• Title/Summary/Keyword: non-$CO_2$ gas

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Study of High Temperature Corrosion Behavior of Fe-Cr Steel in Sewage Sludge-(SO2-O2-H2O-bal. CO2) mixed Gas Environment (하수슬러지-(SO2-O2-H2O-bal. CO2) 혼합 가스 분위기에서 Fe-Cr 강의 고온부식거동 연구)

  • Kim, Min Jung;Park, Joo Chang;Ryu, In Sun
    • Journal of the Korean institute of surface engineering
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    • v.53 no.2
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    • pp.72-79
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    • 2020
  • Two Fe-Cr steels of T22 steel and STS430 steel were corroded at 650 and 750℃ for 100hr in sewage sludge-(0.3% SO2-6% O2-10% H2O-balance CO2) mixed gas environment. T22 steel corroded faster than STS430, indicating that the Cr content significantly influence the corrosion rates. T22 formed thick and non-protective Fe2O3 as the major oxide and Fe3O4 as the minor one. With an increase in corrosion temperature, their corrosion rates increased, being accompanied with formation of pores and cracks in the thickened oxide scales that were non-adherent. STS430 steel formed Fe2O3, Fe3O4 as the outer scale and (Fe, Cr)-O as the inner layer by which its corrosion rate is greatly reduced. Both the T22 and STS430 steel samples formed multi-layered scales by outward diffusion of Fe ions and inward diffusion of oxygen and sulfur ions at high-temperature more than 650℃.

Probing the Conditions for the Atomic-to-Molecular Transition in the Interstellar Medium

  • Park, Gyueun;Lee, Min-Young
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.1
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    • pp.50.2-51
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    • 2021
  • Stars form exclusively in cold and dense molecular clouds. To fully understand star formation processes, it is hence a key to investigate how molecular clouds form out of the surrounding diffuse atomic gas. With an aim of shedding light in the process of the atomic-to-molecular transition in the interstellar medium, we analyze Arecibo HI emission and absorption spectral pairs along with TRAO/PMO 12CO(1-0) emission spectra toward 58 lines of sight probing in and around molecular clouds in the solar neighborhood, i.e., Perseus, Taurus, and California. 12CO(1-0) is detected from 19 out of 58 lines of sight, and we report the physical properties of HI (e.g., central velocity, spin temperature, and column density) in the vicinity of CO. Our preliminary results show that the velocity difference between the cold HI (Cold Neutral Medium or CNM) and CO (median ~ 0.7 km/s) is on average more than a factor of two smaller than the velocity difference between the warm HI (Warm Neutral Medium or WNM) and CO (median ~ 1.7 km/s). In addition, we find that the CNM tends to become colder (median spin temperature ~ 43 K) and abundant (median CNM fraction ~ 0.55) as it gets closer to CO. These results hints at the evolution of the CNM in the vicinity of CO, implying a close association between the CNM and molecular gas. Finally, in order to examine the role of HI in the formation of molecular gas, we compare the observed CNM properties to the theoretical model by Bialy & Sternberg (2016), where the HI column density for the HI-to-H2 transition point is predicted as a function of density, metallicity, and UV radiation field. Our comparison shows that while the model reproduces the observations reasonably well on average, the observed CNM components with high column densities are much denser than the model prediction. Several sources of this discrepancy, e.g., missing physical and chemical ingredients in the model such as the multi-phase ISM, non-equilibrium chemistry, and turbulence, will be discussed.

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A Study on Concentration Detection Technology of Air Mixing Gas according to Temperature Variation for Refrigerator Foam System (온도변화에 따른 냉장고 발포시스템용 에어믹싱가스 농도검출기술에 관한 연구)

  • Koo, Yeong-Mok;Yang, Jun-Suk;Jo, Sang-Young;Kim, Min-Seong;Noh, Chun-Su
    • Journal of the Korean Society of Industry Convergence
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    • v.19 no.2
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    • pp.95-100
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    • 2016
  • This study proposes the temperature compensation algorithm using thermopile detector for non-dispersive infrared Nitrogen gas sensor. From the output voltage of thermistor that is attached onto the infrared detector, the ambient temperature was extracted. The effects of temperatures on the properties of sensor module characteristics of narrow bandpass filter, optical cavity and infrared lamp, and air mixing gas have been introduced in order to implement the temperature compensation algorithm.

Measurement of Flow and Scalar Distribution at Gas Turbine Inlet Section (가스터빈 입구에서의 유동 및 스칼라 분포 특성)

  • Hong, Sung-Kook;Ireland, Peter;Denman, Paul
    • The KSFM Journal of Fluid Machinery
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    • v.13 no.4
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    • pp.45-50
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    • 2010
  • The goal of paper is to investigate the flow and scalar distribution through the HP Nozzle Guide Vane (NGV) passage. Flow and scalar distribution measurement are conducted by using 5-hole pressure probe and $CO_2$ tracing technique, respectively. Three different experimental cases are considered depending on cooling flow condition. The result shows that the vortical secondary flow patterns are observed clearly and these flow characteristics maintain through the NGV passage regardless of cooling flow injection. Compared to center region, the high axial velocity flow is observed near wall region due to cooling flow injection. Without cooling flow, the $CO_2$ (scalar) distribution becomes to be uniform quickly due to the strong flow mixing phenomenon. However, in cases of cooling flow, scalar distribution is significantly non-uniform.

