• Title/Summary/Keyword: optimum site

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Synthesis of Garnet in the Ca-Ce-Gd-Zr-Fe-O System (Ca-Gd-Ce-Zr-Fe-O계에서의 석류석 합성 연구)

  • Chae Soo-Chun;Jang Young-Nam;Bae In-Kook;Yudintsev S.V.
    • Economic and Environmental Geology
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    • v.38 no.2 s.171
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    • pp.187-196
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    • 2005
  • Structural sites which cations can occupy in garnet structure are centers of the tetrahedron, octahedron, and distorted cube sharing edges with the tetrahedron and octahedron. Among them, the size of cation occuping at tetrahedral site (the center of tetrahedron) is closely related with the size of a unit cell of garnet. Accordingly, garnet containing iron with relative large ionic radii in tetrahedral site can be considered as a promising matrix for the immobilization of the elements with large ionic radii, such as actinides in radioactive wastes. We synthesized several garnets with the batch composition of $Ca_{1.5}GdCe_{0.5}ZrFeFe_3O_{12}$, and studied their properties and phase relations under various conditions. Mixed samples were fabricated in a pellet form under a pressure of $200{\~}400{\cal}kg/{\cal}cm^2$ and were sintered in the temperature range of $1100\~1400^{\circ}C$ in air and under oxygen atmospheres. Phase identification and chemical analysis of synthesized samples were conducted by XRD and SEM/EDS. In results, garnet was obtained as the main phase at $1300^{\circ}C$, an optimum condition in this system, even though some minor phases like perovskite and unknown phase were included. The compositions of garnet and perovskite synthesized from the batch composition of $Ca_{1.5}GdCe_{0.5}ZrFeFe_3O_{12}$ were ranged $[Ca_{l.2-1.8}Gd_{0.9-1.4}Ce_{0.3-0.5}]^{VIII}[Zr_{0.8-1.3}Fe_{0.7-1.2}]^{VI}[Fe_{2.9-3.1}]^{IV}O_{12}$ and $Ca_{0.1-0.5}Gd_{0.0-0.8}Ce_{0.1-0.5}\;Zr_{0.0-0.2}Fe_{0.9-1.1}O_3$, respectively. Ca content was exceeded and Ce content was depleted in the 8-coordinated site, comparing to the initial batch composition. This phenomena was closely related to the content of Zr and Fe in the 6-coordinated site.

A Study on the Vegetation Landscape and Management Methods of Buyongdae on Hahoe Village, Andong (안동 하회마을 부용대(芙蓉臺) 일원의 식물상 및 관리방안)

  • Oh, Hyun-Kyung;Rho, Jae-Hyun;Choi, Yung-Hyun
    • Journal of the Korean Institute of Traditional Landscape Architecture
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    • v.31 no.1
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    • pp.13-27
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    • 2013
  • This study investigated flora and vascular plants area around Buyongdae where include optimum view point Okyeonjeongsa and Gyeomamjeongsa in Hahoe Village, Andong. Based on the findings, the aim of results was attempted to suggest the management plan of the vegetation area around Buyongdae which designated UNESCO World cultural heritage and folk village in Korea. The results of the study is as the following. All flora of this site, Buyongdae in Andong, were 301 taxa; 89 families, 217 genera, 251 species, 1 subspecies, 38 varieties and 11 forms. Vegetation of each of areas in site was classified Pinus densiflora as representative forest around Buyongdae, Quercus variabilis forest around Gyeomamjjeongsa and Koelreuteria paniculata forest in river cliff of Buyongdae. The 14 taxa(Polygala tenuifolia, Koelreuteria paniculata, and others) as the rare plants and the 7 taxa(Weigela subsessilis, and others) as endemic species were recorded in the surveyed site among the whole flora. The specific plants which is categorized to degree by the Ministry of Environment appeared as 32 taxa; degree IV was 4 species; Polygala tenuifolia, etc. and degree III was 10 species; Hypodematium glandulosopilosum, Pyrrosia petiolosa, etc. and degree I was 13 species; Hemiptelea davidii, Zizyphus jujuba var. jujuba, etc. Also, the 11 taxa were recorded in limestone area as the chamaephyte; Hypodematium glandulosopilosum, Celtis koraiensis, Siphonostegia chinensis, Artemisia gmelini, and others. The naturalized plants recorded as 25 taxa; Viola arvensis, Erechtites hieracifolia, etc. and invasion of Sicyos angulatus which is ecosystem disturbing plants. The naturalization rate(NR) was 8.3% and the urbanization index(UI) was 7.8% by field survey. For recovery of indigenous to traditional vegetation landscape in Buyongdae, Pinus rigida of upper-growth and Alnus sibirica of middle-growth need thinning. In addition, the site demands both sustainable management through long-term monitering and gradual elimination method for the naturalized plants including Sicyos angulatus where found in Kyumamjeongsa. Particularly, intentional planting for decoration and cultivation around Hwachunseowon, Helianthus tuberosus must be substitute with the native plants. Meanwhile, Polygala tenuifolia is potently demanded preventing habitate, confirming additional habitate, seed securing and preservation of gene resource internally or externally. Koelreuteria paniculata; denoting feature of river cliff, including Hypodematium glandulosopilosum, Siphonostegia chinensis, Zizyphus jujuba var. jujuba, Pyrrosia petiolosa, and Celtis koraiensis, also need an assertive preservation. Futhermore, Wisteria floribunda for. floribunda, located around Galmo rock to Chunggil course, remained by colonizing form, need preservation and observation for a while. Beside that, the information boards are required to educate visiting user about safe regulations on the narrow way in rock hill.

