• Title/Summary/Keyword: non-dipole effect

Search Result 15, Processing Time 0.028 seconds

Estimation of Excited State Dipole Moment of Exalite Dyes by Solvatochromic Shift Studies

  • Inamdar, S. R.;Nadaf, Y.F.;Deshpande, D.K.;Karguppikar, A.M.
    • Journal of Photoscience
    • /
    • v.9 no.1
    • /
    • pp.29-32
    • /
    • 2002
  • The solvent effect in a series of polar and non-polar solvents of varying dielectric constants and refractive indices has been investigated by studying electronic spectra (S$_1$band) of a series of exalite laser dyes at room temperature (25$\pm$1$\^{C}$). These data are used to determine the magnitude ($\mu$$\_$e/) and direction ($\theta$) of the electric dipole moments in the first electronically excited state. The results indicate that the observed band systems in these compounds may be attributed to ←$\pi$ transition.

  • PDF

An Algorithm for the Characterization of Surface Crack by Use of Dipole Model and Magneto-Optical Non-Destructive Inspection System

  • Lee, Jin-Yi;Lyu, Sung-Ki;Nam, Young-Hyun
    • Journal of Mechanical Science and Technology
    • /
    • v.14 no.10
    • /
    • pp.1072-1080
    • /
    • 2000
  • Leakage magnetic flux (LMF) is widely used for non-contact detection of cracks. The combination of optics and LMF offers advantages such as real time inspection, elimination of electrical noise, high spatial resolution, etc. This paper describes a new nondestructive evaluation method based on an original magneto-optical inspection system, which uses a magneto-optical sensor, LMF, and an improved magnetization method. The improved magnetization method has the following characteristics: high observation sensitivity, independence of the crack orientation, and precise transcription of the geometry of a complex crack. The use of vertical magnetization enables the visualization of the length and width of a crack. The inspection system provides the images of the crack, and shows a possibility for the computation of its depth.

  • PDF

2D-QSAR Analyses on The Tyrosinase Inhibitory Activity of 2-[(2,6-Dioxocyclohexyl)methyl]-cyclohexane-1,3-dione Analogues (2-[(2,6-Dioxocyclohexyl)methyl]cyclohexane-1,3-dione 유도체의 Tyrosinase 저해활성에 관한 2D-QSAR 분석)

  • Kim, Sang-Jin;Sung, Nack-Do
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.40 no.4
    • /
    • pp.383-390
    • /
    • 2014
  • The following conclusion was made from the 2D-QSAR model for the tyrosinase inhibitory activity according to the variation of the substituents R1 and R2 in analogues of compound 2-[(2,6-dioxocyclohexyl)methyl]cyclohexane- 1,3-dione (1-23). The best optimized 2D-QSAR model was $Obs.pI_{50}=-0.295({\pm}0.031)TDM$ $-0.120({\pm}0.014)DMZ+0.135({\pm}0.050)DMX.R_2+6.382({\pm}0.17)$, and the correlation $r^2=0.905$) of which was greater than its predictability ($q^2=0.843$). The magnitude of the effect of tyrosinase inhibitory activities was in order of TDM > $DMX.R_2{\geq}DMZ$, and it tended to increase as the hydrophobicity of substrate molecule (ClogP > 0) as well as the steric favor of substituent $R_1$ increased. The analysis of the model implies that inhibitory activity of substrate molecule will increase as $DMX.R_2$ (Dipole moment X component of $R_2$-substituent) increases, while TDM (Total Dipole Moment) and DMZ(Dipole Moment of Z-Component) decrease. As such, it is deemed feasible to conclude, that in order to increase the inhibitory effect, it would be rather desirable to replace the polar groups within the molecules with non-polar functional groups.

Improved performance of n-type organic field-effect transistor with a non-conjugated polyelectrolyte layer

  • Park, Yu Jung;Cha, Myoung Joo;Lee, Jin Hee;Cho, Shinuk;Seo, Jung Hwa;Walker, Bright
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2016.02a
    • /
    • pp.151.2-151.2
    • /
    • 2016
  • We characterized the n-type organic field-effect transistors (OFETs) with non-conjugated polyelectrolytes (NPEs) interlayers as the electron injection layer. Novel NPEs with various ions (Cl-, Br-, I-) improved the electron mobility from $5.06{\times}10^{-3}$ to $2.10{\times}10^{-2}cm^2V^{-1}s^{-1}$ in OFETs based [6,6]-Phenyl-$C_{61}$-butyric acid methyl ester (PCBM) when $PEIEH^+I^-$ spin-cast from 0.6% solution was deposited onto the PCBM layer. Reduced electron injection barrier (${\phi}_e$) at NPE/metal electrode interface was induced by dipole formation and led to increase the electron injection and transport. These findings are important for understanding how NPEs function in devices, the improvement of device performance, and the design of new materials for use in optoelectronic devices.

