• 제목/요약/키워드: non-dipole effect

검색결과 15건 처리시간 0.025초

Estimation of Excited State Dipole Moment of Exalite Dyes by Solvatochromic Shift Studies

  • Inamdar, S. R.;Nadaf, Y.F.;Deshpande, D.K.;Karguppikar, A.M.
    • Journal of Photoscience
    • /
    • 제9권1호
    • /
    • pp.29-32
    • /
    • 2002
  • The solvent effect in a series of polar and non-polar solvents of varying dielectric constants and refractive indices has been investigated by studying electronic spectra (S$_1$band) of a series of exalite laser dyes at room temperature (25$\pm$1$\^{C}$). These data are used to determine the magnitude ($\mu$$\_$e/) and direction ($\theta$) of the electric dipole moments in the first electronically excited state. The results indicate that the observed band systems in these compounds may be attributed to ←$\pi$ transition.

  • PDF

An Algorithm for the Characterization of Surface Crack by Use of Dipole Model and Magneto-Optical Non-Destructive Inspection System

  • Lee, Jin-Yi;Lyu, Sung-Ki;Nam, Young-Hyun
    • Journal of Mechanical Science and Technology
    • /
    • 제14권10호
    • /
    • pp.1072-1080
    • /
    • 2000
  • Leakage magnetic flux (LMF) is widely used for non-contact detection of cracks. The combination of optics and LMF offers advantages such as real time inspection, elimination of electrical noise, high spatial resolution, etc. This paper describes a new nondestructive evaluation method based on an original magneto-optical inspection system, which uses a magneto-optical sensor, LMF, and an improved magnetization method. The improved magnetization method has the following characteristics: high observation sensitivity, independence of the crack orientation, and precise transcription of the geometry of a complex crack. The use of vertical magnetization enables the visualization of the length and width of a crack. The inspection system provides the images of the crack, and shows a possibility for the computation of its depth.

  • PDF

2-[(2,6-Dioxocyclohexyl)methyl]cyclohexane-1,3-dione 유도체의 Tyrosinase 저해활성에 관한 2D-QSAR 분석 (2D-QSAR Analyses on The Tyrosinase Inhibitory Activity of 2-[(2,6-Dioxocyclohexyl)methyl]-cyclohexane-1,3-dione Analogues)

  • 김상진;성낙도
    • 대한화장품학회지
    • /
    • 제40권4호
    • /
    • pp.383-390
    • /
    • 2014
  • 기질 분자로서 2-[(2,6-dioxocyclohexyl)methyl]cyclohexane-1,3-dione 유도체(1-23)들의 분자 내 치환기($R_1$$R_2$)가 변화함에 따른 tyrosinase 수용체의 저해활성에 관한 2D-QSAR 모델로부터 다음과 같은 결론을 얻었다. 유도된 최적의 2D-QSAR 모델은 $Obs.pI_{50}=-0.295({\pm}0.031)TDM$ $-0.120({\pm}0.014)DMZ+0.135({\pm}0.050)DMX$. $R_2+6.382({\pm}0.17)$이었으며, 예측성($q^2=0.843$)보다는 상관성($r^2=0.905$)이 큰 모델이었다. Tyrosinase 저해활성은 TDM > $DMX.R_2{\geq}DMZ$ 순으로 영향을 미치었으며, 기질분자의 소수성(ClogP > 0)이 크고, $R_1$-치환기의 입체적 크기가 클수록 더욱 증가하는 경향을 나타내었다. 모델을 분석한 결과, 분자 내 $R_2$-치환기 상 X-축 성분의 쌍극자능률($DMX.R_2$)이 클수록, 그리고 분자 전체의 쌍극자능률(TDM; Total Dipole Moment)과 Z-성분의 쌍극자능률(DMZ; Dipole Moment of Z-Component)이 작을수록 기질분자의 tyrosinase 저해활성이 높아짐을 암시하였다. 따라서 tyrosinase 저해활성은 기질분자 및 $R_2$-치환기의 전자 친화력에 기인한 것으로 예상되었다. 그러므로 저해활성을 증가시키려면 분자 내 극성 그룹을 소수성에 기여하는 비극성 작용기로 대체함이 바람직할 것으로 예측되었다.

Improved performance of n-type organic field-effect transistor with a non-conjugated polyelectrolyte layer

  • Park, Yu Jung;Cha, Myoung Joo;Lee, Jin Hee;Cho, Shinuk;Seo, Jung Hwa;Walker, Bright
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
    • /
    • pp.151.2-151.2
    • /
    • 2016
  • We characterized the n-type organic field-effect transistors (OFETs) with non-conjugated polyelectrolytes (NPEs) interlayers as the electron injection layer. Novel NPEs with various ions (Cl-, Br-, I-) improved the electron mobility from $5.06{\times}10^{-3}$ to $2.10{\times}10^{-2}cm^2V^{-1}s^{-1}$ in OFETs based [6,6]-Phenyl-$C_{61}$-butyric acid methyl ester (PCBM) when $PEIEH^+I^-$ spin-cast from 0.6% solution was deposited onto the PCBM layer. Reduced electron injection barrier (${\phi}_e$) at NPE/metal electrode interface was induced by dipole formation and led to increase the electron injection and transport. These findings are important for understanding how NPEs function in devices, the improvement of device performance, and the design of new materials for use in optoelectronic devices.

