• Title/Summary/Keyword: off gas hydrogen

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Development of WT-FC Hybrid System for Off-Grid (오프그리드용 풍력-연료전지 하이브리드 시스템 개발)

  • Choi, Jong-Pil;Kim, Kwang-Soo;Park, Nae-Chun;Kim, Sang-Hun;Kim, Byeong-Hee;Yu, Neung-Su
    • New & Renewable Energy
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    • v.3 no.2 s.10
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    • pp.60-67
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    • 2007
  • This paper describes the design and integration of the wind-fuel cell hybrid system. The hybrid system components included a wind turbine, an electrolyzer (for generation of H2), a PEMFC (Proton Exchange Membrane Fuel Cell), hydrogen storage tank and BOP (Balance of Plant) system. The energy input is entirely provided by a wind turbine. A DC-DC converter controls the power input to the electrolyzer, which produces hydrogen and oxygen form water. The hydrogen used the fuel for the PEMFC. Hydrogen may be produced and stored in high pressure tank by hydrogen gas booster system. Wind conditions are changing with time of day, season and year. So, wind power is a variable energy source. The main purpose with these WT-FC hybrid system is to store hydrogen by electrolysis of water when wind conditions are good and release the stored hydrog en to supply the fuelcell when wind is low.

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Numerical Study on the Effects of Gravity Direction and Hydrogen Filling Rate on BOG in the Liquefied Hydrogen Storage Tank (액체수소 저장 탱크의 중력 방향 및 수소 충전율이 BOG에 미치는 영향에 관한 수치적 연구)

  • YOUNG MIN SEO;HYUN WOO NOH;DONG WOO HA;TAE HYUNG KOO;ROCK KIL KO
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.4
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    • pp.342-349
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    • 2023
  • In this study, a numerical simulations were conducted to analyze the phase change behavior of a liquid hydrogen storage container. The effects of gravity direction and hydrogen filling rate on boil-off gas (BOG) in the storage container were investigated. The study employed the volume of fluid, which is the phase change analysis model provided by ANSYS Fluent (ANSYS, Canonsburg, PA, USA), to investigate the sloshing phenomenon inside the liquefied hydrogen fuel tank. Considering the transient analysis time, two-dimensional simulation were carried out to examine the characteristics of the flow and thermal fields. The results indicated that the thermal flow characteristics and BOG phenomena inside the two-dimensional liquefied hydrogen storage container were significantly influenced by changes in gravity direction and hydrogen filling rate.

Adiabatic Performance of Layered Insulating Materials for Bulk LH2 Storage Tanks (대용량 액체 수소 저장탱크를 위한 다층단열재의 단열성능 분석)

  • KIM, KYEONGHO;SHIN, DONGHWAN;KIM, YONGCHAN;KARNG, SARNG WOO
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.6
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    • pp.642-650
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    • 2016
  • One of the most feasible solution for reducing the excessive energy consumption and carbon dioxide emission is usage of more efficient fuel such as hydrogen. As is well known, there are three viable technologies for storing hydrogen fuel: compressed gas, metal hydride absorption, and cryogenic liquid. In these technologies, the storage for liquid hydrogen has better energy density by weight than other storage methods. However, the cryogenic liquid storage has a significant disadvantage of boiling losses. That is, high performance of thermal insulation systems must be studied for reducing the boiling losses. This paper presents an experimental study on the effective thermal conductivities of the composite layered insulation with aerogel blankets($Cryogel^{(R)}$ Z and $Pyrogel^{(R)}$ XT-E) and Multi-layer insulation(MLI). The aerogel blankets are known as high porous materials and the good insulators within a soft vacuum range($10^{-3}{\sim}1$ Torr). Also, MLI is known as the best insulator within a high vacuum range(<$10^{-6}{\sim}10^{-3}$ Torr). A vertical axial cryogenic experimental apparatus was designed to investigate the thermal performance of the composite layered insulators under cryogenic conditions as well as consist of a cold mass tank, a heat absorber, annular vacuum space, and an insulators space. The composite insulators were laminated in the insulator space that height was 50 mm. In this study, the effective thermal conductivities of the materials were evaluated by measuring boil-off rate of liquid nitrogen and liquid argon in the cold mass tank.

