• 한국정보디스플레이학회:학술대회논문집
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• 2009.10a
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• pp.758-761
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• 2009

The electroluminescent devices with the phenylnaphthyldiamine HTMs as the hole-transporting layer were more efficient than that with the biphenyldiamine HTM 1. Particularly, the life-time of the device IV using HTM 2 is about two times longer than that of the reference device III with HTM 1 within the measured current density, indicating more effective recombination at the emitting layer of device IV.

• Bulletin of the Korean Chemical Society
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• v.1 no.2
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• pp.49-54
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• 1980

Solutions of $Ni^{2+}$ and $Cd^{2+}$ were mixed with the solutions of various dibasic organic acids in the presence of cation exchange resin at room temperature. The distribution ratios of the metal ions between resin and solution were measured, using radioactive metal ions as tracer. From the observed variation of the distribution ratios with acid anion concentrations, it was concluded that $Ni^{2+}$ and $Cd^{2+}$ formed one-to-one complexes with succinate, malonate, o-phthalate and tartarate ions in aqueous, 20 % ethanol-water and 20 % acetone-water solutions. The results of the present study indicated that the relative stabilities of the complexes in solution increased generally in the order : $Ni^{2+}$ < $Cd^{2+}$ complexes. Succinate < malonate < o-phthalate < tartarate complexes. Aqueous < mixed solvent systems.

• Journal of Radiopharmaceuticals and Molecular Probes
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• v.7 no.2
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• pp.141-146
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• 2021

With increasing interest in fluorinated compounds, nucleophilic fluorination reaction has been generally used for synthesizing fluorine-containing chemicals. However, alkali metal fluorides (MFs) generally have low solubility and reactivity in organic solvent. To overcome these problems, various phase transfer catalysts (PTCs) have been investigated. Calix-arene is known as to capture the metal cation(M⁺), and therefore in this review, we would like to introduce several kinds of calix-arene based PTCs, such as bis-tert-alcohol-functionalized crown-6-calix[4]arene (BACCA), oligo-ethylene glycol linked bis-triethyleneglycol crown-5-calix[4]arene (BTC5A), and ionic liquid functionalized calix-arene based catalyst, as well as ion-pair receptor crown-6-calix[4]arene-capped calix[4]pyrrole.

• Korean Journal of Organic Agriculture
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• v.5 no.1
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• pp.125-135
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• 1996

A study was made to investigate the possibility of treating various organic waste of cattle manure, swine manure, goat manure, apple pomace, chinese medicine residue and coffee less by feeding these to earthworms and then by studying the growth and reproductive efficiency of earthworms, and the chemical composition of worm cast and its production. The results are summarized as follows. 1. When the feed for earthworms were in good condition which were cattle manure, swine manure and apple pomace, the reproductive efficiency of earthworms was improved however in worse condition the feed of which were goat manure and chinese medicine residue, the increasing rate(IR) became faster. 2. Despite the high content of organic matter(OM) in coffee lees, the earthworms fed coffee lees showed significantly lower reproductive efficiency and increasing rate(IR) than those fed other organic waste due mainly to its lower pH and lower total nitrogen(TN) content. Therefore, when coffee lees is considered to be fed to earthworms, it is believed necessary to be mixed with addiveves or other organic waste in order to improve the feed condition. 3. pH in swine manure, goat manure, apple pomace, chinese medicine residue and coffee lees became neutralized by being fed by earthworms. 4. Available P2O5 and exchangeable cation(EC) of earthworm cast were a little increased compared to those of feed. The contents of Mn, Fe and Cu in earthworm cast were a little decreased to compared to those of feed. 5. The contents of Mn, Fe and Cu in earthworm cast were a little a decreased to compared to those of feed. 6. Mean fresh weight of earthworm at final time(FW2) was negatively correlated with number of young worms(NY)(P<0.01), but positively with increasing rate(IR) (P<0.001) and C/N ratio(P<0.05) respectively. Number of cocoons (NC) and fresh weight of cocoons(WC) were positively(P<0.01) correlated with fresh weight of young worms (WY) and digested matter(DI) but negatively(P<0.001) correlated with residual matter(WY) and digested matter(DI) but negatively(P<0.001) correlated with residual matter(RW). Number of young worms(NY) and fresh weigh of young worms(WY) were negatively(P<0.001) correlated with increasing rate(IR), however increasing rate(IR) of earthworm was positively(P<0.05) correlatedd with C/N ratio.

• Korean Journal of Organic Agriculture
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• v.20 no.1
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• pp.81-89
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• 2012

This study was investigated to evaluate the effects of fertilizer application of surface and broadcast for rice culture on the soil chemical, physical, and microbial properties as well as growth and yield of rice. The application was made with 'Dongjin 1' rice at Jeollanam-do Agricultural Research & Extension Services from 2008 to 2010. Soil organic matter and cation concentrations were increased by surface and broadcast applications, respectively. Plots treated by surface application tended to be higher seasonal N-mineralization rate in the organic fertilizer and seasonal soil organic matter than those of broadcast application. Soil physical properties seemed to be improved by the broadcast application, and soil microbial properties were increased by the surface application. Surface application increased 5% of rice yield compared to that of broadcast.

