• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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• pp.251-252
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• 2012

Recently, the growing interest in organic microelectronic devices including OLEDs has led to an increasing amount of research into their many potential applications in the area of flexible electronic devices based on plastic substrates. However, these organic devices require a gas barrier coating to prevent the permeation of water and oxygen because organic materials are highly susceptible to water and oxygen. In particular, high efficiency OLEDs require an extremely low Water Vapor Transition Rate (WVTR) of $1{\times}10^{-6}g/m^2$/day. The Key factor in high quality inorganic gas barrier formation for achieving the very low WVTR required ($1{\times}10^{-6}g/m^2$/day) is the suppression of defect sites and gas diffusion pathways between grain boundaries. In this study, we developed an $Al_2O_3$ nano-crystal structure single gas barrier layer using a Neutral Beam Assisted Sputtering (NBAS) process. The NBAS system is based on the conventional RF magnetron sputtering and neutral beam source. The neutral beam source consists of an electron cyclotron Resonance (ECR) plasma source and metal reflector. The Ar+ ions in the ECR plasma are accelerated in the plasma sheath between the plasma and reflector, which are then neutralized by Auger neutralization. The neutral beam energies were possible to estimate indirectly through previous experiments and binary collision model. The accelerating potential is the sum of the plasma potential and reflector bias. In previous experiments, while adjusting the reflector bias, changes in the plasma density and the plasma potential were not observed. The neutral beam energy is controlled by the metal reflector bias. The NBAS process can continuously change crystalline structures from an amorphous phase to nano-crystal phase of various grain sizes within a single inorganic thin film. These NBAS process effects can lead to the formation of a nano-crystal structure barrier layer which effectively limits gas diffusion through the pathways between grain boundaries. Our results verify the nano-crystal structure of the NBAS processed $Al_2O_3$ single gas barrier layer through dielectric constant measurement, break down field measurement, and TEM analysis. Finally, the WVTR of $Al_2O_3$ nano-crystal structure single gas barrier layer was measured to be under $5{\times}10^{-6}g/m^2$/day therefore we can confirm that NBAS processed $Al_2O_3$ nano-crystal structure single gas barrier layer is suitable for OLED application.

• Journal of the Optical Society of Korea
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• 제17권5호
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• pp.423-427
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• 2013

We present the preparation and characteristics of liquid-phase sensors based on nano-porous silicon multilayer structures for determination of organic content in gasoline. The principle of the sensor is a determination of the cavity-resonant wavelength shift caused by refractive index change of the nano-porous silicon multilayer cavity due to the interaction with liquids. We use the transfer matrix method (TMM) for the design and prediction of characteristics of microcavity sensors based on nano-porous silicon multilayer structures. The preparation process of the nano-porous silicon microcavity is based on electrochemical etching of single-crystal silicon substrates, which can exactly control the porosity and thickness of the porous silicon layers. The basic characteristics of sensors obtained by experimental measurements of the different liquids with known refractive indices are in good agreement with simulation calculations. The reversibility of liquid-phase sensors is confirmed by fast complete evaporation of organic solvents using a low vacuum pump. The nano-porous silicon microcavity sensors can be used to determine different kinds of organic fuel mixtures such as bio-fuel (E5), A92 added ethanol and methanol of different concentrations up to 15%.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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• pp.372-372
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• 2012

We have studied a fabrication of Poly (3,4-ethylenedioxythiophene) (PEDOT) wire arrays and structures with various feature sizes from hundreds micrometers to tens nanometers. PEDOT is well-known as a conducting material, can be grown by a vapor pressure polymerization (VPP) method. The VPP technique is a bottom-up processing method that utilizes the organic arrangement of macromolecules to easily produce ordered aggregates. Also, liquid-bridge-mediated nanotransfer molding (LB-nTM), which was reported as a new direct patterning method recently, is based on the direct transfer of various materials from a mould to a substrate through a liquid bridge between them. The PEDOT nanowires grown by VPP method and transferred on a substrate to use LB-nTM method have been investigated by Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Selected Area Electron Diffraction (SAED), X-Ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), and electrical properties.

