• Title/Summary/Keyword: optimum mixture ratio

Search Result 346, Processing Time 0.023 seconds

Synthesis of Diglyceride Containing Caprylic acid by Immobilized Lipase Catalyzed Esterification of Monoglyceride in a Solvent Free System (모노글리세리드와 카프릴산으로부터 고정화 리파제를 사용한 디글리세리드 생산)

  • Lee, Jang-Woon;Kang, Sung-Tae
    • Microbiology and Biotechnology Letters
    • /
    • v.37 no.4
    • /
    • pp.365-370
    • /
    • 2009
  • For the production of diglyceride (DG) containing medium chain fatty acid, which could be utilized as a substrate to structured lipid production, monoglyceride (MG) and caprylic acid were reacted in the presence of lipase. The reaction system was well mixed homogeneously without using any organic solvent. Among the lipases investigated, Lipozyme RM IM and Novozym 435 were selected on the basis of equilibrium DG yields from the medium chain fatty acid and MG. And reaction conditions such as addition of molecular sieve, water content of immobilized lipase, reaction temperature, and mole ratio of MG/caprylic acid are optimized to increase DG production by using Lipozyme RM IM. DG content of reaction mixture showed 8% increase by adding molecular sieve to reaction mixture. Removal of water from the immobilized lipase could affect seriously equilibrium content of DG. More than 2.8%(w/w) removal of water from the support could make 44% of DG. Optimum temperature was found to $60^{\circ}C$. Temperature shift from $60^{\circ}C$ to $25^{\circ}C$ resulted in increase of free fatty acid (FFA) content. The equilibrium DG yield was not seriously affected by on MG/caprylic acid molar ratio. However, at the stoichiometric ratio of 1:1 the highest DG yield was obtained. Increasing MG/caprylic acid ratio from 0.3 to 1.8 decreased FFA content from 34% to 13%, while MG content increased from 27% to 50%.

The Synthesis of Potassium Hexatitanate Whisker by the Flux Process (융제법에 의한 육티탄산칼륨 Whisker의 합성)

  • Lee, Chul-Tae;Kim, Sung-Weon;Lee, Jin-Sik;Kim, Young-Myoung;Kwon, Kung-Taek
    • Applied Chemistry for Engineering
    • /
    • v.5 no.3
    • /
    • pp.478-500
    • /
    • 1994
  • The preparation of potassium hexatitanate whisker by flux method was investigated. In this study, 8 types synthesis of flux such as $V_2O_5$, $Bi_2O_3$, $B_2O_3$, $Pb_3O_4$, KCl, $K_4P_2O_7$, $K_2WO_4$ and $K_2MoO_4$ were tested to find a suitable flux for the synthesis of potassium hexatitanate whisker. Effects of various reaction variables such as reaction temperature, time, $TiO_2$ mole ratio to $K_2CO_3$, flux mole ratio to the mixture of $K_2CO_3$ and $TiO_2$, and slow-cooling treatment on the crystallization of potassium hexatitanate whisker were investigated. $K_2MoO_4$ and $K_2WO_4$ were better flux than others tested for the synthesis of potassium hexatitanate. In the presence of $K_2MoO_4$ or $K_2WO_4$ flux, the optimum condition for the synthesis of potassium hexatitanate whisker was that reaction temperature of $1000{\sim}1100^{\circ}C$, reaction time of 5 hours, $TiO_2$ mole ratio to $K_2CO_3$ of 6.0, and flux mole ratio to mixture ($K_2O+nTiO_2$) of 4.0. Slow-cooling treatment showed good effect on the growth of long fibrous potassium hexatitanate.

