• Journal of Industrial and Engineering Chemistry
• /
• v.68
• /
• pp.24-32
• /
• 2018

Nanocellulose was surface-functionalized toward the applications in enhanced oil recovery (EOR) as a green alternative. The focus of this paper is on the effect of this material based nanofluid (NF) on foam lamella stabilization through studying its bubble breakup dynamics and flow behaviors in constricted mircofluidic devices. The NF stabilized foam produced an improved flow resistance across the capillary largely due to the capillary trapped bubbles at the contraction. The "snap-off" caused the NF stabilized foam to produce finer textured bubbles, which can migrate readily forward to the deep porous media, as revealed by the pressure profiles.

• Proceedings of the SCSK Conference
• /
• 1999.10a
• /
• pp.65-74
• /
• 1999

We have studied the stability of W/O high internal phase emulsions(HIPE) containing water, cetyl dimethicone copolyol and oils varying magnesium sulfate in the range 0 to 0.5wt% and oil polarities, respectively. The rheological consistency was mainly destroyed by the coalescence of the deformed water droplets. The greater the increase of concentrated modulus was, the less coalescence occurred and the more consistent the concentrated emulsions were. The increasing pattern of complex modulus versus volume fraction has been explained with the resistance to coalescence of the deformed interfacial film of water droplets in concentrated W/O emulsion. The stability is dependent on: (i) the choice of the oil is important, the requirements coincide with the requirements for the formation of the rigid liquid crystalline phases :5; and (ii) addition of salts the aqueous phase opposes the instability due to coalescence:. Increasing the salt concentration increases the refractive index of the aqueous phase. It lowers the difference in the refractive index between the oil and aqueous phases. This decreases the attraction between the water domains, thus increasing the stability.

• Proceedings of the Korean Geotechical Society Conference
• /
• 1997.06c
• /
• pp.1.2-22
• /
• 1997

Anisotropic behaviour in soils and soft rocks may be either fabric of stress related ultra in practice is invariably a combination of both. Theoretical studies in the paper include tile iMluence oil untrained strength of assuming both the critical state and Mo21r-Coulomb concepts to hold, and the influence of elastic anisotropy oil predicted undrained effective stress paths. The predictions stemming from these theoretical concepts are examined in the light of evidence from triaxial compression and extension tests oil laboratory prepared, compacted and natural clays and from triaxial compression tests on clay shales. The experimental studies also show the Buence of sample orientation on untrained snear strength, as wen as the iIBluence of anisotropy old the effective stress angle cishearing resistance and of stress patn on measured stiffness.

• Journal of Electrochemical Science and Technology
• /
• v.8 no.2
• /
• pp.133-145
• /
• 2017

Palm oil production is among the highest worldwide, and it has been mainly used in the food industry and other commodities. Currently, a lot of palm oil production has been destined for the synthesis of biodiesel; however, its use in applications other than the food industry has been questioned. Thereby for a sustainable development, in this paper the use of palm oil of low quality for corrosion inhibitors synthesis is proposed. The performance of the synthesized inhibitors was evaluated by using electrochemical techniques such as open circuit potential measurements, linear polarization resistance and electrochemical impedance spectroscopy. The results indicate that the fatty amides from palm oil are excellent corrosion inhibitors with protection efficiencies greater than 98%. Fatty amides molecules act as cathodic inhibitors decreasing the anodic dissolution of iron. When fatty amides are added, a rapid decrease in the corrosion rate occurs due to the rapid formation of a molecular film onto carbon steel surface. During the adsorption process of the inhibitor a self-organization of the hydrocarbon chains takes place forming a tightly packed hydrophobic film. These results demonstrate that the use of palm oil for the production of green inhibitors promises to be an excellent alternative for a sustainable use of the palm oil production.

• Corrosion Science and Technology
• /
• v.7 no.1
• /
• pp.13-15
• /
• 2008

Aiming at the corrosion circumstances and corrosion prevention needs of downhole oil tubes, series protective coatings for downhole oil tubes have been developed in the authors' laboratory, including a baked type coating YG-01 and an air curing type coating YG-03, etc. The performance investigation of the coatings has been done for testing their corrosion resistance, mainly including salt fog test, immersion test in oil-field waste water and various acid solutions, high temperature and high pressure test in alkali solution or $H_2S/CO_2$ environment, as well as some other performances. The investigation results show that oil tube anti-corrosion coatings developed here can endure over 4000 hrs salt fog test, over 1000 hrs immersion in various acid solutions at room temperature and in boiling oil-field waste water. In addition, the coatings can keep intact after experiencing test in alkali solution under 70 MPa pressure at $150^{\circ}C$ for 24 hrs, and in simulative sour gas environment under the total pressure of 32 MPa ($P_{H_{2}S}=3.2MPa$, $P_{CO_{2}}=3.2MPa$) at $90^{\circ}C$ for 168 hrs, which show that the coatings can be used for corrosion prevention in downhole environments with specific high temperature and high pressure, such as sour gas wells. The other testing results show the oil tube protective coatings have excellent comprehensive performance.

