• Applied Chemistry for Engineering
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• v.9 no.3
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• pp.330-335
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• 1998

The objectives of this study are summarized with two. The one is to remove of $COD_{Cr}$, color and turbidity with coagulation and ozonation in nonbiodegradable landfill leachate, the other is to compare of water qualities with pre-ozonation and post-ozonation. The results are summarized as follows ; 1) 90 minutes ozonation with $75mgO_3/min$($4.5gO_3/hr$) was conducted at pH 4,7, 10 to remove $COD_{Cr}$. Removal efficiencies were investigated with 48.2%, 52.6%, and 62.3% respectively. As increasing pH, $COD_{Cr}$ removal efficiencies were increased, it was considered that hydroxyl radical($OH{\cdot}$) which strongly oxdize and nonselectively react with organic compounds, was rapidly produced by ozone self-decomposition at high pH. 2) Alum, ferric chloride and ferrous sulfate were used for coagulation as inorganic coagulant. Ferric chloride was investigated with optimal coagulant, and it removed $COD_{Cr}$ about 12.0% at pH5 and dosage of $2,000m{\ell}/{\ell}$. Cation(C-101P), anion(A-601P) and nonion(SC-050) were tested to remove organic pollutants in landfill leachate. Cation(C-101P) was investigated with the most effective organic coagulant, and removal efficiency of $COD_{Cr}$ was 19.8% at pH5 and dosage of $100m{\ell}/{\ell}$. 3) Color and turbidity were removed up to 88.6%, 97.0% at pH10, when contacted 90 minutes with ozone, respectively. These removal efficiencies were much higher than those of $COD_{Cr}$ and $COD_{Mn}$. It was considered that ozone could oxdize the triggering materials of color and turbidity selectively and preferentially. 4) $COD_{Cr}$, color and turbidity were more effectively removed with pre-ozonation than post-ozonation about 8%, 3.5% and 1% respectively. These results were well corresponed with other's studies that pre-ozonation will increase the effect of coagulation.

• Korean Journal of Soil Science and Fertilizer
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• v.34 no.2
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• pp.129-133
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• 2001

This studies was carried out to investigate the effects of long term application of organic matters for 21 years from 1979 to 1999. The organic matters were applicated 5 ton $ha^{-1}$ as rice straw and 10 ton $ha^{-1}$ as compost. The used soil was paddy soil of Junbuk series. The obtained results are as follows: For 21 years, the changes of organic matter content of sail was from 22g $kg^{-1}$ to 21g $kg^{-1}$ in the plot of no organic application, but from 25g $kg^{-1}$ to 29gkg^(-1) in the plot of organic matter application. The changes of cation excange capacity of soil were lower gradually in the plot of non-appilcation of organic matter, but were not changed in the plots of rice straw and compost appilcation. The changes of rice yield were highly decreased after 10 years in the plot of no organic matter application, but rice yield were not highly changed in the plot of organic matter application. As conclusion, sussesive application of organic matters is improving physico-chemical properties of soil and is increasing rice yield.

• Korean Journal of Environment and Ecology
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• v.26 no.6
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• pp.868-875
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• 2012

This study was carried out to analyze the vegetation properties, soil characteristics and ordination of Hemerocallis hongdoensis population in South Korea. The Hemerocallis hongdoensis population was classified into Mallotus japonicus dominant population, Viburnum wrightii dominant population, Melampyrum setaceum dominant population. Hemerocallis hongdoensis were mainly distributed along the coast of south-western iland of the Korean penninsula and it's population was located at an elevation of 6m to 362m. In the study sites, soil organic matter, total nitrogen, exchangeable potassium, exchangeable calcium, exchangeable magnesium, cation exchange capacity and soil pH were 16.18~21.70%, 0.56~0.97%, 0.42~0.88mg/kg, $3.38{\sim}5.65cmol^+/kg$, $1.12{\sim}2.38cmol^+/kg$, $25.93{\sim}41.45cmol^+/kg$, and 4.45~4.86 respectively. Mallotus japonicus dominant population was found in the steep sloped area that has high percentage of cation exchange capacity and total nitrogen than other populations. Viburnum wrightii dominant population was found gentle sloped area that has low percentage of cation exchange capacity and total nitrogen. Melampyrum setaceum dominant population was found in the medium sloped area that has medium percentage of cation exchange capacity and total nitrogen. Current status of Hemerocallis hongdoensis habitats is very vulnerable with local development constantly threatening the species' survival. Thus, concrete conservation plans to protect natural habitats should be set up as soon as possible.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.48 no.3
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• pp.196-199
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• 2003

