• Title/Summary/Keyword: nylon 46/6

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Crystallization of Poly(1,4-diaminobutane-co-adipic acid-co-ε-caprolactam-co-diethylenetriamine) Copolymer Fiber (Poly(1,4-diaminobutane-co-adipic acid-co-ε-caprolactam-co-diethylenetriamine) 공중합체 섬유의 결정거동)

  • Jo, Kuk Hyun;Song, Jihyeon;Cho, Hyun-Hok;Jang, Soon-Ho;Lee, Hyun Hwi;Kim, Nam Cheol;Kim, Hyo Jung
    • Textile Coloration and Finishing
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    • v.28 no.4
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    • pp.231-238
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    • 2016
  • We investigated the evolution of crystal formation as a function of drawing ratio in poly(1,4-diaminobutane-co-adipic acid-co-${\varepsilon}$-caprolactam-co-diethylenetriamine)(nylon 466T) copolymer formed by four monomers, i.e 1,4-diaminobutane, adipic acid, ${\varepsilon}$-caprolactam, diethylenetriamine(DETA), using synchrotron X-ray scattering measurement. In case of pristine(as spun) nylon 466T fiber, it was consisted with unoriented nylon $6{\alpha}$ and unoriented nylon $46{\alpha}$ phases. As increase the drawing ratio, unoriented nylon $6{\alpha}$ was transformed to oriented ${\gamma}$ phase, while unoriented nylon $46{\alpha}$ changed to oriented $46{\alpha}$ phase. The effect of the addition of DETA was not observed in the pristine fibers. However, DETA affected to restrict the formation of crystals at the maximum drawing condition, and as a result it had a role to increase the moisture regain.

Electrical Properties and Electromagnetic Shielding Effectiveness of Milled Carbon Fiber/Nylon Composites (분쇄형 탄소 섬유/나일론 복합재료의 전기적 성질과 전자파 차폐 효율)

  • 김창제;최형도;서광석;윤호규
    • Polymer(Korea)
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    • v.27 no.3
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    • pp.201-209
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    • 2003
  • DC and AC electrical conductivity and electromagnetic interference shielding effectiveness of milled carbon fiber/nylon composites were investigated with the kind of nylon matrix. Percolation transition at which the conductivity is sharply increased was observed at about 7 vol% of milled carbon fiber. Nylon 46 as a matrix was more effective to obtain high electrical conductivity than nylon 6, and the difference in conductivity was occurred by the treatment of coupling agent. Frequency dependence of AC conductivity could be explained by relaxation phenomenon at just below percolation and resonance phenomenon at 40 vol% of carbon fiber, respectively. Negative temperature coefficient phenomenon was found in all composites. Electromagnetic interference shielding effectiveness was increased with the concentration of carbon fiber. At a high conductivity region the return loss was more dominant to the total shielding effectiveness than the absorption loss.

Investigation of Surface Morphology for Nylon 4,6 Thin Film by Molecular Layer Deposition

  • Gwon, Deok-Hyeon;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.419-419
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    • 2012
  • We fabricated the Polyamide 4,6 (PA46) thin film using Adipoyl chloride and 1,4-butadiamine. PA46 film was grown at $70^{\circ}C$ by Molecular Layer Deposition (MLD) method. MLD is sequential and self-terminating fabrication method for organic thin film. The growth rate of PA46 is $3.5{\acute{\AA}}$ cycle. The thickness of PA46 film was measured by Ellipsometer. Surface morphology of this film was investigated by Atomic Force Microscopy (AFM) and roughness is directly proportional to number of growing cycles.

