• Title/Summary/Keyword: organic dye

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Organic Electroluminescence Device using Dye doped Emitting (색소 doped 유기EL 소자에 의한 고효율화)

  • 임장순;강성종;노병규;오환술
    • Proceedings of the IEEK Conference
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    • 2000.11b
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    • pp.261-264
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    • 2000
  • Organic light emitting diodes(OLEDs) have been expected to find an application as a new type of display since C. W. Tang and VanSlyke first reported on high performance OLEDs. This paper has been stuied a green organic EL device using dye doped emitting layer such as C6(Coumarin 6). In the Alq-based e]ectroluminescence diodes, we applied highly fluorescent molecular(Coumarin 6) and obtained enhancement in the electroluminescence efficiency.

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A Study on Silver Dye Bleach Process for the Development of Color-photography (천연색 사진현상에서 은색소 표백법에 관한 고찰)

  • 박경환
    • Journal of the Korean Graphic Arts Communication Society
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    • v.1 no.1
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    • pp.43-48
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    • 1983
  • For the development of colored-proto grapby, the silver dye blech processes were extensively studied. For the first time, the developed silver was main catalyst, but recently active organic compounds are widely used as organic catalyst. They were guinoxaline and phenazine derivatives and it may forrned protonated free radical(${AH_2}^+$) under the presence of strong acid. Herewith the chemical reaction involved those catalyst and it's kinetic theory were described. Also, properties of the product with organic catalyst and improved process was reviewed.

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Photocatalytic degradation of textile dye CI Basic Yellow 28 wastewater by Degussa P25 based TiO2

  • Konecoglu, Gulhan;Safak, Toygun;Kalpakli, Yasemen;Akgun, Mesut
    • Advances in environmental research
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    • v.4 no.1
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    • pp.25-38
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    • 2015
  • Wastewaters of textile industry cause high volume colour and harmful substance pollutions. Photocatalytic degradation is a method which gives opportunity of reduction of organic pollutants such as dye containing wastewaters. In this study, photocatalytic degradation of C.I. Basic Yellow 28 (BY28) as a model dye contaminant was carried out using Degussa P25 in a photocatalytic reactor. The experiments were followed out at three different azo dye concentrations in a reactor equipped UV-A lamp (365 nm) as a light source. Azo dye removal efficiencies were examined with total organic carbon and UV-vis measurements. As a result of experiments, maximum degradation efficiency was obtained as 100% at BY28 concentration of $50mgL^{-1}$ for the reaction time of 2.5 h. The photodegradation of BY28 was described by a pseudo-first-order kinetic model modified with the langmuir-Hinshelwood mechanism. The adsorption equilibrium constant and the rate constant of the surface reaction were calculated as $K_{dye}=6.689{\cdot}10^{-2}L\;mg^{-1}$ and $k_c=0.599mg\;L^{-1}min^{-1}$, respectively.

Coloration behaviors of phthalocyanine reactive dye on nylon substrates: experiments, empirical modeling and statistical analysis

  • Kim, Byung-Soon;Ravikumar, K.;Yoon, Seok-Han;Son, Young-A
    • Textile Coloration and Finishing
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    • v.19 no.2
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    • pp.14-23
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    • 2007
  • This research article explores the use of phthalocyanine reactive dye on nylon substrate. The effect of factors such as pH, temperature, liquor ratio and alkali addition on level of dye exhaustion, fixation and total fixation efficiency. Low pH, high temperature and low liquor ratio were found to be suitable conditions for maximum % exhaustion values. The effect of sulphatoethylsulphone(SES) and vinylsulphone(VS) form of the dyes on level of dye fixation was also discussed. The optimized exhaustion (%E), fixation(%F) and total fixation efficiency were determined. Modification of the dyeing process with alkali addition displayed that dye fixation(%) increased by alkali addition. Vinylsulphone(VS) moiety of the dye was found to be superior to. maximum fixation (%F). Appropriate predictable empirical models, relatively a new approach in dyeing processes, were developed incorporating interactions effects of temperature, pH and liquor ratio for predicting % exhaustion, fixation and total fixation efficiency. The significance of the mathematical model developed was ascertained using microsoft excel regression(solver) analysis module. High correlation coefficient was obtained (R2=0.9895 for % exhaustion, R2=0.9932 for fixation, R2=0.9965 for total fixation efficiency) for the model which shows prominent prediction capacity of the model for my conditions. The predictable polynomial equations developed from tile experimental results were thoroughly analyzed by ANOVA (Analysis of Variance) statistical concepts.

