• 제목/요약/키워드: orange

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Removal of ciprofloxacin from aqueous solution by activated carbon prepared from orange peel using zinc chloride

  • Koklu, Rabia;Imamoglu, Mustafa
    • Membrane and Water Treatment
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    • 제13권3호
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    • pp.129-137
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    • 2022
  • In this study, the removal of Ciprofloxacin (CPX) from aqueous solutions was investigated by a new activated carbon adsorbent prepared from orange peel (ACOP) with chemical activation using ZnCl2. The physicochemical properties of orange peel activated carbon were characterized by proximate and ultimate analysis, scanning electron microscopy, BET surface area determination and Fourier transformation infrared spectroscopic studies. According to Brunauer-Emmett-Teller isotherm and non-local-density functional theory, the cumulative surface area, pore volume and pore size of ACOP were determined as 1193 m2 g-1, 0.83 cc g-1 and 12.7 Å, respectively. The effects of contact time, pH, temperature and ACOP dose on the batch adsorption of CPX were studied. Adsorption equilibrium data of CPX with ACOP were found to be compatible with both the Langmuir and Freundlich isotherms. CPX adsorption capacity of ACOP was calculated as 181.8 mg g-1 using Langmuir isotherm. The CPX adsorption kinetics were found to be harmonious with the pseudo-second-order kinetic model. Conclusively, ACOP can be assessable as an effective adsorbent for the removal of ciprofloxacin (CPX) from aqueous solutions.

OLED 조명을 위한 Yellow, Orange, Red 인광 재료 (Yellow, Orange, and Red Phosphorescent Materials for OLED Lightings)

  • 정효철;박영일;김범진;박종욱
    • 공업화학
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    • 제26권3호
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    • pp.247-250
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    • 2015
  • 유기 발광 다이오드(OLED)는 학문 및 산업 분야에서 많은 관심을 받아왔다. OLED는 기존에 사용되고 있는 광원들과는 달리 면 발광, 친환경적인 에너지 사용, 대면적, 초경량, 그리고 초박형 등의 차별화된 특징을 가지고 있기 때문에 최근 조명 시장에서 많은 관심을 받고 있다. 게다가, OLED 조명은 LED 형광등을 대체할 수 있는 차세대 조명으로써 주목되고 있다. 본 논문에서는 white OLED (WOLED)에 적용되고 있는 대표적인 인광 발광 재료들을 소개하며, 특히 yellow, orange, red 인광 물질들의 화학구조와 소자효율을 정리하였다. 이러한 선행연구의 물질들을 이해하고 인광 물질들을 체계적으로 분류함으로써 새로운 발광 재료를 연구하고 개발함에 있어서 많은 도움이 되리라고 생각한다.

고엽제의 건강위해성 평가를 위한 연구설계와 방법 제안 (A Proposal of study Designs and Methods for Evaluating the Adverse Health Effects of Agent Orange among Korean Vietnam Veterans)

  • 이상욱;원종욱;홍재석;오희철
    • Journal of Preventive Medicine and Public Health
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    • 제34권3호
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    • pp.228-236
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    • 2001
  • Objectives : To propose a feasible, valid and appropriate study designs and epidemiologic methods for evaluating the adverse health effects of Agent Orange-chemical defoliants used in Vietnam- in Korea. Methods : A literature study was peformed on Agent Orange, herbicides, pesticides and dioxins. The study subjects, study design, exposure assessment and health outcomes assessment were examined in each study. The potential data sources for the study subjects, study design, exposure assessment and health outcomes assessment in Korea were investigated. Results and Conclusion : In earlier Korean studies, research subjects for studying the effects of Agent Orange were identified from the patients or persons who claimed to have Agent Orange-related diseases due to the difficulties in identifying the entire population of Vietnam veterans in Korea. In this study, an attempt was made to identify the total number of Vietnam veterans in Korea. As a result, the addresses of 20,000 Vietnam veterans were obtained. It is proposed that a retrospective cohort design on a sample of the total number of Vietnam veterans is a feasible and appropriate study design. Self report questionnaires and military records were proposed to assess the exposure level. It is believed that measuring the plasma or tissue TCDD should be used only for a validation study assessing the level of exposure. For the health outcomes assessment, it is possible to obtain the mortality, cancer frequency, physical examination, screening and medical insurance record data.

