• Title/Summary/Keyword: organic combination

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Barrier property Enhancement of Plastic Substrates for Flexible Display by Inorganic-organic Hybrid Multilayer

  • Kim, Hyun-Gi;Ryu, Hyun-Sun;Kim, Sung-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.617-619
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    • 2008
  • Inorganic-organic hybrid multilayers were formed on the plastic substrate to enhance the barrier properties of substrate to water vapor and oxygen transport. Plasma pretreatment of substrate with $Ar/O_2$ lead to adhesion improvement and the densification of inorganic layer on the substrates. Combination of $SiO_xN_y$ layer and silanenanoclay composite layer offered quite good barrier properties (WVTR and OTR) to PES substrate.

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유기수은 유발 뇌손상에 미치는 셀레늄의 작용기전 및 전자현미경적 관찰

  • Jhoo, Wnag-Kee;Kim, Hyoung-Chun;Song, Ke-Yong
    • Toxicological Research
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    • v.7 no.1
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    • pp.73-81
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    • 1991
  • The present study was performed to explore the antioxidant effect of selenium on damaged brain induced by organic mercury. Male ICR mice were given consecutively 7 injections for 7 days of : (I) sodium selenite 1 mg/kg s.c. alone, (2) methylmercuric chloride 10mg/kg s.c. alone, (3) methylmercuric chloride simultaneously in combination with sodium selenite, and (4) saline alone as control respectively. Based on the above protocol, we monitored various oxyradical scavenging system as well as the finding of electron microscopy. The results from brain tissues were as follows` 1. Selenium inhibited the rate of generation of superoxide radical.

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The Effects of Preozonation on Organic Removal in Biological Activated Carbon Fluidized Bed (생물활성탄 유동상에서 전오존처리가 유기물 제거에 미치는 영향)

  • 우달식;곽필재;남상호
    • Journal of environmental and Sanitary engineering
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    • v.13 no.1
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    • pp.166-173
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    • 1998
  • This study was to investigate the effects of preozonation on the waterborne organic removal by the biologically active GAC fluidized bed on a laboratory scale. The raw water to be treated comes from midstream of Han river. As the ozone dose was increased in the range of $1~3{;\}mgO_{3}/mgDOC$, it produced BDOC from 1.82 to 2.65 times. And BDOC formation can be expressed as [BDOC] = 0.74 + 0.21[DOC] ($R^{2}{\;}={\;}0.8399$). The effects of combination of ozonation followed by BACFB (Biological Activated Carbon Fluidized Bed) process were analyzed. At the ozone doze of $1~3{\;}mgO_{3}/mgDOC$, the large fraction of BDOC was removed by BACFB, but parameter revealed only around 10% reduction.

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Mixed Electrolytes of Organic Solvents and Ionic Liquid for Rechargeable Lithium-Ion Batteries

  • Choi, Ji-Ae;Shim, Eun-Gi;Scrosati, Bruno;Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3190-3194
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    • 2010
  • Mixed electrolytes formed by the combination of 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide (BMP-TFSI) ionic liquid and standard liquid electrolyte are prepared and characterized. Linear sweep voltammetry measurements demonstrate that these mixed systems exhibit a wide electrochemical stability window, allowing them to be suitable electrolyte for carbonaceous anode-based lithium-ion batteries. Lithium-ion cells composed of graphite anode and $LiCoO_2$ cathode are assembled using the mixed electrolytes, and their cycling performances are evaluated. The cell containing proper content of BMP-TFSI shows good cycling performance comparable to that of a cell assembled with organic electrolyte. The presence of BMP-TFSI in the mixed electrolyte contributes to the reduction of the flammability of electrolyte solution and the improvement of the thermal stability of charged $Li_{1-x}CoO_2$ in the electrolyte solution.

Development of an alignment free mask patterning as a new fabrication method for high efficiency white organic light-emitting diodes

  • Joo, Chul-Woong;Jeon, Soon-Ok;Yook, Kyoung-Soo;Lee, Jun-Yeob
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.752-754
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    • 2009
  • High efficiency white organic light emitting diodes were fabricated by using an alignment free mask patterning method. Only red/green emission without any blue emission was observed in the red/green patterned region and blue emission was emitted in other area. A combination of the red/green and blue emission gave a high efficiency white emission. A maximum current efficiency of 30.7 cd/A and a current efficiency of 25.9 cd/A at 1000 cd/$m^2$ were obtained with a color coordinate of (0.38, 0.45).

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Simulation study on the optical structures for improving the outcoupling efficiency of organic light-emitting diodes

  • Jeong, Su Seong;Ko, Jae-Hyeon
    • Journal of Information Display
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    • v.13 no.4
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    • pp.139-143
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    • 2012
  • In this study, optical simulation was used to compare three optical structures that could be applied to the typical organic light-emitting diode to increase the outcoupling efficiency. These were spherical scattering particles (treated as Mie scatterers) embedded in the glass substrate, microlenses formed on the glass substrate, and a diffusing layer (DL) with a Gaussian scattering distribution function inserted between the indium tin oxide (ITO) and the glass substrate. It was found that the application of microlens array and that of scattering particles in the glass substrate exhibited similar enhancements in the outcoupling efficiency when the density and the refractive index of the scattering particles were optimized. The DL located at the interface between the glass and the ITO further enhanced the efficiency because it could further extract the trapped light in the waveguide mode. The appropriate combination of these three structures increased the outcoupling efficiency to about 42%, which is much greater than the typical values of 15-20% when there is no optical structure for light extraction.