• Journal of the Korea Organic Resources Recycling Association
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• v.25 no.3
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• pp.79-89
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• 2017

Changes in pH, EC and water soluble cation and anion of the bed material in the rearing box of earthworms were investigated while sewage sludges or night soil sludge were cumulatively supplied to the 15 grams of initial earthworm population in the rearing box. Initial biochemical properties of sludges such as pH, EC, V.S. and water content were at the edible levels for earthworm. However, as the cumulative amount of sludges supplied to the earthworms were increased, pH of bed material in the rearing box was lowered and EC was increased, which meant that salt contents of bed material in the rearing box had been accumulated. Water soluble cations and anions were also accumulated in the bed material of the rearing box. Accumulation rates of ${NO_3}^-$ were especially prominent. Consequently, feeding rates of earthworm populations were reduced to nearly zero and earthworm populations finally died.

• Korean Journal of Soil Science and Fertilizer
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• v.17 no.4
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• pp.337-342
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• 1984

224 profiles representing 19 soil series were subjected to multiple regresion analysis to determine the relative contribution of organic matter(OM) and clay content to total cation exchange capacity(CEC) in sandy soil. The independent variables were OM and clay, with the dependent variable CEC. Simple correlation coefficients showed high significance at CEC-OM and CEC-clay. The partial regression coefficients indicated that CEC for each gram of OM was calculated to be 0.549 and 1.351 meq of top and subsoil. The clay contributions of top and subsoil were 0.247 and 0.226 meq, respectively. The standard partial regression coefficients appeared that clay content was 1.23 times as important as orgnic matter in predicting CEC.

• Journal of Environmental Science International
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• v.20 no.2
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• pp.185-197
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• 2011

Sorption of chlorinated pesticides such as 2,4-dichlorophenoxyacetic acid (2,4-D) and atrazine onto natural clays (montmorillonite and zeolite) modified with cationic surfactant, hexadecyltrimethyl-ammonium (HDTMA) and a natural soil was investigated using batch adsorbers. The clays were transformed from hydrophilic to hydrophobic by the cation exchange between clay surface and HDTMA up to 100% of the cation exchange capacity (CEC). Physicochemical characteristics of the sorbents such as pH, PZC (point of zero charge), organic carbon content ($f_{oc}$), fourier transform infrared spectroscopy (FT-IR), differential thermogravimetric analysis (DTGA) and X-ray diffraction (XRD) were analyzed. Sorption isotherm models such as Freundlich and Langmuir were fitted to the experimental data, resulting Langmuir model ($R^2$ > 0.986) was fitted better than Freundlich model ($R^2$ > 0.973). Sorption capacity ($Q^0$) for 2,4-D and atrazine was in the order of HDTMA-montmorillonite > HDTMA-zeolite > natural soil corresponding to the increase in organic carbon content ($f_{oc}$). The sorption of the pesticides was also affected by pH. The sorption of 2,4-D decreased with the increase in pH, whereas that of atrazine was not changed. This indicated that the sorption capacity ($Q^0$) of 2,4-D and atrazine was not affected by the solution pH because they exist as anionic (deprotonated) forms at pH above pKa. The results indicate that organoclay has a promising potential to reduce chlorinated pesticides in the effluent from golf courses.

• Journal of Forest and Environmental Science
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• v.15 no.1
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• pp.71-76
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• 1999

This study compared soil characteristics and carbon storage between urban and natural lands in Chunchon. Soil pH was lower in natural lands (5.0) than in urban lands (6.6), and therefore exchangeable cation was a little lower in natural lands. Organic matter and cation exchange capacity were respectively, 1.4 and 1.7 times higher in natural lands than in urban lands, while available $P_2O_5$ was about 3.2 times higher in urban lands. Organic carbon storage in soils averaged $24.8{\pm}1.6$ (standard error) t/ha in urban lands and $31.6{\pm}1.6t/ha$ in natural lands, 1.3 times greater than in urban lands. Annual carbon accumulation in soils of natural lands was 1.3 t/ha/yr (litterfall minus decomposition). The carbon storage in Chunchon' s soils equaled about 31% of annual carbon emission (245,590 t/yr).

• Journal of Korean Society of Forest Science
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• v.97 no.3
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• pp.296-304
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• 2008

This study was carried out to analyze vegetation and soil characteristic, and ordination of Stewartia koreana community. The Stewartia koreana community was classified into Acer mono subcommunity, Pinus densiflora subcommunity, Sapium japonicum subcommunity, and Stewartia koreana typical subcommunity. In the study sites, soil organic matter, nitrogen, available phosphorous, exchangeable K, exchangeable Ca, exchangeable Mg concentration, cation exchange capacity, and soil pH were ranged from 14.31~34.27%, 0.33~0.77%, 7.83~22.88(mg/kg), 0.23~1.07(me/100 g), 0.29~2.93(me/100 g), 0.33~1.49(me/100 g), 10.47~22.48(me/100 g), and 4.65~4.96, respectively. The area of the Acer mono subcommunity, found in highlands, showed that contained the highest organic substances, nitrogen, available phosphorous, and cation exchangeable capacity concentration among the communities. The low elevation regions where the Pinus densiflor subcommunity is formed, showed the lowest concentrations of exchangeable Ca, and Mg.