• Title/Summary/Keyword: one-bath

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Studies on the Synthesis of Bisphenol Sulfonate Polymers and Their Staining Resist Effect in the Dyeing of Nylon/cotton Union ( II ) (Bisphenol sulforn산계 고분자의 합성 및 나일론 오염방지성에 관한 연구 (II))

  • 최영주;송승종;윤남식
    • Textile Coloration and Finishing
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    • v.13 no.2
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    • pp.87-92
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    • 2001
  • In the Previous studies, we reported about the synthesis of poly(3-methylence-3-methylenesodiumbisulfite-bis(4-hydroxypheny )sulfone] (PMSBPS ) and their effect on the staining of direct dye on nylon in the dyeing of nylon/cotton union. The results shoved that PMSBPS have good staining resist effect on nylon in the dyeing of nylon/cotton union. In this study, the staining resist effects of PMSBPS in varied dyeing process and method were investigated, and the fastness to washing, light, and rubbing of the deed N/C unions was tested. The results are as follows , 1. In the two bath two step method, the staining of direct dye on nylon was decreased with the concentration of PMSBPS, and the fastness to washing, light, and rubbing of the dyed N/C unions were increased by addition of PMSBPS. 2. In the one bath two step method, optimun concentration of PMSBPS was 4% 0.w.f..

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Influences of Complexing Agents on the Formation of the Perpendicular Magnetic Film by the Electroless Plating (무전해 도금에 의한 수직자기 박막제조시의 착화제의 영향)

  • Kim, Yeong-U;Park, Jeong-Il;Park, Gwang-Ja;Kim, Jo-Ung;Ham, Yong-Muk;Lee, Ju-Seong
    • Journal of the Korean institute of surface engineering
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    • v.20 no.4
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    • pp.135-143
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    • 1987
  • Various complexing agents were investigated to see the effects on the normal orientation of HCP structure of Co-alloy to the film plane in ammoniacal electroless plating bath. To obtain the optimum condition, several complexing agents were investigated to compare the C-axis perpendicular orientation. Results were that succinate - citrate, malonate - succinate, malonate bath were useful for that purpose. Among these complexing agents, succinate - citrate system was obtained as the best one. X-ray diffraction patterns were used to compare the film properties with C-axis perpendicular orientation.

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Natural Indigo Dyeing of Wool by the One Step Reduction/Dyeing Method (일단계 환원/염색에 의한 모직물의 천연인디고 염색)

  • Son, Kyung-Hee;Shin, Youn-Sook;Yoo, Dong-Il
    • Journal of the Korean Society of Clothing and Textiles
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    • v.34 no.3
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    • pp.508-517
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    • 2010
  • One-step reduction/dyeing method was optimized for wool dyeing with natural indigo dye in this study. The effects of reduction/dyeing conditions including dye temperature and time, the pH of bath, concentration of dye, and reducing agent on dye uptake and color were investigated. The dye uptake was higher with no addition of alkali. Dyeing was carried out through the use of only sodium hydrosulfite in the bath. The maximum dye uptake was obtained at $60^{\circ}C$ for 30min and the dyed fabrics appeared in the PB Munsell color range. Dye uptake improved with the increase of a natural indigo dye concentration with the same sodium hydrosulfite concentration. At a higher dye uptake, the fabric color became more purplish and the maximum absorption shifted from 660nm to 620nm. Color reproducibility was reliable with a color difference in the range of 0.41~1.43. Regardless of color strength, washing and dry cleaning fastnesses were good with a 4/5 rating, and fastnesses to rubbing and light were acceptable with a 3/4~4 rating.

Preparation and Optimization of Silicone Softener for PP Finish (PP가공용 실리콘 유연제의 제조 및 유연최적화)

  • You, Hyuk-Jae;Chung, Dong-Jin;Jung, Choong-Ho;Kim, Myung-Soo;Hahm, Hyun-Sik;Park, Hong-Soo;Kim, Tae-Ok
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.3
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    • pp.191-196
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    • 2004
  • An emulsion of octadecamidoethylaminoethyl dodecate (which provides softness) and an emulsion silicone oil KF-96 (which provides lubricity) were separately synthesized. Then PP finishing softeners (SSA-7) was prepared by blending of the synthesized emulsions with beef tallow hardened oil (a softness improving agent). PP finishing treatment was carried out with the prepared SSA-7 and PP finishing resin by a one bath method, and several physical properties were tested. As a result, crease recovery, tear strength, softness, lubricity, and bending resistance were all good, indicating that the prepared SSA-7 is a good PP finishing softener.

