• Title/Summary/Keyword: optimum dosage

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Optimization of the Turbidity Removal Conditions from TiO2 Solution Using a Response Surface Methodology in the Electrocoagulation/Flotation Process (전기응집/부상 공정에서 반응표면분석법을 이용한 TiO2 수용액의 탁도 처리조건 최적화)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.35 no.6
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    • pp.491-499
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    • 2009
  • The removal of turbidity from $TiO_2$ wastewater by an electrocoagulation/flotation process was studied in a batch reactor. The response surface methodology (RSM) was applied to evaluate the simple and combined effects of the three main independent parameters, current, NaCl dosage and initial pH of the $TiO_2$ solution on the turbidity removal efficiency, and to optimize the operating conditions of the treatment process. The reaction of electrocoagulation/flotation was modeled by use of the Box-Behnken method, which was used for the fitting of a 2nd order response surface model. The application of RSM yielded the following regression equation, which is an empirical relationship between the turbidity removal efficiency of $TiO_2$ wastewater and test variables in uncoded unit: Turbidity removal (%)=69.76+59.76Current+11.98NaCl+4.67pH+5.00Current${\times}$pH-160.11$Current^2-0.34pH^2$. The optimum current, NaCl dosage and pH of the $TiO_2$ solution to reach maximum removal rates were found to be 0.186 A, 0.161 g/l and 7.599, respectively. This study clearly showed that response surface methodology was one of the most suitable method to optimize the operating conditions for maximizing the turbidity removal. Graphical response surface and contour plots were used to locate the optimum point.

Experimental study of graphene oxide on wollastonite induced cement mortar

  • Sairam, V.;Shanmugapriya, T.;Jain, Chetan;Agrahari, Himanshu Kumar;Malpani, Tanmay
    • Advances in concrete construction
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    • v.12 no.6
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    • pp.479-490
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    • 2021
  • Present research is mainly focused on, microstructural and durability analysis of Graphene Oxide (GO) in Wollastonite (WO) induced cement mortar with silica fume. The study was conducted by evaluating the mechanical properties (compressive and flexural strength), durability properties (water absorption, sorptivity and sulphate resistance) and microstructural analysis by SEM. Cement mortar mix prepared by replacing 10% ordinary portland cement with SF was considered as the control mix. Wollastonite replacement level varied from 0 to 20% by weight of cement. The optimum replacement of wollastonite was found to be 15% and this was followed by four sets of mortar specimens with varying substitution levels of cementitious material with GO at dosage rates of 0.1%, 0.2%, 0.3% and 0.4% by weight. The results indicated that the addition of up to 15%WO and 0.3% GO improves the hydration process and increase the compressive strength and flexural strength of the mortar due to the pore volume reduction, thereby strengthening the mortar mix. The resistance to water penetration and sulphate attack of mortar mixes were generally improved with the dosage of GO in presence of 15% Wollastonite and 10% silica fume content in the mortar mix. Furthermore, FE-SEM test results showed that the WO influences the lattice framework of the cement hydration products increasing the bonding between silica fume particles and cement. The optimum mix containing 0.3% GO with 15% WO replacement exhibited extensive C-S-H formation along with a uniform densified structure indicating that calcium meta-silicate has filled the pores.

A Study on the Optimum Condition and GMB Addition in Emulsifying (에멀젼화의 퇴적조건과 예감제 첨가에 관한 연구)

  • 안명석;조명찬;김종현
    • Explosives and Blasting
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    • v.22 no.1
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    • pp.1-4
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    • 2004
  • The gelatine dynamite, which has been traditionally used in Korea as the 2nd generation explosive, is now being rapidly replaced by an emulsion explosive because of the change in life environment economic schemes, and safety reasons. However, there has been lack of study in the surfactant which is an important factor in manufacturing technology of emulsion explosives, and especially GMB technology has not been used in Korea. In this study, effective usage of surfactant with optimum dosage and optimum mixing temperature of GMB was investigated to increase safety and effectiveness.

Characteristics of manganese removal by ozonation: Effect of existing co-ion and optimum dosage (오존을 이용한 용존성 망간 제거 특성: 공존이온의 영향 및 최적주입량)

  • Kwak, Yeonwoo;Lee, Seulki;Lee, Yongsoo;Hong, Seongho
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.2
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    • pp.145-152
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    • 2018
  • This study is focused on manganese (Mn(II)) removal by ozonation in surface water. Instant ozone demand for the water was 0.5 mg/L in the study. When 0.5 mg/L of Mn(II) is existed in water, the optimum ozone concentration was 1.25 mg/L with reaction time 10 minutes to meet the drinking water regulation. The ozone concentration to meet the drinking water regulation was much higher than the stoichiometric concentration. The reaction of soluble manganese removal was so fast that the reaction time does not affect the removal dramatically. When Mn(II) is existed with Fe, the removal of Mn(II) was not affected by Fe ion. However As(V) is existed as co-ion the removal of Mn(II) was decreased by 10%. Adding ozone to surface water has limited effect to remove dissolved organic matter. When ozone is used as oxidant to remove Mn(II) in the water, the existing co-ion should be evaluated to determine optimum concentration.

