• 제목/요약/키워드: ordered structure

검색결과 385건 처리시간 0.025초

B2형 규칙(Ni,Co)Al의 상분리와 강도 (Phase Decomposition and Strength of B2-Ordered (Ni,Co)Al)

  • 한창석;김윤채
    • 열처리공학회지
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    • 제9권2호
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    • pp.79-90
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    • 1996
  • Transmission electron microscopy(TEM) investigation on the phase decomposition of B2-ordered (Ni,Co)Al supersaturated with Ni and Co has revealed the precipitation of $(Ni,Co)_2Al$ which has not been expected from the reported equilibrium phase diagram. The $(Ni,Co)_2Al$ phase has a hexagonal struture and takes a rod-like shape with the long axis of the rod parallel to the <111> directions of the B2 matrix. By aging at temperatures below 873 K, a long period Superlattice Structure appears in the hexagonal $(Ni,Co)_2Al$ Phase. The orientation relationship between the $(Ni,Co)_2Al$ Precipitates and the B2-(Ni,Co)Al matrix is found to be$(0001)_p$ // $(111)_{B2}$ and $[\bar{1}2\bar{1}0]_P$ // $[\bar{1}10]_{B2}$, Where the suffix p and B2 denote the $(Ni,Co)_2Al$ precipitate and the B2-(Ni,Co)Al matrix, respectively. (Ni,Co)Al hardens appreciably by the fine precipitation of the $(Ni,Co)_2Al$ phase. Energy dispersive spectroscopy was used to analyze the compositions of each phase formed in B2-(Ni,Co)Al.

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Molecular Design for the Formation of Two-dimensional Molecular Networks: STM Study of ${\gamma}$-phenylalanine on Au(111)

  • Jeon, A-Ram;Youn, Young-Sang;Lee, Hee-Seung;Kim, Se-Hun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.205-205
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    • 2011
  • The self-assembly of ${\gamma}$-phenylalanine on Au(111) at 150 K was investigated using scanning tunneling microscopy (STM). Phenylalanine can potentially form two-dimensional (2D) molecular networks through hydrogen bonding (through the carboxyl and amino groups) and ${\pi}-{\pi}$ stacking interactions (via aromatic rings). We found that ${\gamma}$-phenylalanine molecules self-assembled on Au(111) surfaces into well-ordered structures such as ring-shaped clusters (at low and intermediate coverages) and 2D molecular domains (intermediate and monolayer coverages), whereas ${\alpha}$-phenylalanine molecules formed less-ordered structure on Au(111). The self-assembly of ${\gamma}$- but not ${\alpha}$-phenylalanine may be related to the flexibility of the carboxyl and amino groups in the molecule. Moreover, as expected, the 2D molecular network of ${\gamma}$-phenylalanine on Au(111) was mediated by a combination of hydrogen bonding and ${\pi}-{\pi}$ stacking interactions.

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고분자전해질형 연료전지에서 산소극을 위한 백금-크롬-니켈 합금촉매의 전극특성 (Electrode Performance of Pt-Cr-Ni Alloy Catalysts for Oxygen Electrode in Polymer Electrolyte Fuel Cell)

  • 심중표;이홍기
    • 한국재료학회지
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    • 제10권12호
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    • pp.831-837
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    • 2000
  • 고분자전해질형 연료전지에서 촉매의 활성을 증가시키기 위하여 기존에 사용되고 있는 백금과 전이금속인 chromium, nickel과의 합금을 제조하였다. XRD를 이용하여 합금의 구조가 $33^{\circ}$에서 superlattice line을 가지고 있는 것으로 보아 face centered cubic 구조를 가진 ordered alloy로 이루어졌다는 것을 알 수 있었다. 열처리 온도가 증가할수록 합금의 입자 크기는 증가하였으며, 결정 격자 상수는 감소하였다. 전지성능테스트, cyclic voltammogram 등을 통하여 mass activity, specific activity, Tafel slope, 개회로 전압을 측정한 결과, 합금촉매의 활성이 순수한 백금촉매보다 크게 향상되었음을 알 수 있었다.