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Functional Verification of Nylon Wire Cutting-Type Holding & Release Mechanism for 6U CubeSat's Solar Panel (나일론선 절단방식 6U 큐브위성용 태양전지판 구속분리장치의 기능검증)

  • Park, Yeon-Hyeok;Go, Ji-Seong;Chae, Bong-Geon;Lee, Seong-Ho;Oh, Hyun-Ung
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.46 no.10
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    • pp.867-875
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    • 2018
  • Conventional nylon wire cutting-type holding and release mechanisms (HRMs) are limited to securely hold the solar panel under launch environment as the size of the panel increases because the nylon wire is tightened directly on the surface of the solar panel. In this study, we proposed a nylon wire cutting-type HRM for 6U CubeSat's solar panel applying elliptic-shaped bracket with a Ball & Socket interface. The proposed HRM has the advantage of higher holding capability along in-plane and out-of plane directions of solar panel and simplicity in tightening process of nylon wire. The design drivers of structural design of CubeSat's solar panel with the proposed HRM were defined by structural analysis under launch loads. In addition, The design effectiveness of the proposed HRM was verified through the functional tests according to the thickness of nylon wire and the number of wire winding under various temperature conditions.

Afterpolymerization and Depolymerization of Poly-${\varepsilon}$-Caproamide in Molten State (용융상태에서의 Poly-${\varepsilon}$-Caproamide의 후중합과 해중합)

  • Dong-ho Lee;Chang-soo Kim;Tae-oan Ahn
    • Journal of the Korean Chemical Society
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    • v.17 no.1
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    • pp.40-46
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    • 1973
  • The afterpolymerization of nylon 6 was carried out in three different reaction conditions, nitrogen flow, sealing and evacuation. The viscosity and reduced weight of polymer were increased by increasing the reaction time and temperature, and viscosity of polymers at constant reaction temperature was decreased as the following order: nitrogen flow >sealing >evacuation. The activation energy of afterpolymerization was 10.5 kcal/mole.

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The Changes of Capsaicinoids and AST A Color Value of Red Pepper Powder Packed with Different Packaging Materials (포장재를 달리한 고춧가루의 저장조건에 따른 capsaicinoids와 색상 함량 변화)

  • 이선미;박재복;김선아;황인경
    • Korean journal of food and cookery science
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    • v.19 no.4
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    • pp.439-446
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    • 2003
  • This study was performed to investigate the change in the chemical components of red pepper powder using different packaging materials and various storage conditions. Red pepper powders with 11 and 15% initial moisture content were packed with five different materials and stored at different temperatures (0, 20, and 30 C) for a one year period. Over the storage period, each combination was periodically sampled, and examined for composition changes. The five packaging materials were: linear low density polyethylene(LLDPE), nylon/LLDPE(Ny/LLDPE), saran coated ethylene vinyl acetate copolymer/linear low density polyethylene(B650), nylon/Tie/nylon/ethylene-vinyl alcohol copolymer/nylon/Tie/LLDPE(RDX-2787) and oriented polypropylene/alumimum/LLDPE(OPP/Al/LLDPE), and the three storage conditions were (28.3${\pm}$1.0)$^{\circ}C$ with (15.5${\pm}$2.8)% relative humidity, (18.6${\pm}$0.5)$^{\circ}C$ with (46.6${\pm}$4.9)% RH, and (0${\pm}$2)$^{\circ}C$ with (80${\pm}$10)% RH, respectively. The moisture contents of all samples changed according to the relative storage humidity, except those of the samples packed with OPP/Al/LLDPE, which remained constant throughout the storage period. The capsaicinoids content of the red pepper powder did not change significantly for 6 months, but gradually decreased after that until about 85% of the original amount remained at the final stage of storage. The ASTA color values of all samples decreased gradually throughout the storage period. The higher the storage temperature, the more severe the deterioration. The color deterioration seemed greatly related to the existence of oxygen, as the deterioration was especially severe in the samples packed with LLDPE and B650, where the oxygen transmission rate were highest among the five packaging materials.

