• Title/Summary/Keyword: organic N

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The fabrication of organic EL device for high contrast (고휘도 발광을 위한 유기 EL 소자 제작)

  • 여철호;손철호;박정일;장선주;박종화;이영종;정홍배
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.166-169
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    • 2000
  • The Organic Electroluminescence (OEL) device, that was consisted of ALq3(8-hydroxyquinoline aluminum) and TPD(N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,1'-biphenyl-4,4'-diamine), has been used. We investigated characteristics of brightness and current density about OEL that was oxidated each layers. We used two samples that were fabricated each continuous and non-continuous method. Emission was observed above 10mA/$\textrm{cm}^2$ and luminance was measured to be 1530cd/$\textrm{cm}^2$ at a current density of 100mA/$\textrm{cm}^2$. A luminance of over 2600cd/$\textrm{cm}^2$ was also observed after the final fabrication process.

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Comparison of Soil Physico-chemical and Microbial Characteristics in Soil of 'Niitaka' Pear Orchards between Organic and Conventional Cultivations (유기농법과 관행농법에 의해 재배한 '신고'배 과원 토양의 물리화학적 및 미생물학적 특성 비교)

  • Choi, Hyun-Sug;Li, Xiong;Kim, Wol-Soo;Lee, Youn;Jee, Hyeong-Jin
    • Korean Journal of Organic Agriculture
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    • v.19 no.2
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    • pp.229-243
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    • 2011
  • Consumers' interest and government's support for the fruits rapidly increased organic fruit productions. This study was examined to compare the soil physicochemical and microbial properties of orchards soil in conventionally and organically management systems. Organic cultivation had lower soil bulk density, solid phase, and penetration resistance than the conventional cultivation. Soil pH and organic matter contents increased from March to August, and the values were greater in the organic cultivation than the conventional cultivation. Total nitrogen (N) and phosphorous concentrations decreased from March to August, and the organic soils had greater N but lower phosphorous concentrations than the conventional soils. Soil microbial carbon biomass increased 36% and 15% for organic and conventional cultivations, respectively, from March to August. Soil microbial N biomass was greater in June than March or August, and the organic cultivation had a greater biomass N compared to the conventional cultivation. Soil dehydrogenase and chitinase activities were greater in June than in March or August. ${\beta}$-glucosidase activity declined in both cultivations, while the phosphatase activity increased. Organic cultivation had greater enzyme activities in March, June, and August, except for the acid phosphatase activity in June.

Comparison of Organic Matter Distribution in Major Tributaries of the Nakdong River (낙동강 지류하천에서 TOC와 COD 유기물의 분포 비교)

  • Kim, Heung-Seop;Hong, Jong-Jin;Seong, Jin-Uk;Choi, Kwang-Soon;Park, Je-Chul
    • Journal of Korean Society on Water Environment
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    • v.29 no.5
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    • pp.618-624
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    • 2013
  • This study was conducted to suggest the concentration distribution of organic matters in 348 tributaries of Nakdong River, and to review the validity of the conversion of organic matter indexes. The average concentration of organic matters in the tributaries was TOC 2.4 mgC/L, DOC 2.1 mgC/L, COD 1.0 mgC/L, respectively. DOC ratio to TOC is 87% and COD ratio is 44%. First tributaries shows higher organic pollution than second tributaries. The correlation between TOC and COD was relatively high as 0.796 (p < 0.01, n = 670). Based upon these results, a regression analysis was conducted. The results showed that TOC concentration was 2.5 times higher than COD concentration. In conclusion, it is appropriate to use TOC for the management of all organic matters. Furthermore, there is a need to build organic matter-related Databases for more rivers so as to establish TOC standards and manage the water quality.

Direct printing of organic single crystal nanowire arrays by using Liquid-bridge-mediated nanotransfer molding

  • Oh, Hyun-S.;Baek, Jang-Mi;Sung, Myung-M.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.473-473
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    • 2011
  • In recent years, organic thin film transistors OTFTs based on conductive-conjugated molecules have received significant attention. We report a fabrication of organic single crystal nanowires that made on Si substrates by liquid bridge-mediated nanotransfer molding (LB-nTM) with polyurethane acrylate (PUA) mold. LB-nTM is based on the direct transfer of various materials from a stamp to a substrate via a liquid bridge between them. In liquid bridge-transfer process, the liquid layer serves as an adhesion layer to provide good conformal contact and form covalent bonding between the organic single crystal nanowire and the Si substrate. Pentacene is the most promising organic semiconductors. However pentacene has insolubility in organic solvents so pentacene OTFTs can be achieved with vacuum evaporation system. However 6, 13-bis (triisopropylsilylethynyl) (TIPS) pentacene has high solubility in organic solvent that reported by Anthony et al. Furthermore, the substituted rings in TIPS-pentacene interrupt the herringbone packing, which leads to cofacial ${\pi}-{\pi}$ stacking. The patterned TIPS-Pentacene single crystal nanowires have been investigated by Atomic force microscopy (AFM), Transmission Electron Microscopy (TEM), X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and electrical properties.

