• Title/Summary/Keyword: oil based

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Silicone oil에 기초한 microemulsion을 이용한 DNAPL의 제거

  • 권태순;백기태;이재영;양중석;양지원
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.479-482
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    • 2003
  • In this study, the solubilization of dense nonaqueous phase liquid (DNAPL) using oil-based emulsion was investigated for aquifer remediation. The micro-sized oil emulsion has large surface areas and buoyancy force, therefore it can be effective in treating DNAPL pool of the aquifer without downward migration of DNAPLs. The emulsion was prepared using silicone oil and mechanical homogenization. And the prepared emulsion had micro-sized similar distribution: 99 % in number and 80 % in volume were less than 10${\mu}{\textrm}{m}$. As target pollutants, trichloroethylene and 1, 2 dichlorobenzene were selected. All of used DNAPLs were solubilized successfully in oil-based emulsion. Even at low oil percentage, emulsion showed good solubility against pollutants. Therefore, the remediation using oil-based emulsion was considered as an effective alternative in dealing with DNAPLs of the aquifer.

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Authentication of Rapeseed Oil Using an Electronic Nose Based on Mass Spectrometry (MS-전자코를 이용한 유채유의 진위 여부 판별)

  • Hong, Eun-Jeung;Son, Hee-Jin;Choi, Jin-Young;Noh, Bong-Soo
    • Korean Journal of Food Science and Technology
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    • v.43 no.1
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    • pp.105-109
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    • 2011
  • To determine mixing ratios for mixtures of rapeseed oil and other oils, an electronic nose (E-nose) based on a mass spectrometer system was used. Rapeseed oil was blended with soy bean oil or corn oil at ratios of 100:0, 97:3, 94:6, 91:9, 88:12, 85:15, and 80:20, respectively. The intensities of each fragment from the mixed rapeseed oil by E-nose based on MS were completely different from those of the soy bean oil and corn oil. The obtained data were used for discriminant function analysis (DFA). DFA plots indicated a significant separation of pure rapeseed oil and soy bean oil or corn oil and their mixtures. The added concentration of soy bean oil or corn oil to rapeseed oil was highly correlated to the first discriminant function score (DF1). When soy bean oil was added to rapeseed oil, it was possible to predict the following equation: DF1=-0.170*conc. of soy bean oil+0.431 ($r^2=0.989$). For corn oil the equation was: DF1=-0.1*conc. of corn oil+0.4 ($r^2=0.844$). The use of an E-nose based on a MS system is as an efficient method for the authentication of pure rapeseed oil.

Apparatus for Monitoring Oil Oxidation Using a Plurality of UV Fluorescence Light-reflecting Members (복수 경로를 지닌 자외선 형광측정기를 이용한 오일 산화도 측정장치)

  • Kong, H.;Han, H.G.;Markava, L.V.
    • Tribology and Lubricants
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    • v.26 no.3
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    • pp.167-174
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    • 2010
  • An apparatus for measuring oil oxidation was developed, which is capable of being mounted to mechanical devices for detecting power of fluorescent light reflected from oil in real time as an indication of the oil oxidation. This device has an advantage over conventional fluorescence spectrometers where the thin film is required for the measurement. Clean and used oil samples (mineral and synthetic oils) were tested by the developed apparatus that calculates a fluorescence quantum yield and a light absorption coefficient of the oil based upon the signals from the two light-receiving members and evaluates the degree of oil oxidation of test oils based on the fluorescence quantum yield. Results generally show that the developed device is able to effectively evaluate oil oxidation characteristics on-site in the field.

A Study on Properties of Crude Oil Based Derivative Linked Security (유가 연계 파생결합증권의 특성에 대한 연구)

  • Sohn, Kyoung-Woo;Chung, Ji-Yeong
    • Asia-Pacific Journal of Business
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    • v.11 no.3
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    • pp.243-260
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    • 2020
  • Purpose - This paper aims to investigate the properties of crude oil based derivative security (DLS) focusing on step-down type for comprehensive understanding of its risk. Design/methodology/approach - Kernel estimation is conducted to figure out statistical feature of the process of oil price. We simulate oil price paths based on kernel estimation results and derive probabilities of hitting the barrier and early redemption. Findings - The amount of issuance for crude oil based DLS is relatively low when base prices are below $40 while it is high when base prices are around $60 or $100, which is not consistent with kernel estimation results showing that oil futures prices tend to revert toward $46.14 and the mean-reverting speed is faster as oil price is lower. The analysis based on simulated oil price paths reveals that probability of early redemption is below 50% for DLS with high base prices and the ratio of the probability of early redemption to the probability of hitting barrier is remarkably low compared to the case for DLS with low base prices, as the chance of early redemption is deferred. Research implications or Originality - Empirical results imply that the level of the base price is a crucial factor of the risk for DLS, thus introducing a time-varying knock-in barrier, which is similar to adjust the base price, merits consideration to enhance protection for DLS investors.

New Bio-based Polymeric Materials from Plant Oils

  • Uyama, Hiroshi
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.359-359
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    • 2006
  • This study deals with development of new bio-based polymeric materials from epoxidized soybean oil (ESO). The curing of ESO in the presence of organophilic montmorillonite produced an oil polymer-clay nanocomposite ("green nanocomposite") showing flexible property. A green nanocomposite (oil polymer-silica nanocomposite) coatings were synthesized by an acidcatalyzed curing of ESO with 3-glycidoxypropyltrimethoxysilane. The curing of ESO in the presence of a biodegradable plastic, poly(caprolactone), produced a composite with semi-IPN structure. The mechanical properties of the composite was much superior to those of polyESO. These new oil-based materials have large potential for applications in various fields.

