• Korean Journal of Optics and Photonics
• /
• v.5 no.4
• /
• pp.481-486
• /
• 1994

We demonstrate z-scan method as a tool for investigating the molecular orientational order in organic solution when high static electric field is applied. Experiments are performed for the solution of 0.5% (by weight) 4-dimethylamino-4'-nitrostilbene in cyclopentanone and nonlinear refractive index $n_{2}$, is measured to be $-0.905\times10^{-8}\textrm{cm}^2/MW$ at $1.064{\mu}m$. When static electric field of 3.45 KV fmm is applied, the anisotropy ratio of n, is measured to be 1.34 and the molecular orientational order parameters $

_2 and

_4$ are found to be 0.092 and -0.128, respectively. ively.

• Korean Journal of Optics and Photonics
• /
• v.5 no.4
• /
• pp.473-480
• /
• 1994

We have applied nonlinear interferometry of coherent anti-Stokes Raman spectroscopy (CARS) to measure the nonresonant third order susceptibilities of various gases. For the experiment, we placed two gas cells serially and filled the first cell with argon as a calibration standard and the second cell with gases under test. The interference fringes of the CARS signals generated in the two gas cells were obtained by changing the thickness of the phase shifting unit which was made of BK-7 glass. The total effective nonresonant susceptibilities were determined from the measured amplitudes of the interference fringes of the CARS signals of the gases. The nonresonant susceptibilities were obtained by subtracting off resonant vibrational contributions from the total effective susceptibilities. The results of this work are compared with the published data and the overall uncertainty is estimated to be less than 5%. an 5%.

• Journal of the Optical Society of Korea
• /
• v.20 no.4
• /
• pp.470-475
• /
• 2016

In this paper, the effects of filter parameters on a supercontinuum-based all-optical thresholder are experimentally investigated. By tuning the filter parameters, the power transfer function and power transmission function are tailored. The experimental results show that a thresholder with short center wavelength has a better power function, and the slope in the middle level of the thresholder increases with increasing bandwidth. Through tuning the filter parameters, the thresholder can achieve a steplike power transfer function for optical thresholding, and a steplike power transmission function for optical self-switching. This makes the supercontinuum-based thresholder more flexible, and allows customization of performance to meet different demands in various applications.

• Journal of the Korean Vacuum Society
• /
• v.12 no.S1
• /
• pp.70-73
• /
• 2003

Sum-frequency vibrational spectroscopy has recently been used to investigate the surface of the various polymers and was able to find the chemical compositions and structures specific to the surface. Here we report our studies on two specific polymer samples to demonstrate its capability. Polyimide thin films were made by spin coating on fused quartz and $CaF_2$ substrates. The sum-frequency signal originating mainly from the air/polymer interface showed markedly different spectra, indicating the structural change of the polymer surface depending on the underlying substrate. Various polyethylene surfaces were also investigated by sum-frequency vibrational spectroscopy. The surface of polyethylene samples in the CH-region showed different sum-frequency spectra, presumably due to the trace amount of additives having much higher concentration at the air/polymer interface. These examples demonstrate the surface and interface of the polymer could have different structure and chemical composition from those of a bulk, which can be studied effectively by surface nonlinear optical spectroscopy.

• Korean Journal of Optics and Photonics
• /
• v.9 no.5
• /
• pp.342-347
• /
• 1998

We present a theoretical analysis of Gaussian beam propagation in nonlinear Kerr media by using aberration-free approximation and Huygens-Fresnel diffraction integral and obtain a simple analytic formular for Z-scan characteristics. Z-scan experiments are carried out on amorphous $As_2S_3$ thin film and compared with the theory developed, showing good agreement. The sign and the value of ${\gamma}$ have been measured at 633 nm to be $+8.65{\times}10^{-6}\textrm{cm}^2/W$. We also measured the far-field intensity profiles, which confirm again self-focusing effect.

• Korean Journal of Optics and Photonics
• /
• v.4 no.3
• /
• pp.301-308
• /
• 1993

Phenomenological nonlinear gain saturation effect on the modulation characteristics in a multi-electrode DBR laser, when the lasing wavelength changes, continuously is analized theoretically. FM efficiency, 3 dB bandwidth, and resonance frequency decrease with increasing bias current to the passive section, except increasing the flat FM response. It is found that the nonlinear gain saturation effect severely affects the modulation characteristics such as FM/IM response, 3 dB bandwidth, resonance frequency and CPR, but hardly affects the behavior of continuous frequency tuning.

