• Title/Summary/Keyword: ordered structure

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Phase Decomposition and Strength of B2-Ordered (Ni,Co)Al (B2형 규칙(Ni,Co)Al의 상분리와 강도)

  • Han, Chang-Suck;Kim, Youn-Che
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.2
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    • pp.79-90
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    • 1996
  • Transmission electron microscopy(TEM) investigation on the phase decomposition of B2-ordered (Ni,Co)Al supersaturated with Ni and Co has revealed the precipitation of $(Ni,Co)_2Al$ which has not been expected from the reported equilibrium phase diagram. The $(Ni,Co)_2Al$ phase has a hexagonal struture and takes a rod-like shape with the long axis of the rod parallel to the <111> directions of the B2 matrix. By aging at temperatures below 873 K, a long period Superlattice Structure appears in the hexagonal $(Ni,Co)_2Al$ Phase. The orientation relationship between the $(Ni,Co)_2Al$ Precipitates and the B2-(Ni,Co)Al matrix is found to be$(0001)_p$ // $(111)_{B2}$ and $[\bar{1}2\bar{1}0]_P$ // $[\bar{1}10]_{B2}$, Where the suffix p and B2 denote the $(Ni,Co)_2Al$ precipitate and the B2-(Ni,Co)Al matrix, respectively. (Ni,Co)Al hardens appreciably by the fine precipitation of the $(Ni,Co)_2Al$ phase. Energy dispersive spectroscopy was used to analyze the compositions of each phase formed in B2-(Ni,Co)Al.

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Molecular Design for the Formation of Two-dimensional Molecular Networks: STM Study of ${\gamma}$-phenylalanine on Au(111)

  • Jeon, A-Ram;Youn, Young-Sang;Lee, Hee-Seung;Kim, Se-Hun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.205-205
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    • 2011
  • The self-assembly of ${\gamma}$-phenylalanine on Au(111) at 150 K was investigated using scanning tunneling microscopy (STM). Phenylalanine can potentially form two-dimensional (2D) molecular networks through hydrogen bonding (through the carboxyl and amino groups) and ${\pi}-{\pi}$ stacking interactions (via aromatic rings). We found that ${\gamma}$-phenylalanine molecules self-assembled on Au(111) surfaces into well-ordered structures such as ring-shaped clusters (at low and intermediate coverages) and 2D molecular domains (intermediate and monolayer coverages), whereas ${\alpha}$-phenylalanine molecules formed less-ordered structure on Au(111). The self-assembly of ${\gamma}$- but not ${\alpha}$-phenylalanine may be related to the flexibility of the carboxyl and amino groups in the molecule. Moreover, as expected, the 2D molecular network of ${\gamma}$-phenylalanine on Au(111) was mediated by a combination of hydrogen bonding and ${\pi}-{\pi}$ stacking interactions.

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Electrode Performance of Pt-Cr-Ni Alloy Catalysts for Oxygen Electrode in Polymer Electrolyte Fuel Cell (고분자전해질형 연료전지에서 산소극을 위한 백금-크롬-니켈 합금촉매의 전극특성)

  • Sim, Jung-Pyo;Lee, Hong-Gi
    • Korean Journal of Materials Research
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    • v.10 no.12
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    • pp.831-837
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    • 2000
  • To improve the catalytic activity of platinum on polymer electrolyte fuel cell(PEFC), platinum was alloyed with cobalt and nickel at various temperature. By XRD, it was observed the crystal structure of alloy catalysts were the ordered face centered cubic(f.c.c) due to the superlattice line at $33^{\circ}$. As heat-treatment temperature was increased, the particle size of alloys also were increased and the crystalline lattice parameters were decreased. According to the results from mass activity, specific activity and Tafel slope measured by cell performance test and cyclic voltammogram, the catalyst activities of alloys are higher than that pure platinum.