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Aspergillus Saitoi가 생산(生産)하는 섬유소분해효소(纖維素分解酵素)에 관(關)한 연구(硏究) -(1 보(1 報)) 온주밀감 통조림 제조시(製造時) 내과피(內果皮) 분해제거(分解除去)에 관(關)한 연구(硏究)- (Studies on Cellulolytic Enzymes produced by Aspergillus saitoi -(1) Studies on the endocarp remove canning process of mandarine orange syrup-)

  • 이순애;오석흔;윤정의;이성호
    • 한국식품과학회지
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    • 제3권1호
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    • pp.25-28
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    • 1971
  • Aspergillus saitoi가 생산(生産)하는 섬유소분해효소(纖維素分解酵素)의 생산조건(生産條件)과 밀감내과피(內果皮)의 탈피효과(脫皮效果)를 검토한 결과(結果)는 다음과 같다. 1. Asp. saitoi의 배양최적(培養最適) 온도(溫度)는 $30^{\circ}C$, 시간(時間)은 72시간(時間)에서 섬유소(纖維素) 생성능(生成能)이 가장 좋았다. 2. 본효소(本酵素)를 10배(倍) 농도로 희석하여 (희석효소액 : 밀감 2 : 1) $40^{\circ}C$의 항온조(恒溫槽)에서 $3.5{\sim}4$시간(時間) 작용(作用)시킨 것이 탈피정도(脫皮程度), 풍미(風味), 광택(光澤)이 우수하여 밀감 syrup 통조림 제조조건으로 최적(最適)이었다.

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강황 추출물, 오렌지피 및 전해수 처리가 날치(Cypselurus agoo agoo)알의 품질에 미치는 효과 (Effects of Curcuma aromatica Extract and Orange Rind Mixed Liquor on the Quality of Cypselurus agoo agoo Roe Treated with Electrolyzed Water)

  • 김꽃봉우리;김동현;선우찬;홍용기;안동현
    • 한국수산과학회지
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    • 제45권2호
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    • pp.122-131
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    • 2012
  • This study was performed to examine the effects of Curcuma aromatica (CA) and orange rind on the quality and sensory score of flying fish $Cypselurus$ $agoo$ $agoo$ roe treated with electrolyzed water during frozen storage ($-18^{\circ}C$). The pH was decreased with increasing amounts of CA extract added to flying fish roe and during frozen storage. The flying fish roe treated with CA extract showed increased yellowness, as compared to flying fish roe with no CA extract added and untreated with electrolyzed water (untreated). The flying fish roe containing CA extract maintained greater hardness than did untreated flying fish roe. The volatile basic nitrogen and trimethylamine contents of treated flying fish roe were lower than those of untreated flying fish roe during frozen storage. The results of volatile organic compound tests showed that the contents of alcohol, acid and ketone compounds in flying fish roe treated with CA extract and orange rind were relatively decreased, but the limonene content of treated flying fish roe was increased compared to that of untreated flying fish roe. In sensory evaluation, flying fish roe containing 0.05 and 0.1% of CA were preferred over others. In conclusion, CA and orange rind increased the quality and sensory scores of flying fish roe treated with electrolyzed water.

무지개 당근의 carotenoid와 당 함량 분석 (Analysis of carotenoids and soluble sugars in the Rainbow carrots)

  • 김사랑;김연미;전상진;박종태;김재한
    • 농업과학연구
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    • 제41권2호
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    • pp.107-112
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    • 2014
  • Coloring agents in food materials plays important roles in the development of attractive products as well as in the functionality of food such as antioxidant or vitamin supplementation. Carrot has been used as an orange coloring agent in the decoration of food but also a major source of vitamin A complex. Though orange has been considered a typical color of carrot, the Rainbow carrot has been developed recently, which exhibit the various colors such as red, pale yellow, purple, orange or their mixtures. After categorization onto 8 groups by their colors, vitamin A complex (${\beta}$-carotene, lycopene and lutein) and soluble sugars (glucose, fructose, and sucrose) have been analyzed in carrots. The ${\beta}$-carotene was abundant in the groups of orange (Group-O) or groups with the orange color (group-OP, and group-YOP). The content of lycopene content was exclusively high in the red color carrot (group-R). The highest lutein contents were observed from the yellow-purple (group-YP) group. Meanwhile, little amounts of lycopene and ${\beta}$-carotene were observed in yellow-purple (group-YP) nor yellow (group-Y) on yellow (group-Y). Among the reducing sugars in 'rainbow carrots', the amount of sucrose was two times higher than those of fructose and glucose. However, the content of glucose, fructose and sucrose as well as the total reducing sugars did not differ between color groups suggesting little variations on their tastes.

