• Title/Summary/Keyword: organic acids.

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Studies on the Processing Conditions and the Taste Compounds of the Sardine Sauce Extracts (속성 정어리간장 엑스분의 가공조건 및 정미함분에 관한 연구)

  • LEE Eung-Ho;JEE Seung-Kil;AHN Chang-Bum;KIM Jin-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.21 no.1
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    • pp.57-66
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    • 1988
  • As a method of utilization of sardine, the processing conditions of the sardine sauce extracts and the taste compounds of products were investigated. To prepare the sardine sauce extracts, chopped sardine was mixed with $1\%$, onion powder, $1\%$ garlic powder, $1\%$ red pepper powder, loft koji and $50\%$ water, and then hydrolyzed under different conditions of hydrolysis. The optimum conditions for hydrolysis were $55^{\circ}C$, 6 hours, pH 6.5-7.0. After hydrolysis, the hydrolysates were heated at $100^{\circ}C$ for 20 minutes with $5\%$ soybean protein isolate for inactivation of enzymes and improvement of bitter taste of the hydrolysates. Finally, $10\%$ salt was added to develop the characteristic taste of sauce extracts. The major taste compounds of the products were free amino acids, non-volatile organic acids and nucleotides and their related compounds. The major free amino acids in the products were arginine, histidine, lysine, glutamic acid, phenylalanine, leucine and alanine. The contents of these free amino acids were in the range of $68.2\%\;to\;69.9\%$ of the total free amino acids of products. The major non-volatile organic acids ill the products were lactic acid and $\alpha-ketoglutaric$ acid which occupied more than $95\%$ of total non-volatile organic acids. The contents of free amino acids, non-volatile organic acids and nucleotides and their related compounds were not changed during storage. Total creatinine, betaine and TMAO were seemed to act an auxiliary role in taste of the products. Judging from the results of chemical experiments and sensory evaluation, the product prepared with koji and soybean protein isolate was excellent as seasoning materials.

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Effects of Organic Materials on Soil Chemical Properties (유기물(有機物)의 시용(施用)이 토양(土壤)의 화학적(化學的) 성질(性質)에 미치는 영향(影響))

  • Oh, Wang-Keun
    • Korean Journal of Soil Science and Fertilizer
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    • v.11 no.3
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    • pp.161-174
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    • 1979
  • A review was made on the effect of organic matter application on the chemical characteristics of soils such as pH, solubilities of minerals, and cation exchange capacity mainly at flooded rice soils. The review can be summarized as follows: 1. Application of organic material such as rice straw and compost in flooded rice soil leads to a temporary lowering of soil pH at the earlier stage of soil reduction, due to the production of various organic acids and carbonic acid. This temporary lowered pH is replaced with the production of alkaline substances such as ammonia as the reduction of soil proceeds. 2. Incorporation of organic materials intensifies the ferrous iron, dissolving various minerals, virtually to the increase in electrical conductivity of soils. 3. Organic materials also play an important role in dissolving soil minerals through the production of various chelating agents. 4. Application of soil organic matter significantly increases cation exchange capacity of soils. 5. Continuous application of rice straw or compost leads to the increase in soil organic matter content to some extent, up to the level of equilibrium. In soils low in organic matter the equilibrium level is attained with five years continuous application of compost. 6. The manner of chemical fertilizer application influences the accumulation of organic matter applied in soils. Low levels of fertilization lowers the accumulation while high levels of fertilization accerelates the accumulation.

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On the Forming Processes of Soil Humic Substances and its Physiological Effects on Plants (토양(土壤) 부식물(腐植物)의 생성(生成)과 효과(効果)에 대(對)한 고찰(考察))

  • Lim, Sun-Uk
    • Korean Journal of Soil Science and Fertilizer
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    • v.6 no.1
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    • pp.67-73
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    • 1973
  • Soil humic substances are defined as a humified part of the soil organic matters and regarded to play beneficial roles for colloid chemical properties and the fertility of the soils. This paper is referred to review the present trend of the studies on the forming processes of humic substances and on the effect on plant metabolism by some organic compounds that are directly absorbed by plants. It is generally considered that the humic substances are formed organic matters in soil or plant materials through numerous organic or biochemical processes. However, the nature of the constituting "core" and of attachment of carbohydrate, nitrogen containing compounds like protein, phenolic compounds and metals to the core are unclear though various models are suggested. It is reviewed that some organic compounds, phenclic acids, derived from humic substances are effective on plant metablism in many cases, although the mechanisms are remained to be clarified.

