• Journal of Dairy Science and Biotechnology
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• v.35 no.4
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• pp.244-248
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• 2017

The effects of ultrasonic (1.2~1.7 kJ/g TS) pretreatment on the solubilization of dairy and livestock sludge were separately evaluated to investigate the possibility of recycling dairy sludge as a potential source of organic carbon. Compared to other industrial wastewater and sewage sludge, dairy sludge has higher organic matter content and no toxic materials. The solubilization rates of dairy and livestock sludge, at a specific energy input of 1.7 kJ/g TS, were 14.5% and 10.6%, respectively. After the 90-minute ultrasonic treatment, the soluble COD (chemical oxygen demand) increased about 7.1 times that of the initial SCOD, at an increase rate of $0.022m^{-1}$. In comparison, the increase in soluble nitrogen, which was ~3.4 times that of the initial soluble nitrogen concentration, was much smaller than the increase in SCOD; thus, the C/N ratio increased from 4.0 to 8.7.

• Journal of the Korea Organic Resources Recycling Association
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• v.27 no.3
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• pp.27-39
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• 2019

In this study, thermal-alkali pre-treatment (THAP) optimal condition and co-digestion efficiency with THAP of the mixture food waste and sewage sludge were evaluated for improving the performances of co-digestion for mixed food waste and sewage sludge. The optimal condition of THAP was evaluated for solubilization COD, CST(Capillary Suction Time), TTF(Time to Filter), and volatile fatty acids (VFAs) with THAP temperature and NaOH concentration. In addition, the co-digestion of mixed food waste and sewage sludge were evaluated using biochemical methane potential (BMP) test. The optimal THAP reaction temperature and NaOH concentration of food waste and sewage sludge were $140^{\circ}C$ and 60 meq/L to solubilization COD over 20%, CST and TTF under 60sec and VFAs concentration over 12,000 mg-COD/L, respectively. The optimal condition of co-digestion of mixed food waste and sewage sludge equal to THAP condition. Therefore, it was determined that the optimal condition of THAP reaction temperature and NaOH concentration for co-digestion of mixed food waste and sewage sludge were $140^{\circ}C$ and 60 meq/L, respectively.

• Journal of Korean Society on Water Environment
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• v.26 no.1
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• pp.81-88
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• 2010

This study was conducted to find the capability of comparison of overall oxygen transfer coefficient in the membrane coupled high performance reactor (MPHCR) in treating high organic loading wastewater. Effluent quality had been analyzed while the influent organic loading rate was changed from 2 to $7kg\;COD/m^3{\cdot}day$. The oxygen transfer coefficients had been investigated using two-phase nozzle for operating variables which were internal circulation flowrate (5~8 L/min), air flow rate (0.0125~0.2 L/min), liquid temperature ($10{\sim}20^{\circ}C$), and pure-oxygen flow rate (0.0125~0.2 L/min). The overall oxygen transfer coefficient was increased with flowrate of internal circulation and air and high temperature. Especially, internal circulation flow rate showed distinct effect on overall oxygen transfer coefficient due to an increase of gas holdup and air-liquid contract area by two-phase nozzle. In the high range of organic loading rate from 4 to $7kg\;COD/m^3{\cdot}day$, the removable efficiency of COD was 91%. Conventional activated sludge process usually treat organic loading from 0.32 to $0.64kg\;COD/m^3{\cdot}day$ however, the MPHCR can treat 10 to 20 times higher if it would be compared to the conventional activated sludge process. Foaming problem often happened and caused biomass wash out of the reactor, therefore, the foaming should be controlled for the enhanced operation.

