changes in free sugar of citrus fruits on the different harvesting stages and varieties showed a little differencies. The content of sucrose, glucose and maltose in citrus juice were $44.9{\sim}66.0%,\;15.7{\sim}25.7%\;and\;17.5{\sim}30.1%$, respectively. As the fruits were matured, free sugar was increased, but organic acid was decreased gradually. The major organic acids from the fruit juice were citric acid, malic acid and oxalic acid. Citric acid content exceeded 90%, oxalic acid ranged less than 3.58% and malic acid ranged $0.98{\sim}9.45%$ in total organic acids. Both naringin and hesperidin content showed markedly high in immature fruits, and in rind compare to fruit juice. Naringin and hesperidin content decreased as peel coloration progressed. It was estimated that fully matured fruits would be useful for making processed products, which lead to less turbity and less bitterness.

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Determination of Organic acids of Kochuzang prepared from various Starch Sources (전분질원료(澱粉質原料)를 달리한 고추장의 유기산정량(有機酸定量))

  • Lee, Taik-Soo;Park, Sung-Oh;Lee, Myung-Whan
    • Applied Biological Chemistry
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    • v.24 no.2
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    • pp.120-125
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    • 1981
  • Organic acids of Kochuzang (red pepper paste) prepared from glutinous rice, polished barley, wheat flour and sweet potato were analyzed by a gas chromatography. Lactic, pyruvic, succinic, fumaric, malic, pyroglutamic and citric acid were identified. And trace amount of oxalic acid was found in the Kochuzang prepared from sweet potato. The dominant organic acid of all samples was pyroglutamic acid, followed by pyruvic and citric acid. The organic acids were lower in Kochuzang from wheat flour than in other samples. The contents of succinic and fumaric acid were highest in Kochuzang prepared from sweet potato and were lowest in polished barley Kochuzang.

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Antioxidative Activity and Tyrosinase Inhibition Effect of Fractions from the Extract of Inonotus obliquus (차가버섯 용매별 분획물의 항산화 활성과 Tyrosinase 저해 활성)

  • Im, Do-Youn;Lee, Kyoung-In
    • Korean Journal of Pharmacognosy
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    • v.48 no.1
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    • pp.46-50
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    • 2017
  • This study was conducted to investigate the antioxidative activities and tyrosinase inhibition effects of fractions from the distilled water extract of Inonotus obliquus. Moreover, GC-MS based analysis with trimethylsilyl (TMS) derivatization was carried out for active compound in the extract of I. obliquus. In DPPH radical scavenging ability, $SC_{50}$ values of the ethyl acetate fraction was 0.393 mg/ml as a result of the most effective than other fractions. Meanwhile, aqueous fraction showed higher effect in tyrosinase inhibitoty activity. In GC-MS based analysis with TMS derivatization, 7 compounds including syringic acid, vanillic acid and protocatechuic acid were observed in ethyl acetate fraction, and oxalic acid is the main compound in aqueous fraction. As a result, it was confirmed that oxalic acid in aqueous fraction from the distilled water extract of I. obliquus was a compound showing tyrosinase inhibition effect.

Effect of oxalic acid on the iron content of pottery stone (도석의 탈철에 관한 Oxalic acid의 영향에 관한 연구)

  • Kim Kyung-Nam;Park Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.6
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    • pp.257-261
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    • 2004
  • The pottery stones from the Taebek area consist of abundant quartz with kaolinite. In this study, the characteristics of pottery stones were examined by XRD (X-ray diffractometer), XRF (X-ray fluorescence spectrometer), TG-DTA and SEM (Scanning Electron Microscope). The chemical compositions of the raw ore showed 71.75 wt%$SiO_2$, 22.10 wt%$Al_2O_3$, 1.86 wt%CaO, 2.97 wt%$K_2O$, 0.62 wt%$Fe_2O_3$. When pottery stone of 3 mm size was leached at $80^{\circ}C$ with 10 % oxalic acid, the content of $Fe_2O_3$ was reduced from 0.62 wt% to 0.24 wt% and the whiteness was enhanced. Grinding of pottery stone was conducted by a planetary ball mill using media of zirconia, the average particle size was 2~5 $\mu\textrm{m}$.