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Study of Chemical Parameters on Butchery wastes as a Bulking Agent in Composting of Swine Manure (돈분의 퇴비화에 있어 원보조재의 혼합비에 따른 최종산물의 화학적인 조성 연구)

  • 이상환;김인호;홍종욱;권오석;김정우
    • Korean Journal of Organic Agriculture
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    • v.9 no.3
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    • pp.93-101
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    • 2001
  • This study was conducted to evaluate chemical parameters on butchery wastes as a bulking agent in composting of swine manure. Treatments included T1 : Swine manure + Rice hull, T2 ; Swine manure + Rice hull + Vermiculite, T3 ; Swine manure + Rice hull + Perlite, T4, Swine manure + Vermiculite, T5 : Swine manure + Vermiculite + Perlite, T6 ; Swine manure + Perlite, T7 ; Swine manure + lice hull + Vermiculite + Perlite. During the composting period, changes of temperature and pH were showed traditionally composting trend. Moisture, organic matter, total nitrogen and C/N ratio were higher rice hull than vermiculite and perlite treatments. Ammonia-N and EC were not differences among the treatments. In heave metal, Cd and Cr were showed higher in vermiculite treatments than other treatments. Rice hull treatments were decreased volatile fatty acids compared to that of other treatments. In conclusion, rite hull containing high organic content was greater composting effects than vermiculite and perlite containing low organic content.

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Organic Acids Content of the Selected Korean Apple Cultivars (우리나라 사과 일부 품종의 유기산 함량)

  • Do, Young-Sook;Whang, Hea-Jeung;Ku, Ja-Eel;Yoon, Kwang-Ro
    • Korean Journal of Food Science and Technology
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    • v.37 no.6
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    • pp.922-927
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    • 2005
  • Total and individual organic acid contents of Malus domestica Borkh, cultivars, Tsugaru, Fuji Jonathan (Hong-Ok), and New Jonagold(Sin-Heung) apples, were investigated. Average titratable acidities measured by titration method and total organic acids content determined by HPLC were 241.64-444.52 and 364.23-680.80mg%, respectively. Average total organic acid contents were Jonathan 630.80mg%, New Jonagold 471.04mg%, Fuji 403.80mg%, and Tsugaru 364.23mg%, Contents of DL-malic, citric, fumaric, and quinic acid were 351.98 (Tsugaru)-579.88mg% (Jonathan), 2.14 (Fuji)-12.95mg% (Jonathan), 0.012 (Fuji)-0.060mg% (Jonathan), and 8.91 (Tsugaru)-14.20mg% (Fuji), respectively. Succinic acid was detected only from Jonathan (27.53mg%) and New Jonagold (5.20mg%), while maleic acid was not detected from all cultivars. Ratio of L-malic acid and DL-malic acid contents were 0.98-1.02 in all apple cultivars.

Effects of Organic Amendments on Soil Microbial Community in Red Pepper Field (시용 유기물의 종류가 고추 재배지 토양 미생물상에 미치는 영향)

  • Park, Kee-Choon;Kim, Yeong-Suk;Kwon, Oh-Hoon;Kwon, Tae-Ryong;Park, Sang-Gu
    • Korean Journal of Soil Science and Fertilizer
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    • v.41 no.2
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    • pp.118-125
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    • 2008
  • Diverse organic amendments available in local areas have been used to improve soil quality in red pepper field and so the need for investigating the soil chemical and biological properties changed by the organic amendments application is increasing. Soil microbial diversities were measured by phospholipid fatty acid (PLFA) and Biolog $EcoPlate^{TM}$. Compost was most effective for improving soil chemical properties including pH, EC, total nitrogen, P, K, and Ca, and bark increased soil organic matter significantly (P=0.05). Compost increased the fatty acids indicating actinomycetes and vascular arbuscular fungi, and ratio of cy19:0/18:1w7c and monounsaturated fatty acids/saturated fatty acids in soils in PLFA analysis. Bark increased soil fungal indicators in PLFA analysis (P=0.05). Principal component analysis of Biolog EcoPlate data and PLFA differentiated the compost- and bark-amended soils from other organic matteramended soils especially the soil incorporated with compost. More researches are needed to use bark for improving soil microbial properties because the soil chemical and microbiological properties caused by compost and bark are significantly different.

Leaching of Rare Metals from Spent Petroleum Catalysts by Organic Acid Solution (석유화학공정 폐촉매에 함유된 희유금속의 유기산 침출)

  • Le, Minh Nhan;Lee, Man Seung
    • Resources Recycling
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    • v.28 no.6
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    • pp.36-45
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    • 2019
  • The spent petroleum catalysts contain rare metals such as vanadium, nickel, molybdenum, and cobalt. Therefore, the leaching of these rare metals from spent petroleum catalysts by organic acid was investigated in the present study. The leaching efficiency of metals by organic acid was in the following order: oxalic acid > tartaric acid > citric acid > maleic acid > ascorbic acid. Among the organic acids employed in this work, oxalic acid can be considered to be superior to the other acids in terms of metals leaching efficiency. The effect of several leaching conditions such as temperature, acid concentration, pulp density, stirring speed, and reaction time on the leaching of metals was investigated. Vanadium and molybdenum were selectively dissolved by oxalic acid from the spent catalysts. The leaching kinetics of vanadium by oxalic acid was also investigated. An activation energy of 8.76 kJ/mol indicated that the leaching kinetics of vanadium by oxalic acid solution was controlled by mass transfer.