Effects of Film Packaging and Gas Composition on the Distribution and Quality of Ginseng Sprouts (새싹인삼의 필름포장과 가스조성이 품질특성에 미치는 영향)

  • Chang, Eun Ha;Lee, Ji Hyun;Choi, Ji Weon;Shin, Il Sheob;Hong, Yoon Pyo
    • Korean Journal of Medicinal Crop Science
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    • v.28 no.2
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    • pp.152-166
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    • 2020
  • Background: Ginsenosides, which have various physiological activities, are known to be abundant in the leaves and roots of ginseng. Ginseng sprouts can be used as a fresh vegetable and roots, stems, and leaves of ginseng can be consumed. This study aimed to investigate the effect of carbon dioxide treatment and the modified atmosphere (MA) packaging method in suppressing quality deterioration during the distribution of ginseng sprouts. Methods and Results: Ginseng sprouts were packed using Styrofoam, barrier film + non gas treatment, barrier film + gas treatment, 15 ㎛ polyamide (PA) double film + non gas treatment, 15 ㎛ PA double film + gas treatment, 25 ㎛ PA film + non gas treatment, or 25 ㎛ PA film + gas treatment. Quality parameters including gas composition, relative humidity, chlorophyll SPAD (Soil Plant Analysis Development) value, firmness, and rate of quality loss in ginseng sprouts were monitored at the following temperatures: 20℃, and 10℃. Ginseng sprouts packaged with 25 ㎛ PA film showed loss in quality because of wilting owing to low relative humidity within the film. Chlorophyll and firmness did not differ between film and gas treatments. The time point at which the combined loss from softening and decay owing to fungal, and bacterial infection and wilt reached 20% was considered the limit of distribution. At 20℃, the packaging not included in the 20% distribution loss rate limit or up to 7 days was 15 ㎛ PA double film + gas treatment. At 10℃, the packaging not included in the 20% distribution loss rate limit for up to 18 days were barrier film + gas treatment and 15 ㎛ PA double film + gas treatment. Conclusions: The film packaging suitable for the distribution of ginseng sprouts was found to be the barrier film and PA film with low gas permeability and maintaining hygroscopicity at 95% relative humidity. To prevent the loss in quality of ginseng sprouts, gas treatment (8% of O2 and 18% of CO2) in the film was found to be more suitable than no gas treatment for inhibition of decay.

Removal of Styrene Using Different Types of Non-Thermal Plasma Reactors (저온플라즈마 반응기의 형태에 따른 스타이렌 분해 특성에 관한 연구)

  • Park, Jeong-Uk;Choi, Kum-Chan;Kim, Hyun-Ha;Ogata, Atsushi;Futamura, Shigeru
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.2
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    • pp.215-223
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    • 2005
  • Non-thermal plasma decomposition of gas-phase styrene was investigated in this study using three different types of plasma reactors; dielectric-barrier discharge (DBD) reactor, surface discharge (SD) reactor and plasma-driven catalyst (PDC) reactor packed with 2.0 wt% $Ag/TiO_2$ catalysts. The main parameters used for the comparative assessment of the plasma reactors include the decomposition efficiency, carbon balance, byproduct distribution, COx ($CO+CO_2$) selectivity and COx yield. The SD and the DBD reactors showed better conversion efficiency of styrene than that of the PDC reactor due to their larger capability in ozone formation. On the other hand, the PDC reactor showed better carbon balance, the yield and the selectivity of COx. The required specific input energies to achieve 100% carbon balance from the decomposition of 100 ppmv styrene using the plasma alone reactors and the PDC reactor were 420 J/L and 110 J/L, respectively. The major decomposition products in gas-phase were CO, $CO_2$ and HCOOH regardless of the types of plasma reactors. In the case of SD and DBD reactors, the $CO_2$ selectivity ranged in $39.5{\sim}60%$. The $CO_2$ selectivity in the PDC reactor was in range of $68.5{\sim}75.5%$.

