• 제목/요약/키워드: non-porous surface

검색결과 115건 처리시간 0.026초

이중층 몰리브데늄을 후면전극으로 적용한 비진공법 CuInSe2 태양전지의 특성 (Characterization of Non-vacuum CuInSe2 Solar Cells Deposited on Bilayer Molybdenum)

  • 황지섭;윤희선;장윤희;이장미;이도권
    • Current Photovoltaic Research
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    • 제8권2호
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    • pp.45-49
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    • 2020
  • Molybdenum (Mo) thin films are widely used as back contact in copper indium diselenide (CISe) solar cells. However, despite this, there are only few published studies on the properties of Mo and characteristics of CISe solar cells formed on such Mo substrates. In this studies, we investigated the properties of sputter deposited Mo bilayer, and fabricated non-vacuum CISe solar cells using bilayer Mo substrates. The changes in surface morphology and electrical resistivity were traced by varying the gas pressure during deposition of the bottom Mo layer. In porous surface structure, it was confirmed that the electrical resistivity of Mo bilayer was increased as the amount of oxygen bonded to the Mo atoms increased. The resulting solar cell characteristics vary as the bottom Mo layer deposition pressure, and the maximum solar cell efficiency was achieved when the bottom layer was deposited at 7 mTorr with a thickness of 100 nm and the top layer deposited at 3 mTorr with a thickness of 400 nm.

프로판올 첨가에 따른 PVC 용액의 박막 형성과 표면 특성에 미치는 영향 (Effect of the Addition of Propanol to PVC Solution on the Structure of Thin Film and its Surface Property)

  • 박재남;신영식;이원규
    • 공업화학
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    • 제26권1호
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    • pp.35-39
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    • 2015
  • 범용성 고분자인 폴리염화비닐(PVC)의 용매에 대한 용해도 차이를 이용하여 미세다공성 구조의 표면을 갖는 초소수성 박막을 제조하고 박막의 형상에 따른 표면 특성을 분석하였다. 용매로 테트라하이드로퓨란과 비용매인 프로판올로 구성된 PVC 용액을 딥코팅으로 물과의 접촉각이 $150^{\circ}$ 이상인 초소수성 PVC 박막을 얻었다. PVC 박막 제조과정의 표면 건조공정에서 온도가 증가는 표면 거칠기를 상대적으로 감소시켜 표면의 소수성 특성 저하를 가져왔다. PVC 용액에 비용매인 프로판올의 양을 증가시키면 코팅 박막의 표면 거칠기가 균일해지고 접촉각을 증가시키는 효과를 보였다. 초소수성의 PVC 박막 표면을 산소 플라즈마 처리하면 노출시간에 따라 친수성으로 표면특성이 변환됨을 확인하였다.

하이드레이트 펠릿의 비평형 분해과정 수치해석 (NUMERICAL ANALYSIS OF NON-EQUILIBRIUM HYDRATE PELLET DECOMPOSITION)

  • 강정호;남진현;김찬중;송명호
    • 한국전산유체공학회지
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    • 제13권4호
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    • pp.50-57
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    • 2008
  • The prediction of hydrate pellet decomposition characteristics is required to design the regasification process of GTS (gas to solid) technology, which is considered as an economic alternative for LNG technology to transport natural gas produced from small and stranded gas wells. Mathematical model based on the conservation principles, the phase equilibrium relation, equation of gas state and phase change kinetics was set up and numerical solution procedure employing volume averaged fixed grid formulation and extended enthalpy method are implemented. Initially, porous methane hydrate pellet is at uniform temperature and pressure within hydrate stable region. The pressure starts to decrease with a fixed rate down to the final pressure and is kept constant afterwards while the bounding surface of pellet is heated by convection. The predicted convective heat and mass transfer accompanied by the decomposed gas flow through hydrate/ice solid matrix is reported focused on the comparison of spherical and cylindrical pellets having the same effective radius.

