• 제목/요약/키워드: organic pollution load

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수질오염총량관리제에서 난분해성 유기물질 관리 필요성 및 개선방안 (Necessity of Refractory Organic Matters Management in Total Maximum Daily Loads (TMDLs))

  • 박재홍;박배경;이재관;류덕희
    • 한국물환경학회지
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    • 제29권3호
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    • pp.393-399
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    • 2013
  • To control organic matters, it needs to manage not only biodegradable organic matters but also refractory organic matters. Refractory organic matters from municipal wastewater, industrial wastewater, non-point sources and etc., have been continuously discharged to the near watersheds. It is estimated that the refractory organic matter ratios are continuously increased in waterbody. In watersheds of the Total Maximum Daily Loads (TMDLs), it was investigated that COD/BOD ratios increased in many unit watersheds of the 4 major river basins. The portions COD/BOD ratios increased were found to be a 97% of Geum River unit watersheds, a 81% of Yeongsan/Seumjin River unit watersheds, a 78% of Nakdong River unit watersheds, a 70% of Han River unit watersheds, respectively. Therefore, it has become important for establishment of effective management strategies to control refractory organic matter in watersheds of the Total Maximum Daily Loads (TMDLs). In order to properly manage organic matters including refractory organic matters, the present organic indicator (BOD) has to be converted to TOC (or COD). Compared to COD and BOD, TOC, as a organic matter indicator, is evaluated more appropriate.

함평만의 유입오염부하량 및 물질수지에 관한 연구 (A Study on the Inflowing Pollution Load and Material Budgets in Hampyeong Bay)

  • 김종구;장효상
    • 해양환경안전학회지
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    • 제22권1호
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    • pp.1-10
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    • 2016
  • 본 연구에서는 함평만의 육상기인오염 물질의 유입특성을 파악하고, 물질순환을 정량화하기 위해, Simple box model을 적용하였다. 함평만의 하천 유입 오염부하 특성을 보면, BOD, COD, TOC의 평균 유기물질 오염부하가 각각 79.7 kg-BOD/day, 144.06 kg-COD/day, 93.0 kg-TOC/day를 나타내었다. 하천별 유기물 유입 오염부하량은 손불 방조제>주포교>양만단지 순으로 나타났다. 계절별로는 하계 강우시기인 7월에 높은 부하 특성을 보였다. 영양염류의 평균 유입 오염부하는 각각 20.9 kg-DIN/day, 17.1 kg-DIP/day, 148 kg-TN/day, 37.4 kg-TP/day를 나타내었다. 하천별 영양염 유입부하량은 양만단지>백옥교>주포교 순으로 나타났다. 박스모델을 이용한 함평만 물질수지에서 담수체류시간은 52.4일로 해수교환이 낮은 반 폐쇄성 해역의 특성을 나타내었다. 영양염 물질수지에서 용존 무기질소의 경우 ${\Delta}DIN$이 (-)의 탈질상태를 나타내어 유입된 질소보다 광합성에 의한 소비 및 외해 유출이 큰 경향을 보였다. 용존 무기인의 경우 ${\Delta}DIP$가 (+)를 나타내어 유기물 분해에 의한 공급, 퇴적물의 용출부하, 하천 유입부하가 식물플랑크톤에 의한 소비 및 외해 유출보다 큰 것으로 나타나 축적되는 경향을 보였다.

한강권역 우심지류 하천의 유기물 분포 특성 (The Distribution Characteristics of Organic Matters in the Contaminated Tributaries of Han River Region)

