• Title/Summary/Keyword: off gas hydrogen

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Development of WT-FC Hybrid System for Off-Grid (오프그리드용 풍력-연료전지 하이브리드 시스템 개발)

  • Choi, Jong-Pil;Park, Nae-Chun;Kim, Sang-Hun;Kim, Byeong-Hee;Nam, Yun-Su;Yu, Neung-Su
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.383-386
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    • 2007
  • This paper describes the design and integration of the wind- fuel cell hybrid system. The hybrid system components included a wind turbine, an electrolyzer (for generation of H2), a PEMFC (Proton Exchange Membrane Fuel Cell), storage system and BOP (Balance of Plant) system. The energy input is entirely provided by a wind turbine. A DC-DC converter controls the power input to the electrolyzer, which produces hydrogen and oxygen form water. The hydrogen used the fuel for the PEMFC. The hydrogen is compressed and stored in high pressure tank by hydrogen gas booster system.

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Experimental Study on the Flame Behavior and the NOx Emission Characteristics of Low Calorific Value Gas Fuel (저 발열량 가스 연료의 화염거동 및 NOx 발생 특성에 관한 실험적 연구)

  • Kim, Yong-Chul;Lee, Chan
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.05a
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    • pp.89-93
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    • 1999
  • Experimental studies are conducted to investigate the flame stability and the thermal/fuel NOx formation characteristics of the low calorific value(LCV) gas fuel. Synthetic LCV fuel gas is produced through mixing carbon monoxide, hydrogen, nitrogen and ammonia on the basis that the thermal input of the syngas fuel into a burner is identical to that of natural gas, and then the syngas mixture is fed to and burnt with air on flat flame burner. Flame behaviors are observed to identify flame instability due to blow-off or flash-back when burning the LCV fuel gas at various equivalence ratio conditions. Measurements of NOx in combustion gas are made for comparing thermal and fuel NOx emissions from the LCV syngas combustion with those of the natural gas one, and for analyzing ammonia to NOx conversion mechanism. In addition, the nitrogen dilution of the LCV syngas is preliminarily attempted as a NOx reduction technique.

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HORIZON EXPANSION OF THERMAL-HYDRAULIC ACTIVITIES INTO HTGR SAFETY ANALYSIS INCLUDING GAS-TURBINE CYCLE AND HYDROGEN PLANT

  • No, Hee-Cheon;Yoon, Ho-Joon;Kim, Seung-Jun;Lee, Byeng-Jin;Kim, Ji-Hwang;Kim, Hyeun-Min;Lim, Hong-Sik
    • Nuclear Engineering and Technology
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    • v.41 no.7
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    • pp.875-884
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    • 2009
  • We present three nuclear/hydrogen-related R&D activities being performed at KAIST: air-ingressed LOCA analysis code development, gas turbine analysis tool development, and hydrogen-production system analysis model development. The ICE numerical technique widely used for the safety analysis of water-reactors is successfully implemented into GAMMA, with which we solve the basic equations for continuity, momentum conservation, energy conservation of the gas mixture, and mass conservation of 6 species (He, N2, O2, CO, CO2, and H2O). GAMMA has been extensively validated using data from 14 test facilities. We developed a tool to predict the characteristics of HTGR helium turbines based on the throughflow calculation with a Newton-Raphson method that overcomes the weakness of the conventional method based on the successive iteration scheme. It is found that the current method reaches stable and quick convergence even under the off-normal condition with the same degree of accuracy. The dynamic equations for the distillation column of HI process are described with 4 material components involved in the HI process: H2O, HI, I2, H2. For the HI process we improved the Neumann model based on the NRTL (Non-Random Two-Liquid) model. The improved Neumann model predicted a total pressure with 8.6% maximum relative deviation from the data and 2.5% mean relative deviation, and liquid-liquid-separation with 9.52% maximum relative deviation from the data.