WTO 반덤핑협정하의 제로잉 효과와 적법성 - 미국-오렌지주스 사건을 중심으로 - (A Study on Effect and Legitimacy of Zeroing on the WTO Anti-dumping Agreement - Focusing on US-Orange Juice case -)

  • 김철수;하충룡
    • 통상정보연구
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    • 제16권3호
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    • pp.465-486
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    • 2014
  • 본 연구는 브라질 오렌지 주스사건의 제로잉에 대한 판결을 분석하고 있다. 미국은 동 사건에서 행정재심사에서 제로잉을 사용하였고, '거래에 대한 가중평균' 제로잉의 사용을 금한다는 이전 상소기구의 판례를 따르는 패널 판결이 내려졌다. 그러나 패널의 판결이 분쟁해결시스템내의 '안정성과 예측가능성'을 고려하여 나왔다는 점에 주목하면서, 동일한 법적 문제에 대한 상소기구의 판례에 대한 선례구속원칙이 암묵적으로 적용되고 있음을 판단할 수 있었다. 하지만 상소기구의 판결에 대한 패널의 이견 또한 확인할 수 있었다. 미국-오렌지주스사건의 판결이 오랫동안 이어져 온 제로잉 사용을 금지할 수 있을 것 같지만 제2.4조 하의 공정비교요건의 확대적용은 제로잉에 대한 쟁점을 지속시킬 가능성을 가지고 있는 것으로 판단된다. 다행스러운 것은 동 사건의 판결에 맞추어 행정재심사에 대한 제로잉을 금지하겠다는 미국의 발표가 있었다. 결국 제로잉에 대한 여러 분쟁이 남아있지만, 미국-오렌지주스 사건의 판결이 반덤핑협정하의 제로잉관행에 대한 최종적인 판결이라고 조심스럽게 예상해 본다.

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Metabolic engineering of Lilium ${\times}$ formolongi using multiple genes of the carotenoid biosynthesis pathway

  • Azadi, Pejman;Otang, Ntui Valentaine;Chin, Dong Poh;Nakamura, Ikuo;Fujisawa, Masaki;Harada, Hisashi;Misawa, Norihiko;Mii, Masahiro
    • Plant Biotechnology Reports
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    • 제4권4호
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    • pp.269-280
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    • 2010
  • Lilium ${\times}$ formolongi was genetically engineered by Agrobacterium-mediated transformation with the plasmid pCrtZW-N8idi-crtEBIY, which contains seven enzyme genes under the regulation of the CaMV 35S promoter. In the transformants, ketocarotenoids were detected in both calli and leaves, which showed a strong orange color. In transgenic calli, the total amount of carotenoids [133.3 ${\mu}g/g$ fresh weight (FW)] was 26.1-fold higher than in wild-type calli. The chlorophyll content and photosynthetic efficiency in transgenic orange plantlets were significantly lowered; however, after several months of subculture, they had turned into plantlets with green leaves that showed significant increases in chlorophyll and photosynthetic efficiency. The total carotenoid contents in leaves of transgenic orange and green plantlets were quantified at 102.9 and 135.2 ${\mu}g/g$ FW, respectively, corresponding to 5.6- and 7.4-fold increases over the levels in the wild-type. Ketocarotenoids such as echinenone, canthaxanthin, 3'-hydroxyechinenone, 3-hydroxyechinenone, and astaxanthin were detected in both transgenic calli and orange leaves. A significant change in the type and composition of ketocarotenoids was observed during the transition from orange transgenic plantlets to green plantlets. Although 3'-hydroxyechinenone, 3-hydroxyechinenone, astaxanthin, and adonirubin were absent, and echinenone and canthaxanthin were present at lower levels, interestingly, the upregulation of carotenoid biosynthesis led to an increase in the total carotenoid concentration (+31.4%) in leaves of the transgenic green plantlets.