Purity assessment using quantitative NMR: establishment of SI traceability in organic analysis

  • Choi, Kihwan
    • Journal of the Korean Magnetic Resonance Society
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    • v.24 no.1
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    • pp.30-37
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    • 2020
  • Quantitative nuclear magnetic resonance (qNMR) has been gaining attention as a purity assessment method. In particular, qNMR is recognized as the primary method to realize the Internal System of Units (SI) in organic analysis. The capability of quantitative analysis is recognized as the beginning of NMR development. NMR signals are proportional to the number of nuclei and qNMR has been used in various fields, such as metabolomics and food and pharmaceutical analysis. However, careful sample preparation and thorough optimization of measurement parameters are required to obtain accurate and reliable results. In this review, quantitative methods used in qNMR are discussed, and the important factors to be considered also introduced. The recent development of qNMR techniques including combination with chromatography and, multidimensional NMR are also presented.

Fabrication and characterization of photocurable inorganic-organic hybrid materials using organically modified colloidal-silica nanoparticles and acryl resin

  • Kang, Dong-Jun;Han, Dong-Hee;Kang, Young-Taec;Kang, Dong-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.422-422
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    • 2009
  • Photocurable inorganic-organic hybrid materials were prepared from colloidal-silica nanoparticles synthesized through the solgel process and using acryl resin. The synthesized colloidal-silica nanoparticles had uniform diameters of around 20 nm, and they were organically modified, using methyl and methacryl functional silanes, for efficient hybridization with acryl resin. The organically modified and stabilized colloidal-silica nanoparticles could be homogeneously hybridized with aeryl resin without phase separation. The successfully fabricated hybrid materials exhibit efficient photocurability and simple film formation due to the photopolymerization of the organically modified colloidal-silica nanoparticles and acryl resin upon UV exposure. The fabricated hybrid films exhibit an excellent optical transmission of above 90% in the visible region as well as an enhanced surface smoothness of around 1 nm RMS roughness. In addition, the hybrid films exhibit improved thermal and mechanical characteristics, much better than those of acryl resin. More importantly, these photocurable hybrid materials fabricated through the synergistic combination of colloidal-silica nanoparticles with acryl resin are candidates for optical and electrical applications.

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Impedance spectroscopy analysis of organic light emitting diodes with the $CF_4$ anode plasma treatment ($CF_4$ 플라즈마 처리된 ITO박막을 이용한 유기 EL 소자의 성능향상에 관한 임피던스 분석)

  • Park, Hyung-June;Kim, Hyun-Min;Lee, Jun-Sin;Sohn, Sun-Young;Jung, Dong-Geun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.320-321
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    • 2006
  • In this work, impedance Spectroscopic analysis was applied to study the effect of plasma treatment on the surface of indium-tin oxide (ITO) anodes using $CF_4g$ as and to model the equivalent circuit for organic light emitting diodes (OLEDs) with the $CF_4$ plasma treatment of ITO surface at the anodes. This device with ITO/TPD/$Alq_3$/LiF/Al structure can be modeled as a simple combination of a resistor and a capacitor. The $CF_4$ plasma treatment on the surface of ITO shifts the vacuum level of the ITO as a result of which the barrier height for hole injection at the ITO/organic interface is reduced. The Impedance spectroscopy measurement of the devices with the $CF_4$ plasma treatment on the surface of ITO anodes shows change of values in parallel resistance ($R_p$) and parallel capacitance ($C_p$).

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The thermal stabilization characteristics of electrolyte membrane in high temperature electrolysis[HTE] (고온 수전해 전해질 막의 열안정화 특성 고찰)

  • Choi, Ho-Sang;Son, Hyo-Seok;Sim, Kyu-Sung;Hwang, Gab-Jin
    • Transactions of the Korean hydrogen and new energy society
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    • v.16 no.2
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    • pp.150-158
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    • 2005
  • Added ratio of 8YSZ powder and organic compounds (solvent, plasticizer, dispersant, binder) properly. It manufactured electrolysis membrane by wet process that make slurry and dry process that do not use organic compounds. In the case of wet process, harmony combination and method of organic compound are an importance element in slurry manufacture. This slurry did calcine at temperature of 140$^{\circ}C$ in Furnace and manufactured electrolyte disk by Dry pressing method. Like this, manufacturing disk sintered at temperature of $1300^{\circ}C,\;1400^{\circ},\;1500^{\circ}C$ in Furnace and completed electrolysis membrane. Confirmed change of crystal structure and decision form through analysis of density, SEM, XRD according to change of sintering temperature, and considered relation with ion conductivity.