• The Korean Journal of Ceramics
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• 제6권1호
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• pp.58-63
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• 2000

The preparation of Y-doped $SrZrO_3$powder by ultrasonic spray pyrolysis was investigated as a representative system, in order to produce fine, single phase multicomponent oxide powders. A precursor solution containing metal nitrates, citric acid and ethylene glycol was atomized glycol was atomized with an ultrasonic spray nozzle. Gel particles formed by organic functional groups were pyrolyzed and subsequently calcined at $800^{\circ}C$ to obtain well-crystallized, single perovskite phase. Most of large particles exhibited macroscopic pores and weak agglomeration between primary particles. However, strong agglomeration was observed in the surfaces of large particles. The effect of the microstructures of these particles on size reduction to submicron particles was described.

• 한국대기환경학회지
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• 제34권1호
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• pp.120-143
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• 2018

The analytical methods and their ambient levels of organic nitrogenous compounds such as nitrosamines, nitramines (nitroamines), imines, amides and nitro-polycyclic aromatic hydrocarbons (nitro-PAHs) in the atmosphere are summarized and discussed. Sampling for the analysis of organic nitrogenous compounds was mostly conducted using high volume air sampler. The direct liquid extraction (DLE) using sonification and the pressurized liquid extraction (PLE) using the accelerated solvent extraction (ASE) have been frequently employed for the extraction of organic nitrogenous compounds in the atmospheric samples. After extraction, clean-up via filtration and the solid phase extraction (SPE) and concentrations using nitrogen and rotary evaporator have been generally conducted but in some studies the clean-up and concentration steps have been omitted to prevent the loss of analyte and improve the recovery rate of the analytical procedure. Instrumental analysis was mainly carried out using gas chromatography (GC) or the high performance liquid chromatography (HPLC) coupled with the single quadrupole mass spectrometer or tandem mass spectrometer in the electron ionization (EI), positive chemical ionization (PCI) and negative chemical ionization (NCI) mode and analysis sensitivity of nitrosamines and nitramines were higher in NCI mode. Desirable sampling and analysis methods for analyzing particulate organic nitrogenous compounds are suggested.

• 한국전기전자재료학회논문지
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• 제22권1호
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• pp.53-60
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• 2009

$ZrTiO_4$ dielectric thin films were coated by metal-organic decomposition, and annealed by rapid thermal processing up to $900^{\circ}C$ for their crytallization. Crystallized single-phase $ZrTiO_4$ thin films were fabricated above the annealing temperature of $800^{\circ}C$, but their grains were randomly oriented without specific textured orientation. Best dielectric properties were presented by the sample annealed at $800^{\circ}C$ which had crystalline structure and flat surface. Dielectric constant of the film was maintained at 32 throughout full frequency range up to 6 GHz, and dielectric loss was varied between 0.01 and 0.04.

• Korean Chemical Engineering Research
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• 제50권6호
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• pp.1021-1026
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• 2012

단일 액적 시스템에서의 비정상상태 물질 전달에 대한 연구를 진행하였다. 단일 액적계를 위한 이성분계로는 옥탄올(연속상)-물(분산상) 시스템이 이용되었으며 동반되는 불균일 반응으로는 아민추출제(tri-n-octylamine,TOA)를 이용한 숙신산 추출 반응을 모델 시스템으로 선정하였다. 점도, 밀도, 용질의 분배계수, 연속상에서 하강하는 액적의 종말 속도, 용질과 추출제의 확산계수 등과 같은 시스템의 기본 특성을 파악하기 위한 실험과 이론적 계산들이 수행되었다. 액적의 종말 속도는 숙신산 농도에는 크게 영향을 받지 않는 것으로 보이나 TOA가 없을 때는 숙신산 농도에 따라 약간 증가하는 경향을 보였고, TOA 농도 증가와 함께 감소하였다. 액적의 낙하는 수직 낙하 경로를 기준으로 좌우로 진동하면서 움직이는 경향을 보였다. 낙하하는 액적에서의 물질 전달 관찰을 위해 물질 전달 셀을 제작하여 시간에 따른 액적 내의 평균 농도 변화를 관찰하였고, 그 결과를 무차원 변수를 이용하여 해석하였다. 50 g/L의 숙신산 농도 조건하에서 TOA 농도를 0.1과 0.5 mol/kg 으로 조절하였을 때, 전자의 경우에는 관찰 시간 범위 내에서 일정한 Sh 값을 유지하여 용질의 이동 방향으로의 농도 기울기가 감소함에 따라 훌럭스도 그에 비례하여 감소함을 알 수 있었지만, 후자의 경우에는 시간의 경과와 함께 Sh가 급격히 증가하는 현상을 보여 계면에서의 숙신산 훌럭스 감소에 비해 농도기울기 감소가 상대적으로 빠르게 일어남을 알 수 있다.