하이드레이트 펠릿의 비평형 분해과정 수치해석 (NUMERICAL ANALYSIS OF NON-EQUILIBRIUM HYDRATE PELLET DECOMPOSITION)

  • 강정호;남진현;김찬중;송명호
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 학술대회
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    • pp.268-275
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    • 2008
  • The prediction of hydrate pellet decomposition characteristics is required to design the regasification process of GTS (gas to solid) technology, which is considered as an economic alternative for LNG technology to transport natural gas produced from small and stranded gas wells. Mathematical model based on the conservation principles, the phase equilibrium relation, equation of gas state and phase change kinetics was set up and numerical solution procedure employing volume averaged fixed grid formulation and extended enthalpy method are implemented. Initially, porous methane hydrate pellet is at uniform temperature and pressure within hydrate stable region. The pressure starts to decrease with a fixed rate down to the final pressure and is kept constant afterwards while the bounding surface of pellet is heated by convection. The predicted convective heat and mass transfer accompanied by the decomposed gas flow through hydrate/ice solid matrix is reported focused on the comparison of spherical and cylindrical pellets having the same effective radius.

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하이드레이트 펠릿의 비평형 분해과정 수치해석 (NUMERICAL ANALYSIS OF NON-EQUILIBRIUM HYDRATE PELLET DECOMPOSITION)

  • 강정호;남진현;김찬중;송명호
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년 추계학술대회논문집
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    • pp.268-275
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    • 2008
  • The prediction of hydrate pellet decomposition characteristics is required to design the regasification process of GTS (gas to solid) technology, which is considered as an economic alternative for LNG technology to transport natural gas produced from small and stranded gas wells. Mathematical model based on the conservation principles, the phase equilibrium relation, equation of gas state and phase change kinetics was set up and numerical solution procedure employing volume averaged fixed grid formulation and extended enthalpy method are implemented. Initially, porous methane hydrate pellet is at uniform temperature and pressure within hydrate stable region. The pressure starts to decrease with a fixed rate down to the final pressure and is kept constant afterwards while the bounding surface of pellet is heated by convection. The predicted convective heat and mass transfer accompanied by the decomposed gas flow through hydrate/ice solid matrix is reported focused on the comparison of spherical and cylindrical pellets having the same effective radius.

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SiO2 나노입자 현탁액의 충돌 및 퍼짐에 관한 실험적 연구 (Experimental study on impact and spreading of SiO2 nanoparticle colloidal suspension droplets)

  • 허형규;이상준
    • 한국가시화정보학회지
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    • 제11권3호
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    • pp.12-16
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    • 2013
  • The impact and spreading behaviors of silicon dioxide nanoparticle colloidal suspension droplets were quantitatively visualized using a high-speed imaging system. Millimeter-scale droplets were generated by a syringe pump and a needle. Droplets of different velocity were impacted on a non-porous solid surface. Images were consecutively recorded using a CMOS high-speed camera at 5000 fps (frames per second) for millimeter-scale droplets. Temporal variations of droplet diameter, velocity and maximum spreading diameters were evaluated from the sequential images captured for each experimental condition. Effects of Reynolds number, Weber number, and particle concentration were investigated experimentally.

Stability analysis of porous multi-phase nanocrystalline nonlocal beams based on a general higher-order couple-stress beam model

  • Ebrahimi, Farzad;Barati, Mohammad Reza
    • Structural Engineering and Mechanics
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    • 제65권4호
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    • pp.465-476
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    • 2018
  • This article investigates buckling behavior of a multi-phase nanocrystalline nanobeam resting on Winkler-Pasternak foundation in the framework of nonlocal couple stress elasticity and a higher order refined beam model. In this model, the essential measures to describe the real material structure of nanocrystalline nanobeams and the size effects were incorporated. This non-classical nanobeam model contains couple stress effect to capture grains micro-rotations. Moreover, the nonlocal elasticity theory is employed to study the nonlocal and long-range interactions between the particles. The present model can degenerate into the classical model if the nonlocal parameter, and couple stress effects are omitted. Hamilton's principle is employed to derive the governing equations and the related boundary conditions which are solved applying an analytical approach. The buckling loads are compared with those of nonlocal couple stress-based beams. It is showed that buckling loads of a nanocrystalline nanobeam depend on the grain size, grain rotations, porosities, interface, elastic foundation, shear deformation, surface effect, nonlocality and boundary conditions.