This experiment was conducted to evaluate the differences in physicochemical properties of soil, grain yield and milling recovery ratio and grain appearance of rice grown in long-term no-till and ordinary till systems. The paddy in no-till rice system was unploughed but straw-mulched for 15 years from 1988 to 2002 at the Experimental Paddy of Gyeongnam Agricultural Research and Extension Services, while the paddy in ordinary till system was ploughed and puddled every crop year, A 5cm organic layer was formed in 11-year no-till rice system, in which exchangeable cation and phosphate were accumulated. In no-till paddy organic matter, bulk density and solid phase of surface soil significantly increased, while pH, exchangeable cation, phosphate, liquid and gaseous phase decreased. Tillage made the very top soil soft, but made deep soil below 5cm significantly hard. In the 1st year of no-till, topsoil showed hard, but in the process of the time in no-till system, the top- and sub-soil showed softer, Yield and yield components of rice showed no differences between till- and no-till rice systems. Milling recovery ratio and grain appearance were not significantly different between no-till and till-rice systems.

• Korean Journal of Soil Science and Fertilizer
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• v.38 no.5
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• pp.247-252
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• 2005

Soil pH is an intensity factor of releasing hydrogen ion which is buffered by aluminum. It depends on pH buffer capacity of Al whether soil pH is governed directly by cations or not. A study was conducted to elucidate the pattern of pH changes by soil EC. Fertilizer and three kinds of organic manures composed of cow and pig and fowl dropping and one kind of rice straw compost were added independently into upland sandy loam soil. This treated soils and four upland soils under plastic film house having different levels in electrical conductivity (EC) were incubated with field capacity at $30^{\circ}C$ for 5, 10, 20 and 40 days. Soil pH varied directly as the cations contained in organic materials according to degree of saturating pH buffer capacity (pBC) of sandy loam soil. pH of the soils under plastic film house was lowered by soil EC due to governing by overplus of cation beyond pBC.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2011.03a
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• pp.36-36
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• 2011

We synthesized new dye sensor based on indole compound. Through the UV-vis absorptions, we analyzed chemosensing properties to explain metal binding properties. The peak absorptions increased at 472 nm when added metal cations($Cd^{2+}$, $Cu^{2+}$, $Hg^{2+}$, $Fe^{2+}$, $Zn^{2+}$, $Ni^{2+}$ and $Cr^{3+}$) and gradually decreased the peak at 516 nm. Thus, this UV-Vis absorption behavior clearly showed the metal binding reaction. To measure energy level of used dye sensor, HOMO/LUMO energy value was calculated with cyclovaltagramm(CV) and using computational calculation method, in which we estimated the optimum structure of dye sensor. CV and computational calculation method, both compared to find suitable geometric structure. (with almost same energy values.) From the computational calculation, dye sensor has plane structure. So, Amine and ketone in the dye sensor faced each other and makes position to bind metal cations. In addition, these positions was supported pull-push electron system and generated MLCT process, when the dye sensor was bonded with the metal cations and resulted chemosensing properties. Through the electrochemical and computational calculation method analyze, we proposed the chemosensing principles that the dye sensor bind the metal cation between ketone and amine. Finally, the formation type of metal ion bindings was determined by Job's plot measurements.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.7 no.1
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• pp.50-58
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• 2004