  • 김호섭;박윤희;김용삼;김상용
    • 한국물환경학회지
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    • 제34권5호
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    • pp.494-502
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    • 2018
  • The purpose of this study was to understand distribution characteristics of organic matters through concentration of $BOD_5$, $COD_{Mn}$ and TOC in 31 streams in Han River region, and to establish the relationship among organic matter concentration, and discharge load and flow rate. Concentration of $BOD_5$ and TOC in 22 streams were above IV grade except 9, and the average 80.9 % of total organic matter (by TOC) accounted for dissolved organic type. Correlation among organic matter parameters were higher ($r^2$ > 0.78) and the relationship between TOC and $COD_{Mn}$ concentration was higher than $BOD_5$. Ratio of biodegradable organic matter/total organic matter in the 31 streams was estimated at 41.4 % with $BOD_5$ oxidation rate, and 78.0 % with $BOD_5/COD_{Mn}$ concentration ratio. Ratio of $NBOD/BOD_5$ concentration in four sites with $BOD_5/COD_{Mn}$ concentration ratio exceeding 1 ranged from 54.5 % ~ 79.3 %. Among 979 flow rate data measured at 31 streams, 87 % of measured data was below 0.1 cms and increased water pollution under low flow conditions. Correlation between $BOD_5$ concentration and $BOD_5$ discharge load in the watershed was low, and it was revealed that several streams have more $BOD_5$ delivery load than $BOD_5$ discharge load. Results suggest that many biodegradable forms of organic matter are being introduced into the stream from pollutant sources in the watershed.

경작지에서 볏짚거적의 비점오염물질 저감 평가 (Evaluation of NPS Pollutant Reduction of Rice Straw Mats in Field)

  • 원철희;신민환;최용훈;임경재;한영한;권재혁;최중대
    • 한국농공학회논문집
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    • 제55권4호
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    • pp.37-44
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    • 2013
  • We have examined the effect of rice straw mat (RSM) on the reduction of non-point source (NPS) pollution loads at soybean cultivations. The slope of the experimental plot was about 3 %. Monitoring was carried out for four years at conventional tillage (CT) in 2008~2009 years and RSM covered tillage in 2010~2011 years. Thirty-two rainfall events were monitored and analyzed during the study period. During the 2 years of 2008 and 2009, 20 rainfall runoff events were monitored. But in 2010 years, only 2 rainfall runoff events could be monitored. And in 2011 years, 10 rainfall runoff events was monitored. It was because the RSM cover enhanced infiltration and reduce runoff in 2010 and 2011. Average NPS pollution load (organic matters) of the RSM covered field was reduced by 72.1~94.2 % compared to that of CT field. NPS pollution load of TN and TP reduced by 67.5 % and 55.7 %, respectively. Especially, SS pollution load was reduced by 97.3 %. Based on the results, rice straw mat cover was considered as a promising best management practices (BMP) to reduce NPS pollution load. However, it was recommended that the results are limited to the field conditions and the same experiments must be performed on different soil textures, slopes, and crops if it is applied to the development of policies.

해수운동모델을 이용한 황해 환경용량의 개략 산정 (A Rough Estimation of Environmental Capacity in the Yellow Sea using a Numerical Hydrodynamic Model)

  • 김광수;김동명;박청길
    • 한국해양환경ㆍ에너지학회지
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    • 제2권1호
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    • pp.63-73
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    • 1999
  • 3파원 해수유동모델을 이용하여 황해의 잔차류를 시뮬레이션한 결과, 북위 34° 25' 위도선을 통한 잔차류량은 조석주기당 약 4km³, 체류시간은 약 6년으로 산성되었고, 황해의 남동 경계선을 통한 잔차류량은 조석주기당 약 13km³, 체류시간은 약 2.5년으로 산정되었다. 황해의 용존산소량은 하계의 해수중 용존산소를 5.0mg/ℓ이상으로 유지하면서, 약 58×10/sup 6/ton의 화학적 산소요구량(COD)윽 수용할 수 있으므로, 유기오염 부하량의 한계로 표현한 황해의 환경용량은 황해고 유입하는 주요 하천들의 연간 유기오염 부하량의 약 8배에 해당한다. 하계에 있어서, 북위 34ℓ 25' 위도선의 전체 수층을 통한 잔차류량은 하루에 약 57×10³ton의 용존산소를 수송하고, 또한 황해의 남동 경계선의 전체 수층을 통한 잔차류량은 하구에 약 203×10³ton의 용존산소를 수송하는 것으로 산정되었다. 따라서 황해가 해수중의 용존산소를 전혀 감소시키지 않고, 유입 하천의 유기오염 부하량을 수용할 수 있는 환경용량은, 북위 34° 25' 위도선을 통한 잔차류에 의한 용존산소 수송량을 기준으로 표현할 경우에는 황해고 유입하는 주요 하천들의 화학적 산소요구량(COD) 부하의 약 3배에 해당하고, 또한 황해의 남동 경계선을 통한 잔차류에 의한 용존산소 수송량을 기준으로 표현하면, 황해로 유입하는 주요 하천들의 화학적 산소요구량(COD) 부하의 약 10배에 해당한다.