오렌지향과 valeric acid향에 대한 뇌파와 자율신경계반응에 나타난 후각 감성 (Differences of EEG and autonomic responses between olfactory stimuli with orange and valeric acid in human)

  • 백은주;이윤영;이배환;문창현;이수환
    • 한국감성과학회:학술대회논문집
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    • 한국감성과학회 1997년도 한국감성과학회 연차학술대회논문집
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    • pp.75-79
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    • 1997
  • The present study was designed to investigate whether there is a consistint changes in the signals from the central and autonomic nervous systim due to olfactory stimulation. The olfactory stimuli were 0.6% orange and 2.5% valeric acid and the stimuli through the olfactory stimulator soth controlled consistint flow, controlled concentration, and saturated with vapour to prevent drying the nasal mucosa. A room air blunk served as the control stimulus, EEG was recorede from 4channels according to the international 10-20 systim. Additionally, ECG, EOG, heart rate, skin conductance and resputation were recorded comtinuously. The fast Fourier transform analysis of EEG waves was analysed with the power spectra. Averaged power spectra were computed for the following frequency bands ; delta(0-4.5Hz), theta (4.5-7Hz), alphal(7-9.5Hz), alpha2 (9.5-12.5Hz) and beta(12.5-30Hz). Withthe results of the subjective sensibility test for the ordor, the orange was related to pleasant and familiar and the valeric acid was realted to snpleasant and bothersome. There is the difference between orange and valeric acid in alphal at PG2-A2 channel. While the unpleasant stimuli seem to be increased in alphal, alpha2 and beta waves at all channels. Also, the heart rate, galvaric skin resistance seem to be decreased by pleasant stimuli and thd unpleasant stimuli shdwed the opposite. In respiration, respiration rate had been declinig tendency, and input/output ampoitued and duration showed an upward trend by olfactory stimulation with orange, while opposite by valeric acid. In conclusion, the consistent EEG changes and the autonomic responses suggests the possibilities of the subjective signal of human sensibility.

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Orange Phosphorescent Organic Light-emitting Diodes Using a Spirobenzofluorene-type Phospine Oxides as Host Materials

  • Jeon, Young-Min;Lee, In-Ho;Lee, Chil-Won;Lee, Jun-Yeob;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • 제31권10호
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    • pp.2955-2960
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    • 2010
  • Spiro-type orange phosphorescent host materials, 9-diphenylphosphine oxide-spiro[fluorene-7,9'-benzofluorene] (OPH-1P) and 5-diphenylphosphine oxide-spiro[fluorene-7,9'-benzofluorene] (OPH-2P) were successfully prepared by a lithiation reaction followed by a phosphination reaction with diphenylphosphinic chloride. The EL characteristics of OPH-1P and OPH-2P as orange host materials doped with iridium(III) bis(2-phenylquinoline)acetylacetonate ($Ir(pq)_2acac$) were evaluated. The electroluminescence spectra of the ITO (150 nm)/DNTPD (60 nm)/NPB (30 nm)/OPH-1P or OPH-2P: $Ir(pq)_2acac$ (30 nm)/BCP (5 nm)/$Alq_3$ (20 nm)/LiF (1 nm)/Al (200 nm) devices show a narrow emission band with a full width at half maximum of 75 nm and $\lambda_{max}$ = 596 nm. The device obtained from OPH-1P doped with 3% $Ir(pq)_2acac$ showed an orange color purity of (0.580, 0.385) and an efficiency of (14 cd/A at 7.0 V). The ability of the OPH-P series to combine a high triple energy with a low operating voltage is attributed to the inductive effect of the P=O moieties and subsequent energy lowering of the LUMO, resulting in the enhancement of both the electron injection and transport in the device. The overall result is a device with an EQE > 8% at high brightness, but operating voltage of less than 6.4 V, as compared to the literature voltages of ~10 V.