Approximate Yield Criterion for Voided Anisotropic Ductile Materials

  • Kim, Youngsuk;Sungyeun Won;Kim, Dogsoo;Hyunsung Son
    • Journal of Mechanical Science and Technology
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    • 제15권10호
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    • pp.1349-1355
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    • 2001
  • As most fractures of ductile materials in metal forming processes occurred due to the results of evolution of internal damage - void nucleation, growth and coalescence. In this paper, an approximate yield criterion for voided (porous) anisotropic ductile materials is developed. The proposed approximate yield function is based on Gurson's yield function in conjunction with the Hosford's non-quadratic anisotropic yield criterion in order to consider the characteristic of anisotropic properties of matrix material. The associated flow rules are presented and the laws governing void growth with strain are derided. Using the proposed model void growth of an anisotropic sheet under biaxial tensile loading and its effect on sheet metal formability are investigated. The yield surface of voided anisotropic sheet and void growth with strain are predicted and compared with the experimental results.

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황산 용액에서 Al6061 합금의 아노다이징 피막 형성거동 (Formation Behavior of Anodic Oxide Films on Al 6061 Alloy in Sulfuric Acid Solution)

  • 문성모;정기훈;임수근
    • 한국표면공학회지
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    • 제51권6호
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    • pp.393-399
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    • 2018
  • Formation behavior of aluminum anodic oxide (AAO) films on Al6061 alloy was studied in view of thickness, morphology and defects in the anodic films in 20 vol.% sulfuric acid solution at a constant current density of $40mA/cm^2$, using voltage-time curve, observation of anodized specimen colors and surface and cross-sectional morphologies of anodic films with anodization time. With increasing anodizing time, voltage for film formation increased exponentially after about 12 min and its increasing rate decreased after 25 min, followed by a rapid decrease of the voltage after about 28 min. Surface color of anodized specimen became darker with increasing anodizing time up to about 20 min, while it appeared to be brighter with increasing anodizing time after 20 min. The darkened and brightened surfaces with anodizing time are attributed to an increase in thickness of porous anodic oxide film and a chemical damage of the films due to heat generated by increased resistance of the film, respectively. Cross-sectional observation of AAO films revealed the formation of defects of crack shape at the metal/oxide interface after 15 min which prevents the growth of AAO films. Width and length of the crack-like defect increased with anodizing time up to 25 min of anodizing, and finally the outer part of AAO films was partly dissolved or detached after 30 min of anodizing, resulting in non-uniform surface structures of the AAO films.

A frame work for heat generation/absorption and modified homogeneous-heterogeneous reaction in flow based on non-Darcy-Forchheimer medium

  • Hayat, Tasawar;Ahmad, Salman;Khan, Muhammad I.;Khan, Muhammad I.;Alsaedi, Ahmed
    • Nuclear Engineering and Technology
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    • 제50권3호
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    • pp.389-395
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    • 2018
  • The present work aims to report the consequences of Darcy-Forchheimer medium in flow of Cross fluid model toward a stretched surface. Flow in porous space is categorized by Darcy-Forchheimer medium. Further heat transfer characteristics are examined via thermal radiation and heat generation/absorption. Transformation procedure is used. The arising system of nonlinear ordinary differential equations is solved numerically by means of shooting method. The effects of different flow variables on velocity, temperature, concentration, skin friction, and heat transfer rate are discussed. The obtained outcomes show that velocity was enhanced with the increase in the Weissenberg number but decays with increase in the porosity parameter and Hartman number. Temperature field is boosted by thermal radiation and heat generation; however, it decays with the increase in the Prandtl number.