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Behavior of Hazardous Organic Compounds in Low-Pressure Nanofiltration Process (저압 나노여과 공정에서의 유해성 유기물질의 거동)

  • Oh, Jeong-Ik;Lee, Seockheon;Lee, Bo-Young
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.2
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    • pp.165-173
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    • 2004
  • Behavior of hazardous organic compounds including bisphenol A, phtalic acid, and phosphoric acid in low pressure nanofiltration process were investigated. In the case of NTR729HF, rejection of all target organic compounds except 2-H-Benzothiazol and 2-isopropyl phenol was more than 90%. The lowest rejection for 2-H-Benzothiazol was observed in another membranes. The UTC60 and UTC20 showed similar rejection characteristics of hazardous organic compounds. Although the rejection of Bisphenol A, n-buthyl benzenesulfoneamide, N-ethyl-p-toluensulfonamide, 2-H-benzothiazol, p-t-butylphenol and 2-isopropyl phenol was less than 30%, the rejection of tributyl phosphate, triethyl phosphate, camphor, 2,2,4 trimethyl 1,3 pentandiol and diphenyl amine was more than 90% in the case of UTC60 and UTC20. The rejection characteristics of various hazardous organic compounds were converted into one parameter Ks, which was proposed in the diffusion-convection model. The Ks of hazardous organic compounds were discussed by comparing with their solute size represented by Stokes radius. The diffusion convection model considering Ks was successful to interpret rejection characteristics of hazardous organic compounds by low-pressure nanofiltration membranes.

Engineered nanoparticles in wastewater systems: Effect of organic size on the fate of nanoparticles

  • Choi, Soohoon;Chen, Ching-Lung;Johnston, Murray V.;Wang, Gen Suh;Huang, Chin-Pao
    • Membrane and Water Treatment
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    • v.13 no.1
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    • pp.29-37
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    • 2022
  • To verify the fate and transport of engineered nanoparticles (ENP), it is essential to understand its interactions with organic matter. Previous research has shown that dissolved organic matter (DOM) can increase particle stability through steric repulsion. However, the majority of the research has been focused on model organic matter such as humic or fulvic acids, lacking the understanding of organic matter found in field conditions. In the current study, organic matter was sampled from wastewater treatment plants to verify the stability of engineered nanoparticles (ENP) under field conditions. To understand how different types of organic matter may affect the fate of ENP, wastewater was sampled and separated based on their size; as small organic particular matter (SOPM) and large organic particular matter (LOPM), and dissolved organic matter (DOM). Each size fraction of organic matter was tested to verify their effects on nano-zinc oxide (nZnO) and nano-titanium oxide (nTiO2) stability. For DOM, critical coagulation concentration (CCC) experiments were conducted, while sorption experiments were conducted for organic particulates. Results showed that under field conditions, the surface charge of the particles did not influence the stability. On the contrary, surface charge of the particles influenced the amount of sorption onto particulate forms of organic matter. Results of the current research show how the size of organic matter influences the fate and transport of different ENPs under field conditions.

Design, Synthesis and Spectral Characterization of Novel 2-morpholino-N-(4,6-diarylpyrimidin-2-yl)acetamides (새로운 2-morpholino-N-(4,6-diarylpyrimidin-2-yl)acetamides의 합성과 분광학적 특성의 연구)

  • Kanagarajan, Vijayakumar;Thanusu, Jayaraman;Gopalakrishnan, Mannathusamy
    • Journal of the Korean Chemical Society
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    • v.54 no.1
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    • pp.49-54
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    • 2010
  • A new series of novel 2-morpholino-N-(4,6-diarylpyrimidin-2-yl)acetamides 34-42 is synthesized by the condensation of 2-chloro-N-(4,6-diarylpyrimidin-2-yl)acetamides 25-33 with morpholine in the presence of anhydrous potassium carbonate. The synthesized compounds have been characterized by melting point, elemental analysis, MS, FT-IR, one-dimensional NMR ($^1H$ & $^{13}C$) spectroscopic data.

