• Title/Summary/Keyword: optical absorbance

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A Study on Dosimetric Characterization of Direct Yellow 12 Dye at High Radiation γ-Dose

  • Batool, Javaria;Shahid, Shaukat Ali;Ramiza, Ramiza;Akhtar, Nasim;Naz, Afshan;Yaseen, Maria;Ullah, Inam;Nadeem, Muhammad;Shakir, Imran
    • Bulletin of the Korean Chemical Society
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    • v.33 no.7
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    • pp.2265-2268
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    • 2012
  • Aqueous solution of oxygenated Direct yellow 12 dye has been evaluated spectrophotometrically as a possible gamma rays dosimeter. The neutral (pH-7), alkaline (pH-12.5) and acidic (pH-5.5) aqueous solution of the dye were prepared and exposed to various gamma doses. Absorption spectra of unirradiated and irradiated solutions were recorded at 400 nm peak. The increase in absorbance with the increase in irradiation dose was observed from 1 to 6 kGy. The stability response of the dye solution for different environmental conditions such as temperature (low & high), light and darkness were investigated during post irradiation storage for ten days. The dye solution showed high stability in darkness for the studied period. The optical density of the dye solution was found to be decreased at high temperature storage.

The lyophilization and stability of Salmonella typhi Ty21a (Salmonella thphi Ty21a의 동결 건조와 안정성)

  • 김세란;박동우;전홍렬;김희준;한성순;김기호;김홍진
    • YAKHAK HOEJI
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    • v.43 no.6
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    • pp.793-797
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    • 1999
  • Salmonella typhi Ty21a is an attenuated strain of S. typhimurium and used for oral typhoid vaccine. In an attempt to increase the stability of Ty21a manufacturing typhoid vaccine, we studied about the stability of freeze-dried Th21a including additives at various temperature conditions. In order to investigate the freeze-drying rate of Ty21a according to various absorbance, we lyophilized Ty21a by using 8% sucrose as a stabilizer. The optimal freeze-drying rate of Ty21a was appeared when OD (optical density) value of the growth was between 2.5 and 3.0. To investigate the stability of Ty21a at various temperature, the viability was measured after storaging the freeze-dried Ty21a at the room temperature, cold and freezing condition for 1 week. The viability of Ty21a in cold and freezing storage condition was 5 times more stable than in room temperature. To search the most stable additives for the freeze-dried Ty21a, the viability of Ty21a including additives at the various storage condition was estimated. Mannitol and loctose were the most stable additives. Theses results suggest that the OD value of Ty21a growth, low temperature, mannitol and lactose are important factors for the optimal freeze-drying rate, the stable storage and the most stable additives, respectively.

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Optical properties of Al doped ZnO Nanofibers Prepared by electrospinning (전기방사를 이용한 Al이 첨가된 ZnO 나노섬유의 제조 및 광학 특성평가)

  • Song, Chan-Geun;Yoon, Jong-Won
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.5
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    • pp.205-209
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    • 2011
  • Zinc oxide has semi-conductivity and super conductivity characteristics. It can be used optically and is applied on many areas such as gas sensor, solar cell and optical waveguide. In this paper, to improve optical characteristics of ZnO, aluminum was added on zinc oxide. Zinc oxide and aluminum zinc oxide was fabricated as nano fiber form. ZnO solution was created by mixing poly vinyl pyrrolidone, ethyl alcohol, and zinc acetate. An Al doped ZnO was created by adding aluminum solution to ZnO sol. By applying these sols on electro spinning method, nano fibers were fabricated. These fibers are heat treated at 300, 500, and $700^{\circ}C$ degrees and were analyzed with X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) to examine the nano structures. TGA and DSC measurement was also used to measure the change of mass and calorie upon temperature change. The absorbance of ZnO and Al-doped ZnO was carried out by UV-vis measurement.