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Efficient Data Storage & Query Processing Methods in Military Ubiquitous Sensor Networks (군 USN 환경에서 효율적인 데이터 저장 및 질의 처리 방법 연구)

  • Kwon, Young-Mo;Choi, Hyun-Sik;Chung, Yon-Dohn
    • Journal of the Korea Institute of Military Science and Technology
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    • v.13 no.5
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    • pp.875-885
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    • 2010
  • Recently, the role of Ubiquitous Sensor Network(USN) has been considered to be essential for supporting the near future Network Centric Warfare(NCW) and Tactical Information Communication Network(TICN). In this paper, we explore a set of data storage methods(external storage, local storage and data storage) and query processing methods in WSN. In particular, we focus on analyzing a novel data structure for supporting the local storage method, named the partial ordered tree(POT). The main idea behind POT is that sensor readings are usually correlated with the physical spatial domain. With the help of POT, only a small portion of sensor nodes participate in query processing tasks, and thus network lifetime is greatly increased. Through a series of simulation experiments, we demonstrate that the POT based local storage method clearly outperforms the existing data storage methods in terms of the energy-efficiency, which directly affects the network lifetime, for processing exact match queries, range queries and top-k queries.

The study of the c($2{\times}2$) ordered Mn surface alloy Pd(001)

  • Jung, J.W.;Kim, S.H.;Park, C.Y.;Seo, J.K.;Min, H.G.;Byun, D.H.;Kim, J.S.
    • Journal of Korean Vacuum Science & Technology
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    • v.4 no.3
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    • pp.68-72
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    • 2000
  • We have deposited Mn on Pd(oon) at RT up to 30 ML. LEED pattern changed from p($1{\times}1$) to c($2{\times}2$) order below 0.5 ML Mn deposition. During Mn deposition, we have not found any changes in the peak position and the intensity of LEED I/V curve. Using LEED I/V curve analysis for each coverage, we found atomic structure and surface composition of c($2{\times}2$) ordered Mn alloy on Pd(001) surface. Above 1 Ml Mn, in the first layer the Mn subplane lies above the Pd subplane by 0.32 ${\AA}$. This result is very different from the earlier result of Jona et al., who contended that after annealing at 200 for 2 min, a buckled first layer with the Mn subplane lower than the Pd subplane by 0.2 ${\AA}$.

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Fabrication of Polymer Master with High Aspect Ratio by Using Anodic Aluminum Oxidation (양극산화공정을 이용한 고세장비의 폴리머 마스터 제작)

  • Kwon, J.T.;Shin, H.G.;Seo, Y.H.;Kim, B.H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.285-287
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    • 2008
  • AAO(Anodic Aluminum Oxidation) method has been known that it is practically useful for the fabrication of nano-structures and makes it possible to fabricate the highly ordered nano masters on large surface and even on the 2.5 or 3D surface at low cost comparing to the expensive e-beam lithography or the conventional silicon processing. In this study, by using the multi-step anodizing and etching processes, highly ordered nano patterned master with concave shapes was fabricated. By varying the processing parameters, such as initial matter and chemical conditions; electrical and thermal conditions; time scheduling; and so on, the size and the pitch of the nano pattern can be controlled. Consequently, various alumina/aluminum nano structures can be easily available in any size and shape by optimized anodic oxidation in various aqueous acids. In order to replicate nano patterned master, the resulting good filled uniform nano molded structure through electro-forming process shows the validity of the fabricated nano pattern masters.

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MIMO Detection Algorithms in Binary PAM DS UWB Communication (이진 PAM DS UWB 통신에서 MIMO 검출 기법)

  • Kang, Yun-jeong;Kim, Gil-nam;Kim, Sang-choon
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2009.05a
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    • pp.447-450
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    • 2009
  • In this paper, binary pulse-antipodal modulation (2PAM) direct-sequence (DS) ultra-wideband (UWB) system is applied to multiple input multiple output (MIMO) system using vertical bell lab layered space-time (V-BLAST) structure to achieve high-data-rate communications over indoor wireless channels. The relationship between antenna dimension and BER performance of 2PAM DS UWB MIMO system is discussed. In the receiver of UWB-MIMO system, various MIMO detection algorithms such as zero-forcing (ZF), ZF-ordered successive interference cancellation (OSIC), minimum-mean-square-error (MMSE), MMSE-OSIC and maximum likelihood (ML) are comparatively studied.