• Journal of the Korea Organic Resources Recycling Association
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• v.12 no.1
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• pp.75-83
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• 2004

Temperature-phased anaerobic digestion (TPAD), anaerobic sequencing batch reactor (ASBR), and co-digestion technologies were combined together in order to overcome low efficiencies of conventional anaerobic sewage sludge digestion processes. In the performance, TPAD-ASBR process showed high VS removal efficiency over 60% up to the organic loading rate (OLR) of 2.7 g VS/L/d. The first-stage of TPAD-ASBR and control system played a most significant role in VS destruction and methane production. Methane production rate (0.79 l $CH_4/L/d$) of the system was higher than that (0.59 l $CH_4/L/d$) of the control system. The substrate characteristics of the sewage sludge, such as low VS concentration (1.5%, w/w) and biodegradability, were properly improved by the addition of food waste as a co-substrate, leading to more efficient VS removal and methane production. With several track studies, it was revealed that the independent solid retention time (SRT) of those systems prevented untreated particles from outflowing and also, extended the retention time of the active biomass for further degradation. Consequently, it was confirmed that the sequencing batch operation of the TPAD process using co-substrate was a promising alternative for the recycling of sewage sludge with low VS content.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.3
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• pp.110-116
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• 2016

Biogas yields point of view, the possibility of reusing excess sludge treated by thermal pretreatment for the purpose of improving the efficiency of the anaerobic digestion process has been investigated in recent year. Thermal pretreatment technology was considered as a pretreatment technique to improve excess sludge properties because of the solubilization of particulate organics. As a view point of sludge reduction and recycle, however, many researchers focused on the ability of particulate hydrolysis and COD solubilization under a high temperature, and few reports have addressed on the physical/chemical characteristics changing. This research was performed to evaluate the effects of a various temperature and chemical additives on carbon formation and fractionation in treated slurry from thermal pretreatment. Based on the results, it was revealed that oxidants injection and temperature changing have significantly caused the change of carbon fractions in slurry from thermal pretreament. Especially, it was considered that the efficiencies of particle hydrolysis increased with the increase of the reaction temperature. Low molecular weight(Mw < 350 g/mol) organic carbon formation increased with the increase of oxidants injection. It was expected that results of this research will provide an overview of the characteristics of thermal pretreatement for excess sludge reduction and recycle.

• Korean Journal of Environmental Agriculture
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• v.34 no.2
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• pp.91-97
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• 2015

BACKGROUND: Earthworms are essential detritus feeders that play a vital role in the process of decomposition of organic matter and soil metabolism. The complex process of partial breakdown of organic matter and mixing with mucous and gut microbial flora in the form of earthworm cast results in the reduction of the toxicity. This study focused on the change of cast amount and pollutant contents before and after the eating of the organic waste and upland soil with the two species of earthworm. METHODS AND RESULTS: The two species of earthworms were compared to the cast production. In the upland soil material, the daily amount of worm's cast was 1.42 g in E. andrei and 0.40 g in A. agrestis. In the organic waste material, the cast of E. andrei was 0.78~0.83 g and the cast of A. agrestis. have not been collected because all earthworms died after the treatment. The heavy metals treated in the upland soil were evaluated the impact of the worm excretion. With the E. andrei, the cast production was decreased 0.1~0.8 times in zinc, 0.2~0.5 times in copper, and 0.1~0.7 times in cadmium compared to the control treatment according to the levels of concentration. With A. agrestis, the cast amount was decreased 0.3~1.1 times in zinc, 0.2~0.3 times in copper, and 0.1~2.1 times in cadmium, respectively. The changes of pollutant contents before and after the eating of the organic wastes with E. andrei were studied. In the treatment of the Alcohol Fermentation Processing Sludge and the Fruit Juice Processing Sludge, heavy metal content of the cast was increased 0.7~53.3% compared to the sludge materials. PAHs contents were decreased 50.1% in the cast of the Alcohol Fermentation Processing Sludge and 36.6% in the cast of the Fruit Juice Processing Sludge, respectively. CONCLUSION: In conclusion, although the A. agrestis was bigger than E. andrei in size and weight, the cast amount of A. agrestis was small. The two species of earthworm was less excretion with high concentration of heavy metals. While the heavy metals such as zinc, copper, and cadmium were considerably accumulated in the cast, the total compounds, PAHs were fairly decomposed. There results would provide us for restoring contaminated soil and cleaning organic wastes.