  • PDF

Improving Soil Washing/flushing Process using a Mixture of Organic/inorganic Extractant for Remediation of Cadmium (Cd) and Copper (Cu) Contaminated Soil (유/무기산 혼합용출제를 이용한 중금속(카드뮴,구리)오염토양 처리공법(soil washing/flushing) 개선에 대한 연구)

  • Lee, Hong-Kyun;Kim, Dong-Hyun;Jo, Young-Hoon;Do, Si-Hyun;Lee, Jong-Yeol;Kong, Sung-Ho
    • Journal of Soil and Groundwater Environment
    • /
    • v.14 no.2
    • /
    • pp.17-25
    • /
    • 2009
  • The applicability of soil washing/flushing to treat a contaminated soil with cadmium (Cd) and copper (Cu) using a mixture of organic/inorganic extractant was evaluated in laboratory-scale batch and column tests. Citric acid was the effective extractant to remove Cd and Cu from the soil among various organic acids except EDTA. Carbonic acid was chosen as inorganic extractant which was not only low toxicity to environment, but also increasing soil permeability. Moreover, the optimum ratio of organic and inorganic extractant to remove Cd and Cu was 10 : 1, and this ratio of organic and inorganic extractant achieved removal efficiencies of Cd (46%) and Cu (39%), respectively. The increasing flow rate of extractant could explain the phenomena of soil packing when carbonic acid was used with organic extractant (i.e. EDTA and citric acid). Therefore, a mixture of organic extractant with inorganic extractant, especially carbonic acid, could resolve a problem of soil packing when this extractant was applied to a field application to remove Cd and Cu using in-situ soil flushing process.

Antioxidant Activity of Methylene Chloride Extracts Obtained from Glucose-Ammonia (1M+8M) Browning Mixtures (Glucose-Ammonia (1M+8M) 갈색화(褐色化) 반응액(反應液)에서 얻어진 Methylene Chloride 추출물(抽出物)의 항산화(抗酸化) 효과(?果))

  • Paik, Hyang-Deok;Kim, Dong-Hoon
    • Korean Journal of Food Science and Technology
    • /
    • v.11 no.2
    • /
    • pp.93-98
    • /
    • 1979
  • An attempt was made to investigate the antioxidant activity of methylene chloride extracts of a glucose-ammonia browning reaction mixture, which contain pyrazines, important intermediate prod ucts of Maillard-type browning reactions. Methylene chloride extracts were obtained from a glucose-ammonia(1M+8M) browning reaction mixture, which had been heated at $100^{\circ}C$. for 4 hours. The molar ratio of the reactants and the reaction time were reported to be the optimum ratio and time for the maximum formation of pyrazines. The methylene chloride extracts and furfural (for comparison purpose) were added to edible rapeseed oil substrates, and the resulting substrates and the control were stored at $37.0{\pm}1.0^{\circ}C$. Peroxide values (POV), thiobarbituric acid values (TBA-values) and acid values (AV) of the substrates and the control were determined regularly during a 34-day storage period. The antioxidant activity of the methylene chloride extracts and furfural was estimated on the basis of POV, TBA-value and AV-development of the substrates and the control. It was found that the methylene chloride extracts of the glucose-ammonia (1M+8M) browning mixture possessed considerable antioxidant activity. Furfural also showed some activity.

  • PDF

Mechanical Properties and Field Implementation of Floor Mortar Incorporated with VAE Polymer (VAE 폴리머를 이용한 모르타르 바닥재의 역학적 특성과 현작 적용성)

  • Bang, Jin-Wook;Lee, Sun-Mok;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.21 no.3
    • /
    • pp.27-34
    • /
    • 2017
  • Recently, the importance of the industrial warehouse floor has been increasing due to the development of the distribution and logistics industry. In this present study, an early-hardening polymer floor mortar which can compensate for the limitation of conventional cement based floor mortar regarding fluidity and long curing time was developed. In order to achieve the early-hardening of mortar characteristic ultra rapid hardening cement was used as binder. Four types of mixture proportions in accordance with the vinyl acetate ethylene(VAE) polymer contents with range from 10% to 20% and the other proto proportion without VAE polymer were designed. Mechanical experiments including the fluidity test, compressive strength test, bending test, bond test, and abrasion test were conducted for all mixture proportions. From the flow test result, it was possible to achieve the high flow with 250 mm by controlling the amount of superplasticizer. The incorporation of VAE polymer was found to affect the compressive strength reduction, however, the flexural strength was higher than that of the proto mixture, and it was evaluated to increase the compressive strength / flexural strength ratio. Moreover, at least 2.6 times higher bond strength and more than 4 times higher abrasion resistance were secured. From the mechanical experiments results, the optimum mixing ratio of the VAE polymer was determined to be 10%. As a result of application and monitoring, it shows that it has excellent resistance to cracking, discoloration, impact, and scratch as well as bond performance compared to the cement based floor mortar.