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군 USN 환경에서 효율적인 데이터 저장 및 질의 처리 방법 연구 (Efficient Data Storage & Query Processing Methods in Military Ubiquitous Sensor Networks)

  • 권영모;최현식;정연돈
    • 한국군사과학기술학회지
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    • 제13권5호
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    • pp.875-885
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    • 2010
  • Recently, the role of Ubiquitous Sensor Network(USN) has been considered to be essential for supporting the near future Network Centric Warfare(NCW) and Tactical Information Communication Network(TICN). In this paper, we explore a set of data storage methods(external storage, local storage and data storage) and query processing methods in WSN. In particular, we focus on analyzing a novel data structure for supporting the local storage method, named the partial ordered tree(POT). The main idea behind POT is that sensor readings are usually correlated with the physical spatial domain. With the help of POT, only a small portion of sensor nodes participate in query processing tasks, and thus network lifetime is greatly increased. Through a series of simulation experiments, we demonstrate that the POT based local storage method clearly outperforms the existing data storage methods in terms of the energy-efficiency, which directly affects the network lifetime, for processing exact match queries, range queries and top-k queries.

The study of the c($2{\times}2$) ordered Mn surface alloy Pd(001)

  • Jung, J.W.;Kim, S.H.;Park, C.Y.;Seo, J.K.;Min, H.G.;Byun, D.H.;Kim, J.S.
    • Journal of Korean Vacuum Science & Technology
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    • 제4권3호
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    • pp.68-72
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    • 2000
  • We have deposited Mn on Pd(oon) at RT up to 30 ML. LEED pattern changed from p($1{\times}1$) to c($2{\times}2$) order below 0.5 ML Mn deposition. During Mn deposition, we have not found any changes in the peak position and the intensity of LEED I/V curve. Using LEED I/V curve analysis for each coverage, we found atomic structure and surface composition of c($2{\times}2$) ordered Mn alloy on Pd(001) surface. Above 1 Ml Mn, in the first layer the Mn subplane lies above the Pd subplane by 0.32 ${\AA}$. This result is very different from the earlier result of Jona et al., who contended that after annealing at 200 for 2 min, a buckled first layer with the Mn subplane lower than the Pd subplane by 0.2 ${\AA}$.

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양극산화공정을 이용한 고세장비의 폴리머 마스터 제작 (Fabrication of Polymer Master with High Aspect Ratio by Using Anodic Aluminum Oxidation)

  • 권종태;신홍규;서영호;김병희
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2008년도 춘계학술대회 논문집
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    • pp.285-287
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    • 2008
  • AAO(Anodic Aluminum Oxidation) method has been known that it is practically useful for the fabrication of nano-structures and makes it possible to fabricate the highly ordered nano masters on large surface and even on the 2.5 or 3D surface at low cost comparing to the expensive e-beam lithography or the conventional silicon processing. In this study, by using the multi-step anodizing and etching processes, highly ordered nano patterned master with concave shapes was fabricated. By varying the processing parameters, such as initial matter and chemical conditions; electrical and thermal conditions; time scheduling; and so on, the size and the pitch of the nano pattern can be controlled. Consequently, various alumina/aluminum nano structures can be easily available in any size and shape by optimized anodic oxidation in various aqueous acids. In order to replicate nano patterned master, the resulting good filled uniform nano molded structure through electro-forming process shows the validity of the fabricated nano pattern masters.

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이진 PAM DS UWB 통신에서 MIMO 검출 기법 (MIMO Detection Algorithms in Binary PAM DS UWB Communication)

  • 강윤정;김길남;김상준
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2009년도 춘계학술대회
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    • pp.447-450
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    • 2009
  • 본 논문에서는 2PAM(binary pulse-antipodal modulation) DS(direct-sequence) UWB(ultra-wideband) 시스템을 V-BLAST(vertical bell lab layered space-time) 구조를 사용하는 MIMO(multiple input multiple output) 시스템에 적용하여 실내 무선 채널 환경에서 고속 데이터 전송률을 달성하고자 한다. 이러한 2PAM DS UWB MIMO 시스템의 BER 성능과 송수신 안테나의 차원과의 관계가 논의된다. 또한, UWB-MIMO 시스템의 수신기에서는 ZF(zero-forcing), ZF-OSIC(ordered successive interference cancellation), MMSE(minimum-mean-square-error), MMSE-OSIC, ML(maximum likelihood)과 같은 다양한 MIMO(multiple input multiple output)와 같은 다양한 MIMO 검출기법이 비교, 분석된다.