Speculation of Optical Cavity for Improving Optical Gas Sensor's Characteristics (광학적 가스센서 특성 향상을 위한 광 공동 구조의 고찰)

  • Yi, Seung-Hwan;Park, Jong-Seon
    • Journal of the Korean Institute of Gas
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    • v.12 no.4
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    • pp.63-68
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    • 2008
  • This paper describes about the simulation and the experimental results of optical cavity with curved mirror surface and vertical mirror surface to improve the light intensity and efficiency of the optical sensors. When we use the vertical mirror surface, the distribution of light reached to the filter surface of detector shows an elliptical shape. Whereas, the curved mirror surface focuses the light into circular shape. Therefore, due to focusing effects in case of using curved mirror surface, the light intensity per unit area has been improved. Consequently, the output voltage of gas sensor has been expected to increase. Based upon the simulation, the experiment of gas sensor has been conducted with $CO_2$ gas from 0ppm to 2,500 ppm at 250 ppm step and $25^{\circ}C$, 45%R.H. ambient. The output voltage of gas sensor that has a curved mirror surface increases approximately 200 mV than that of vertical mirror surface.

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Fabrication and Characteristics of C(IG)(SeS)2 Absorbers by Selenization and Sulfurization

  • Son, Young-Ho;Jung, Myoung-Hyo;Choi, Seung-Hoon;Choi, Jung-Kyu;Kim, Jin-Ha;Lee, Dong-Min;Park, Joong-Jin;Lee, Jang-Hee;Jung, Eui-Chun;Kim, Jung-Hun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.361-361
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    • 2011
  • Cu(InGa)(SeS2) (CIGS) thin film solar cells have recently reached an efficiency of 20%. Recent studies suggest a double graded band gap structure of the CIGS absorber layer to be a key issue in the production of high efficiency thin film solar cell using by sputtering process method. In this study, Cu(InGa)(SeS2) absorbers were manufactured by selenization and surfulization, we have deposited CIG precusor by sputtering and Se layer by evaporation before selenization. The objective of this study is to find out surfulization effects to improve Voc and to compare with non-surfulization Cu(InGa)Se2 absorbers. Even if we didn't analysis Ga depth profile of Cu(InGa)(SeS2) absorbers, we confirmed increasing of Eg and Voc through surlization process. In non-surfulization Cu(InGa)Se2 absorbers, Eg and Voc are 0.96eV and 0.48V. Whereas Eg and Voc of Cu(InGa)(SeS2) absorbers are 1.16eV and 0.57V. And the efficiency of 9.58% was achieved on 0.57cm2 sized SLG substrate. In this study, we will be discussed to improve Eg and Voc through surfulization and the other method without H2S. gas.

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Comparison of catalytic activity through gas-solid reaction models in CO2 gasification of lignite with alkali metal salts and iron sulfate (알칼리금속염과 철황산염을 촉매로 한 갈탄의 CO2 가스화반응에서 기체-고체 반응모델을 적용한 촉매활성의 비교)

  • Bungay, Vergel C.;Song, Byungho
    • Journal of Energy Engineering
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    • v.23 no.1
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    • pp.58-66
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    • 2014
  • Catalytic gasification of a low rank coal- Inner Mongolian lignite has been carried out with carbon dioxide. The gasification reactions were performed in a thermogravimetric analyzer at temperatures of $600^{\circ}C$ to $900^{\circ}C$. The kinetic parameters were evaluated using three different gas-solids reaction models and the prediction ability of each model were compared. Among the models evaluated, the modified volumetric model was found to correlate best both the non-catalytic and catalytic gasification reactions. The theoretical models, homogeneous and shrinking-core models, were found to satisfactorily correlate gasification reactions for the non-catalytic and $FeSO_4$-catalyzed reactions. In case of alkali metal catalysts, the catalytic activity was mostly pronounced at a low temperature of $600^{\circ}C$ and observed to decrease by 50% as the temperature was increased to $700^{\circ}C$, and it remained nearly constant at temperature over $800^{\circ}C$. The order of catalytic activity was found to be: $K_2CO_3$ > $Na_2CO_3$ > $K_2SO_4$ > $FeSO_4$.

Temperature and Concentration measurement using Semi-conductor diode laser (반도체레이져를 이용한 온도 및 농도의 계측)

  • Chung, D.H.;Noh, D.S.;Ikeda, Yuji
    • 한국연소학회:학술대회논문집
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    • 2000.12a
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    • pp.168-174
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    • 2000
  • A diode laser sensor system based on absorption spectroscopy techniques has been developed to measure $CO_2$ concentration and temperature non-intrusively in high temperature combustion environments using a 2.0 ${\mu}m$ DFB(Distributed Feedback) laser. Two optics was fabricated in pig-tail fashion and all optical components were implemented in a single box. The evolution of measurement sensitivity was done using test cell by changing sweep frequency and $CO_2$ concentration. Gas temperature was determined from the ratio of integrated line strengths. Species concentration was determined from the integrated line intensity and the measured temperature. The result show that the system has 2% error in wide operation frequency range and accuracy of $CO_2$ concentration was about 3%. The system was applied to measure temperature and concentration in the combustion region of a premixed $CH_4$ +air triangular flame. The measurement results of gas temperature agreed well with thermocouple results. Many considerations were taken into account to reduce optical noise, etalon effect, beam steering and base line matching problem. The evaluations results and actual combustion measurement demonstrate the practical and applicability for in-situ and real time combustion monitoring in a practical system.

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