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인공강우를 이용한 축산 자원화물의 비점오염 배출 특성 분석 (Analysis of Livestock Resources on NPS Pollution Characteristics by Rainfall Simulation)

  • 원철희;최용훈;신민환;서지연;최중대
    • 한국농공학회논문집
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    • 제53권2호
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    • pp.67-74
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    • 2011
  • This research focused on the investigation of runoff and nonpoint sources (NPS) pollution characteristics from small soil box plots treated by livestock waste composts. An indoor rainfall simulation was performed over the plots for 60 minutes. Simulated rainfall intensities were 32.4, 43.2, 50.3 and 57.1 mm/hr respectively. Slope of soil box plots was $10^{\circ}$ and $20^{\circ}$, respectively. Rainfall simulation replicated 5 times and the experiment was conducted every four days five times. As the slope of soil box increased, NPS pollution loads increased. And as rainfall intensity was increased from 32.4 to 57.1 mm/hr, NPS pollution loads gradually increased, too. Discharge of NPS pollution loads was the largest in the first simulation and thereafter decreased gradually. Discharged BOD load to the total applied load from $10^{\circ}$ plots, ranged 0.2 to 0.7 %, was 8.4 to 50.0 % lower than slope $20^{\circ}$ plots. When the application rate increased twice, the increase of pollution load was between 1.7~5.7 times. Analysis of Pearson's correlation coefficient showed that organic matter content in pig compost and NPS pollution loads were correlated well. While under liquid compost application, the correlation coefficients between them were not good. It was concluded that application of livestock resources need to consider long-term weather forecast and if necessary, NPS reduction measures must be preceded in order to reduce NPS pollution discharge.

부산지역 도시하천 표층 퇴적물 오염도 평가에 관한 연구 (Contamination Assessment of Surface Sediments in Urban Rivers, Busan)

  • 곽진숙;손정원;김주인;송복주
    • 한국물환경학회지
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    • 제37권4호
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    • pp.296-305
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    • 2021
  • This work investigated heavy metal pollution in surface sediments of rivers in Busan, Korea. Surface sediments were analyzed in order to conduct contamination assessment of organic matter, nutrients, and heavy metal concentrations. Contamination assessment of heavy metals was conducted using geoaccumulation index (Igeo), pollution load index (PLI), and potential ecological risk index (RI). Accumulation of organic matter and nutrients were affected by water discharged from sewage treatment plant. The concentrations of organic matter and nutrients were found to be greater in points which were close to the sewage treatment plant more than points furthest. The concentrations of Pb, Zn, Cu, Cd, Hg, As, Cr, and Ni were found to be greater in surface sediment more than in the background. The mean concentrations of heavy metals were in the order of Zn (323.5 mg/kg) > Cu (70.5 mg/kg) > Pb (39.8 mg/kg) > Cr (33.4 mg/kg) > Ni (13.5 mg/kg) > As (9.4 mg/kg) > Cd (0.84 mg/kg) > Hg (0.092 mg/kg). The result of geoaccumulation indices indicated that Hg > Cr > Cu > Ni > Zn > As > Pb > Cd were found in order of severe contamination by heavy metals. From PLI and RI analysis, it was evident that the Suyeonggang 2 was the most contaminated river.