Molecular Cloning and Characterization of a Bile Salt Hydrolase from Lactobacillus acidophilus PF01

  • Oh, Hae-Keun;Lee, Ji-Yoon;Lim, Soo-Jin;Kim, Min-Jeong;Kim, Geun-Bae;Kim, Jung-Hoan;Hong, Soon-Kwang;Kang, Dae-Kyung
    • Journal of Microbiology and Biotechnology
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    • v.18 no.3
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    • pp.449-456
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    • 2008
  • Phenotypic screening for bile salt hydrolase (BSH) activity was performed on Lactobacillus acidophilus PF01 isolated from piglet feces. A gene encoding BSH was identified and cloned from the genomic library of L. acidophilus PF01. The bsh gene and surrounding regions were characterized by nucleotide sequence analysis and were found to contain a single open reading frame (ORF) of 951 nucleotides encoding a 316 amino acid protein. The potential bsh promoter region was located upstream of the start codon. The protein deduced from the complete ORF had high similarity with other BSHs, and four amino acid motifs located around the active site, FGRNXD, AGLNF, VLTNXP, and GXGXGXXGXPGD, were highly conserved. The bsh gene was cloned into the pET21b expression vector and expressed in Escherichia coli BLR(DE3) by induction with 0.1mM of isopropylthiogalactopyranoside. The BSH enzyme was purified with apparent homogeneity using a $Ni^{2+}$-NTA agarose column and characterized. The overexpressed recombinant BSH enzyme of L. acidophilus PF01 exhibited hydrolase activity against tauroconjugated bile salts, but not glycoconjugated bile salts. It showed the highest activity against taurocholic acid. The maximum BSH activity occurred at approximately $40^{\circ}C$. The enzyme maintained approximately 70% of its maximum activity even at $60^{\circ}C$, whereas its activity rapidly decreased at below $37^{\circ}C$. The optimum pH was 6, and BSH activity was rapidly inactivated below pH 5 and above pH 7.

A Study on the Location Analysis of Public Service Facilities Considering Spatial Efficiency and Equity (효율성과 형평성을 고려한 공공시설 입지분석에 관한 연구 - 금산군 문화시설을 대상으로 -)

  • Yun, Jeong-Mi;Lee, Shin-Hoon
    • Journal of the Korean Association of Geographic Information Studies
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    • v.13 no.2
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    • pp.1-10
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    • 2010
  • The purpose of this research is to establish location models for public service facilities considering efficiency as well as equity. And it suggests the method of spatial evaluation reflected the real world. Finally, this research is applied to the analysis on the optimum location of cultural facilities in Geumsan. This research adopts the expert survey for site selection factors and applys AHP for the relative weights. Secondly, it assorts the urban area by satellite image for the spatial analysis on the real world. Next, it adopts the Location-Allocation Model for the location evaluation and embodies the unequal population distribution according to the location model establishment. Finally, it conducts the more specific spatial analysis reflected the real world through the two methods applications; both spatial analysis(Grid analysis) and Network analysis.

