• Korean Journal of Crystallography
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• v.11 no.1
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• pp.1-5
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• 2000

An another symmetric cone conformational isomer of p-tert-butylcalix[4]arene hexanoate(C/sub 68/H/sub 96/O/sub 8/) was prepared and was determined by X-ray diffraction method. The crystals are orthorhombic, Pbca, a=20.625(3) Å, b=21.291(3)Å, c=30.22(4)Å, V=13271(2)ų and Z=8. The intensity data were collected on an Enraf-Noninus CAD-4 diffractometer with a graphite monochromated Mo-Kα radiation. The structure was solved by direct method and refined by least-squares calculations to a final R value of 0.138 for 2394 observed reflections. The molecular conformation is distorted symmetric cone with the flattening B and D phenyl rings.

• Korean Journal of Crystallography
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• v.11 no.1
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• pp.46-51
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• 2000

The molecular structures of 2-SC₄H₃CH=NN(H)C/sub 6/H/sub 5/(C/sub 11/H/sub 10/N₂S) and (GaMe₂)₂(2-SC₄H₃CH=NNC/sub 6/H/sub 5/)₂(C/sub 26/H/sub 30/Ga₂N₄S₂) have been determined by X-ray diffraction. Crystallographic data for 2-SC₄H₃CH=NN(H)C/sub 6/H/sub 5/:orthorhombic space group P2₁2₁2₁, a=6.108(1)Å, b=7.593(1)Å, c=22.356(2)Å, V=1037.1(3)ų, Z=4, R=0.0613. Crystallographic data for (GaMe₂)₂(2-SC₄H₃CH=NNC/sub 6/H/sub 5/)₂:monoclinic space group P2₁/n, a=15.996(2) Å, c=9.879(3)Å, β=100.07.(2)°, V=2764.599)ų, Z=4, R=0.0503.

• Journal of the Korean Ceramic Society
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• v.34 no.11
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• pp.1182-1186
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• 1997

La0.8Ca0.2Cr0.98O3 powder was prepared using the modified Pechini process. Various crystalline phases formed during thermal decomposition were investigated. (La,Ca)CrO4 phase, first formed from the precursor, was transformed to (La,Ca)CrO3 and CaCrO4 above 80$0^{\circ}C$, which remained up to 110$0^{\circ}C$. However, only (La,Ca)CrO3 phase consisting of orthorhombic and intermediate rhombohedral polymorphs was observed after sintering at 125$0^{\circ}C$. The specimens sintered at 140$0^{\circ}C$ exhibited 98% of relative density and rather wide grain size distribution with average grain size of 3-4 ${\mu}{\textrm}{m}$. Densification and grain growth of the specimens observed above 125$0^{\circ}C$ were presumably attributed to liquid phase sintering resulted from melting of Ca3(CrO4)2 phase.

• Proceedings of the KIEE Conference
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• 2001.07c
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• pp.1396-1398
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• 2001

The $HoSi_2$ compounds prepared by codeposition of Si and Ho, and $HoSi_2$ by sintering method were investigated electrical and Hall effect. The crystal structure of samples showed a orthorhombic structure, and lattices constant is a=9.8545 $\AA$, b=7.7935 $\AA$, c=7.8071 $\AA$. Hall effect shows a n-type conductivity in the sintered $HoSi_2$. The electrical resistivity values was 1.608${\Omega}cm^{-1}$ and carrier mobility was $6.9{\times}10^1cm^2/V{\cdot}sec$ at low room temperature.

• Proceedings of the KIEE Conference
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• 2001.07c
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• pp.1500-1502
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• 2001

Plate-type ${\beta}-FeSi_2$ single crystals were grown using $FeSi_2$, Fe, and Si as starting materials by the chemical transport reaction method. The ${\beta}-FeSi_2$ single crystal was an orthorhombic structure. The direct optical energy gap was found to be 0.87eV at 300K. Hall effect shows a n-type conductivity in the ${\beta}-FeSi_2$ single crystal. The electrical resistivity values was 1.608$\Omega$cm and electron mobility was $3{\times}10^{-1}cm^2/V{\cdot}sec$ at room temperature.