Performance Analysis of a Gas Turbine for Power Generation Using Syngas as a Fuel (Syngas를 연료로 사용하는 발전용 가스터빈의 성능해석)

  • Lee, Jong-Jun;Cha, Kyu-Sang;Sohn, Jeong-Lak;Joo, Yong-Jin;Kim, Tong-Seop
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.1
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    • pp.54-61
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    • 2008
  • Integrated Gasification Combined Cycle (IGCC) power plant converts coal to syngas, which is mainly composed of hydrogen and carbon monoxide, by the gasification process and produces electric power by the gas and steam turbine combined cycle power plant. The purpose of this study is to investigate the influence of using syngas in a gas turbine, originally designed for natural gas fuel, on its performance. A commercial gas turbine is selected and variations of its performance characteristics due to adopting syngas is analyzed by simulating off-design gas turbine operation. Since the heating value of the syngas is lower, compared to natural gas, IGCC plants require much larger fuel flow rate. This increases the gas flow rate to the turbine and the pressure ratio, leading to far larger power output and higher thermal efficiency. Examination of using two different syngases reveals that the gas turbine performance varies much with the fuel composition.

Design and Self-sustainable Operation of 1 kW SOFC System (1kW 고체산화물 연료전지(SOFC) 시스템 설계 및 자열운전)

  • Lee, Tae-Hee;Choi, Jin-Hyeok;Park, Tae-Sung;Yoo, Young-Sung;Nam, Suk-Woo
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.5
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    • pp.384-389
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    • 2009
  • KEPRI (Korea Electric Power Research Institute) has studied planar type solid oxide fuel cell (SOFC) stacks using anode-supported cells and kW class co-generation systems for residential power generation. In this work, a 1 kW SOFC system consisted of a hot box part, a cold BOP (balance of plant) part, and a hot water reservoir. The hot box part contained a SOFC stack made up of 48 cells, a fuel reformer, a catalytic combustor, and heat exchangers. Thermal management and insulation system were especially designed for self-sustainable operation in that system. A cold BOP part was composed of blowers, pumps, a water trap, and system control units. When the 1 kW SOFC stack was tested using hydrogen at $750^{\circ}C$, the stack power was about $1.2\;kW_e$ at 30 A and $1.6\;kW_e$ at 50 A. Turning off an electric furnace, the SOFC system was operated using hydrogen and city gas without any external heat source. Under self-sustainable operation conditions, the stack power was about $1.3\;kW_e$ with hydrogen and $1.2\;kW_e$ with city gas respectively. The system also recuperated heat of about $1.1\;kW_{th}$ by making hot water.

Numerical Analysis of Steam-methane Reforming Reaction for Hydrogen Generation using Catalytic Combustion (촉매 연소를 열원으로 한 수증기-메탄개질반응 전산유체해석)

  • Lee, Jeongseop;Lee, Kanghoon;Yu, Sangseok;Ahn, Kookyoung;Kang, Sanggyu
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.2
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    • pp.113-120
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    • 2013
  • A steam reformer is a chemical reactor to produce high purity hydrogen from fossil fuel. In the steam reformer, since endothermic steam reforming is heated by exothermic combustion of fossil fuel, the heat transfer between two reaction zones dominates conversion of fossil fuel to hydrogen. Steam Reforming is complex chemical reaction, mass and heat transfer due to the exothermic methane/air combustion reaction and the endothermic steam reforming reaction. Typically, a steam reformer employs burner to supply appropriate heat for endothermic steam reforming reaction which reduces system efficiency. In this study, the heat of steam reforming reaction is provided by anode-off gas combustion of stationary fuel cell. This paper presents a optimization of heat transfer effect and average temperature of cross-section using two-dimensional models of a coaxial cylindrical reactor, and analysis three-dimensional models of a coaxial cylindrical steam reformer with chemical reaction. Numerical analysis needs to dominant chemical reaction that are assumed as a Steam Reforming (SR) reaction, a Water-Gas Shift (WGS) reaction, and a Direct Steam Reforming(DSR) reaction. The major parameters of analysis are temperature, fuel conversion and heat flux in the coaxial reactor.

