• 제목/요약/키워드: oil-degradation

검색결과 405건 처리시간 0.025초

METHANOGENIC FERMENTATION OF FAT-CONTAINING WASTEWATER MEDIATED BY IRON

  • Zubair, A.;Ivanov, V.;Kim, In-S.
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2000년도 춘계학술발표대회
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    • pp.109-112
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    • 2000
  • Long chain fatty acids (LCFA) are potential inhibitors of bacteria involved in anaerobic digestion because of their surface activity. Precipitation of long-chain fatty acids with iron can improve the anaerobic degradation due to their precipitation and reducing surface properties. Degradation of stearic acid was improved in the presence of iron (II). The methane production was increased 1.6 times as compared to control. Iron-containing soil was applied for degradation of vegetable oil as model case. The methane production was increased 1.5 times as compared to control. Yield of methane production was 0.09 and 0.06L/g COD in experiment and control respectively. Optimum COD/Fe ratio was found 20 mg/mg. Iron (II) can be produced in the treatment system from iron (III) hydroxide or iron containing minerals.

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High oil phase에서 Rhodococcus rhodochrous IGTS8의 Dibenzothiophene 분해능 향상을 위한 조건 조사

  • 최윤규;박홍우
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2000년도 추계학술발표대회 및 bio-venture fair
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    • pp.540-543
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    • 2000
  • 본연구에서는 Rhodococcus rhodochrous IGTS8 균주를 사용하여 고농도의 유상에서 탈황효율을 높이기 위한 오일 함유비, pH, 영양물질의 영향을 조사하였다. 오일 함유비에 의한 영향은 유상이 30%이하일 경우 그리 크지 않았으며, pH 조절에 의해 50%, 영양물질의 강화에 의해 32%의 탈황효율이 증가했다. 강화배지에서 pH를 조절하며 배양한 결과, 기존의 배양에 비해 136% 탈황효율이 증가했다.

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바이오매스의 Fast Pyrolysis 공정과 Bio-Oil의 특성 (Review on the East Pyrolysis of Biomass and Characteristics of Bio-Oil)

  • 명소영;박영권;전종기;김주식
    • 자원리싸이클링
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    • 제13권1호
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    • pp.3-13
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    • 2004
  • 바이오매스의 이용은 과거부터 지속되어 왔지만 최근 들어 새로운 대체에너지로의 활용이라는 측면에서 집중적인 연구가 시도되고 있다. 바이오매스를 이용하는 방법으로서의 fast pyrolysis는 다른 방법들보다 고부가가치의 화학물질을 생성할 수 있다는 점에서 크게 주목을 받고 있다. 이 리뷰 논문은 현재 fast pyrolysis를 바이오매스 전환 공정으로 이용하고 있는 실례를 선보이고 그 공정에서 생산되는 생성물인 bio-oil의 특성을 소개하고 있다.

가정용 고무장갑의 기름에 의한 내구성 변화 (Degradation of Household Rubber Gloves by Edible Oils)

  • 정혜원;유화숙
    • 한국의류학회지
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    • 제27권9_10호
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    • pp.1093-1100
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    • 2003
  • Following a treatment with edible oils and/or washing, the tensile properties of vulcanized rubber were measured to assess the effect of the sorbed edible oil. Rubber soiled with soybean oil, after 8 weeks storage in a 30$^{\circ}C$ incubator, retained 61% of its original strength, and rubber soiled and washed retained the 73%. The strength of the rubber soiled with oil decreased remarkably during the first 2 weeks. After repeating this soiling and/or washing 7 times, the soiled rubber had only 16% of its original strength, the rubber soiled and washed had 45%. In all cases, breaking elongations were not decreased as much as tensile strengths; therefore , more of the elasticity of the rubber remained than did the strength. From these results it is concluded that washing after soiling with oils is very helpful in maintaining the strength of rubber. In this study, three different surfactant solutions, AS, AE and AS/AE, were used. In the AS solution, the contact angle of the soybean oil was greater and the work of the detergency was the smaller than in either the AE or the AS/AE solution, the loss of the strength of the rubber washed in AS solution did not decrease significantly. These results suggest that rolling-up, emulsification and solubilization also participate in the removal of oil from rubber.

온도 변수에 대한 유류의 휘발특성 및 탄화수소 화합물의 존재비에 관한 연구 (Evaporation Characteristics of Oil and Abundance Ratio of Hydrocarbon Compounds at Different Temperatures)

  • 최정식
    • 해양환경안전학회지
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    • 제27권7호
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    • pp.1116-1123
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    • 2021
  • 해수에 유출된 유류는 대기와 해수와의 접촉을 통해 다양한 풍화 과정(증발, 확산, 분산, 유화, 용해, 산화, 침전 및 생물분해 등)을 통해 물리·화학적 변화와 함께 생물학적 분해과정을 겪는다. 본 연구에서는 여러 가지 풍화작용 중 가장 즉각적이고 빠르며 오염물질의 질량에 가장 큰 영향을 미치는 인자라고 알려진 증발(evaporation)에 대한 영향을 확인해보고자 하였다. 휘발유, 등유, 경유를 대상으로 25 ℃(해수 연평균 온도)와 35℃(적도 부근 온도) 조건에서 유류의 휘발특성을 비교하였다. 이를 위해, 일정 기간마다 채취한 유류를 전처리하여 GC/MS 분석을 수행하고, 탄화수소의 변화량을 계산하여 비교하였다.