Preparation of Nano Titania Sols and Thin Films added with Transition Metal Elements (전이금속원소들이 첨가된 나노 티타니아 졸 및 코팅막 제조)

  • Lee K.;Lee N. H.;Shin S. H.;Lee H. G.;Kim S. J.
    • Korean Journal of Materials Research
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    • v.14 no.9
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    • pp.634-641
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    • 2004
  • The photocatalytic performance of $TiO_2$ thin films coated on porous alumina balls using various aqueous $TiOCl_2$ solutions as starting precursors, to which 1.0 $mol\%$ transition metal ($Ni^{2+},\;Cr^{3+},\;Fe^{3+},\;Nb^{3+},\;and\;V^{5+}$) chlorides had been already added, has been investigated, together with characterizations for $TiO_2$ sols synthesized simultaneously in the same autoclave through hydrothermal method. The synthesized $TiO_2$ sols were all formed with an anatase phase, and their particle size was between several nm and 30 nm showing ${\zeta}-potential$ of $-25{\sim}-35$ mV, being maintained stable for over 6 months. However, the $TiO_2$ sol added with Cr had a much lower value of -potential and larger particle sizes. The coated $TiO_2$ thin films had almost the same shape and size as those of the sol. The pure $TiO_2$ sol showed the highest optical absorption in the ultraviolet light region, and other $TiO_2$ sols containing $Cr^{3+},\;Fe^{3+}\;and\;Ni^{2+}$ showed higher optical absorption than pure sol in the visible light region. According to the experiments for removal of a gas-phase benzene, the pure $TiO_2$ film showed the highest photo dissociation rate in the ultraviolet light region, but in artificial sunlight the photo dissociation rate of $TiO_2$ coated films containing $Cr^{3+},\;Fe^{3+}\;and\;Ni^{2+}$ was measured higher together with the increase of optical absorption by doping.

Real-time Measurements of Water Level and Temperature using Fiber-optic Sensors Based on an OTDR (광섬유와 OTDR을 이용한 실시간 수위 및 온도 측정)

  • Sim, Hyeok In;Yoo, Wook Jae;Shin, Sang Hun;Jang, Jaeseok;Kim, Jae Seok;Jang, Kyoung Won;Cho, Seunghyun;Moon, Joo Hyun;Lee, Bongsoo
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.63 no.9
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    • pp.1239-1244
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    • 2014
  • In this study, two fiber-optic sensors were fabricated to measure water level and temperature using optical fibers, a coupler, a Lophine and an OTDR (optical time-domain reflectometer). First, using Fresnel's reflection generated at the distal-ends of each optical fiber, which was installed at different depth, we measured the water level according to the variation of water level. Next, we also measured the temperature of water using a temperature sensing probe based on the Lophine, whose absorbance changes with the temperature. The measurable temperature range of the fiber-optic sensor is from $5^{\circ}C$ to $65^{\circ}C$ because the maximum operation temperature of the optical fiber without a physical deterioration is up to $80^{\circ}C$.

The Structural and Optical Properties of GaAs- SiO2 Composite Thin Films With Varying GaAs Nano-particle Size (GaAs 나노입자 크기에 따른 SiO2 혼합박막의 구조적 광학적 특성)

  • Lee, Seong-Hun;Kim, Won-Mok;Sin, Dong-Uk;Jo, Seong-Hun;Jeong, Byeong-Gi;Lee, Taek-Seong;Lee, Gyeong-Seok
    • Korean Journal of Materials Research
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    • v.12 no.4
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    • pp.296-303
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    • 2002
  • For potential application to quantum mechanical devices, nano-composite thin films, consisting of GaAs quantum dots dispersed in SiO$_2$ glass matrix, were fabricated and studied in terms of structural, chemical, and optical properties. In order to form crystalline GaAs quantum dots at room temperature, uniformly dispersed in $SiO_2$matrix, the composite films were made to consist of alternating layers of GaAs and $SiO_2$in the manner of a superlattice using RF magnetron sputter deposition. Among different film samples, nominal thickness of an individual GaAs layer was varied with a total GaAs volume fraction fixed. From images of High Resolution Transmission Electron Microscopy (HRTEM), the formation of GaAs quantum dots on SiO$_2$was shown to depend on GaAs nominal thickness. GaAs deposits were crystalline and GaAs compound-like chemically according to HRTEM and XPS analysis, respectively. From measurement of optical absorbance using a spectrophotometer, absorption edges were determined and compared among composite films of varying GaAs nominal thicknesses. A progressively larger shift of absorption edge was noticed toward a blue wavelength with decreasing GaAs nominal thickness, i.e. quantum dots size. Band gaps of the composite films were also determined from Tauc plots as well as from PL measurements, displaying a linear decrease with increasing GaAs nominal thickness.