• Bulletin of the Korean Chemical Society
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• 제26권12호
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• pp.1996-2000
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• 2005

Headspace hanging drop liquid phase micro-extraction (HS-HD-LPME) is studied as a novel solvent-based sample pretreatment method for floral volatile aroma compounds. This paper reports on application of the HSHD- LPME combined with GC-MS for the analysis of linalool component emitted from evening primrose flowers. The effect of several variables on the method performance was investigated. Additionally, the separation of enantiomers on a cyclodextrin capillary column was performed to identify chirality of (−)-linalool component. Since the unsurpassed volume of a few micro-liters of solvent is used, there is minimal waste or exposure to toxic organic solvents. This method enables to combine extraction, enrichment, clean-up, and sample introduction into a single step prior to the chromatographic process.

• 한국응용약물학회:학술대회논문집
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• 한국응용약물학회 2003년도 Annual Meeting of KSAP : International Symposium on Pharmaceutical and Biomedical Sciences on Obesity
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• pp.105-105
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• 2003

A rapid and reproducible high performance liquid chromatographic assay of prazosin in human plasma was developed. After addition of internal standard (IS, terazosin hydrochloride) and alkalization of the plasma, the drug and IS were extracted into t-butylmethylether. The organic phase was back-extracted into 0.05% phosphoric acid and 50 ${\mu}\ell$ of the acid solution was injected into a reverse-phase C18 column with a mobile phase consisting of water : acetonitrile : triethylamine = 75 : 25 : 0.1 (pH 5.0). The samples were detected utilizing a fluorescence detector. A

• 한국산학기술학회논문지
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• 제17권6호
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• pp.588-597
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• 2016

본 연구는 유기성폐기물의 혼합슬러지를 개량형 단상 혐기성 소화공정에서 각각의 혼합비율에 따른 바이오가스 생산효율 향상에 관한 연구로, 연구에 사용된 유기성폐기물의 종류는 하수 생슬러지, 음폐수 및 가축분뇨이다. BMP test를 통해 잠재적 메탄발생량을 확인한 결과 단일시료의 경우 가축분뇨가 $1.55m^3CN4/kgVS$로 가장 높게 평가되었고, 혼합시료(생슬러지, 음폐수, 가축분뇨)의 경우는 각각의 비율을 50% : 30% : 20%로 하였을 때 $0.43m^3CN4/kgVS$로 가장 높게 나타났다. 반면 실증플랜트에서 혼합슬러지 최적 혼합비율은 생슬러지(68.5) : 음폐수(18.0) : 가축분뇨(13.5)로 나타나 BMP test와 다소 상이한 결과를 보였다. 이는 혼합슬러지 성상변화와 체류시간 등 소화조 운전조건 변화에 기인한 결과로 판단되며, 단상 혐기성 소화조의 바이오가스 생산량이 $2,514m^3/d$, 메탄함량 62.8%로 조사되어 설계능력인 바이오가스 생산량 $2,319m^3/d$ 기준으로 볼 때 최대성능을 발휘하는 것으로 평가되었다. 아울러 본 연구를 통해 혐기성 소화방식에 있어 소화조의 안정적인 운영과 소화효율 측면에서 고효율 방식인 2상 소화방식을 도입하는 것이 유리하나 기존의 단상 소화방식에 있어서도 소화효율 개선 및 성능향상이 가능하다는 것을 알 수 있었다.