Chinese Cabbage Growth Effected by Black Vinyl Mulching and Organic Fertilizer Application in Spring Season (유기질비료 시용시 흑색비닐 멀칭이 봄 배추 생육에 미치는 영향)

  • Yun, Hong-Bae;Lee, Jong-Sik;Lee, Ye-Jin;Kim, Rog-Young;Song, Yo-Sung;Han, Seung-Gap;Lee, Yong-Bok
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1107-1111
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    • 2011
  • Organic fertilizers application has become a popular alternatives to reduce the dependence on chemical fertilizer in Korean farming systems. In this study, we evaluated the nitrogen (N) use efficiency and growth performance of Chinese cabbage grown by black vinyl mulching after application of organic and chemical fertilizers compared with no-mulching. The treatments included chemical fertilizer alone as control (NPK, N-$P_2O_5-K_2O$ : $320-78-198kg\;ha^{-1}$), organic fertilizer alone (OF100), 70% organic fertilizer and 30% chemical fertilizer (OF70+N30), and 30% organic fertilizer and 70% chemical fertilizer (OF30+N70), which were all applied in the no-mulching plots and in plots with black vinyl mulching. Daily means soil temperature was $2^{\circ}C$ higher in the black vinyl mulched treatments throughout the 54 days compared with no-mulched treatments. OF100 with black vinyl mulching gave highest soil inorganic N content. Also, Chines cabbage yield increased 46% by black vinyl mulched compared with no-mulching in OF100 treatment. Without mulching, N use efficiency was, 44, 26, 29, and 27% in NPK, OF100, OF70+N30, and OF30+N70, respectively. However, black vinyl mulching much more effectively increased N use efficiencies by 56, 55, 51, and 39% in the same treatments in the order as mentioned above. Conclusively, combined organic and chemical fertilizers application with black vinyl mulching could be good practical technique to reduce a amount of used nitrogen because of its greater ability to enhance N use efficiency.

The Luminance Characteristics of Organic ELD Based on Znq2 and TPD (Znq2와 TPD에 기초한 유기 ELD의 발광 특성)

  • Jung Seung-Jun;Park Soo-Gil
    • Journal of the Korean Electrochemical Society
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    • v.3 no.1
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    • pp.1-4
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    • 2000
  • The Bis(8-oxyquinolino) zinc lII (Znq2) were synthesized successfully from zinc chloride $(ZnCl_2)$ as a initial material . The organic electroluminescece devices (ELDs) were fabricated with N-N'-diphenyl-N-N'-bis (3-meth-ylphenyl)-1,1'-biphenyl-4,4'-diamine (TPD) which act as a hole transporting layer and the Znq2 act as an EL emitting layer and electron transporting layer. In order to maximize luminance of ELD, TPD/Znq2/Al were deposited onto cleaned indium tin oxide (ITO) by changing thickness of EL emitting layer. The photoluminescence (PL) results show that Znq2 compound emits yellow green from 540nm. electrochemical behavior with V-J and V-L curve of carrier injection was investigated from 6 V. respectively. The maximum luminance were defected about $838 cd/m^2$. From these results, ai synthesized Znq2 material maybe one of the useful material of organic EL display material.

Dispersion of Organic Phase by Agitation in a n-Hexane/p-TSA Aqueous Solution System (n-헥산/p-TSA 수용액계에서 교반에 의한 유기상의 분산)

  • Kim, Tae-Ok;Chun, Jong-Han
    • Applied Chemistry for Engineering
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    • v.2 no.3
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    • pp.209-215
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    • 1991
  • The effect of agitation on the dispersion of organic phase was investigated in an immiscible liquid system (n-hexane/40 wt % p-TSA aqueous solution). Four different types of six-bladed turbine impellers were used : a flat blade type and three screen blade types. The experimental results showed that the extent of dispersion of organic phase at the same agitation speed was decreased in the order of flat blade, 60 mesh, 40 mesh, and 20 mesh screen blades. Otherwise, it was increased with increasing the concentration of TBA as a surfactant agent and with decreasing volume fraction of organic phase. Also, the minimum agitation speed for a complete dispersion was increased in the order of flat blade, 60 mesh, 40 mesh, and 20 mesh screen blades. However, the minimum power consumption did not vary significantly. In this condition, the relationship between Power number and Reynolds number was expressed as $N_p=a\;N_{Re}{^b}$, where the values of constant a and constant b were ranged 2200~4100 and -0.69~-0.63 respectively.

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