Journal of the Korean Applied Science and Technology (한국응용과학기술학회지)

The Korean Society of Applied Science and Technology (한국응용과학기술학회)
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On study antioxidant effect and aroma component of natural citrus by SC-$CO_2$ Extraction

초임계추출의 천연물 시트러스계의 항산화효과와 향기성분 연구

  • Lim, Deok-Jum (Dept. of Industrial Chemistry, Pukyoung National University) ;
  • Chun, Byung-Soo (Food Science & Technology, Pukyoung National University) ;
  • OH, Dae-Hee (Dept. of Industrial Chemistry, Pukyoung National University)
  • Received : 2014.06.01
  • Accepted : 2014.06.25
  • Published : 2014.06.30
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Abstract

Citrus essential oil were extracted from citron peel of cultivated in Gohong (CCP) using environmentally friendly supercritical carbon dioxide method. Antioxidant activity and aroma composition of the essential oils extracted by the SC-$CO_2$ method were evaluated by comparing with those extracted by organic solvent method. Fatty acid composition, DPPH scavenging, and antioxidant activity of the oils obtained by different extraction condition of SC-$CO_2$ method were investigated and their antioxidant activities were compared with commercially available lavender, eucalyptus and tea tree oils. As the results, linoleic acid was most abundantly found from CCP oil extracted by the SC-$CO_2$ method and cis-11,144-eicosadienoic acids was second abundantly found. Radical scavenging ability of DPPH was 98% when the concentration of CCP oil was 50 mg/mL. This scavenging ability increased with the increase of oil concentration. On the other hand, flavonoids content (84 mg/100g) of the CCP oil extracted by the SC-$CO_2$ method was slightly higher than that (75 mg/100g) by hexane extraction. The results, obtained from CCP oil by GC-MS, indicated that, among 66 components, the content of terpenes was 55.8% and limonene was 27.3%.

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References

  1. J. H. Park, ect, Effect of Ethanol Extract from Peel of Citrus joun and Poncirus trifoliata on Antioxidant and Immune Activity, J. of life science, 18 (3), 403-408 (2008). https://doi.org/10.5352/JLS.2008.18.3.403
  2. S. M, Njoroge, Ukeda H, Sawamura M.. Changes in the volatile composition of yuzu(Citrus junos Tanaka) cold pressed oil during storage. J. Agric Food Chem, 44, 550-556 (1996). https://doi.org/10.1021/jf950284k
  3. H. S, Song Sawamura M, Ito T, Kawashimo K, Ukeda : Quantitative determination and characteristic flavour of Citrus junos (yuzu) peel oil. Flavour Frag J. 15, 245-250 (2000). https://doi.org/10.1002/1099-1026(200007/08)15:4<245::AID-FFJ904>3.0.CO;2-V
  4. Hashinaga F, Herman Z, Hashegawa S.. Limonoids in seeds of yuza (Citrus junos Sieb. ex Tanaka). Nippon Shokuhin Kogyo Gakkaishi 37, 380-382 (1990). https://doi.org/10.3136/nskkk1962.37.5_380
  5. J. Y. Jeong, Optimization of extraction conditions for limonin and nomilin in citron seed. MS Thesis. Chungbuk National University, Cheongju, Korea. (2008).
  6. Miyake Y, Yammamoto K, Tsujihara N, Osawa T. Protective effects of lemon flavonoids on oxidative stress in diabetic rats. Lipids 33, 689-695 (1998). https://doi.org/10.1007/s11745-998-0258-y
  7. Berkarda B, Koyuncu H, Soybir G, Baycut F. Inhibitory effect of hesperidin on tumour initiation and promotion in mouse skin. Res Exp Med.198, 93-99 (1998). https://doi.org/10.1007/s004330050093
  8. Calomme M, Pieters L, Vlietinck A, Vanden BD. Inhibition of bacterial mutagenesis by citrus flavonoids. Planta Med. 62 : 222-226 (1996). https://doi.org/10.1055/s-2006-957864
  9. E. M, Galati Trovato A, Kirjavainen S, Forestieri AM, Eossitto A, Monforte MT. Biological effects of hesperidin, A citrus flavonoid (note III):Antihypertensive and diuretic activity in rat. Farmaco, 51: 219-221 (1996).
  10. Basile A, Sorbo S, Giordano S, Ricciardi L, Ferrara S, Montesano D, Castaldo Cobianchi R, Vuotto ML, Ferrara L. Antibacterial and allelopathic activity of extract from Castanea sativa leaves. Fitoterapia 71: S110-S116 (2000). https://doi.org/10.1016/S0367-326X(00)00185-4
  11. Mannheim, C. H. and Passy, N, Aroma recovery and retention in fruit juices. Flavours, 323 (1975).
  12. Eric D. Lund and William L. Bryan, Composition of lemon oil distilled from commercial mill waste. J. Food Sci., 41, 1194 (1976). https://doi.org/10.1111/j.1365-2621.1976.tb14415.x
  13. C. H. Oh, Jung-Han Kim, Kyoung- Rae Kim and Hey-Joon (1989), Flavor Components of Poncirus trifoliata, Koren J. Food Sci. technal, 21, 749-754.
  14. J. h. Lee, Study on Antioxidant and Antimicrobial Activity of Oil Extracted from Brown Seaweed(Laminaria japonica) Added Wheat Germ using Supercritical Carbon Dioxide. Ms. Thesis, Pukyoung National Untiversity. Korea, (2013).
  15. Herrman, K (1989). Occurrence and content of hydroxycinnamic and hydroxybenzoic acid compounds in foods. Crit. Rev. Food Sci. Nutr. 28, 315-347 https://doi.org/10.1080/10408398909527504
  16. Yusof, S., G. H. Mohd and G. Sweeking.. Naringin content in local Citrus fruits. Food chmistry. 37, 113-121 (1990). https://doi.org/10.1016/0308-8146(90)90085-I
  17. J. H. Park, B. W. Kang, Ji Eun Kim, Min Jeong Seo, Young Choon Lee, Jai Heon Lee, Woo Hong Joo, Yung Hyun Choi, Hak Seob Lim, Yong Kee Jeong, Bok Kyu Lee, Effect of Ethanol Extract from Peel of Citrus junos and Poncirus trifoliata on Antioxidant and Immune Activity. Journal of Life Science. 18 (3): 403-408 (2008).
  18. H. S. Yang Effect adding Extracts of Kalopanacis cortex on Quality Characterists of Chicken Feet Stock. Ph. Thesis. Pukyoung National University (2014).