  • PDF

Analysis of Highschool Students' Misconception Textbooks Related to the Declination (편각과 관련된 고등학생들의 오개념 및 교과서 분석)

  • Lee, Gyu-Ho
    • Journal of the Korean earth science society
    • /
    • v.32 no.6
    • /
    • pp.687-703
    • /
    • 2011
  • The declination is an important concept because it is the underlying concept to understand the plate tectonics and also is used to decide one's location by using the compass and the map in real life. So this study surveys the description of declination being used in six of the seventh curriculum earth science II textbooks followed by the investigation of the possible of misconceptions that the highschool students might have. Utilizing an inventory of key concept, this study examines the actual misconceptions of highschool students, and investigates the relationship between misconceptions and textbooks. As a result, highschool students possess some misconceptions particularly with respect to the magnetic north pole which is caused by a lack of explanation about declination and by a wrong illustration. Therefore we suggest that detailed explanations of declination with non-dipole effect and precise illustrations be provided in the textbook for students th have a better understanding about declination.

Theoretical Consideration of Nondestructive Testing by use of Vertical Magnetization and Magneto-Optical Sensor

  • Lee, Jinyi;Tetsuo Shoji;Dowon Seo
    • Journal of Mechanical Science and Technology
    • /
    • v.18 no.4
    • /
    • pp.640-648
    • /
    • 2004
  • This paper describes a new magnetization method for non-destructive testing with magneto-optical sensor (denoted as MO sensor) which have the following characteristic : high observation sensitivity, independence of the crack orientation, and precise imaging of a complex crack geometry such as multiple cracks. When a magnetic field is applied normally to the surface of a specimen which is significantly larger than its defects, approximately the same magnetic charge per unit area occurs on the surface of the specimen. If there is a crack in the specimen, magnetic charge per unit area has the same value at the bottom of the crack. The distribution of the vertical component of the magnetic flux density, B$\_$Z/, is almost uniform over the no-crack area (denoted as B$\_$Z,BASE/), while the magnetic flux density is smaller in the surroundings of the crack(denoted as B$\_$Z,CRACK/) If B$\_$Z, BASE/ is a bit larger than the saturated magnetic flux density of the MO sensor (B$\_$s/) , then small magnetic domains occur over the crack area and a large domain over the non-crack area because B$\_$Z,CRACK/ is smaller than B$\_$s/.

Response of Water Tetramer to Intense Femtosecond Laser Pulses

  • Wang, Zhiping;Xu, Xuefen;Qian, Chaoyi;Wang, Yanbiao;Wang, Xu
    • Current Optics and Photonics
    • /
    • v.1 no.4
    • /
    • pp.278-283
    • /
    • 2017
  • We theoretically study the dynamics of water tetramer in intense femtosecond laser pulses with different frequencies. The simulations are carried out by incorporating the molecular dynamics method non-adiabatically into the time-dependent local-density approximation (TDLDA-MD). Three typical scenarios of water tetramer including the normal vibration with enlarged OH bonds, free OH bonds breaking and the pure Coulomb explosion are presented by investigating the electronic and ionic dynamics. The result indicates that the ionization is enhanced and the corresponding fragmentation effect as well as the damping of the dipole moment are found more notably when increasing the laser frequency especially when the frequency falls in the resonant region of the absorption spectra. The study of the level depletion reveals that the ratio of the emission amount from different levels can be controlled by changing the laser frequency referring to the Keldysh parameter.

Water carrying iron (iii) oxide (Fe3O4) ferrofluid flow and heat transfer due to deceleration of a rotating plate

  • Bhandari, Anupam
    • Structural Engineering and Mechanics
    • /
    • v.82 no.5
    • /
    • pp.679-690
    • /
    • 2022
  • This research effort examines the flow behavior and heat transfer assessment of water carrying iron (iii) oxide magnetic fluid due to a rotating and moving plane lamina under the influence of magnetic dipole. The effect of rotational viscosity and magnetic body force is taken into consideration in the present study. The involvement of the moving disk makes a significant contribution to the velocity distribution and heat transfer in rotational flow. Vertical movement of the disk keeps the flow unsteady and the similarity transformation converts the governing equation of unsteady flow into nonlinear coupled differential equations. The non-dimensional equation in the present system is solved through the finite element procedure. Optimizing the use of physical parameters described in this flow, such results can be useful in the rotating machinery industries for heat transfer enhancement.

Studies on the Estimation of Theromodynamic Properties for the Non-Azeotropic Refrigerant Mixtures (혼합냉매의 열역학적 물성치 추산에 관한 연구)

  • 김민수;김동섭;노승탁;김욱중;윤재호
    • Transactions of the Korean Society of Mechanical Engineers
    • /
    • v.14 no.5
    • /
    • pp.1337-1348
    • /
    • 1990
  • Estimations of the thermodynamic properties are made for the selected binary non-azeotropic refrigerant mixtures including R13B1/R114, R22/R114, R12/R114, R152a/R114, R13B1/R152a and R13B1/R12 using the Peng-Robinson equation of state and mixing rules. In this study, we find that the binary interaction coefficients for the above mixtures have an effect upon the vapor-liquid equilibria and the thermodynamic properties. As the binary interaction coefficient becomes larger, the deviation from the idealized model, say, Raoult`s rule, is obvious. A correlation is proposed to relate the binary interaction coefficient to the difference between the dipole moments op each pure refrigerant. Vapor-liquid equilibrium are also accurately estimated using the binary interaction coefficient. Pressure-enthalpy and temperature-entropy relations are plotted for a certain composition ratio of each refrigerant mixture. Results show that the estimating method in this study can be applied to the investigation of the thermodynamic properties for the binary non-azeotropic refrigerant mixtures.