부하반환법에 의한 20KVA 비정질 변압기의 경년열화 연구 (Aging Test of 20kVA Amorphous Core Transformer by Loading Back Method)

  • 민복기;송재성;정영호;임정재
    • 대한전기학회논문지
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    • 제43권2호
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    • pp.278-285
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    • 1994
  • Aging test was done by loading back method for 20kVA amorphous core transformers manufactured by Hyosung Industries Co. and korea Electric Power Corporation. Iron losses, copper losses and insulation oil temperatures of the transfromers was measured for all the testing period. Expected life of amorphous core transformers on the basis of the degradation of the insulators was 46 years at 100% load, and 2.4 years at 130% load. Average temperature rising of transformer oil of amorphous core transformers was higher than that of silicon steel core transformers. Hence lowering the oil temperature by optimized design is needed for improving the expected life of the amorphous transformers.

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Effect of the crude oil environment on the electrical conductivity of the epoxy nanocomposites

  • Seyed Morteza Razavi;Soroush Azhdari;Fathollah Taheri-Behrooz
    • Advances in nano research
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    • 제15권4호
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    • pp.285-294
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    • 2023
  • This study is aimed to investigate the electrically conductive properties of epoxy nanocomposites exposed to an acidic environment under various mechanical loads. For simultaneous assessment of the acidic environment and mechanical load on the electrical conductivity of the samples, the samples with and without carbon nanotubes were exposed to the acidic environment under three different loading conditions for 20 days. Then, the aged samples' strength and flexural stiffness degradation under crude oil and bending stress were measured using a three-point flexural test. The aged samples in the acidic environment and under 80 percent of their intact ultimate strength revealed a 9% and 26% reduction of their electrical conductivity for samples with and without CNTs, respectively. The presence of nanoparticles declined flexural stiffness by about 16.39%. Scanning electron microscopy (SEM) images of the specimen were used to evaluate the dispersion quality of CNTs. The results of this study can be exploited in constructing conductive composite electrodes to be used in petroleum environments such as crude oil electrostatic tanks.

Influence of Electrical Aging on Space Charge Dynamics of Oil-Impregnated Paper Insulation under AC-DC Combined Voltages

  • Wang, Yan;Li, Jian;Wu, Sicheng;Sun, Peng
    • Journal of Electrical Engineering and Technology
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    • 제8권6호
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    • pp.1512-1519
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    • 2013
  • Oil-impregnated paper is a major type of insulation used in oil-filled converter transformers for both traditional and new energy systems. This paper presents and analyzes the results of the experiment conducted on the electrical aging of oil-impregnated paper under AC-DC combined voltages using the pulsed electro-acoustic (PEA) technique. The formation and dynamics of space charge affected the performance of insulation material. The electrical aged oil-paper insulation was obtained through electrical aged experiments under the voltages. Based on the PEA technique, measurements were carried out when the oil-paper insulation system was subjected to different stressing and aging times. The space charge dynamics in the bulk of the oil-paper insulation system with different aging times were measured and analyzed. Characteristic parameters such as the total charge injection amount, the total charges of fast moving and slow moving, and the distortion factor of electric field were calculated and discussed. Results show that the longer electrical aging time, the more charges trapped in the bulk of aging sample. It leads to larger distortion factor of electric field in the bulk of aging samples and accelerate degradation of oil-paper insulation under AC-DC combined voltages.

Thermal Destruction of Waste Insulating Oil Containing PCBs under High Temperature and Pressurized Conditions

  • Seok, Min-Gwang;Lee, Gang-Woo;Lee, Jae-Jeong;Kim, Min-Choul;Kim, Yang-Do;Jung, Jong-Hyeon;Shon, Byung-Hyun
    • Environmental Engineering Research
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    • 제17권3호
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    • pp.157-165
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    • 2012
  • This experimental study was performed to obtain thermal energy from the combustion of synthetic gas, produced by the pyrolysis of insulating oil containing polychlorinated biphenyls (PCBs) in a high temperature and high pressure reactor. The average synthetic gas generated was $59.67Am^3/hr$ via the steady state gasification of insulating oil waste (20 kg/hr) with average concentrations (standard deviation) of $CO_2$, CO, and $H_2$ in the synthetic gas of $38.63{\pm}3.11%$, $35.18{\pm}1.93%$, and $28.42{\pm}1.68%$, respectively. The concentrations of the PCBs in the transformer insulating oil and synthetic gas after its gasification, and the concentrations of the dioxins that could be produced from the incomplete degradation of PCBs were measured. It was revealed that the PCBs in the insulating oil were composed of the series from tetrachlorobiphenyl to octachlorobiphenyl. However, only the #49, #44, #52, and #47/75/48 congeners were detected from the synthetic gas after gasification of the insulating oil and in the flue gas from the combustor. In conclusion, the experimental conditions suggested in this study were very useful for the appropriate treatment of insulating oil containing PCBs. Also, fuel gas containing CO and $H_2$ can be obtained from the pyrolysis of insulating oil containing PCBs.