The Effects of pH and Dosages According to Qualities of Raw Waters and Basicity of Coagulants (원수 수질특성과 응집제 염기도에 따른 응집 pH 및 주입량의 영향)

  • Park, Noh-Back;Lee, Bum;Tian, Dong-Jie;Lee, Young-Ju;Jun, Hang-Bae
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.5
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    • pp.581-593
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    • 2010
  • The objectives of this study were to investigate the effects of raw water pH and basicity of coagulants on turbidity removal with several raw waters having different level of turbidity, alkalinity and pH. Raw waters were sampled from M, S and B water treatment plants(WTP) located at Miryang, Nakdong, Han river, respectively. Six coagulants which have different levels of basicity and aluminum contents were used for this evaluation. High basicity of the coagulant helped to properly control coagulation processes for treating turbid and low alkali raw water. It was difficult for operators to determine optimum coagulant dose for high basicity coagulants, since residual turbidity tended to decrease continuously as coagulant dose increased. Turbidity removal efficiencies with high basicity coagulants(E and F) were higher than the other coagulants at ambient pH for the M WTP. Turbidity removal efficiencies, however, at adjusted pH 7.0 showed similar among six coagulants. Residual turbidity kept low at excess dosages with high basicity coagulants. Optimum coagulant dosages at adjusted pH 7.0 showed higher than those at ambient pH in M WTP. On the contrary in B WTP, optimum coagulant dosage at ambient pH were higher than that at adjusted pH 7.0.

Induced Mutant by Gamma Rays and Genetic Analysis for Mutant Characters in Flue-cured Tobacco Variety (Nicotiana tabacum L.) I. Induced Mutations and Characteristics of Mutant (황색종 연초 품종의 Gamma선에 의한 돌연변이 유수 및 변이형질의 유전분석 I. 돌연변이 유기 및 변이체의 특징)

  • Jung, Seok-Hun;Lee, S.C.;Kim, H.B.
    • Journal of the Korean Society of Tobacco Science
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    • v.14 no.1
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    • pp.12-23
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    • 1992
  • This experiment was conducted to determine the optimum dosage of gamma rays for inducing artificial mutation of several mutant characters in the flue-cured tobacco. 1) In Hicks and BY 104, the gammarays irradiation has no significantly different effect on seed germination from the control. However, the average dosage for 50% growth inhibition was 25-30kr for all the varieties tested, which inhibition 46-52% and 43-57% of the seedling growths for Hicks and BY 104, respectively. 2) A mutant line 83H-5 was selected from Hicks by irradiation gamma ray at the level of 30kr. It has white flower, more resistance to bacterial wilt, Pssudomonas solanacearum, lower plant and stalk height, narrower leaf width, larger leaf shape index(lento width) and later days to flower when compared with the original variety Hicks. 3) White flower was recessive to pink flower in F, and Br (F1 X Hicks) progenies. F2 population of the cross gave segregation ratio of 3 pink flower:1 white flower, and B, (F1 X 83H-5) Population gave 1:1 ratio. Results showed that the white flower character is governed by a single recessive gene.

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Zeolite Filtration for Ammonium Nitrogen Removal in Drinking Water Treatment (정수처리에서 암모니아성질소 제거를 위한 제올라이트 여과)

  • 김우항;김충환
    • Journal of Environmental Science International
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    • v.12 no.3
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    • pp.281-286
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    • 2003
  • This study was conducted to evaluate the feasibility of ammonia removal by zeolite adsorption in drinking water treatment. In generally, drinking water treatment process is conducted coagulation/flocculation, sedimentation, sand filtration and disinfection. We tested feasibility with two method, one is powdered zeolite dosing to coagulation tank and the other is to substitute granular zeolite for sand of sand filter. In powdered zeolite test, raw water is used tap water with putting of 2 mg/l of NH$_4$$\^$+/-N. Filtration of granular zeolite was conducted with 80 cm of effective column high and 120 m/d of flow rate. At above 100 mg/1 of zeolite dosage, ammonia concentration was decreased below 0.5 mg/l of NH$_4$$\^$+/-N in powdered zeolite test. But, turbidity was increased to 30 NTU by powdered zeolite dosage. That turbidity was scarcely decreased in generally coagulant using condition in drinking water treatment. In granular zeolite test, ammonia was not detected in treated water until 8 days. This result suggest that using of granular zeolite in sand filter could be removal ammonia in winter. But we need regeneration at zeolite filtration for ammonia removal. So, it is to make clear that zeolite regeneration ability was compared KCl with NaCl. The result reveal that KCl was more excellent than NaCl. Optimum regeneration concentration of KCl was revealed 100 mM. Regeneration efficient was not increased at pH range 10∼12.5.