울산 태화강 하구역 퇴적물의 유기물 및 미량금속 오염도 평가 (Evaluation of Pollution Level for Organic Matter and Trace Metals in Sediments around Taehwa River Estuary, Ulsan)

  • 황동운;이인석;최민규;김청숙;김형철
    • 한국수산과학회지
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    • 제48권4호
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    • pp.542-554
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    • 2015
  • Grain size, the content of ignition loss (IL), and the concentrations of chemical oxygen demand (COD), acid volatile sulfide (AVS), and trace metals (Fe, Mn, Cu, Pb, Zn, Cd, Cr, As, and Hg) in surface sediments from the Taehwa River estuary, Ulsan, were measured to evaluate pollution levels and potential ecological risks of organic matter and trace metals in estuarine sediment. The mean grain size (Mz) of sediments in the study region ranged from $-0.8-7.7{\varphi}$ (mean $2.8{\pm}2.4{\varphi}$). Surface sediments in the upstream region of the Taehwa River were mainly composed of coarse sediments compared to the downstream region. The concentrations of IL, COD, AVS and trace metals in the sediment were much higher at downstream sites of Myeongchon Bridge in the vicinity of industrial complexes than at upstream sites of those in the vicinity of the residential areas due to the anthropogenic input of organic matter and trace metals by industrial activities. On the basis of several geochemical assessment techniques [sediment quality guidelines (SQGs), enrichment factor (EF), geoaccumulation index ($I_{geo}$), pollution load index (PLI) and ecological risk index (ERI)], the surfaces sediments in the study region are not highly polluted for trace metals, except for As. However, the higher concentrations in downstream study regions of the Taehwa River could impact benthic organisms including shellfish (i.e. Manila clam) in sediments.

간척지 담수호유역의 오염물질 배출구조 및 시공간적 유출특성 (Characteristics of Pollution Source Structures and Temporal and Spatial Discharge from the Drainage Basin of a Reclaimed Area)

  • 엄명철;공동수;정동일;권순국
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 1999년도 Proceedings of the 1999 Annual Conference The Korean Society of Agricutural Engineers
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    • pp.739-746
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    • 1999
  • Discharge characteristics of organic materials and nutrients were estimated in the catchment area of relaimed area-Saemankeum-. Discharge load of BOD5 was high in the domestic system, while nitrogen and phosphorous were discharged mainly from the livestock system and the land . Load was so dependent on the precipitation that it increased in the rainy season, particulary in nitrogen and phosphorus. Loads from nonpoint sources in this area were higher compared with others.

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강우시 고속도로 노면 유출 오염부하 발생 특성 분석 (Relationship between Pollutant and Influence Factors in Highway runoff)

  • 강희만;이두진;배우근;강혜진
    • 상하수도학회지
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    • 제26권1호
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    • pp.47-54
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    • 2012
  • This study analyzed influence factors and the correlation among pollutants which affect occurrence of leaked pollution based on the long-term runoff flow and water quality investigation results to understand the characteristics of highway rainfall runoff pollution load. According to the result of correlation analysis on TSS (Total Suspended Solid) concentration, anteceded dry days, rainfall intensity, traffic volume and etc. as major influence factors of highway rainfall runoff pollution loads, the correlations were weak or scarce in most items. These results might be attributed that runoff pollutant concentration changes vary severely on changes of rainfall intensity and rainfall duration within rainfall and it is affected by disturbances of vehicles and street cleaning and etc. as characteristics of the highway. While Cu, Fe and Zn which are discharged with high concentrations out of heavy metals showed high correlation with particulate matter, organic matter(COD), nutrient(TN, TP), Ni and Pb showed relatively low correlation in a correlation evaluation by pollutant. Significant correlation with traffic volumes was not shown and TSS concentration even decreased in accordance with increase of the traffic volume. In the comparison with precedent studies, it was considered necessary additional analysis of the effects of rainfall section analysis, road type, disturbances of surface contaminants by vehicles, rainfall and climate conditions, surrounding terrains etc.