• Title/Summary/Keyword: nylon6

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Effects of the Polyurethane Contents and Blend Time on the Crystalline Structure and Mechanical Properties of Nylon 6/PU Blend (폴리우레탄 함량과 블렌드 시간이 Nylon 6/pu 블렌드의 결정구조 및 기계적 특성에 미치는 영향)

  • 윤철수;지동선
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.474-477
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    • 2002
  • 열가소성 폴리우레탄(PU)은 우수한 탄성을 갖는 유용한 고분자중의 하나로 섬유나 플라스틱에 널리 사용되고 있다. PU는 상온보다 높은 유리전이 온도(T$_{g}$)를 갖는 유리상의 hard segment와 상온보다 낮은 유리전이 온도(T$_{g}$)를 갖는 고무상의 soft segment로 구성되어 있으며 열역학적으론 비상용성으로 인하여 미세 상분리 구조를 가지게 되어 고무보다 높은 탄성률과 우수한 인장 회복거동을 갖게 된다[1-3]. (중략)

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Effect of Washing and Subsequent Heat Treatment on Water Repellency and Mechanical Properties of Nylon 6, Triacetate and Silk Fabrics Treated with Hydrocarbon Resins

  • Park, Hyei-Ran;Lee, Mun-Cheul;Nishi, Kenji;Wakida, Tomiji
    • Textile Coloration and Finishing
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    • v.20 no.6
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    • pp.87-91
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    • 2008
  • It is commonly known that water repellency of the fabric treated with fluorocarbon resin brings about a decrease by the washing and recovers by the subsequent heat treatment. In this article, effect of the water repellency was investigated on the nylon 6, triacetate and silk fabrics treated with hydrocarbon and silicon resins. Hydrocarbon and silicon resins have been widely used in the textile finishing as the softening and water proofing agents. The fabrics were treated with hydrocarbon resins, Paragium JQ and RC (Ohara Paragium Chemical Co.) and a silicon resin, Poron MR (Shinetsu Chemical Co.), and then washed and subsequently heat treated. Although the water repellency increased by the resin treatment, it decreased by the washing apparently and recovered a little by the heat treatment. The effect of the heat treatment was small comparing with that of the fluorocarbon resin. Furthermore, as a mechanical property of the treated fabric, KES shearing and bending hysteresis parameters, modulus and hysteresis width of the hydrocarbon resin-treated nylon 6, triacetate and silk fabrics decreased by the heat treatment after washing. Therefore, the treatment is effective at improving the softening of the fabric in water repellent finish.

STUDIES ON PROTEIN DEGRADABILITIES OF FEEDSTUFFS IN BANGLADESH

  • Khandaker, Z.H.;Tareque, A.M.M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.9 no.6
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    • pp.637-642
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    • 1996
  • This experiment was conducted to determine RDP values of locally available feedstuffs that are commonly used in ruminant rations in Bangladesh. Four cattle were fistulated in the rumen for the in situ nylon bag studies. Seventeen different feedstuff sample (9 roughages and 8 concentrates) were evaluated in $4{\times}14cm$ nylon bags and incubated in the rumen for different periods of time (2, 6, 12, 24, 48 and 72 h). The variation in crude protein (CP) contents reflected on the average CP disappearance value throughout the rumen incubation. Soluble fraction (a), insoluble but degradable fraction (b) along with the rate of degradation also varied widely among the various feedstuffs. Under 2% of rumen outflow rate, the percentages of the calculated protein degradabilities of roughages were rice straw, 16.7; maize grass, 70.6; oat grass, 70.8; dhal grass, 71.1; sunhemp, 78.4; napier grass, 62.4; matikalai grass, 72.1; khesarikalai grass, 76.9 and daincha browse, 78.4, respectively. The results in the protein degradabilities (%) in 8% ruminal outflow rate of concentrates were wheat bran, 61.6; rice polish (red), 61.3; rice polish (auto), 30.9; mustard oil cake, 71.8; sesame oil cake, 74.2; coconut oil cake, 57.9; soybean meal, 49.2 and fish meal, 37.9, respectively.

A Study on the Fine Sturcture of Nylon 6 Films by Crysallization under Pressure (Nylon 6 Film의 압력결정화에 의한 미세구조 변화)

  • Park, Myung Soo;Lee, Chul Soo;Gu, Ja Gil
    • Textile Coloration and Finishing
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    • v.8 no.6
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    • pp.1-8
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    • 1996
  • The crystal structures of Nylon 6 films with the changes of pressure, temperature, and the processing time were examined. The accompanying physical property changes such as the weight fraction, the crystallinity, the crystal size, the initial modulus, and the thermal properties, gives the following results. When the sample is processed at 16$0^{\circ}C$, the weight fraction is not changed significantly with varying pressure. However, at 18$0^{\circ}C$ a significant change of the weight fraction was found with increasing pressure above 5 ton/in$^{2}$ so as to increase the crysallinity. As long as the ct transition is concerned we found that it begins from 14$0^{\circ}C$ and is completed at 18$0^{\circ}C$ and 9 ton/$in^{2}$ of pressure with the processing time of 120 min. The increase of the initial modulus is believed to be due to the increase of the number of the tie chains and the tension resulting from the change of the crystal size in the direction perpendicular to the direction of the applied pressure. The meltiong point change is due to the pressurized crystallization was not observed.