• Proceedings of the Korean Environmental Health Society Conference
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• 2001.04a
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• pp.19-25
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• 2001

Recently in Korea, treatment and disposal of organic wastes have being the mostimportant is sue due to governmental strong regulation of landfill banning Especially the sewage sludge and food wastes will be restricted from the direct landfilling, after the year 2003 and 2005 respectively. Thus the considerable change in treatment methods of organic wastes is founded to transfer toward recycling the organic wastes, In these trends. vermicomposting is being enlightened newly in Korea. In November of 1999. the first symposium focusing the organic waste treatment using the earthworm was held with attending many peoples including earthworm company, experts. and professors. In that symposium, it was reported that the vermicomposting plants treating organic wastes had increased to about 80 plants and had treated about 110,000 tons per year in Korea Many local governments and companies showed the interest in vermicomposting of organic wastes and needed the collaboration with each other and foreign countries. In for reclamation materials, the extraction of some medical drugs from earthworm was expanding the research and development fields, In this paper, the history of vermicomposting in Korea was reviewed and the present stanls and future aspect were showed.

• Journal of the Korea Organic Resources Recycling Association
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• v.8 no.1
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• pp.109-120
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• 2000

In the analysis of the common categories, moisture contents and organic concentrations were not much different according to the types of industry or treatment facilities. When heavy metals contribution of the sludge from domestic and industrial wastewater treatment facilities was analyzed, As, Hg and Cr concentrations were relatively high among 42 standards of the fertilizer law. As concentration war higher in 28 of 42 facilities (67%) than limits of the fertilizer law. Hg concentration was not acceptable in the 21 of 42 facilities (50%). Cr concentration was not acceptable in 9 of 42 facilities (21%). From these results, It is found that As is the most frequently detectable component and contaminant than any other heavy metals in sludges. The data from this experiment was also compared with the guidelines of harmful organics and the rest of heavy metals that are regulated by some of the foreign countries. Be, Se and Mo concentrations were lower than the limits. Among the organics, the average concentration of PCB (10 samples) was 26.2 ppb. The highest concentration was 162.6 ppb in the sludge of the municipal wastewater treatment facilities and the lowest concentration was 2.14 ppb from the skin manufacturing industry. From the leaching analysis of re-manufacturing goods from the sludge, most of them was acceptable on the regulation law but Cr concentration was over the limit.

• Applied Chemistry for Engineering
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• v.22 no.2
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• pp.173-177
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• 2011

In this study, the formation of $AlPO_4$-type porous materials from alum sludge was investigated. The materials were synthesized by the reaction of aluminum hydroxide and phosphoric acid with an organic template. Cationic surfactant, natural humic acid, and amino acids were used for the organic template. The residual organic templates were removed by calcination at $600^{\circ}C$ in the air. Powder X-ray diffraction patterns showed the charicteristic patterns of the $AlPO_4$-type porous materials. The morphology of the material was examined using a scanning electron microscopy. The coordination environment of $Al^{3+}$ ion was investigated by $^{27}Al$ MAS NMR technique. Both tetrahedrally and octahedrally coordinated$Al^{3+}$ ions were found in the as-synthesized samples while all $Al^{3+}$ ions were tetrahedrally coordinated in the calcined products. The development of mesopore in the solid material was confirmed by the measurement of BET specific surface area. Finally, they were used for removal of toxic formaldehyde from the air and the formaldehyde molecules were adsorbed on the surface of pores. In conclusion, $AlPO_4$-type porous materials from alum sludge might be applicable in the removal of toxic volatile organic compounds from the air.

• Biotechnology and Bioprocess Engineering:BBE
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• v.5 no.6
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• pp.469-474
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• 2000

In order to enhance the degradation efficiency of waste activated sludge (WAS) by thermophilic aerobic digestion, an ultrasonic pretreatment was examined. It was observed that ultrasonic pretreatment increased the solubilization of organic matter in the WAS and that the solubilization ratio of the organics increased during the first 30 min but did not extensively increase thereafter. Therefore, a pretreatment time of 30 min was determined to be the economical pretreatment time from the experimental results. From the digestion experiments, which was conducted using the WAS collected from an oil refinery plant in Inchon, Korea, investigating the effects of an ultrasonic pretreatment on thermophilic aerobic digestion, it was confirmed that the proposed ultrasonic pretreatment was effective at enhancing the release of the cellular components in WAS and the degradation of released components in the thermophilic aerobic digestion.