  • PDF

편각과 관련된 고등학생들의 오개념 및 교과서 분석 (Analysis of Highschool Students' Misconception Textbooks Related to the Declination)

  • 이규호
    • 한국지구과학회지
    • /
    • 제32권6호
    • /
    • pp.687-703
    • /
    • 2011
  • 편각은 판구조론 이해의 바탕이 되는 개념이며 실생활에서 지도와 나침반을 이용하여 자신의 위치를 결정할 때도 쓰이는 중요한 개념이다. 이에 제 7차 교육과정에서 사용되고 있는 6종의 지구과학 II 교과서에서 편각에 대한 설명이 어떻게 기술되어 있는지 확인하고 고등학생들이 오개념을 가질 수 있는 가능성을 조사하였다. 개념 검사지를 통해 실제로 나타나고 있는 고등학생들의 오개념을 확인하고 교과서와의 연관성을 알아보았다. 그 결과 고등학생들은 특히 자북극과 관련하여 오개념을 가지고 있었고 이는 교과서의 편각에 대한 설명 부족과 함께 잘못된 삽화와 밀접한 관계가 있었다. 따라서 편각에 대한 정확한 이해를 위해서는 비쌍극자 효과를 추가한 편각의 설명이 필요하고 이에 따른 삽화의 제시가 필요함을 확인하였다.

Theoretical Consideration of Nondestructive Testing by use of Vertical Magnetization and Magneto-Optical Sensor

  • Lee, Jinyi;Tetsuo Shoji;Dowon Seo
    • Journal of Mechanical Science and Technology
    • /
    • 제18권4호
    • /
    • pp.640-648
    • /
    • 2004
  • This paper describes a new magnetization method for non-destructive testing with magneto-optical sensor (denoted as MO sensor) which have the following characteristic : high observation sensitivity, independence of the crack orientation, and precise imaging of a complex crack geometry such as multiple cracks. When a magnetic field is applied normally to the surface of a specimen which is significantly larger than its defects, approximately the same magnetic charge per unit area occurs on the surface of the specimen. If there is a crack in the specimen, magnetic charge per unit area has the same value at the bottom of the crack. The distribution of the vertical component of the magnetic flux density, B$\_$Z/, is almost uniform over the no-crack area (denoted as B$\_$Z,BASE/), while the magnetic flux density is smaller in the surroundings of the crack(denoted as B$\_$Z,CRACK/) If B$\_$Z, BASE/ is a bit larger than the saturated magnetic flux density of the MO sensor (B$\_$s/) , then small magnetic domains occur over the crack area and a large domain over the non-crack area because B$\_$Z,CRACK/ is smaller than B$\_$s/.

Response of Water Tetramer to Intense Femtosecond Laser Pulses

  • Wang, Zhiping;Xu, Xuefen;Qian, Chaoyi;Wang, Yanbiao;Wang, Xu
    • Current Optics and Photonics
    • /
    • 제1권4호
    • /
    • pp.278-283
    • /
    • 2017
  • We theoretically study the dynamics of water tetramer in intense femtosecond laser pulses with different frequencies. The simulations are carried out by incorporating the molecular dynamics method non-adiabatically into the time-dependent local-density approximation (TDLDA-MD). Three typical scenarios of water tetramer including the normal vibration with enlarged OH bonds, free OH bonds breaking and the pure Coulomb explosion are presented by investigating the electronic and ionic dynamics. The result indicates that the ionization is enhanced and the corresponding fragmentation effect as well as the damping of the dipole moment are found more notably when increasing the laser frequency especially when the frequency falls in the resonant region of the absorption spectra. The study of the level depletion reveals that the ratio of the emission amount from different levels can be controlled by changing the laser frequency referring to the Keldysh parameter.

Water carrying iron (iii) oxide (Fe3O4) ferrofluid flow and heat transfer due to deceleration of a rotating plate

  • Bhandari, Anupam
    • Structural Engineering and Mechanics
    • /
    • 제82권5호
    • /
    • pp.679-690
    • /
    • 2022
  • This research effort examines the flow behavior and heat transfer assessment of water carrying iron (iii) oxide magnetic fluid due to a rotating and moving plane lamina under the influence of magnetic dipole. The effect of rotational viscosity and magnetic body force is taken into consideration in the present study. The involvement of the moving disk makes a significant contribution to the velocity distribution and heat transfer in rotational flow. Vertical movement of the disk keeps the flow unsteady and the similarity transformation converts the governing equation of unsteady flow into nonlinear coupled differential equations. The non-dimensional equation in the present system is solved through the finite element procedure. Optimizing the use of physical parameters described in this flow, such results can be useful in the rotating machinery industries for heat transfer enhancement.

혼합냉매의 열역학적 물성치 추산에 관한 연구 (Studies on the Estimation of Theromodynamic Properties for the Non-Azeotropic Refrigerant Mixtures)

  • 김민수;김동섭;노승탁;김욱중;윤재호
    • 대한기계학회논문집
    • /
    • 제14권5호
    • /
    • pp.1337-1348
    • /
    • 1990
  • 본 연구에서는 Peng-Robinson 상태 방정식을 기본으로 하여 먼저 단일 성분의 냉매에 대한 열역학적 물성치를 구한 뒤 그 정확도를 검증하고, 동일한 형태의 상태식 과 적절한 혼합 법칙을 통해 혼합냉매의 기액 평형 상태와 냉동 및 열펌프 사이클 해 석에 필요한 엔탈피와 엔트로피 등의 열역학적 물성치를 추산하고자 한다.단일 성 분의 냉매로서는 R13B1, R22, R12, R152a, R114를 택하였고, 혼합냉매로서는 앞의 단 일성분 냉매를 혼합한 것 중에서 그 기초적인 실험 자료가 아미 알려진 R13B1/R114, R22/R114, R12/R114 R152a/R114, R13B1/R152a 및 R13B1/R12를 택하였다. 이는 추후 상이한 냉매를 단일식으로 나타낼 수 있는 대응상태의 원리를 사용한 열물성 계산의 기반이 될 수 있을 것이다.