Chemical Leaching of Co, Cu, Ni, Al, Fe by Organic acid from Cobalt Concentrate (코발트 정광(精鑛)으로부터 유기산(有機酸)을 이용(利用)한 Co, Cu, Ni, Al, Fe의 화학적(化學的) 침출(浸出))

  • Ahn, Jae-Woo;Ahn, Hyo-Jin;Kim, Meong-Woon
    • Resources Recycling
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    • v.20 no.6
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    • pp.63-70
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    • 2011
  • Enviromental friendly leaching process for the recovery of cobalt and copper from the cobalt concentrate was investigated by organic acids as a leaching reagent. The experimental parameters, such as organic acid type, concentrations of leachant, time and temperature of the reaction as well as the solid to liquid ratio were tested to obtain the optinum conditions for the leaching of cobalt and copper. The results showed that citric acid was the most effective leaching reagent among the organic acids used in this experiment. About 99% of cobalt, 95% of copper and 70% of nickel was dissolved by 2.0 M of citric acid. Addition of 3.0 vol.% of hydrogen perioxide was effective to enhance the leaching efficiency and the optinum temperature was found to be about $70^{\circ}C$.

Microbial Community Diversity in Anaerobic Reactors Digesting Turkey, Chicken, and Swine Wastes

  • Ziganshina, Elvira E.;Belostotskiy, Dmitry E.;Shushlyaev, Roman V.;Miluykov, Vasili A.;Vankov, Petr Y.;Ziganshin, Ayrat M.
    • Journal of Microbiology and Biotechnology
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    • v.24 no.11
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    • pp.1464-1472
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    • 2014
  • The microbial community structures of two continuous stirred tank reactors digesting turkey manure with pine wood shavings as well as chicken and swine manure were investigated. The reactor fed with chicken/swine wastes displayed the highest organic acids concentration (up to 15.2 g/l) and ammonia concentration (up to 3.7 g/l ammonium nitrogen) and generated a higher biogas yield (up to $366ml/g_{VS}$) compared with the reactor supplied with turkey wastes (1.5-1.8 g/l of organic acids and 1.6-1.7 g/l of ammonium levels; biogas yield was up to $195ml/g_{VS}$). The microbial community diversity was assessed using both sequencing and profiling terminal restriction fragment length polymorphisms of 16S rRNA genes. Additionally, methanogens were analyzed using methyl coenzyme M reductase alpha subunit (mcrA) genes. The bacterial community was dominated by members of unclassified Clostridiales with the prevalence of specific clostridial phylotypes in each reactor, indicating the effect of the substrate type on the community structure. Of the methanogenic archaea, methanogens of the genus Methanosarcina were found in high proportions in both reactors with specific methanosarcinas in each reactor, whereas the strict hydrogenotrophic methanogens of Methanoculleus sp. were found at significant levels only in the reactor fed with chicken/swine manure (based on the analyses of 16S rRNA gene). This suggests that among methanogenic archaea, Methanosarcina species which have different metabolic capabilities, including aceticlastic and hydrogenotrophic methanogenesis, were mainly involved in anaerobic digestion of turkey wastes.

Chemical Leaching of Cobalt and Lithium from the Cathode Active Materials of Spent Lithium-ion Batteries by Organic Acid (폐(廢)리튬이온전지(電池) 양극활물질(陽極活物質)에서 유기산(有機廳)을 이용(利用)한 코발트 및 리튬의 화학적(化學的) 침출(浸出))

  • Ahn, Jae-Woo;Ahn, Hyo-Jin
    • Resources Recycling
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    • v.20 no.4
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    • pp.65-70
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    • 2011
  • Environmental friendly leaching process for the recovery of cobalt and lithium from the $LiCoO_2$ was investigated by organic acids as a leaching reagent. The experimental parameters, such as organic acid type, concentrations of leachant and hydrogen peroxide, reaction time and temperature as well as the pulp density were tested to obtain the most effective conditions for the leaching of cobalt and lithium. The results showed that the latic acid was the most effective leaching reagent for cobalt and lithium among the organic acids and was reached about 99.9% of leaching percentage respectively. With the increase of the concentration of citric acid, hydrogen peroxide and temperature, the leaching rate of cobalt and lithium increased. But the increase of pulp density decreased the leaching rate of cobalt and lithium.