Dyeing of Nylon/Cotton Blend with Acid Dyes Using Sodium 2-(2,3- dibromopropionylamino)-5-(4,6-dichloro-1,3,5-triazinylamino)-benzenesulfonate (Sodium 2-(2,3-dibromopropionylamino)-5-(4,6-dichloro-1,3,5-triazinylamino)-benzenesulfonate를 이용한 나일론/면 복합소재의 단일 산성염료 일욕염색)

  • Kim, Mi-Kyung;Yoon, Nam-Sik;Kim, Tae-Kyeong
    • Textile Coloration and Finishing
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    • v.24 no.1
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    • pp.8-17
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    • 2012
  • In order to dye nylon/cotton blended fabrics in solid colors with only acid dyes, a hetero-bifunctional bridge compound (DBDCBS) was examined. The bridge compound was designed to react only onto cotton fabrics first, on which amino-containing acid dyes react later by covalent bonding. By the effect of DBDCBS, amino-containing acid dyes exhibited high affinity toward the cotton fabrics. From the dyeing properties examined at various conditions, the optimum dyeing was decided at pH 4 and $100^{\circ}C$. Consequently, the solid color was obtained on nylon/cotton blended fabrics in one bath dyeing process using only acid dyes. The DBDCBS did not show any negative effect on nylon side in terms of dyeing and physical properties.

Dyeing and Fastness Properties of a Reactive Disperse Dye on PET, Nylon, Silk and N/P Fabrics

  • Bae Jin-Seok;Park Jong-Ho;Koh Joon-Seok;Kim Sung-Dong
    • Fibers and Polymers
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    • v.7 no.2
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    • pp.174-179
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    • 2006
  • Dyeing and color fastness properties of a reactive disperse dye containing an acetoxyethylsulphone group on PET, Nylon, silk and N/P fabrics were examined. The reactive disperse dye exhibited almost the same dyeing properties on PET fabric as a conventional disperse dye except the level of dye uptake. The most appropriate pH and dyeing temperature for the dyeing of Nylon fabric were 7 and $100^{\circ}C$ respectively. The build-up on Nylon fabric was good and various color fastnesses were good to excellent due to the formation of the covalent bond. Application of the reactive disperse dye on silk fabric at pH 9 and $80^{\circ}C$ yielded optimum color strength. The rate of dyeing on Nylon fabric was faster than that on PET fabric when both fabrics were dyed simultaneously in a dye bath, accordingly color strength of the dyed Nylon was higher. The reactive disperse dye can be applied for one-step and one-bath dyeing of N/P mixture fabric with good color fastness.

Minimizing Zinc Consumption In Hot-Dip Galvanizing Lines

  • Bright, Mark;Ellis, Suzanne
    • Corrosion Science and Technology
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    • v.10 no.2
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    • pp.43-46
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    • 2011
  • Zinc consumption in a continuous galvanizing line is one of the highest operating cost items in the facility and minimizing zinc waste is a key economic objective for any operation. One of the primary sources of excessive loss of zinc is through the formation of top dross and skimmings in the coating pot. It has been reported that the top skimmings, manually removed from the bath, typically consist of more than 80% metallic zinc with the remainder being entrained dross particles ($Fe_2Al_5$) along with some oxides. Depending on the drossing practices and bath management, the composition of the removed top skimmings may contain up to 2 wt% aluminum and 1 wt% iron. On-going research efforts have been aimed at in-house recovery of the metallic zinc from the discarded top skimmings prior to selling to zinc recycling brokers. However, attempting to recover the zinc entrapped in the skimmings is difficult due to the complex nature of the intermetallic dross particles and the quality and volume of the recycled zinc is highly susceptible to fluctuations in processing parameters. As such, an efficient method to extract metallic zinc from top skimmings has been optimized through the use of a specialized thermo-mechanical process enabling a continuous galvanizing facility to conserve zinc usage on-site. Also, through this work, it has been identified that filtration of discrete dross particles has been proven effective at maintaining the cleanliness of the zinc. Future efforts may progress towards expanded utilization of filters in continuous galvanizing.