Studies on the Foldability of Coated Board(II) - Influence of operating conditions in creasing and folding process on the foldability of duplex board - (백판지의 제함적성에 관한 연구(제2보) - 괘선/구부림 가공 작업조건이 제함적성에 미치는 영향 -)

  • Lee, Yong-Kyu;Lim, Won-Seok;Kim, Chang-Keun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.4
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    • pp.66-73
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    • 2008
  • When coated paperboard is printed, pressed into a groove with a creasing rule and folded, white line cracking occurs along the crease due to intensive mechanical pressure. The cracking will deteriorates product quality and waste resources. Effects of creasing pressure and ink dosage on the foldability of coated board were investigated. It was shown that applying an optimum pressure is important during creasing. When the pressure was too low, the crease formed was not sufficiently deep enough to enable precise folding. When an excess pressure was applied, fiber bonding was destroyed, resulted in unsatisfactory cracking. When the coated board was folded in machine direction (MD), long cracks were formed along MD. When it folded in cross direction (CD), the cracks were shorter and formed perpendicular to CD. Printing promoted cracking due to the decrease in flexibility of coated board. In addition, uneven ink film layer on the coating layer caused worse cracking.

A SINGLE FLOCCULANT/DUAL FLOCCULATION SYSTEM FOR DEWATERING USING A BRANCHED SELF INVERSING EMULSION FLOCCULANT

  • Bae, Young-Han;Lee, Sung-Sik
    • Environmental Engineering Research
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    • v.11 no.4
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    • pp.208-216
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    • 2006
  • In order to create a single flocculant/dual flocculation system, polyacrylamide-co-trimethyl ammonium ethyl acrylate chloride (TAEAC) polymers with varying molecular weights and structures were prepared for use of flocculants. The higher the cationic density of the polymer is higher, the higher was the conversion rate and the ratio of monomer. An acrylamide as nonionic monomer was less reactive than a TAEAC as cationic monomer. The branched polymer which was polymerized with a cross-linking agent, N, N-methylene bis-acrylamide had a higher stability and higher viscosity than a linear polymer but its dewatering efficiency was poor in a single flocculation system. In the case of single flocculant/dual flocculation, the branched polymer has better flocculation efficiency and the water content of the dewatered cakes was lower than the others, as the result of a re-flocculation effect. The optimum conditions for dual flocculation are a sequence in which the $1^{st}$ and $2^{nd}$ dosage are 75% and 25%/total dosage of a single flocculation system. The dewatering efficiency of a dual flocculation system is improved considerably from 10 to 25% under the experimental conditions used herein.

Cr(VI) removal using Fe2O3-chitosan-cherry kernel shell pyrolytic charcoal composite beads

  • Altun, Turkan;Ecevit, Huseyin
    • Environmental Engineering Research
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    • v.25 no.3
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    • pp.426-438
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    • 2020
  • In this study, cherry kernel shell pyrolytic charcoal was synthesized (CKSC) and composite beads were obtained by blending this pyrolytic charcoal with chitosan and Fe2O3 nanoparticles (Fe-C-CKSC). Cr(VI) adsorption from aqueous solutions by Fe-C-CKSC composite beads and CKSC adsorbents was studied comparatively. The effects of Cr(VI) initial concentration, adsorbent dosage, contact time, pH and temperature parameters on Cr(VI) adsorption were investigated. Adsorption reached an equilibrium point within 120 min for CKSC and Fe-C-CKSC adsorbents. The maximum Cr(VI) removal was obtained at the initial pH value of 1.56 for CKSC and 2.00 for Fe-C-CKSC. The optimum adsorbent dosage was found to be 5 g/L for CKSC and 3 g/L for Fe-C-CKSC. Based on the Langmuir model, the maximum adsorption capacities were calculated as 14.455 mg/g and 47.576 mg/g for CKSC and Fe-C-CKSC, respectively. Thermodynamic and kinetic studies were performed. As a result of adsorption kinetics calculations, adsorption was found to be consistent with the pseudo second order kinetic model. Characterization of the synthesized adsorbents was performed by SEM, BET, FTIR and elemental analysis. This study has shown that low cost adsorbents CKSC and Fe-C-CKSC can be used in Cr(VI) removal from aqueous solutions.