An Experimental Study on Variations of Exhaust Gas Temperature and Concentration with Synthetic Gas Combustion in Exhaust Manifold (배기관에서의 합성가스 연소에 따른 배기가스 온도 및 농도 변화에 관한 실험적 연구)

  • Cho, Yong-Seok;Lee, Seang-Wock;Yang, Seung-Il;Song, Chun-Sub;Park, Young-Joon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.4
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    • pp.56-62
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    • 2008
  • A synthetic gas reformed from hydrocarbon-based fuels consists of $H_2$, CO and $N_2$. Hydrogen contained in the synthetic gas is a very useful species in chemical processes, due to its wide flammability range and fast burning speed. The ESGI (Exhaust Synthetic Gas Injection) technology is developed to shorten the light-off time of three way catalysts through combustion of the synthetic gas in the exhaust manifold during the cold start period of SI engines. Before the ESGI technology is applied to the test engine, the authors set a test rig that consists of gas temperature and composition controllers, an exhaust pulse generator and an exhaust manifold with a visualization window, in order to optimize the point and conditions of injection of the synthetic gas. Through measuring burned gas temperatures and taking photographs of synthetic gas combustion at the outlet of the exhaust manifold, the authors tried to find the optimal injection point and conditions. Analysis of burned gas composition has been performed for various $O_2$ concentrations. As a result, when the synthetic gas is injected at the port outlet of the cylinder No. 4 and $O_2$ concentration exceeds 4%, combustion of the synthetic gas is strong and effective in the exhaust manifold.

Economic Feasibility Study for Commercial Production of Bio-hydrogen (해양바이오수소개발 사업의 상업생산을 위한 예비경제성평가)

  • Park, Se-Hun;Yoo, Young-Don;Kang, Sung Gyun
    • Ocean and Polar Research
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    • v.38 no.3
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    • pp.225-234
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    • 2016
  • This project sought to conduct an economic feasibility study regarding the commercial production of bio-hydrogen by the marine hyperthermophilic archaeon, Thermococcus onnurineus NA1 using carbon monoxide-containing industrial off-gas. We carried out the economic evaluation of the bio-hydrogen production process using the raw material of steel mill by-product gas. The process parameter was as follows: $H_2$ production rate was 5.6 L/L/h; the conversion of carbon monoxide was 60.7%. This project established an evaluation criterion for about 10,000 tonne/year. Inflation factors were considered as 3%. The operating costs were recalculated based on prices in 2014. The total investment required for development was covered 30% by capital and 70% by a loan. The operation cost for the 0.5-year test and integration, and the cost for the first three months in the 50% production period were considered as the working capital in the cost estimation. The costs required for the rental of office space, facilities, and other related costs from the construction through to full-scale production periods were considered as continuing expenses. Materials, energy, waste disposal and other charges were considered as the operating cost of the development system. Depreciation, tax, maintenance and repair, insurance, labor, interest rate charges, general and administrative costs, lubrication and miscellaneous expenses were also calculated. The hydrogen price was set at US$ 4.15/kg for the economic evaluation. As a result, the process was considered to be economical with the payback period of 6.3 years, NPV of 18 billion Won and IRR of 26.7%.

An Experimental Study on Heat Transfer Characteristics of Synthetic Gas($H_2/CO$)Air Premixed Flames in an Impinging Jet Burner - Part 1 : Stretched Lift-off Flames (충돌제트 버너에서 합성가스($H_2/CO$) 공기 예혼합 화염의 열전달 특성에 관한 실험적 연구 - Part 1 : 스트레치된 부상 화염)

  • Kang, Ki-Joong;Jo, Joon-Ik;Lee, Kee-Man
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.04a
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    • pp.453-456
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    • 2011
  • An experimental investigation of the heat transfer characteristics of stretched premixed flames using Synthetic gas has been performed. Hydrogen and carbon mon-oxide which could be extracted from coal gasification process are the main fuel of synthetic-gas. Heat flux at the stagnation point was increased as global strainrate was increased, then the heat flux was decreased when a global strainrate reached a sudden point. Heat flux at the stagnation point is also affected by nozzle to impingement distance. Heat flux was increased as nozzle to impingement place distance was increased. This study is a foundation study of practical use of secondary gases from coals.

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Optimization of SnO2 Based H2 Gas Sensor Along with Thermal Treatment Effect (열처리 효과에 따른 SnO2 기반 수소가스 센서의 특성 최적화)

