• Title/Summary/Keyword: oil extraction

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An investigation on the in si.tu measurement of the oil-concentration

  • Kim, Chang-Nyeun;Park, Young-Moo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.9 no.1
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    • pp.20-28
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    • 2001
  • In order to predict thermodynamic performance of refrigeration system, it is required to know the oil concentration of the refrigerant/oil mixture. The current method is to extract the working mixture and then to measure the oil weight. In this study, oil concentration is measured in si.tu way without any extraction of the working fluid. Based on the measurement, a working equation is presented as follows, C=a +b x t +c x $t^2$ +(d + e x t +f x $t^2$) x SG. C is oil concentration, t is temperature($^{\circ}C). SG Is specific gravity of mixture and a~f is coefficients The oil concentration ranges over 0~l2 wt% and the temperature ranges over 20~50$^{\circ}C. The specific gravity and temperature are measured using the on-line densimeter and thermometer. This working equation enables to predict the oil concentration without any extraction of the mixture. This equation can be applied for R-12/Naphthenic oil and R-134a/P0E oil liquid mixtures.

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Fatty Acid Composition and Stability of Extracted Mackerel Muscle Oil and Oil-Polyethylene Glycol Particles Formed by Gas Saturated Solution Process

  • Haque, A.S.M. Tanbirul;Asaduzzaman, A.K.M.;Chun, Byung-Soo
    • Fisheries and Aquatic Sciences
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    • v.17 no.1
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    • pp.67-73
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    • 2014
  • The oil in mackerel muscle was extracted using an environment friendly solvent, supercritical carbon dioxide (SC-$CO_2$) at a semibatch flow extraction process and an n-hexane. The SC-$CO_2$ was maintained at a temperature of $45^{\circ}C$ under pressures ranging from 15 to 25 MPa. The flow rate of $CO_2$ (27 g/min) was constant during the entire 2 h extraction period. The fatty acid composition of the oil was analyzed using gas chromatography (GC). Significant concentrations of eicosapentaenoic acid (EPA) acid and docosahexaenoic acid (DHA) acid were present in the SC-$CO_2$ extracted oil. The oil extracted using SC-$CO_2$ exhibited increased stability compared with n-haxane extracted oil. Particles of mackerel oil together with the biodegradable polymer, polyethylene glycol (PEG) were formed using a gas saturated solution process (PGSS) with SC-$CO_2$ in a thermostatted stirred vessel. Different temperatures ($45-55^{\circ}C$), pressures (15-25 MPa) and a nozzle size $400{\mu}m$ were used for PGSS with a 1 h reaction time. The stability of mackerel oil in the particles did not changed significantly.

An investigation on the in si.tu measurement of the oil-concentration

  • Kim, Chang-Nyeun;Park, Young-Moo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.8 no.2
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    • pp.80-88
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    • 2000
  • In order to predict thermodynamic performance of refrigeration system, it is required to know the oil concentration of the refrigerant/oil mixture. The current method is to extract the working mixture and then to measure the oil weight. In this study, oil concentration is measured in si.tu way without any extraction of the working fluid. Based on the measurement, a working equation is presented as follows, C=a +b x t +c x $t^2$ +(d + e x t +f x $t^2$) x SG. C is oil concentration, t is temperature($^{\circ}C). SG Is specific gravity of mixture and a~f is coefficients The oil concentration ranges over 0~l2 wt% and the temperature ranges over 20~50$^{\circ}C. The specific gravity and temperature are measured using the on-line densimeter and thermometer. This working equation enables to predict the oil concentration without any extraction of the mixture. This equation can be applied for R-12/Naphthenic oil and R-134a/P0E oil liquid mixtures.