Characteristics and Optimization of the Formula of Mashed Potatoes Using Purple-fleshed Potato (Solanum tuberosum L.) by Mixture Design (혼합물 실험계획법을 이용한 유색감자 자영(Solanum tuberosum L.) 매쉬드 포테이토 분말의 혼합비 최적화 및 매쉬드 포테이토의 특성)

  • Jung, Hwabin;Choi, Ji-il;Yoon, Won Byong
    • Food Engineering Progress
    • /
    • v.21 no.2
    • /
    • pp.167-173
    • /
    • 2017
  • Purple-fleshed potato powder (PFPP) was investigated to determine optimal mixing ratio with milk powder and dextrin to produce a ready-to-eat mashed potato powder. The rheological characteristics, color, and anthocyanin contents were studied at a different concentration of ingredients. The power-law model was applied to explain the mechanical spectra of mashed potatoes which represented the change in structure induced by different mixing ratios. Mixture design was used to obtain the experimental points used to establish the empirical models to describe the effects of each ingredient on the characteristic of the mashed potato. The results of mechanical spectra showed that both storage and loss moduli (G' and G'') were significantly influenced by PFPP and milk powder concentration. The power law parameters n' and n'' showed higher values for the mashed potato with a lower concentration of PFPP and a higher concentration of milk powder, which showed that the gel networks involved in the mashed potato were weaker. The optimum mixing ratio with the highest redness and anthocyanin content, while maintaining the rheological properties similar to the commercial mashed potato, was determined as PFPP:milk powder:dextrin = 90.49:4.86:4.65 (w/w). The proportions of PFPP and milk powder in the formulation significantly changed the characteristics of mashed potato, whereas no significant effect of dextrin was observed in this formulation.

Optimum mixture ratio of functional Lindera glauca for culture of oyster mushroom (Pleurotus ostreatus) (느타리버섯 재배를 위한 기능성자원 감태나무(Lindera glauca) 톱밥의 적정 혼합비율)

  • Lee, Chan-Jung;Jhune, Chang-Sung;Cheong, Jong-Chun;Kong, Won-Sik;Park, Gi-Chun;Lee, Jeang-Hun;Shin, Yu-Su
    • Journal of Mushroom
    • /
    • v.10 no.1
    • /
    • pp.9-14
    • /
    • 2012
  • This study was carried out to investigated optimum mixing ratio of Korean natural Lindera glauca for production of functional oyster mushroom. Total nitrogen and carbon source of Lindera glauca was 0.16% and 40.9%, respectively and C/N ratio was 215. Total nitrogen source and pH of substrate mixed with Lindera glauca was 2.8~3.0 and 4.8~5.0, respectively. The contents of $P_2O_5$, CaO, MgO and $Na_2O$ were increased by increasing Lindera glauca, but there was no significant difference in $K_2O$ content. Mycerial growth was faster at Lindera glauca treatments than that of control. Yields of fruiting body was the highest at Lindera glauca 20%, and dimeter and thick of pileus were increased according to increase of Lindera glauca addition ratio. The L value of pileus was the highest at the Lindera glauca 10% during mushroom harvest, but there was no significant difference in the a-value and the b-value.