Effects of Eu3+ and Tb3+ Activator Ions on the Properties of SrSnO3 Phosphors (Eu3+와 Tb3+ 활성제 이온이 SrSnO3 형광체의 특성에 미치는 영향)

  • Kim, Jung Dae;Cho, Shinho
    • Korean Journal of Materials Research
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    • v.24 no.9
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    • pp.469-473
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    • 2014
  • $SrSnO_3$ phosphor powders were synthesized with two different contents of activator ions $Eu^{3+}$ and $Tb^{3+}$ using the solid-state reaction method. The structural, morphological, and optical properties of the phosphors were investigated using X-ray diffractometry, field-emission scanning electron microscopy, and fluorescence spectrophotometry, respectively. All the phosphors showed a cubic structure, irrespective of the type and the content ratio of activator ions. For $Eu^{3+}$-doped $SrSnO_3$ phosphors, the intensity of the 620 nm red emission spectrum resulting from the $^5D_0{\rightarrow}^7F_2$ transition of $Eu^{3+}$ was stronger than that of the 595 nm orange emission signal due to the $^5D_0{\rightarrow}^7F_1$ transition in the range 0.01-0.05 mol of $Eu^{3+}$, but the ratio of the intensity was reversed in the range 0.10-0.20 mol of $Eu^{3+}$. The variation in the emission intensity indicates that the site symmetry of the $Eu^{3+}$ ions around the host crystal was changed from non-inversion symmetry to inversion. For the $Tb^{3+}$-doped $SrSnO_3$ phosphors under excitation at 281 nm, one strong green emission band at 550 nm and several weak bands were observed. These results suggest that the optimum red and green emission signals can be realized when the activator ion content for $Eu^{3+}$- or $Tb^{3+}$-doped $SrSnO_3$ phosphors is 0.20 mol and 0.15 mol, respectively.

Shear Strength of Weathered Granite Soil Considering Change of Saturation (포화도 변화를 고려한 화강풍화토의 전단강도)

  • Kim, Minwook;Kim, Youngmuk
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.9
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    • pp.5-14
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    • 2010
  • This study was aimed to suggest reliable information of shear strength characteristics due to change of saturation in the landfills or slopes during rainfall infiltration. According to the Mohr-Coulomb failure criteria, the characteristics of shear strength due to change of saturation were analyzed for the weathered residual soils which were sampled in the road construction site of Daejeon city. From the direct shear strength tests, the cohesions and the shear resistance angles were showed maximum values in the condition of optimum moisture content, and then decreased in the condition of wet side compaction. In this study, the cohesions were decreased more than 50% according to increasing saturation by infiltration for the compaction soils. But the reductions of the shear resistance angles were about $1{\sim}2^{\circ}$ which was small value, and thus the changes of the saturation were not nearly influenced the shear resistance angle. The influences of the saturation were seemed to very small for the residual strength parameters according to Mohr-Coulomb failure criteria.

A Study on the Analysis of Connectivity for Green Space Planning in Daejeon Metropolitan City (대전시 녹지계획을 위한 연결성 분석에 대한 연구)

  • Cheong, Yong-Moon;Kim, Sun-Tae;Kim, Myoung-Soo
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.5 no.6
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    • pp.14-23
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    • 2002
  • Daejeon is a large city in Korea and very high-speedly developing city. Recently urban area is expanding and large forest patch is fragmenting into small habitats because of urban sprawl. The fragmentation of large forest patch decreases the size of habitats and increases the loss of biodiversity in urban area. This study is to analysis the connectivity of green space of Daejeon metropolitan city, and suggest the optimum location of greening site and corridor in order to increase the connectivity of green space of Daejeon metropolitan city. The findings of this study are as follows; (1) The result of this study showed that ${\alpha}$ and ${\gamma}$ index are -0.24 and 0.20. A ${\alpha}$ index is very low and a ${\gamma}$ index is relatively low. (2) The dispersion was very high, for urban forest patches were isolated through fragmentation. Therefore, it needed ecological corridors in order to connect the patches. (3) A urban streams were very important in connectivity of urban green space. Urban riparian corridor must be preserved and restored. (4) A urban green space policy and planning must be prepared to increase the connectivity and assessment of alternatives must be accomplished from perspective of connectivity. The results of this study show the practical implications in perspective of green space planning and policy in Daejeon metropolitan city. The suggestions by findings of this study are to connect green space between large forest patch in urban fringe and island green space in inner city. Also, It is required that urban stream is restored to natural feature for use of corridor by wildlife.