The Ejector Design and Test for 5kW Molten Carbonate Fuel Cell (75kW 용융탄산염 연료전지 시스템의 MBOP 개발)

  • Kim, Beom-Joo;Kim, Do-Hyung;Lee, Jung-Hyun;Kang, Seung-Won;Lim, Hee-Chun
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.353-356
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    • 2009
  • A pivotal mechanical balance of plant for 75kW class molten carbonate fuel cells comprise of a catalytic burner and an ejector which has been designed and tested in KEPRI(Korea Electric Power Research Institute). The catalytic burner, which oxidizes residual fuel in the anode tail gas, was operated at several conditions. Some problems arose due to local overheating or auto-ignition, which could limit the catalyst life. The catalytic burner was designed by considering both gas mixing and gas velocity. Test results showed that the temperature distribution is very uniform. In addition, an ejector is a fluid machinery to be utilized for mixing fluids, maintaining vacuum, and transporting them. The ejector is placed at mixing point between the anode off gas and the cathode off gas or the fresh air Several ejectors were designed and tested to form a suction on the fuel tail gas and balance the differential pressures between anode and cathode over a range of operating conditions. The tests showed that the design of the nozzle and throat played an important role in balancing the anode tail and cathode inlet gas pressures. The 75kW MCFC system built in our ejector and catalytic burner was successfully operated from Novembe, 2008 to April, 2009. It recorded the voltage of 104V at the current of 754A and reached the maximum generating power of 78.5kW DC. The results for both stand-alone and integration into another balance of plant are discussed.

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A Study on Temperature Characteristics of Automatic Valve for High Pressure Cylinder of FCV (수소연료전지 자동차 압력 용기용 전자밸브의 온도 특성에 관한 연구)

  • Lee, Hyo-Ryeol;Ahn, Jung-Hwan;Kim, Hwa-Young;Kim, Young-Gu
    • Journal of the Korean Institute of Gas
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    • v.22 no.1
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    • pp.1-8
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    • 2018
  • FCV is installed with a automatic valve attached in an high pressure cylinder to control the hydrogen flow. The supply of hydrogen from the cylinder into the fuel cell stack is controlled via the on/off operation of a solenoid attached to the automatic valve. The solenoid needs to provide the necessary attraction force even at any saturation temperature caused by drive of the vehicle. In this study, the simplified prediction equations for the saturation temperature are suggested. The finite element analysis was performed by steady state technique, according to the boundary condition in order to predict the saturation temperature and attraction force. Finally, the saturation temperature was validated through comparison between the analysis results and measurement results. From the results, the measured saturation temperature $5.9^{\circ}C$ lower with respect to the analysis results. And the error of attraction force ranged from 1.0 to 2.1 N at testing conditions.

Technical Analysis and Future Development of Liquefied Hydrogen Carriers (액화수소 산적 운반선의 기술성 분석 및 향후 개발 과제)

  • Lee, Hyunyong;Kang, Hokeun;Roh, Gilltae;Jung, Inchul
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.28 no.2
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    • pp.361-369
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    • 2022
  • Countries worldwide are shifting to a hydrogen economy to respond to stringent environmental regulations, and the transport of hydrogen between countries is expected to increase in the mid- to long-term. Hydrogen is traded between countries in different forms, such as ammonia, liquid hydrogen, and LOHC (Liquid Organic Hydrogen Carrier), on account of the renewable energy resources in exporting countries, the type of hydrogen use in importing countries, and the technological maturity; however, it is not traded only in a singular form. As marine transportation of ammonia and LOHC is a relatively mature technology compared to that of liquid hydrogen, in this article, we analyzed the technical feasibility of liquid hydrogen carriers while identifying detailed technologies required for their future development and securing possible designs through various technical alternatives.

Process Simulation of LH2 Receiving Terminal with Membrane Storage Tank and Prediction of BOG Generation According to Change of Design Conditions (LH2 멤브레인 저장탱크 인수기지 공정모사 및 설계조건 변화에 따른 BOG 발생량 예측)

  • Kim, Donghyuk;Lee, Yeongbeom;Seo, Heungseok;Kwon, Yongsoo;Park, Changwon;Kwon, Hweeung
    • Journal of the Korean Institute of Gas
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    • v.26 no.5
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    • pp.49-57
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    • 2022
  • If the hydrogen industry is activated in the future, the LH2 receiving terminal with membrane storage tank is a major way to store and send large capacity hydrogen. Since such a LH2 receiving terminal does not currently exist, the process simulation model of it was completed by referring to the design data on existing LNG receiving terminal with same typed storage tank. Based on this model, the amount of BOG generation according to change of design conditions, which is a very important factor in the operation of LH2 receiving terminal, was predicted. Through this, it was attempted to review the appropriate operating conditions to minimize the amount of BOG generated during unloading in LH2 receiving terminal with membrane storage tank.