A Study on the Changes in the Property of Nylon Fabrics Dyed with Safflower Under Ultraviolet-Light(UV) - Focused on the Changes in Color, Strength, and Surface - (홍화 염색 나일론 직물의 자외선에 의한 특성 변화 - 색상, 강도 및 표면 특성 변화를 중심으로 -)

  • Shin, Youn-Sook;Choi, Seung-Youn
    • Journal of the Korean Home Economics Association
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    • v.46 no.9
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    • pp.1-6
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    • 2008
  • The purpose of this study was to investigate the changes in the property of nylon fabrics dyed with safflower red and yellow colorants under Ultraviolet(UV)-light. For this purpose, nylon fabrics dyed with safflower red and yellow colorants were compared with each other after uv-light exposure in terms of K/S value, color changes(${\Delta}E$), morphology, and strength retention. K/S value rapidly decreased with increasing exposure time, but K/S value of the samples dyed with safflower red colorants decreased less than that of samples dyed with safflower yellow colorants. In color changes, as increasing exposure time, $L^*$ increased, $a^*$ decreased, $b^*$ increased, and so ${\Delta}E$ increased in samples dyed with safflower red colorants. In color changes, as increasing exposure time, $L^*$ increased, $a^*$ and $b^*$ decreased, and thereby ${\Delta}E$ increased in the samples dyed with safflower yellow colorants, indicating fading away by uv-light and changes of hue, value and chroma value. But the color change of samples dyed with safflower yellow colorants was less than that of samples dyed with safflower red colorants. SEM pictures showed a severe degradation by uv exposure, regardless of colorants type. Tensile strength slowly decreased until 14 days, and rapidly decreased until 28 days. Strength retention of the samples dyed with safflower yellow colorants was higher than that of the samples dyed with safflower red colorants.

Preparation and physical properties of biodegradable polybutylene succinate/polybutylene adipate-co-terephthalate blend monofilament by melt spinning (용융방사에 의한 생분해성 PBS/PBAT 블랜드 모노 필라멘트 제조 및 물리적 특성)

  • Park, Seong-Wook;Kim, Seong-Hun;Choi, Hea-Sun;Cho, Hyun-Hok
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.46 no.3
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    • pp.257-264
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    • 2010
  • In order to improve the breaking strength and elongation of Polybutylene succinate (PBS) monofilament, the monofilament was produced by blending PBS and Polybutlyne adipate-co-terephthalate (PBAT). The PBS/PBAT blend monofilament was prepared by the melt spinning system, and the weight ratios of the compositions of PBS/PBAT was 100/0, 95/5, 90/10 and 85/15, respectively. The breaking strength, elongation, softness and crystallization of PBS/PBAT blend monofilament were analyzed by using a tensionmeter, softness measurement, X-ray diffractometer in the both dry and wet conditions. The PBS/PBAT blend monofilaments were spun in the take-up velocity of 1.19m/sec under the drawing ratio of 6.8:1 condition. The production volumes of PBS/PBAT blend monofilaments showed 20% less than that of Nylon. The breaking strength of PBS/PBAT blend monofilaments were decreased as PBAT contents increased, while elongation and softness were increased. In case of PBAT content were over 5%, the breaking strength, elongation and softness of PBS/PBAT blend monofilaments were not shown to increase in spite of increasing in PBAT contents. Based on these results, it was possible to make the monofilaments with the maximized physical properties when the PBAT contents at 5%.

Influence of Dry Roasting of Whole Faba Beans (Vicia faba) and Whole Lupin Seeds (Lupinus albus) on Rumen Disappearance and Estimated Intestinal Digestion of CP Using the Optimal Three-Step In Vitro Technique in Dairy Cows