  • Jung, Dong Geon;Lee, Junyeop;Kwon, Jinbeom;Maeng, Bohee;Kim, Young Sam;Yang, Yi Jun;Jung, Daewoong
    • Journal of Sensor Science and Technology
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    • v.31 no.5
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    • pp.348-352
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    • 2022
  • Hydrogen gas (H2) which is odorless, colorless is attracting attention as a renewable energy source in varions applications but its leakage can lead to disastrous disasters, such as inflammable, explosive, and narcotic disasters at high concentrations. Therefore, it is necessary to develop H2 gas sensor with high performance. In this paper, we confirmed that H2 gas detection ability of SnO2 based H2 gas sensor along with thermal treatment effect of SnO2. Proposed SnO2 based H2 gas sensor is fabricated by MEMS technologies such as photolithgraphy, sputtering and lift-off process, etc. Deposited SnO2 thin films are thermally treated in various thermal treatement temperature in range of 500-900 ℃ and their H2 gas detection ability is estimatied by measuring output current of H2 gas sensor. Based on experimental results, fabricated H2 gas sensor with SnO2 thin film which is thermally treated at 700 ℃ has a superior H2 gas detection ability, and it can be expected to utilize at the practical applications.

Design of BOG re-liquefaction system of 20,000 m3 liquid hydrogen carrier

  • Byeongchang Byeon;Hwalong You;Dongmin Kim;Keun Tae Lee;Mo Se Kim;Gi Dock Kim;Jung Hun Kim;Sang Yoon Lee;Deuk Yong Koh
    • Progress in Superconductivity and Cryogenics
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    • v.25 no.3
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    • pp.49-55
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    • 2023
  • This paper presents the design of a re-liquefaction system as a BOG (boil-off gas) handling process in liquid hydrogen transport vessels. The total capacity of the re-liquefaction system was assumed to be 3 ton/day, with a BOR (boil-off rate) of 0.2 %/day inside the cargo. The re-liquefaction cycle was devised using the He-Brayton Cycle, incorporating considerations of BOG capacity and operational stability. The primary components of the system, such as compressors, expanders, and heat exchangers, were selected to meet domestically available specifications. Case studies were conducted based on the specifications of the components to determine the optimal design parameters for the re-liquefaction system. This encompassed variables such as helium mass flow rate, the number of compressors, compressor inlet pressure and compression ratio, as well as the quantity and composition of expanders. Additionally, an analysis of exergy destruction and exergy efficiency was carried out for the components within the system. Remarkably, while previous design studies of BOG re-liquefaction systems for liquid hydrogen vessels were confined to theoretical and analytical realms, this research distinguishes itself by accounting for practical implementation through equipment and system design.

Self-sustainable Operation of a 1kW class SOFC System (1kW급 고체산화물 연료전지 발전시스템 자열운전)

  • Lee, Tae-Hee;Choi, Jin-Hyeok;Park, Tae-Sung;Yoo, Young-Sung
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.57-60
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    • 2008
  • KEPRI has studied planar type SOFC stacks using anode-supported single cells and kW class co-generation systems for residential power generation. A 1kW class SOFC system consisted of a hot box part, a cold BOP part and a water reservoir. A hot box part contains a SOFC stack made up of 48 single cells and ferritic stainless steel interconnectors, a fuel reformer, a catalytic combustor and heat exchangers. Thermal management and insulation system were especially designed for self-sustainable operation. A cold BOP part was composed of blowers, pumps, a water trap and system control units. When a 1kW class SOFC system was operated at $750^{\circ}C$ with hydrogen after pre-treatment process, the stack power was 1.2kW at 30 A and 1.6kW at 50A. Turning off an electric furnace, the SOFC system was operated using hydrogen and city gas without any external heat source. Under self-sustainable operation conditions, the stack power was about 1.3kW with hydrogen and 1.2kW with city gas respectively. The system also recuperated heat of about 1.1kW by making hot water.

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Off-design Performance Characteristics of SOFC-GT Hybrid System Operating with Syngas Fuel (합성가스를 연료로 사용하는 고체산화물연료전지-가스터빈 하이브리드 시스템의 탈설계점 성능 특성)

  • Choi, Jung-Il;Sohn, Jeong-Lak;Song, Seung-Jin;Kim, Tong-Seop
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.3
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    • pp.269-274
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    • 2010
  • As a preliminary study on a SOFC-GT hybrid system integrated a with coal-gasification system, the influence of the concentrations of $H_2$ and CO in syngas on the performance characteristics of the hybrid system is investigated. It is expected that the differences in the heating values of fuels with different compositions trigger the off-design operation of the gas turbine and result in different performance characteristics of the overall hybrid system. Syngas compositions are found to affect the SOFC performance. Performance of hybrid system with carbon monoxide is poorer than the case with hydrogen. In the case of part-load performance with syngas, performance degradation at part-load operating conditions with hydrogen is more dominant than the case with carbon monoxide.