• The Korean Journal of Ceramics
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• v.5 no.4
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• pp.348-352
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• 1999

Barium uranium sulfides, $BaUS_3$ and $BaU_2B_5$, were synthesized in a single phase by the reactin of $(Ba, UO_2)(NO_3)_2$ at Ba/U=1 and 0.5 with carbon disulfide at 1273 K for 6 h. They crystallized in orthorhombic structure with space group, Pnma. The lattice parameters a, b and c are 7.493, 10.38 and 7.238$\AA$ for $BaUS_3$ and 7.525, 8.475 and 11.858$\AA$ for $BaU_2S_5$, respectively. The electrical conductivity of these compunds increased with increasing temperature above 200K, below which however, it was nearly temperature independent. The Hall coefficient suggested that they are n-type semiconductors.

• BMB Reports
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• v.30 no.4
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• pp.296-298
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• 1997

A bacterial glutathione S-transferase from Pseudomonas sp. DJ77 has been crystallized. The crystals diffract to at least $2.3\;\AA$ resolution, and belong to the orthorhombic space group $P2_{1}2_{1}2_{1}$, with cell parameters $a=97.4\;\AA,\;b=100.3\;\AA$, and $c=46.0\;\AA$. There is one dimer molecule of pGST per crystallographic asymmetric unit. with the crystal volume per protein mass of $2.34\;\AA^3/dalton$ and a solvent content of about 47% (v/v).

• Bulletin of the Korean Chemical Society
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• v.31 no.9
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• pp.2565-2570
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• 2010

The orthorhombic $MgB_2C_2$ structure contains well-separated parallel graphite-like $B_2C_2^{2-}$ layers which extend infinitely in two dimensions. Three possible ways to distribute B and C atoms in the hexagonal sublattice sites are adopted. Band structures for the hypothetical distribution patterns are examined to assess the electronic stability of these phases and to account for the observed arrangement by means of extended Huckel tight-binding calculations. The preferred choice is the layer with B and C alternating strictly so that B is nearest neighbor to C and vice versa. A rationale for this is given. Due to the alternation of B and C within the honeycomb layers, $MgB_2C_2$ is a band insulator, which through partial substitution of Mg with Li, is predicted to turn metallic with holes in the $\sigma$ bands at the Fermi level.

• Korean Journal of Crystallography
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• v.12 no.3
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• pp.141-144
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• 2001

From the reaction of Na[Ga(N₃)₄] with PPh₃, an ionic compound [Ph₃P(OH)]/sup +/[N₃]/sup -/ (1) was isolated. Compound 1 was characterized by spectroscopy (¹H-NMR, /sup 13C{¹H}-NMR, and IR) and X-ray diffraction. Crystallographic data for 1 : orthorhombic space group P2₁2₁2₁, a = 10.491 (4) Å, b=11.603(5)Å, c=13.149(5)Å, Z=4, R(wR₂)=0.0547(0.0978).

• Proceedings of the KIEE Conference
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• 2005.11a
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• pp.157-159
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• 2005

In this study, in order to develop Pb-free piezoelectric ceramics, $[Li_{0.04}(Na_{0.44}K_{0.52)-(Nb_{0.86}Ta_{0.10}Sb_{0.04})]O_3$ ceramics were fabricated by conventional mixed oxide method and their piezoelectric characteristics were investigated according to the poling condition. The transition temperature from orthorhombic phase to tetragonal phase observed at $93[^{\circ}C]$ and Curie temperature was $346[^{\circ}C]$. At $50[^{\circ}C]$ poling temperature, dielectric constant, electromecha nical coupling factor kp, piezoelectric $d_{33}$ const ant, coercive field Ec, remanant polarization Pr and mechanical quality factor Qm showed the optimum value of 737, 0.45, 209[pC/N], 1l.34[kV/cm], $7.14[{\mu}C/cm^2]$ and 205, respectively.