  • Yn, P.;Egan, A.R.;Lenry, B.J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.12 no.7
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    • pp.1054-1062
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    • 1999
  • The effects of dry roasting whole faba beans (WFB) and whole lupin seeds (WLS) at 110, 130 or $150{^{\circ}C}$ for 15, 30 or 45 min on rumen (RDCP%), estimated intestinal (IDCP%) and total tract disappearance of CP (TDCP%) and intestinal availability (IARUCP%) of rumen undegraded CP (RUCP%) were determined. The RDCP values were estimated by in sacco technique by incubating nylon bags for 8, 12 and 24 h in the rumen of dairy cows. The IDCP and IARUCP values were estimated using a sequence of ruminal incubation, in vitro incubation in acid-pepsin for 1 h and then in pancreatin for 24 h of three-step in vitro procedure technique. Dry roasting at 130 and $150^{\circ}C$ decreased RDCP with correspondingly increasing IDCP. The IDCP value generally increased from 12.3(raw) to 8.6, 14.8 and 39.6% (WFB) and from 28.3 (raw) to 33.7, 36.2 and 56.2% (WLS) at 8 h rumen incubation; from 2.9 (raw) to 2.9, 4.6 and 23.3% (WFB) and from 19.6 (raw) to 19.0, 24.0 and 46.6% (WLS) at 12 h rumen incubation; from 1.3 (raw) to 1.9, 1.7 and 11.0% (WFB) and from 4.4 (raw) to 4.2, 10.7 and 36.7% (WLS) at 12 h rumen incubation as the temperatures rose to 110, 130 and $150{^{\circ}C}$ respectively. The TDCP values were always high and increased by time in the rumen, the average values of which were 97.9, 96.6; 99.2, 96.9 and 99.6, 98.7% for WFB and WLS, respectively, at 8, 12 and 24 h rumen incubation. But within the same retention time, TDCP was generally unchanged. The average IARUCP increased from 87.3 (raw) to 87.4, 88.7 and 92.0% (WFB); from 87.6 (raw) to 88.9, 91.5 and 93.0% (WLS) at roasting temperatures of 110, 130 and $150{^{\circ}C}$, respectively. It was concluded that dry roasting can shift the digestion of CP from rumen to the lower gastrointestinal tract without depressing the digestion of RUCP. The best processing condition in this study was dry roasting at $150{^{\circ}C}$ for 45 min in terms of effects on the disappearances and availability of CP. Research data on intestinal availability of individual amino acids need to be further investigated.

Mesh selectivity of monofilament and multifilament nylon gill net for Marbled sole (Pleuronectes yokohamae) in the western sea of Korea (서해안 문치가자미 자망의 망지재료에 따른 망목선택성)

  • Kim, In-Ok;Park, Chang-Doo;Cho, Sam-Kwang;Kim, Hyun-Young;Cha, Bong-Jin
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.46 no.4
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    • pp.281-291
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    • 2010
  • To estimate the mesh selectivity of monofilament and multifilament gill net for Marbled sole, Pleuronectes yokohamae, the field testes were carried out 12 times with five different mesh sizes (86.6, 101.0, 121.2, 137.7, 151.5mm) in the western sea of Korea, 2007-2009. The master curve of selectivity was estimated by the extended Kitahara's method. In the field testes, the total number of species and catch were 26 and 987, respectively. The catch number of marbled sole was 728 and occupied 73.8% in total catch. The optimum values of l/m for 1.0 of retention probability in monofilament and multifilament gill net were estimated 0.288 and 0.307, respectively and l/m was estimated to be 0.189, 0.203, 0.213, 0.222 and 0.230 in case of monofilament gill net and 0.171, 0.191, 0.205, 0.216 and 0.227 in case of multifilament gill net when the retention probability were 0.1, 0.2, 0.3, 0.4 and 0.5, respectively. The 0.5 selection range of multifilament gill net was wider about 1.5 times than that of monofilament gill net according as multifilament gill net was 0.216 and monofilament gill net was 0.148. So the multifilament gill net has a low selectivity than that of the monofilament gill net. To estimate the optimum mesh size on first maturity length 19.5cm of marbled sole, the retention probability value of 0.1 was adopted in consideration of using the gill net for marbled sole at present. The optimum mesh size were estimated to be 103.2mm and 114.0mm in monofilament gill net and multifilament gill net, respectively, on first maturity length 19.5cm of marbled sole.