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Separation and Characteristics of Essential Oil from Dendropanax morbiferus (황칠나무 정유의 분리 및 특성)

  • Kim, Seung-Geon;Lee, Ho-Won
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.44-49
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    • 2022
  • Essential oil was separated from Dendropanax morbiferus (DM) by means of hot water extraction and supercritical extraction, respectively, and the separated essential oil was analyzed qualitatively and quantitatively, and the antioxidant effect of essential oil was investigated. In addition, yields of essential oil and Caryophyllene according to the drying and extraction methods for each part of DM were obtained and compared, respectively. The yield of essential oil was found to be high in the order of bark > leaves > twigs > limb. When the freeze-dried DM leaves were supercritically extracted, the yields of essential oil and Caryophyllene were 23.2 g/kg DM and 429.6 mg Caryophyllene/kg DM, respectively. The essential oil of DM showed an antioxidant effect even at a low concentration, and the concentration of the essential oil of SC50, which means 50% of 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging activity, was about 0.34%.

$Einflu{\beta}$ der Extraktionsmethode und Losungsmittel auf einige Minorbestandteile in den rohen Olen und die Autoxydationsbereitschaft der Ole (추출 방법과 용매가 채종유 중 수종 미량성분의 그 자동산화능에 미치는 영향)

  • ;Artur Seher
    • Journal of Food Hygiene and Safety
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    • v.2 no.2
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    • pp.83-88
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    • 1987
  • Effects of the extraction-methods and solvents on some minor components in crude rapeseed-oil and the autooxidation of the oils were examined in this study. The contents of unsaponifiable matters and sterols were not significantly variied depending on the extraction-methods and solvents. Chlorophyll-contents were elevated with the increasing molecular weights of extractionsolvents. Any significant effect of the extraction-temperature on the yield of chlorophyll was not observed. Autoxidation-tendency of the oils was found to be dependent on the boiling points of extraction-solvents.

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Studies on the Some Physical and Chemical Characteristics of Nutmeg Oil by Different Extraction Methods (추출방법에 따른 Nutmeg Oil의 물리적, 화학적 성질에 관한 연구)

  • Jang, Hee-Jin;Ra, Do-Young;Kim, Ok-Chan;Yang, Kwang-Kyu
    • Korean Journal of Food Science and Technology
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    • v.21 no.6
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    • pp.851-856
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    • 1989
  • The physical properties of essential oil of nutmeg extracted in different methods (SDE, Solvent, $CO_2$) were investigated and also the components of essential oil were analyzed using G.C. and G.C./ Mass. Solvent extraction yield was 23% and was higher than those of SDE extraction and $CO_2$ extraction. From the analysis result and physical properties of nutmeg oil, it was conformed that the nutmeg used In this experiment was similar to East Indies type. The content of sabinene was 3.6-14.1%, 28.4-48.7% for myristicin, 1.2-2.1% for elemicin, and 3.6-5.6% for safrole. The camphene was identified in SDE extracts but not in $CO_2$ extracts. The volatile components of SDE extracts and solvent extracts contained large amount of monoterpene and terpene alcohol but $CO_2$ extracts aminly contained aromatic compounds.

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On study antioxidant effect and aroma component of natural citrus by SC-$CO_2$ Extraction (초임계추출의 천연물 시트러스계의 항산화효과와 향기성분 연구)

  • Lim, Deok-Jum;Chun, Byung-Soo;OH, Dae-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.2
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    • pp.285-295
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    • 2014
  • Citrus essential oil were extracted from citron peel of cultivated in Gohong (CCP) using environmentally friendly supercritical carbon dioxide method. Antioxidant activity and aroma composition of the essential oils extracted by the SC-$CO_2$ method were evaluated by comparing with those extracted by organic solvent method. Fatty acid composition, DPPH scavenging, and antioxidant activity of the oils obtained by different extraction condition of SC-$CO_2$ method were investigated and their antioxidant activities were compared with commercially available lavender, eucalyptus and tea tree oils. As the results, linoleic acid was most abundantly found from CCP oil extracted by the SC-$CO_2$ method and cis-11,144-eicosadienoic acids was second abundantly found. Radical scavenging ability of DPPH was 98% when the concentration of CCP oil was 50 mg/mL. This scavenging ability increased with the increase of oil concentration. On the other hand, flavonoids content (84 mg/100g) of the CCP oil extracted by the SC-$CO_2$ method was slightly higher than that (75 mg/100g) by hexane extraction. The results, obtained from CCP oil by GC-MS, indicated that, among 66 components, the content of terpenes was 55.8% and limonene was 27.3%.