One Bath Dyeing of Silk/Synthetic Fibre Blends(IV) - Adsorption Behavior of Acid Dyes/Disperse Dyes on Silk/Acetate - (견/합성섬유 혼방품의 일욕염색(IV) - 산성염료/분산염료 염욕에서의 견/아세테이트의 염착거동 -)

  • 박미라;전재홍;강영의;김공주
    • Textile Coloration and Finishing
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    • v.6 no.1
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    • pp.8-18
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    • 1994
  • In one bath dyeing system of silk/cellulose acetate fiber blend fabric with acid /disperse dyes, adsorption behavior of acid dyes and disperse dyes on silk and cellulose acetate fabrics were examined. In the dyeing of cellulose acetate with C. I. Disperse Red 19(Red 19) and C. I. Disperse Red 60(Red 60) at 8$0^{\circ}C$ and 10$0^{\circ}C$, dye uptake with Red 19 was higher than that with Red 60. When the silk/cellulose acetate dyed with Red 19 and Red 60 at 10$0^{\circ}C$, dye uptake on cellulose acetate was influenced by affinity of the dye to the silk fabric dyed together. When the silk/cellulose acetate dyed with Blue 80/Red 19 and Blue 80/Red 60 at 10$0^{\circ}C$, color of cellulose acetate dyed with Red 19 and Red 60 was not influenced by Blue 80 but silk dyed with Blue 80 was influenced by Red 19 and Red 60. Interrelation of K/S value and Munsell value was scarcely any but showed the change tendency of K/S value.

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Preparation and Physical Properties of Silicone Softner for PP Finish (PP 가공용 실리콘 유연제의 제조와 물성연구)

  • Im, Wan-Bin;Yang, In-Mo;Jung, Choong-Ho;Hahm, Hyun-Sik;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.2
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    • pp.117-122
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    • 2002
  • A silicone softner (SS-5), a permanent press (PP) finish, was prepared by blending silicone oil KF-96 (as a lubricating component) and beef tallow hardened oil (as a softening component) which was synthesized from fatty polyamide salts. The prepared SS-5 and the PP finishing resin were applied to PP finishing cotton cloth and P/C gingham sample by one-bath method. The properties such as crease recovery, tear strength, and bending resistance were tested. The samples treated with SS-5 and PP finishing resin showed improved properties when comparing with the untreated ones, with the ones treated only with PP finishing resin, with ones treated with commercial PP finishing softners and PP finishing resin. The grades of fabric samples treated with 3% SS-5 were fifth grade in the bending resistance test.

One-step microwave synthesis of surface functionalized carbon fiber fabric by ZnO nanostructures

  • Ravi S. Rai;Vivek Bajpai
    • Advances in nano research
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    • v.14 no.6
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    • pp.557-573
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    • 2023
  • The rapid growth of zinc-oxide (ZnO) nanostructures (NSs) on woven carbon fiber (WCF) is reported in this study employing a microwave-aided chemical bath deposition process. The effects of different process parameters such as molar concentration, microwave duration and microwave power on morphologies and growth rate of the ZnO on WCF were studied. Furthermore, an attempt has been taken to study influence of different type of growth solutions on ZnO morphologies and growth rates. The surface functionalization of WCF fabrics is achieved by successful growth of crystalline ZnO on fiber surface in a very short duration through one-step microwave synthesis. The morphological, structural and compositional studies of ZnO-modified WCF are evaluated using field-emission scanning electron microscopy, X-ray diffraction and energy dispersive X-ray spectroscopy respectively. Good amount of zinc and oxygen has been seen in the surface of WCF. The presence of the wurtzite phase of ZnO having crystallite size 30-40 nm calculated using the Debye Scherrer method enhances the surface characteristics of WCF fabrics. The UV-VIS spectroscopy is used to investigate optical properties of ZnO-modified WCF samples by absorbance, transmittance and reflectance spectra. The variation of different parameters such as dielectric constants, optical conductivity, refractive index and extinction coefficient are examined that revealed the enhancement of optical characteristics of carbon fiber for wide applications in optoelectronic devices, carbon fiber composites and photonics.