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Ordered Micropatterns by Confined Dewetting of an Imprinted Polymer Thin Film and Their Microlens Application

  • Lee, Geun-Tak;Yoon, Bo-Kyung;Acharya, Himadri;Park, Cheol-Min;Huh, June
    • Macromolecular Research
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    • 제17권3호
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    • pp.181-186
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    • 2009
  • We fabricated ordered micro/nano patterns induced by controlled dewetting on the topographically patterned PS/P4VP bilayer thin film. The method is based on utilizing microimprinting lithography to induce a topographically heterogeneous bilayer film that allows the controlled dewetting upon subsequent thermal annealing. The dewetting that was initiated strictly at the boundary of the thicker and thinner regions was guided by the presence of the topographic structure. The dewetting front velocity of the microdomains in the confined regions was linearly proportional to the measurement time, which enabled us to control the size of the dewet domain with annealing time. In particular, the submicron sized dot arrays between lines were generated with ease when the dewetting was confined into geometry with a few microns in size. The kinetically driven, non-lithographical pattern structures accompanied the pattern reduction to 400%. The pattern arrays on a transparent glass substrate were especially useful for non-circular microlens arrays where the focal length of the lens was easily tunable by controlling the thermal annealing.

Spiral Magnetic Field Lines in a Hub-Filament Structure, Monoceros R2

  • Hwang, Jihye;Kim, Jongsoo
    • 천문학회보
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    • 제45권1호
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    • pp.59.3-60
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    • 2020
  • We present the results of polarization observations at submillimeter wavelengths towards Monoceros R2 (Mon R2). The polarized thermal dust emission was obtained from SCUBA-2/POL-2 at 450 ㎛ and 850 ㎛, simultaneously. This observation is a part of the JCMT BISTRO survey project. The polarization angle distributions at 450 ㎛ and 850 ㎛ are similar and the mean value of angle differences at two wavelengths is 5.5 degrees. The Mon R2 is one of massive star-forming regions containing a clear hub-filamentary structure. The hub region shows star formation activities, and surrounding filaments provide channels for matters to move into the hub region. It is not well known the role of magnetic fields in a hub-filamentary structure. Some studies have shown well-ordered polarization segments along a filamentary structure and magnetic field morphology traced by polarization segments is interpreted as to help gas flow along the filamentary structrue. Our observations shows that filaments in Mon R2 have spiral structure and the magnetic field lines are parallel to the filaments. We interpret that the spiral structure can be formed by a rotation hub-filament system with gas flowing along the filaments to the hub. We found several dust clumps at the central part of the hub region of the Mon R2. They seems to be formed at locations where spiral field lines meet each other. These results show one observational example that a magnetic field play a role in gas flow.

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LB박막을 이용한 프탈로시아닌의 광증감 기구에 관한 연구 (A Study on Photosensitization Mechanism of Phthalocyanines with LB Films)

  • 김범구;김영순
    • 대한화학회지
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    • 제43권1호
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    • pp.58-68
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    • 1999
  • 프탈로시아닌의 광증감 기구를 연구하기 위하여 가용성 프탈로시아닌, copper(II) 4,5-dicarboxyphthalocyanine[CuPc$(COOH)_2$]와 copper(II) 4,5,4',5'-tetracarboxyphthalocyanine[CuPc$(COOH)_4$]을 합성하였다. 합성된 프탈로시아닌 유도체의 단분자층을 ITO유리기판 위에 LB방법으로 만들었다. CuPc$(COOH)_2$ 의 LB단분자층이 CuPc$(COOH)_4$의 막보다 더 규칙적인 배열구조를 가진 시료가 만들어짐을 표면압력-면적 곡선으로써 확인하였고 프탈로시아닌 유도체의 LB단분자층의 광전류를 측정하였더니 규칙적인 배열의 CuPc$(COOH)_2$[$i_{max}$=20.84nA]가 CuPc$(COOH)_4$[$i_{max}$=10.50nA]보다 전하발생효율이 거의 두배로 나타나는 결과를 얻었다.

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