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Physical Properties of Graphite Nanofiber Filled Nylon6 Composites

  • Park, Eun-Ha;Joo, Hyeok-Jong
    • Carbon letters
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    • v.7 no.2
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    • pp.87-96
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    • 2006
  • This paper describes the physical properties of filled Nylon6 composites resin with nano-sized carbon black particle and graphite nanofibers prepared by melt extrusion method. In improving adhesions between resin and fillers, the surface of the carbon filler materials were chemically modified by thermo-oxidative treatments and followed by treatments of silane coupling agent. Crystallization temperature and rate of crystallization increased with increases in filler concentration which would act as nuclei for crystallization. The silane treatments on the filler materials showed effect of reduction in crystallization temperature, possibly from enhancement in wetting property of the surface of the filler materials. Percolation transition phenomenon at which the volume resistivity was sharply decreased was observed above 9 wt% of carbon black and above 6 wt% of graphite nanofiber. The graphite nanofibers contributed to more effectively in an increase in electrical conductivity than carbon black did, on the other hand, the silane coupling agent negatively affected to the electrical conductivity due to the insulating property of the silane. Positive temperature coefficient (PTC) phenomenon, was observed as usual in other composites, that is, temperature increase results conductivity increase. The dispersity of the fillers were excellently approached by melt extrusion of co-rotational twin screw type and it could be illustrated by X-ray diffraction and SEM.

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Easy and Fast Stitch out Method with a Traction Nylon in Pediatric Sutured Wound (당김줄을 이용한 소아 열상 환부의 쉽고 빠른 발사 방법)

  • Lee, Yoon-Jung;Lee, Kyung-Suk;Kim, Jun-Sik;Kim, Nam-Gyun
    • Archives of Plastic Surgery
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    • v.37 no.2
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    • pp.199-201
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    • 2010
  • Purpose: Except for continuous suture in skin layer, stitching out in facial laceration, we have to hold each knots up and cut the knots by No. 11 blade or small scissors. However, we often have difficulty in stitching out the knots on children who do not cooperate well. Therefore we introduce an easy and fast stitch out method of pediatric lacerations. Methods: From January to May 2009, we studied 15 pediatric patients (mean age 5.6 years old) who had facial laceration on face or underwent any surgery on operation room. For easy stitch out, we left the one string of the first knot long enough to extend at the opposite end of laceration site. And then the extended string was fixed to skin using Steri-strip. Next we do simple interrupted suture including the extended traction nylon string inside the knot. Through this method, we can stitch out all knots simply by lifting up the traction nylon needless to hold the each knot one by one. Results: Until stitching out, the traction nylon was just right position and there was no normal tissue injury during stitch out all knots. Patients were satisfied with the short stitch out time. Conclusion: By using the traction nylon on pediatric laceration suture, we can stitch out all the knots with no normal tissue injury in less time.

Temperature and Frequency Dependences of Ultrasonic Properties in Commercial MC Nylon Polymers (상용 MC Nylon계 고분자 재료에서 초음파 특성의 온도 및 주파수 의존성)

  • Kim, Myung Deok;Kim, Yong Tae;Lee, Kang Il
    • Journal of the Korean Society for Nondestructive Testing
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    • v.32 no.5
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    • pp.509-517
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    • 2012
  • In the present study, temperature and frequency dependences of ultrasonic properties such as attenuation coefficient and phase velocity was investigated for six kinds of commercial MC-Nylon polymer samples. The ultrasonic properties of the samples were measured by using a pulse transmission method in water over a broadband frequency range of 2 to 8 MHz. Water temperature was varied from 10 to $60^{\circ}C$ with the $10^{\circ}C$ interval. The attenuation coefficients of the samples increased with the frequency and the exponent n of frequency dependence ranged within 1.16 to 1.44, slightly deviating from the linear dependence (n=1). The phase velocities of the samples exhibited negative dispersion, i.e., decreasing velocity with increasing frequency, except for ivory sample at $60^{\circ}C$. The frequency-dependent phase velocities of the samples showed the decreasing tendency with increasing temperature.

A New Analytical Method for the $Eu^{+3}$ and $Tb^{+3}$ Ions Using the Luminescence Enhancement by the Treatment of o-Phenanthroline on the Nylon Membrane (Nylon Membrane Filter에서의 발광증폭을 이용한 $Eu^{+3}$$Tb^{+3}$ 이온의 극미량 분석법)

  • An, Seong-Hee;Lee, Byung-Min;Park, Jong-Mok;Kim, Hai-Dong;Jeong, Hyuk
    • Journal of the Korean Chemical Society
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    • v.39 no.9
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    • pp.705-714
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    • 1995
  • A new analytical luminescence method for the Eu+3 and Tb+3 ions was studied using the luminescence enhancement by the treatment of the o-phenanthroline on the nylon membrane. Compared to the specific emission intensities of the ions in aqueous(or ethanol) solution, if the aqueous ion is spotted on the nylon membrane, the luminescence intensities were extremely enhanced. There was additional enhancement effect of the luminescence intensities of the ions on the nylon membrane, if the ion on the nylon membrane is treated with o-phenanthroline. Based on the luminescence enhancement, the detection limits were lowered by more than 7 order of magnitude compared to that of solution sample, and also lowered by about 1 order of magnitude compared to that of previous TLC method. The dynamic ranges and correlation coefficients of the calibration curves near the detection limit were 2∼3 order and ∼0.99, respectively. It was also shown that the luminescence intensity was in its maximum when the ion on the nylon is treated with ∼4 mole ratio of o-phenanthroline. The energy-transfer mechanism was explained for the theoretical background of the luminescence enhancement.

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