• Korean Journal of Optics and Photonics
• /
• v.18 no.1
• /
• pp.14-18
• /
• 2007

Photonic crystal fibers(PCFs) with silica cores within an away of air holes have unique properties. Broad band single-mode and the octave-spanning supercontinuum generation, impossible to achieve in classical fibers, can be realized. The design of PCFs is very flexible. There are two parameters to manipulate: air hole diameter, and lattice pitch. We introduced a fabrication process for control of the parameters to obtain endlessly single mode PCF, which is single mode in a large wavelength range, and highly nonlinear PCF. The numerical analysis and experiments are included.

• Bulletin of the Korean Chemical Society
• /
• v.29 no.5
• /
• pp.933-938
• /
• 2008

2,4-Di-(2'-hydroxyethoxy)benzylidenemalononitrile (3) was prepared and polymerized with terephthaloyl chloride and adipoyl chloride to yield novel Y-type polyesters 4 and 5 containing dioxybenzylidenemalononitrile groups as NLO-chromophores, which constituted parts of the polymer backbone. The resulting polymers 4 and 5 are soluble in common organic solvents such as acetone and N,N-dimethylformamide. Polymers 4 and 5 showed thermal stability up to 300 ${^{\circ}C}$ in thermogravimetric analysis with glass-transition temperatures obtained from differential scanning calorimetry in the range 83-94 ${^{\circ}C}$. The second harmonic generation (SHG) coefficients ($d_{33}$) of poled polymer films at the 1064 nm fundamental wavelength were around $6.48\;{\times}\;10^{-9}$ esu. The dipole alignment exhibited high thermal stability even at 10 ${^{\circ}C}$ higher than $T_g$ and no significant SHG decay was observed below 105 ${^{\circ}C}$ partially due to the main-chain character of polymer structure, which is acceptable for NLO device applications.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.6
• /
• pp.1509-1514
• /
• 2010

Methyl 3,4-di-(2'-hydroxyethoxy)benzylidenecyanoacetate (3) was prepared and condensed with terephthaloyl chloride to yield novel Y-type polyester (4) containing 3,4-dioxybenzylidenecyanoacetate groups as NLO-chromophores, which constituted parts of the polymer main chains. The resulting polymer 4 is soluble in common organic solvents such as acetone and N,N-dimethylformamide. Polymer 4 shows thermal stability up to $280^{\circ}C$ in thermogravimetric analysis with glass-transition temperature obtained from differential scanning calorimetry near $105^{\circ}C$. The second harmonic generation (SHG) coefficient ($d_{33}$) of poled polymer films at the 1064 nm fundamental wavelength is around 2.42 pm/V. The dipole alignment exhibits high thermal stability up to near $T_g$, and there is no SHG decay below $100^{\circ}C$ due to the partial main-chain character of polymer structure, which is acceptable for NLO device applications.

• Bulletin of the Korean Chemical Society
• /
• v.30 no.5
• /
• pp.1080-1084
• /
• 2009

Methyl 2,4-di-(2'-hydroxyethoxy)benzylidenecyanoacetate (3) was prepared and polymerized with terephthaloyl chloride to yield a novel Y-type polyester 4 containing 2,4-dioxybenzylidenecyanoacetate groups as NLOchromophores, which constituted parts of the polymer backbone. The resulting polymer 4 is soluble in common organic solvents such as acetone and N,N-dimethylformamide. Polymer 4 showed thermal stability up to 280 ${^{\circ}C}$ in thermogravimetric analysis with glass-transition temperature obtained from differential scanning calorimetry near 108 ${^{\circ}C}$. The second harmonic generation (SHG) coefficient ($d_{33}$) of poled polymer films at the 1064 nm fundamental wavelength was around $3.54\;{\time}\;10^{-9}$ esu. The dipole alignment exhibited a thermal stability up to near $T_g$ and no significant SHG decay was observed below 100 ${^{\circ}C}$ due to the partial main-chain character of polymer structure, which is acceptable for NLO device applications.