• International Journal of Ocean System Engineering
• /
• v.2 no.4
• /
• pp.209-213
• /
• 2012

Recently, the fuel using in the diesel engines of marine ships has been changed to a low quality of heavy oil because of the steady increase in the price of oil. Therefore, the wear and corrosion in all parts of the engine such as the cylinder liner, piston crown, and spindle and seat ring of exhaust valves has correspondingly increased. The repair welding of a piston crown is a unique method for prolonging its lifetime from an economic point of view. In this case, filler metals with a high corrosion and wear resistance are mainly being used for repair welding. However, often at a job site on a ship, a piston crown is actually welded with mild filler metals. Therefore, in this study, mild filler metals such as CSF350H, E8000B2, and 435 were welded to SS401 steel as the base metal, and the corrosion properties of the weld metals with and without post weld heat treatment were investigated using some electrochemical methods in a 0.1% $H_2SO_4$ solution. The weld metal welded with CSF350H filler metal exhibited the best corrosion resistance among these filler metals, irrespective of the heat treatment. However, the weld metal zones of the E8000B2 and 435 filler metals exhibited better and worse corrosion resistance with the heat treatment, respectively. As a result, it is suggested that in the case of repair welding with CSF350H and 435 filler metals, no heat treatment is advisable, while heat treatment is desirable if E8000B2filler metal is used with repair welding.

• Corrosion Science and Technology
• /
• v.17 no.3
• /
• pp.109-115
• /
• 2018

Electrical Resistance Welding (ERW) on a longitudinal seam-welded pipe has been extensively used in oil and gas pipelines. It is well known that the weld zone commonly suffers from grooving corrosion in ERW pipes. In this paper, the grooving corrosion performances of API X65 grade non-sour service (steel-A) and API X70 grade sour gas resistant (steel-B) steel electrical resistance welding pipelines were evaluated. The microstructure of the bondline is composed of coarse polygonal ferrite grains and several elongated pearlites. The elongated pattern is mainly concentrated in the center of the welded area. The grooving corrosion test and electrochemical polarization test were conducted to study the corrosion behavior of the given materials. A V-shaped corrosion groove was found at the center of the fusion zone in both the steel-A and steel-B ERW pipes, as the corrosion rate of the bondlines is higher than that of the base metal. Furthermore, the higher volume fraction of pearlite at the bondline was responsible for the higher corrosion rate at the bondline of both types of steel.

• Elastomers and Composites
• /
• v.41 no.2
• /
• pp.79-87
• /
• 2006

This study are conducted for the purpose of developing rubber material with noise and crack resistance. Cure characteristics, physical properties, thermal resistance, fuel resistance, abrasion resistance, crack resistance and noise resistance of NBR compounds with the various amounts of oleamide and aramid chip were investigated. From the measurements of cure characteristics and Mooney viscosities, cure characteristics of uncured rubber showed that a torque was decreased as the amount of oleamide increased. Hardness, modulus and elongation of rubber specimens tended to be reduced gradually, however, tensile strength remained unchanged as the amount of the oleamide increased. As a testing results of heat resistance for 70 hours at $120^{\circ}C$ and oil resistance far 70 hours at $40^{\circ}C$, tensile strength and elongation were all reduced. From the TGA/DSC analysis, there was no such a change observed in thermal characteristics of rubber materials. As a result of testing basic physical properties, abrasion resistance, noise resistance and crack resistance, the optimum ratio of oleamide to NBR was found to be 3 phr, while that of aramid to NBR 227001 was 1 phr.

• International Journal of Naval Architecture and Ocean Engineering
• /
• v.6 no.2
• /
• pp.363-379
• /
• 2014

In an effort to cope with recent high oil price and global warming, developments of air lubricated ships have been pursued to reduce greenhouse gas emissions and to save fuel costs by reducing the frictional resistance. In this study, reduction in the frictional resistance by air lubrication with air layers generated on the lower surface of a flat plate was investigated experimentally in the large water tunnel of SSMB. The generated air layers were observed, and changes in the local frictional drag were measured at various flow rates of injected air. The results indicated that air lubrication with air layers might be useful in reducing the frictional resistance at specific conditions of air injection. Accordingly, resistance and self-propulsion tests for a 66K DWT bulk carrier were carried out in the towing tank of SSMB to estimate the expected net power savings.

• Elastomers and Composites
• /
• v.40 no.3
• /
• pp.196-203
• /
• 2005

In this work, the engine oil resistant evaluation and breakdown analysis of room temperature vulcanizing silicone adhesives were performed through the surface properties, thermal stabilities, adhesive strength, and morphology measurements. As a result, the permeation of engine oil into adhesive specimens was carried out from surface to center in the specimens. And the oil content in the adhesive specimens was increased and the Si-O-Si bond of the adhesives was decomposed with increasing the aging time. The TGA results indicated that the thermal degradation was mainly occurred at under and surfaces of the specimens. The tensile strength, elongation, and adhesive strength of the adhesives were significantly decreased after the engine oil resistant tests, which could be attributed to the initial lose of adhesive properties resulting from the engine oil absorption and thermal aging. And the failure mode of the adhesive specimens was changed from cohesive failure to interfacial failure.