Nano-engineered concrete using recycled aggregates and nano-silica: Taguchi approach

  • Prusty, Rajeswari;Mukharjee, Bibhuti B.;Barai, Sudhirkumar V.
    • Advances in concrete construction
    • /
    • v.3 no.4
    • /
    • pp.253-268
    • /
    • 2015
  • This paper investigates the influence of various mix design parameters on the characteristics of concrete containing recycled coarse aggregates and Nano-Silica using Taguchi method. The present study adopts Water-cement ratio, Recycled Coarse Aggregate (%), Maximum cement content and Nano-Silica (%) as factors with each one having three different levels. Using the above mentioned control parameters with levels an Orthogonal Array (OA) matrix experiments of L9 (34) has selected and nine number of concrete mixes has been prepared. Compressive Strength, Split Tensile Strength, Flexural Tensile Strength, Modulus of Elasticity and Non-Destructive parameters are selected as responses. Experimental results are analyzed and the optimum level for each response is predicted. Analysis of 28 days CS depicts that NS (%) is the most significant factor among all factors. Analysis of the tensile strength results indicates that the effect of control factor W/C ratio is ranked one and then NS (%) is ranked two which suggests that W/C ratio and NS (%) have more influence as compared to other two factors. However, the factor that affects the modulus of elasticity most is found to be RCA (%). Finally, validation experiments have been carried out with the optimal mixture of concrete with Nano-Silica for the desired engineering properties of recycled aggregate concrete. Moreover, the comparative study of the predicted and experimental results concludes that errors between both experimental and predicted values are within the permissible limits. This present study highlights the application of Taguchi method as an efficient tool in determining the effects of constituent materials in mix proportioning of concrete.

An Experimental Study on the Reinforcing Effects of Mixtures of Vinyl Strip and Cement on the Sand Specimens (비닐스트립-시멘트 혼합 모래시편의 보강효과에 대한 실험연구)

  • Yu, Jeong-Min;Kim, Jong-Min
    • Journal of the Korean Geotechnical Society
    • /
    • v.34 no.10
    • /
    • pp.5-16
    • /
    • 2018
  • The ever-increasing amount of waste vinyl is causing big environmental problems. In particular, those from farming industry are sometimes left on site or even illegally reclaimed due to the lack of environmental concerns and capacity for collection, which worsens the situation. It is, therefore, believed that the recycling of waste vinyl is the most ideal solution in the viewpoint of environmental preservation. In this context, the potential of vinyl strip as a ground reinforcing material is investigated to expand the application of waste vinyl recycling. In this study, a series of uniaxial compression tests and resonant column tests were performed for sand specimens reinforced with vinyl strips and cement to investigate their reinforcing effects on static and dynamic behaviors. The changes in the uniaxial compressive strength (UCS), the shear modulus and the damping ratio according to the mixing ratio of vinyl strips and cements were analysed for sand specimens, having 40% and 60% relative densities, under various mixing conditions. As a result, both the static and dynamic reinforcing effects of vinyl strip-cement mixture were confirmed and the optimum mixing ratio was proposed.

Optimization of the Extrusion Processing Conditions of Soymilk Residue and Corn Grits Mixture (두유박과 옥분 혼합물 압출성형 제조공정의 최적화)

  • 한규홍;김병용
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.32 no.8
    • /
    • pp.1270-1277
    • /
    • 2003
  • The extrusion conditions of the soymilk residue and corn grits mixtures were optimized. The experiment was designed according to the D-optimal design of response surface methodology (RSM), which shows 18 experimental points including 4 replicates for three independent variables (screw speed, water content and die temperature). The responses variables such as bending force, expansion ratio, bulk density, water solubility index (WSI), water absorption index (WAI), and color values (L*, a*, b*) were evaluated using response surface analysis. Expansion ratio and WSI decreased with increasing water content, whereas bulk density tended to increase with increasing water content. While greater screw speeds enhanced WSI and yellowness, higher moisture contents decreased the expansion ratio and WSI value. However, die temperature did not influence upon the response variables. The optimum extrusion conditions by numerical and graphical methods were similar: the screw speed, water content, and die temperature were 250 rpm, 22.43% and l28.16$^{\circ}C$ by the numerical method; 250 rpm, 22.43%, and 128.02$^{\circ}C$ by graphical method.