Numerical Analysis of Offshore Wind Turbine Foundation Considering Properties of Soft layer in Jeju (제주 연약지층 특성을 고려한 해상풍력기초의 수치해석적 연구)

  • Yang, Ki-Ho;Seo, Sang-Duk;Cho, Yee-Sun;Park, Jeong-Jun
    • Journal of the Korean Geosynthetics Society
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    • v.12 no.4
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    • pp.45-56
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    • 2013
  • Recently, offshore wind farms are increasingly expected, because there are huge resource and large site in offshore. Jeju island has optimum condition for constructing a wind energy farm. Unlike the mainland, Jeju island has stratified structure distribution between rock layers sediments due to volcanic activation. In these case, it can be occur engineering problems in whole structures as well as the safety of foundation as the thickness and distribution of sediment under top rock layer can not support sufficiently the structure. In this paper, the settlement and stress distribution is predicted by numerical analysis when the mono-pile base are constructed on various soft layer between stratified structure. To determine the settlement of the pile foundation supported on stratified rock layer, the geological investigation at the 3 regiions and the results of laboratory experiments of the stratified rock layer is required.

Improved Photolysis of Water from Ti Incorporated Double Perovskite Sr2FeNbO6 Lattice

  • Borse, P.H.;Cho, C.R.;Yu, S.M.;Yoon, J.H.;Hong, T.E.;Bae, J.S.;Jeong, E.D.;Kim, H.G.
    • Bulletin of the Korean Chemical Society
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    • v.33 no.10
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    • pp.3407-3412
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    • 2012
  • The Ti incorporation at Fe-site in the double perovskite lattice of $Sr_2FeNbO_6$ (SFNO) system is studied. The Ti concentration optimization yielded an efficient photocatalyst. At an optimum composition of Ti as x = 0.07 in $Sr_2Fe_{1-x}Ti_xNbO_6$, the photocatalyst exhibited 2 times the quantum yield for photolysis of $H_2O$ in presence of $CH_3OH$, than its undoped counterpart under visible light (${\lambda}{\geq}420nm$). Heavily Ti-doped $Sr_2Fe_{1-x}Ti_xNbO_6$ lattice exhibited poor photochemical properties due to the existence of constituent impurity phases as observed in the structural characterization, as well as deteriorated optical absorption. The higher electron-density acquired by n-type doping seem to be responsible for the more efficient charge separation in $Sr_2Fe_{1-x}Ti_xNbO_6$ (0.05 < x < 0.4) and thus consequently displays higher photocatalytic activity. The Ti incorporated structure also found to yield stable photocatalyst.

[Retracted] The Effect of Welding Conditions on Tensile Characteristics and Thermal Stress of Al 5083 Alloy Applied to Co-environmental Leisure Ships ([논문 철회] 친환경 레져선박에 적용되는 Al 5083 합금의 인장특성 및 열응력에 미치는 용접조건의 영향)

  • Moon, Byung Young;Lee, Ki Yeol;Kim, Kyu Sun
    • Journal of the Society of Naval Architects of Korea
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    • v.51 no.6
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    • pp.548-555
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    • 2014
  • As a considerable, experimental approach, an Auto-carriage type of $CO_2$ welding machine and a MIG(Metal Inert Gas) welding robot under inert gas atmosphere were utilized in order to realize Al 5083 welding applied to hull and relevant components of green Al leisure ships. This study aims at investigating the effect of welding conditions(current, voltage, welding speed, etc) on thermal deformation that occurs as welding operation and tensile characteristics after welding, by using Al 5083, non-ferrous material, applied to manufacturing of co-environmental Al leisure ships. With respect to welding condition to minimize the thermal deformation, 150A and 16V at the wire-feed rate of 6mm/sec were acquired in the process of welding Al 5083 through an auto carriage type of $CO_2$ welding feeder. As to tensile characteristics of Al 5083 welding through a MIG welding robot, most of tensile specimens showed the fracture behavior on HAZ(Heat Affected Zone) located at the area joined with weld metal, except for some cases. Especially, for the case of the Al specimen with 5mm thickness, 284.62MPa of tensile strength and 11.41% of elongation were obtained as an actual allowable tensile stress-strain value. Mostly, after acquiring the optimum welding condition, the relevant welding data and technical requirements might be provided for actual welding operation site and welding procedure specification(WPS).