Synthesis of Metal-free Organic Dye for Dye-sensitized Solar Cell (염료감응 태양전지를 위한 무금속 유기염료의 합성)

  • Pattarith, K.;Pungwiwat, N.;Laosooksathit, S.
    • Journal of the Korean Chemical Society
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    • v.55 no.2
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    • pp.279-282
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    • 2011
  • Dye-sensitized solar cell (DSSC); an alternate energy source harvester has gained some attractive features such as high-energy conversion efficiency low production cost. Dye-sensitizer is a basic component of DSSC, which affecting the performance of the energy conversion efficiency. Current research has been focusing on development of high efficiency, metal-free dye-sensitizers, which would be more environmental friendly. We had successfully explored synthetic route to 6,6'-(1,2,5-oxadiazole-3,4-diyl)dipyridine-2,4-dicarboxylic acid (3A) which has been used as organic sensitizer. Investigation of light conversion efficiency (${\eta}$) of the compound uses standard measurement condition (one sun simulated irradiation, AM 1.5, 100 mW/$cm^2$) showed that it could reach 1.00% ($J_{SC}=2.63\;mAcm^{-2}$, $V_{OC}$=0.64 V and FF=0.59). Under the same conditions, the ruthenium complex (N719) gave the conversion efficiency as high as 4.02%($J_{SC}=10.50\;mAcm^{-2}$, $V_{OC}$=0.67V and FF=0.57).

Effect of Dye Wastewater on Heavy Metal Removal using Carboxylated Alginic Acid Bead (Carboxylated alginic acid bead를 이용한 중금속 제거에 대한 염료폐수의 영향 연구)

  • Jeon, Choong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.4
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    • pp.74-80
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    • 2009
  • Effect of dye wastewater on heavy metal removal using carboxylated alginic acid bead was performed. When carboxylated alginic acid bead was used as support, effect of dye wastewater on adsorption of $Pb^{2+}$ and $Cu^{2+}$ ions was very small. Also, when $Pb^{2+}$ was coexisted with dye wastewater, adsorption process was almost completed within 2-3 hrs and $Pb^{2+}$ ions (50 ppm) was almost removed with 0.3g of bead. This result means that carboxylated alginic acid bead has effective adsorbent for heavy metal removal in dye wastewater.

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The Luminance characteristics of Red OELD based on Znq$_2$ and dye (Znq2와 dye에 의한 적색 OELD의 발광특성)

  • 조민정;최완지;박철현;임기조;박수길;김현후
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.358-360
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    • 2001
  • In this study, the bis(8-oxyquinolino)zinc II (Znq$_2$) were synthesized successfully from zinc chloride (ZnC1$_2$) as a initial material. Then, we fabricated red organic electroluminescent device with a dye (DCJTB)-doped and inserted Znq$_2$ between emission layer and cathode layer for increasing EL efficiency. The hole transfer layer is a N,N'-diphenyl-N,N'-bis-(3-methyl phenyl) -1,1'-diphenyl-4,4'- diamine(TPD), and the host material of emission layer is Znq$_2$. And we study the electrical and optical properties of devices. We found that the device using Znq$_2$ inserting layer result in the increased efficiency.

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Effective Interfacial Trap Passivation with Organic Dye Molecule to Enhance Efficiency and Light Soaking Stability in Polymer Solar Cells

  • Rasool, Shafket;Zhou, Haoran;Vu, Doan Van;Haris, Muhammad;Song, Chang Eun;Kim, Hwan Kyu;Shin, Won Suk
    • Current Photovoltaic Research
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    • v.9 no.4
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    • pp.145-159
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    • 2021
  • Light soaking (LS) stability in polymer solar cells (PSCs) has always been a challenge to achieve due to unstable photoactive layer-electrode interface. Especially, the electron transport layer (ETL) and photoactive layer interface limits the LS stability of PSCs. Herein, we have modified the most commonly used and robust zinc oxide (ZnO) ETL-interface using an organic dye molecule and a co-adsorbent. Power conversion efficiencies have been slightly improved but when these PSCs were subjected to long term LS stability chamber, equipped with heat and humidity (45℃ and 85% relative humidity), an outstanding stability in the case of ZnO/dye+co-adsorbent ETL containing devices have been achieved. The enhanced LS stability occurred due to the suppressed interfacial defects and robust contact between the ZnO and photoactive layer. Current density as well as fill factors have been retained after LS with the modified ETL as compared to un-modified ETL, owing to their higher charge collection efficiencies which originated from higher electron mobilities. Moreover, the existence of less traps (as observed from light intensity-open circuit voltage measurements and dark currents at -2V) are also found to be one of the reasons for enhanced LS stability in the current study. We conclude that the mitigation ETL-surface traps using an organic dye with a co-adsorbent is an effective and robust approach to enhance the LS stability in PSCs.

Luminance Characteristics of a Novel Red-Light-Emitting Device Based on Znq2 and Dye

  • Cho, min-Jeong;Park, Wan-Ji;Lee, Jeong-Gu;Lim, In-Su;Lim, Kee-Joe;Kim, Hyun-Hoo
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.2
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    • pp.16-19
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    • 2002
  • In this study, a novel red emitting organic electroluminescent (EL) device was fabricated with the bis(8-oxyquinolino)zinc II (Znq2) doped dye as an emitting layer. The Znq2 was synthesized successfully from zinc chloride (ZnC1$_2$) as an initial material. Then, we fabricated the red organic EL device with a dye (DCJTB) doped and inserted Znq2 between emission layer and cathode for increasing EL efficiency. The hole transporting layer is a N,N'-diphenyl-N,N'-bis-(3-methylphenyl)-1,1'-diphenyl-4,4-diamine (TPD), and the host material of emission layer is Znq2. And the electrical and luminance characteristics of the device were measured. We found that the EL device with Znq2 inserting layer results in the increasing luminance efficiency.