The aim of this study was to characterize the forest vegetation structure and site of Quercus serrata forest for ecological forest management and ecological niche. The results are as follows : The chemical properties of Q. serrata forest soil were 0.24% of total nitrogen, 8.27 of organic matter, 74ppm of available phosphorous, 1.64(me/100g) of Ca, 0.22(me/100g) of Mg, 0.74(me/100g) of K and 9.3(me/100g) of cation exchangeable capacity. The dominant species in Quercus serrata forest were Quercus serrata, Quercus acutissima, Quercus variabilis, Quercus mongolica, Styrax obassia, Fraxinus rhynchophylla and Styrax japonica. DBH analysis showed that Quercus serrata seems to remain as a dominant species for the present because they had random distribution based on few of big individuality, many of small and middle individuality. But the Q. serrata community is competing with Q. mongolica and F. rhynchophylla, whose density of small individuality has increased. With the classification of TWINSPAN, Q. serrata forest was classified three groups, such as Q. serrata-Acer mono, Q. serrata, Q. serrata-Q. acutissima communities. The results of the correlation analysis of Q. serrata major communities and environment factors are as follows; Q. serrata-A. mono community was found relatively in high elevated and eastern and northern area that has relatively high percentage organic matter. Also Q. serrata community was found in high elevated and eastern and northern area that has high percentage organic matter. Q. serrata-Q. acutissima community was found in low elevated and southern and western area that has low percentage organic matter.

• Applied Chemistry for Engineering
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• v.4 no.1
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• pp.171-177
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• 1993

In decontamination process to remove radioactive materials of reactor cooling system, the metal ions dissolved by organic acids in decontamination solution are separated by use of ion exchange resin in the column. However, organic acids in decontamination solution decrease the apparent affinity of the resin to metal ions. In light of this, some experiments were carried out on the Amberlite IRN-77 cation resin with cobalt and iron to gain a better understanding of the complexation effects on the ion exchange process. Experimental results showed that EDTA among organic acids used as chemical decontaminants predominantly caused reduction of ion exchange capacity of cobaltous ion to resin since this reagent formed the complex with the cobaltous ion stronger than that with the ferrous ion. In contrast, the effects of oxalic acid and citric acid were found to be negligible. And, single and two-component nonlinear equilibrium relationships of the metal ions were established using experimental data.

• Korean Journal of Environmental Agriculture
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• v.3 no.1
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• pp.22-29
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• 1984

The Freundlich-type adsorption isotherms were obtained in this study on the adsorption of linuron, bentazon, trifluralin and butachlor by soils. A strong correlation was shown between soil organic matter content and the adsorption of linuron. Soils with high organic matter content adsorbed more linuron. There was no significant correlation between the adsorption of bentazon and clay content. There was a tendency that increase in organic matter content acts against the adsorption of bentazon. Repulsive forces seemed to exist between negatively charged soil particle surfaces and betazon molecules which become weakly charged negative ions in soil solution. Organic matter content and cation exchange capacity appeared to be enhancing the adsorption of trifluralin and butachlor. Clay content was not significantly correlated with the adsorption of these herbicides. Trifluralin was adsorptive to the greatest extent, followed by linuron and butachlor, bentazon being the least.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.13 no.6
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• pp.75-86
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• 2010

This study used a phytosociolocal approach in classifying the vegetation communities of evergreen broad-leaved forest in Gageodo island of Korea, and the results are as follows: Quercus acuta community was classified into Dendropanax morbifer subcommunity, Daphniphyllum macropodum subcommunity, and Quercus acuta typical subcommunity. In the study sites, soil organic matter, total nitrogen, available phosphorous, exchangeable K, exchangeable Ca, exchangeable Mg, cation exchange capacity, and soil pH were ranged from 15.23~18.89%, 0.73~0.99%, 4.31~15.06 (mg/kg), 1.09~1.13 ($cmol^+$/kg), 21~7.15 ($cmol^+$/kg), 1.33~2.10 ($cmol^+$/kg), 33.04~38.28 ($cmol^+$/kg) and 4.47~4.83 respectively. The Dendropanax morbifer subcommunity were found in sites with high percentage of organic matter, total nitrogen, and low percentage of exchangeable Mg and Ca while the Daphniphyllum macropodum subcommunity were found in sites with low percentage of organic matter, total nitrogen, exchangeable Mg and Ca. The Quercus acuta typical subcommunity were found in sites with high percentage of organic matter, total nitrogen, exchangeable Mg and Ca. It is urgently needed to work for the preparation of an island management plan to the levels of species through habitat conservation.