• 제목/요약/키워드: nonequilibrium state

검색결과 29건 처리시간 0.029초

Rovibrational Energy Transitions and Coupled Chemical Reaction Modeling of H+H2 and He+H2 in DSMC

  • Kim, Jae Gang
    • International Journal of Aeronautical and Space Sciences
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    • 제16권3호
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    • pp.347-359
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    • 2015
  • A method of describing the rovibrational energy transitions and coupled chemical reactions in the direct simulation Monte Carlo (DSMC) calculations is constructed for $H(^2S)+H_2(X^1{\Sigma}_g)$ and $He(^1S)+H_2(X^1{\Sigma}_g)$. First, the state-specific total cross sections for each rovibrational states are proposed to describe the state-resolved elastic collisions. The state-resolved method is constructed to describe the rotational-vibrational-translational (RVT) energy transitions and coupled chemical reactions by these state-specific total cross sections and the rovibrational state-to-state transition cross sections of bound-bound and bound-free transitions. The RVT energy transitions and coupled chemical reactions are calculated by the state-resolved method in various heat bath conditions without relying on a macroscopic properties and phenomenological models of the DSMC. In nonequilibrium heat bath calculations, the state-resolved method are validated with those of the master equation calculations and the existing shock-tube experimental data. In bound-free transitions, the parameters of the existing chemical reaction models of the DSMC are proposed through the calibrations in the thermochemical nonequilibrium conditions. When the bound-free transition component of the state-resolved method is replaced by the existing chemical reaction models, the same agreement can be obtained except total collision energy model.

Reflections of shocks in nonequilibrium flow of air

  • Park, Tae-Hoon
    • 대한수학회논문집
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    • 제10권3호
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    • pp.767-781
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    • 1995
  • In this paper we present computation of a reflected shock in the hypersonic flow of air with chemical reactions. We consider two dimensional steady inviscid hypersonic flow of air around bodies including chemical reaction effects. At a high Mach number, a strong shock is formed in front of the body when a wedge is placed against the flow. In front of the shock, temperature and pressure increase greatly and the flow is in nonequilibrium state. If the shock hits a wall, then a reflected shock is formed in the nonequilibrium flow region. Behind this reflected shock, the temperature and pressure are very high. We carry out the computation of the reflected shock and the flow behind it. The jump conditions at the reflected shock are presented. A technique combining smooth transforms of domain and implicit difference methods is used to overcome numerical difficulties associated with the lack of resolution behind the shock and near the body.

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Microwave plasma emission from tunnel-injected nonequilibrium high-Tc superconductors

  • Lee, Kie-Jin
    • 한국초전도학회:학술대회논문집
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    • 한국초전도학회 2000년도 High Temperature Superconductivity Vol.X
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    • pp.9-14
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    • 2000
  • We report on the novel nonequilibrium nlicrowave emission from quasiparticle-injected high-Tc superconductors. The phenomena have been observed for the current-injected YBCO/I/Au or BSCCO/I/Au thin-film tunnel junctions and BSCCO single-crystal intrinsic Josephson mesa junction samples. For the thin-film tunnel junctions, the emitted radiation appears as broadband. For the intrinsic BSCCO mesa samples, the radiation appears as three different modes of emissions depending on the bias point in the hysteretic current-voltage characteristics; Josephson-emission, nonequilibrium broad emission and sharp coherent microwave emission. The results were interpreted by the Josephson plasma excitation model due to quasiparticle injection.

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무딘 물체의 노즈 반지름이 비평형 유동의 공력 가열에 미치는 영향 (Effects of Nose Radius of Blunt Body on Aerodynamic Heating in Thermochemical Nonequilibrium Flow)

  • 이창호;박승오
    • 한국전산유체공학회지
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    • 제8권4호
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    • pp.34-40
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    • 2003
  • The effect of nose radius on aerodynamic heating is investigated by using the Navier-Stokes code extended to thermochemical nonequilibrium airflow, Spherical blunt bodies, whose nose radius varies from 0.O03048 m to 0.6096 m, flying at Mach 25 at an altitude of 53.34 km are considered. Comparison of heat flux at stagnation point with the solution of Viscous Shock Layer and Fay-Riddell are made. Results show that the flow for very small radius is in a nearly frozen state, and therefore the heat flux due to diffusion is smaller than that due to translational energy. As the radius becomes larger, the portion of heat flux by diffusion becomes greater than that of heat flux by translational temperature and approaches to a constant value.