Design Spectrophotometer for Blocking the $2^{nd}$ diffracted Light (2차 회절광 차단을 위한 분광 광도계 설계)

  • 홍영주;곽윤근;김수현
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.875-880
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    • 2004
  • Stray light is the light except the light of the analytic wavelength and the source of measurement error of absorbance. Some experimental results showed that diffractive grating is the major factor of stray light in spectrophotometer. Through the ray tracing with the software tool, classified the paths of the diffractive light from grating and found the range of wavelength which reach the exit slit. The quantity of the stray light(0.025%) is more than the minimum limit of stray light(0.01%) of the single monochromator. A novel optical layout design method, which prevent the reflected rays entering the diffractive grating is proposed.

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Double Resonance Perfect Absorption in a Dielectric Nanoparticle Array

  • Hong, Seokhyeon;Lee, Young Jin;Moon, Kihwan;Kwon, Soon-Hong
    • Current Optics and Photonics
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    • v.1 no.3
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    • pp.228-232
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    • 2017
  • We propose a reflector-type perfect absorber with double absorption lines using electric and magnetic dipoles of Mie resonances in an array of silicon nanospheres on a silver substrate. In the visible range, hundreds of nanometer-sized nanospheres show strong absorption lines up to 99%, which are enhanced by the interference between Mie scattering and reflections from the silver substrate. The air gap distance between the silicon particles and silver substrate controls this interference, and the absorption wavelengths can be controlled by adjusting the diameter of the silicon particles over the entire range of visible wavelengths. Additionally, our structure has a filling factor of 0.322 when the absorbance is nearly 100%.

Enhanced Performance in Isoindigo Based Organic Small Molecules Field Effect Transistors Using Solvent Additives

  • Park, Yu-Jeong;Jo, Sin-Uk;Seo, Jeong-Hwa
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.392.1-392.1
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    • 2014
  • Isoindigo based small molecules have attracted much attention in the field of optoelectronic devices due to their broad absorbance and high charge carrier mobilitiies. Herein, we investigate the field effect transistor characteristics of a series of isoindigo based donor-acceptor-donor (D-A-D) small molecules containing a variable number of thiophene moieties (named IDT, ID2T, and ID3T) which form pi-bridges between the D and A moieites and a different donor moiety (IDED). In order to improve the carrier mobility, 1-chloronaphthalene (CN) and 1,8-diiodooctane (DIO) as solvent additives were used. The film morphology, crystallinity and optical properties of the materials processed with various concentrations of solvent additives were investigated through atomic force microscopy (AFM), X-ray diffraction (XRD) and UV-vis absorption spectroscopy.

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Optical Properties of Conducting Polymer Poly(3-Alkylthiophene) Solution (도전성 고분자 Poly( 3- Alkylthiophene ) 용액의 광학적 성질)

  • Park, J.H.;SaGong, G.;Lim, J.S.;Kim, T.S.;Gu, H.B.
    • Proceedings of the KIEE Conference
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    • 1990.07a
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    • pp.221-223
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    • 1990
  • In this study, we have studied the optioal properties and $I_2$ doping effect of Poly(3-Akkylthiophene) solution. The end of speotrum absorbance on the solutions of Poly(3 - Octylthiophene), Poly (3-Dodecylthiophene) and Poly(3-Dooooylthiophene) was dependent on temperature. It is bellved that conrod-coil transition dependent on temperature was rod-coil transition. And absortance peak of Poly (3-Dodecylthiophene) in dichloromethane solution increased with increasing the $I_2$ dopant.

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