Enzymatic Hydrolysis Condition of Pretreated Corncob by Oxalic Acid to Improve Ethanol Production (에탄올 생산 향상을 위한 옥살산 전처리 옥수숫대의 효소가수분해 조건 탐색)

  • Lim, Woo-Seok;Lee, Jae-Won
    • Journal of the Korean Wood Science and Technology
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    • v.40 no.4
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    • pp.294-301
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    • 2012
  • In this study, we investigated the features of bioethanol fermentation of corncob biomass after oxalic acid pretreatment as well as enzymatic hydrolysis. The enzymatic hydrolysis was performed with Accellerase 1000 and the highest yield of monomeric sugars ($64.8g/{\ell}$) was obtained at $50^{\circ}C$ and pH 4.5 for 96 hrs hydrolysis period. For the ethanol fermentation the monomeric sugars obtained from pretreated corncob were subjected to the biological treatment using Pichia stipitis CBS 6054. It was turned out that ethanol production from oxalic acid pretreated corncob was the most feasible at 10~14% of biomass loading as well as 15 FPU enzyme amount. Under these fermentation condition, the ethanol yield was approached to 0.47 after 24 hrs fermentation period, which was corresponded to 92.2% of conversion rate.

Evaluations of Y2O3 Powder Synthesized Using Oxalic Acid (옥살산을 이용한 Y2O3 분말제조와 특성 평가)

  • Son, Bo-Young;Jung, Mi-Ewon
    • Korean Journal of Materials Research
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    • v.21 no.8
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    • pp.444-449
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    • 2011
  • Nano-sized $Y_2O_3$ powders were prepared via a sol-gel method starting with $Y(NO_3)_3{\cdot}6H_2O$ (Yttrium(III) nitrate hexahydrate) and water with ethanol as a cosolvent. $Y_2O_3$ is an important rare earth oxide and has been considered for use in nuclear applications, such as ceramic materials, due to its excellent optical and refractory characteristics. It has been used as a chemically stable substrate, a crucible material for melting reactive metals, and a nozzle material for jet casting molten rare earth-iron magnetic alloys. Oxalic acid ($C_2H_2O_4$) has been adopted as a chelating agent in order to control the rate of hydrolysis and polycondensation, and ammonia was added in order to adjust the base condition. The synthesized $Y_2O_3$ powder was characterized using TG/DTA, XRD, FE-SEM, BET and Impedance Analyzer analyses. The powder changed its properties in accordance with the pH conditions of the catalyst. As the pH increases according to the FE-SEM, the grain grew and it showed that the pore size decreased while confirming the effect of the grain size. The nano-material $Y_2O_3$ powders demonstrated that the surface area was improved with the addition of oxalic acid with ammonium hydroxide.

Recovery of Tin and Copper from Waste Solder Stripper by Oxalate Precipitation (옥살레이트 침전법에 의한 폐솔더 박리액에서 주석 및 구리의 회수)

  • Ryu, Seong-Hyung;Ahn, Jae-Woo;Ahn, Hyo-Jin;Kim, Tae-Young
    • Resources Recycling
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    • v.23 no.3
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    • pp.37-43
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    • 2014
  • A study has been made on the recovery of tin and copper from waste solder stripper by oxalate precipitation. With the increasing of the oxalic acid addition, tin was precipitated effectively and removed above 99.5% of tin when the oxalic acid, in an amount 1.0-1.5 times the stoichometric requirement, was added. But, in this case, only 2.0% of copper was precipitated and lead, iron were not precipitated. So, tin was selectively removed from the waste solution. With the increasing of the reaction temperature, the removal percentage of tin was increased and maximum value at arounf $60^{\circ}C$ and decreased with increase in the temperature any more. After filtering the precipitate and drying in oven, $SnO_2$ was obtained from the precipitate. After removal of tin in stripping solution, above 91% of copper was selectively removed by Cu-oxalate by addition of oxalic acid.