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Application and Assessment on the Effectiveness of the Hazard-Based Deployment Model for Oil Recovery Capacity on Water (위해도 기반 해상기름회수능력 배치모델 적용 및 유효성 평가)

  • Ha, Min-Jae;Moon, Jung-Hwan;Yun, Jong-Hwui
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.20 no.5
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    • pp.486-490
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    • 2014
  • In this study, the Hazard-based model to decide regional oil recovery capacity by using AHP is suggested and regional oil recovery capacity is calculated by applying the model. The simulation for oil recovery capacity by mobilization of regional oil recovery equipments is carried out to verify the availability of the model. The worst oil spill accident in Daesan Taean Pyeongtaek region, which is located in geographically disadvantageous position among the regions that the worst oil spill accident may occur, is supposed for the simulation. As a result of simulation, the quantity of oil that can be recovered for three days on the scene of oil spill accident is worked out as $15,841k{\ell}$, which can satisfy the goal of national oil recovery capacity for the worst oil spill accident, therefore the model is verified as practicable.

Role of FT-IR in Assessing Lubricant Degradation - A Study on Palm Oil Methyl Ester Blended Lubricant

  • Maleque, M.A.;Masjuki, H.H.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.351-352
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    • 2002
  • In this paper, studies were made on the palm oil methyl ester (POME) added lubricants using FT-IR for monitoring oil degradation. In order to assess the degradation characteristics of POME added lubricant by FT-IR, static oxidation test was conducted using three different blended lubricants (viz, zero percent POME, five percent POME and ten percent POME with mineral-based oil) for 280 hrs. The oxidation temperature was set at $140^{\circ}C$. FT-IR quantitative data indicate an increased in oxidation products which was formed from 10% POME added lubricants after 280 hrs of oxidation test. The 5% POME added lubricant and mineral-based lubricant (without POME) showed less oxidation product after the test. From the FT-IR spectrum analysis of the oxidized oils it could be concluded that 5% POME can improve the performance of mineral-based oil by forming protective films.

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A Case Study for Influence of Form-oil on Surface Condition of Steam-cured Concrete (증기양생 콘크리트 표면상태에 대한 박리제의 영향 사례연구)

  • Han, Sang Hoon;Yoon, Ju Yong;Hong, Ki Nam;Choi, Jae Wan;Lim, June Woo
    • Journal of the Korean Society of Safety
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    • v.28 no.1
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    • pp.52-56
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    • 2013
  • The purpose of this study is to evaluate the influence of form-oil on steam-cured concrete surface condition. Based, viscosity(high, medium, low) and flash point($26^{\circ}C$, $70^{\circ}C$) of form oil were considered as test variables. The digital image process method was applied for the extraction of air-void area from concrete surface. Test result showed that oil-based form oil reduced air-void by approximately 46% compared to water-based form oil, and the higher the viscosity was, the smaller air-void rate was. In addition, it was conformed that flash point of form oil had a considerable influence on the surface condition of steam-cured concrete.

Oil Film Thickness Measurement of Engine Bearing and Cam/tappet Contact in an Automotive Engine

  • Choi, Jae-Kwon;Min, Byung-Soon;Han, Dong-Chul
    • Tribology and Lubricants
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    • v.11 no.5
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    • pp.71-77
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    • 1995
  • The capacitance technique was used to measure the minimum oil film thickness in engine bearing and the central oil film thickness between cam and tappet. This method is based on the measurement of total capacitance of oil film. For the measurement of the oil film thickness between cam and tappet, two surfaces were assumed to be flat and parallel within the Hertzian region and all the measured capacitance originated from this region. Shear rates from the measured minimum oil film thickness are over 10$^{6}$ sec$^{-1}$ in the greater part in both two cases. The minimum oil film thickness in engine bearing is larger than the surface roughness. Between cam and tappet it is mostly smaller than the surface roughness. In spite of the awkward restriction of the reliability of measured oil film thickness, it was known that the capacitance technique makes it possible to measure the oil film thickness in elastohydrodynamic and mixed lubrication regimes as well as in hydrodynamic regime. Therefore, it is also possible to classify the lubrication regimes based on the oil film thickness.

Prediction of density and viscosity for $CO_2$-oil mixture at low oil concentration (낮은 오일 농도에서 $CO_2$-Oil 혼합물의 밀도와 점성예측)

  • Yun, Rin
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.136-141
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    • 2008
  • Due to environmental concerns $CO_2$ has been reintroduced as a potential candidate to replace HFCs in refrigeration systems since 1990s. In a refrigeration cycle, oil is utilized in lubricating a compressor. However, although oil separators are installed after a compressor oil is prone to leak to the whole system. The mixing of $CO_2$ and oil, even a small amount of oil, the heat transfer performance in heat exchanger deteriorated and the pressure drop inside tube increases. Therefore, it is needed to precisely estimate the mixture thermodynamic properties of $CO_2$-lubricant oil to correctly design a $CO_2$ refrigeration system. The commonly used method in estimating the mixture properties is the mole based weighting model. However, the accuracy of the method can not be assured. In the present study, $CO_2$-lubricant oil mixture properties including viscosity and density were estimated by using the mixture models, based on the equation of state (EOS).

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