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Ordered Micropatterns by Confined Dewetting of an Imprinted Polymer Thin Film and Their Microlens Application

  • Lee, Geun-Tak;Yoon, Bo-Kyung;Acharya, Himadri;Park, Cheol-Min;Huh, June
    • Macromolecular Research
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    • v.17 no.3
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    • pp.181-186
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    • 2009
  • We fabricated ordered micro/nano patterns induced by controlled dewetting on the topographically patterned PS/P4VP bilayer thin film. The method is based on utilizing microimprinting lithography to induce a topographically heterogeneous bilayer film that allows the controlled dewetting upon subsequent thermal annealing. The dewetting that was initiated strictly at the boundary of the thicker and thinner regions was guided by the presence of the topographic structure. The dewetting front velocity of the microdomains in the confined regions was linearly proportional to the measurement time, which enabled us to control the size of the dewet domain with annealing time. In particular, the submicron sized dot arrays between lines were generated with ease when the dewetting was confined into geometry with a few microns in size. The kinetically driven, non-lithographical pattern structures accompanied the pattern reduction to 400%. The pattern arrays on a transparent glass substrate were especially useful for non-circular microlens arrays where the focal length of the lens was easily tunable by controlling the thermal annealing.

Spiral Magnetic Field Lines in a Hub-Filament Structure, Monoceros R2

  • Hwang, Jihye;Kim, Jongsoo
    • The Bulletin of The Korean Astronomical Society
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    • v.45 no.1
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    • pp.59.3-60
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    • 2020
  • We present the results of polarization observations at submillimeter wavelengths towards Monoceros R2 (Mon R2). The polarized thermal dust emission was obtained from SCUBA-2/POL-2 at 450 ㎛ and 850 ㎛, simultaneously. This observation is a part of the JCMT BISTRO survey project. The polarization angle distributions at 450 ㎛ and 850 ㎛ are similar and the mean value of angle differences at two wavelengths is 5.5 degrees. The Mon R2 is one of massive star-forming regions containing a clear hub-filamentary structure. The hub region shows star formation activities, and surrounding filaments provide channels for matters to move into the hub region. It is not well known the role of magnetic fields in a hub-filamentary structure. Some studies have shown well-ordered polarization segments along a filamentary structure and magnetic field morphology traced by polarization segments is interpreted as to help gas flow along the filamentary structrue. Our observations shows that filaments in Mon R2 have spiral structure and the magnetic field lines are parallel to the filaments. We interpret that the spiral structure can be formed by a rotation hub-filament system with gas flowing along the filaments to the hub. We found several dust clumps at the central part of the hub region of the Mon R2. They seems to be formed at locations where spiral field lines meet each other. These results show one observational example that a magnetic field play a role in gas flow.

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A Study on Photosensitization Mechanism of Phthalocyanines with LB Films (LB박막을 이용한 프탈로시아닌의 광증감 기구에 관한 연구)

  • Kim, Bum Goo;Kim, Young Soon
    • Journal of the Korean Chemical Society
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    • v.43 no.1
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    • pp.58-68
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    • 1999
  • The phthalocyanine(Pc) film can not be prepared by LB method because it is insoluble in organic solvents. In order to increase its solubility, two kinds of copper phthalocyanine derivatives (CuPc$(COOH)_2$ and CuPc$(COOH)_4$) were synthesized and their monolayers were prepared by LB method. It is found from the surface pressure-area curves that the LB monolayer film of CuPc$(COOH)_2$ have more ordered structure than that of CuPc$(COOH)_4$. In the photocurrent characteristic the value Of CuPc$(COOH)_2$ was superior to that of CuPc $(COOH)_4$. Therefore, it is found that the charge generation efficiency for phthalocyanines have influenced on its ordered structure as the functional groups.

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