Novel nonequilibrium microwave emission and current-voltage characteristics of $Bi_2$$Sr_2$Ca$Cu_2$$O_{8+d}$ intrinsic Josephson junction mesas

  • Kim, Sun-Mi;Lee, Kie-Jin;Bae, Myung-Ho;Lee, Hu-Jong;Cha, Deok-Joon;Takayuki Ishibashi;Katsuaki Sato;Kim, Jin-Tae
    • Progress in Superconductivity
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    • 제4권2호
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    • pp.104-108
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    • 2003
  • We have measured the transport properties of $Bi_2$$Sr_2$$CaCu_2$$O_{8+d}$ (BSCCO) intrinsic Josephson junction mesa. Transport measurements with current flow along the c-axis, perpendicular to the layer of mesa showed multi-branch structures on the current-voltage characteristics. For single intrinsic junctions, the microwave radiation appears in the form of three different modes of oscillations, which include Josephson emission, nonequilibrium broad emission and sharp coherent microwave emission. Mutual phase interactions between two-mesas structures of BSCCO intrinsic Josephson junctions were studied. The results were explained within the framework of the Josephson plasma excitation model due to quasiparticle injection.n.

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Tunneling effect due to UV irradiation in organic Cu-Pc/$Bi_2$$Sr_2$Ca$Cu_2$$O_{8+$\delta$}$ tunnel junction

  • Kim, Sunmi;Lee, Kiejin;Deokjoon Cha;Takayuki Ishibashi
    • Progress in Superconductivity
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    • 제4권2호
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    • pp.99-103
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    • 2003
  • We studied the nonequilibrium superconductivity due to tunnel injection of polaronic quasiparticle (QP) from organic photoconductor. The transport properties of an organic copper (II) phthalocyanine (Cu -Pc)/d-wave superconductor were investigated in dark and under ultraviolet (UV) radiation for performance of a novel $high -T_{c}$ superconducting three terminal device. We observed that the injection of polaronic QP from the organic Cu -Pc film into the $Bi_2$S $r_2$$CaCuO_{8+{\delta}}$ film generated a substantially larger nonequilibrium effect as compared to the normal QP injection current. We could increase the current gain by UV excitation of the organic photoconductor injector. The tunneling spectroscopy of a Cu -Pc/BSCCO junction exhibited a small enhancement of the zero bias conductance peak under the W excitation. The above phenomena are of importance in developing optically controlled three terminal superconducting device.e.

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팽창률이 일정한 초음속 노즐흐름에 있어서 비평형 응축이 경사충격파에 미치는 영향 (Effects of Nonequilibrium Condensation on an Oblique Shock Wave in a Supersonic Nozzle of Constant Expansion Rate)

  • 강창수;권순범;김병지;홍종우
    • 대한기계학회논문집
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    • 제14권5호
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    • pp.1311-1319
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    • 1990
  • 본 연구에서는 작동유체로서 습증기와 거동이 유사한 습증기를 대기흡입식 간 헐 초음속 풍동을 이용하여, 팽창율이 일정한 노즐을 통하여 팽창시키는 경우에 대하 여 비평형 응축영역내 입치하는 경우에 대하여, 정체점 상태량의 변화에 기인되는 응 축 및 응축형격파가 경사형격파의 형상과 변화에 미치는 영향을 다음의 관점으로부터 연구하였다.

열적, 화학적 비평형 유동해석에서 내재적 시간 적분법의 비교 (Comparison of Implicit Time Integration Schemes for the Analysis of Thermal and Chemical Non-equilibrium Flow)

  • 이창호;박승오
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 1999년도 추계 학술대회논문집
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    • pp.42-47
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    • 1999
  • In this study, we adopt the point symmetric Gauss-Seidel relaxation algorithm to obtain the steady state solution of the Navier-Stokes equations for the thermal and chemical nonequilibrium flow of air. All of the inviscid, viscous flux Jacobians and thermochemical source Jacobians are included in the implicit part Numerical simulation is performed for the thermal and chemical nonequilibrium flow over blunt body and computational results are presented. The convergence history and CPU time of the present computation are compared with the LU-SGS scheme which employs the approximate Jacobians.

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