Indole Crystallization in Coal Tar Absorption Oil using Methanol Solvent Extraction (메탄올 용매추출을 이용한 콜타르 흡수유 중의 인돌 결정화)

  • Ryu, Heeyong;Lee, Sangheon;Shin, Sungsoon
    • Applied Chemistry for Engineering
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    • v.33 no.2
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    • pp.166-172
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    • 2022
  • A method of efficiently purifying high value-added indole among components of coal tar absorption oil was studied using a step-by-step process of extraction-distillation-crystallization. The coal tar absorption oil used in this study contains 1.2% naphthalene, 0.1% quinoline, 0.4% isoquinoline, 6.4% indole, 21.0% 1-methylnaphthalene, 48.8% 2-methylnaphthalene, and 11.7% biphenyl as main components. For the separation and purification of indole, methanol was first used as a solvent to separate indole species in the coal tar absorption oil into an extract phase. And then methanol was recovered by distillation. Subsequently, an extraction solution where methanol was removed was mixed with normal hexane, and then crystallized to recover indole having a purity of 99.3%. Based on the experiments of this study, a purification process scheme for indole in coal tar absorption oil was proposed.

The Impact of Oil Exploration and Development on the Dynamic Structure of Tariff Imposed by Oil Importing Country: The Case of OPEC (석유 탐사 및 개발이 석유 수입관세의 동태적 부과구조에 미치는 영향: OPEC의 경우)

  • Lee, Dug Man
    • Environmental and Resource Economics Review
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    • v.25 no.2
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    • pp.255-276
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    • 2016
  • This paper is designed to investigate the dynamic structure of optimal tariff imposed by the oil importing country from OPEC when OPEC increases the oil reserves through exploration and development. For this purpose, we used a Stckelberg differential game modeling approach, and tried to analyze two cases such that the one is the extraction cost is dependent on the oil reserves and the other is the extraction cost is independent of it. On the basis of this analysis, we propose that the importing contry has to impose dynamically inconsistent tariffs if the extraction cost is dependent on the oil reserves. Otherwise, she should impose dynamically consistent tariffs announced at initial time. In addition, we found that whether or not the exporting country uses some portion of oil produced for domestic consumption does not affect our policy proposition stated above.

Effects of Particle Size and High Pressure Process on the Extraction Yield of Oil Compounds from Soybean Powder Using Hexane and Supercritical Fluid (입자 크기와 초고압 처리에 따른 유기용매와 초임계 유체 추출법에서의 대두유 추출수율의 변화)

  • Yoon, Won-Byong
    • Food Engineering Progress
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    • v.15 no.3
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    • pp.203-208
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    • 2011
  • Effects of particle size and high pressure processing on the extraction rate of oil compounds from soybean powder were evaluated by Soxhlet method using hexane and supercritical fluid extraction (SFE) using $CO_{2}$. SFE was carried out at 4,000 psi and $50^{\circ}C$ for 4 hr. The mean particle sizes were varied from 26.7 to 862.0 ${\mu}m$ by controlling milling time. Saturation solubility increased as the particle size decreased. At large particle size, high pressure processing (HPP) showed higher extraction yield in both hexane extraction and SFE, but, as the particle size decreased, the HPP was irrelevant to the extraction yield in SFE. The higher extraction rate obtained from the smaller particle size. The scanning electronic microscopy of soybean powder treated by HPP showed pores on the surface of the particle. The higher extraction rate and yield from HPP treatment might be due to the less internal resistance of transferring the solvent and miscellar in the solid matrix by collapsing of tissues.