• Title/Summary/Keyword: noble gas

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Hydrogeochemistry and Origin of $CO_2$ and Noble Gases in the Dalki Carbonate Waters of the Chungsong Area (청송 달기탄산약수의 수리지화학과 탄산 및 영족기체 기원)

  • Jeong, Chan-Ho;Kim, Kyu-Han;Nagao, Keisuke
    • The Journal of Engineering Geology
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    • v.22 no.1
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    • pp.123-134
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    • 2012
  • Hydrochemical analyses, carbon isotopic (${\delta}^{13}C_{DIC}$) analyses, and noble gas isotopic ($^3He/^4He$ and $^4He/^{20}Ne$) analyses of the Dalki carbonate waters in the Chungsong area were carried out to elucidate their hydrochemical composition and to determine the source of $CO_2$ gas and noble gases. The carbonate waters have a pH of between 5.93 and 6.33, and an electrical conductivity 1950 to $3030{\mu}S/cm$. The chemical composition of all carbonate waters was Ca(Mg)-$HCO_3$, with a high Na content. The contents of Fe, Mn, and As in some carbonate waters exceed the limit stipulated for drinking water. The concentrations of major ions are slightly higher than those reported previously. The ${\delta}^{13}C_{DIC}$ values range from -6.70‰ to -4.47‰, indicating that the carbon originated from a deep-seated source. The $^3He/^4He$ and $^4He/^{20}Ne$ ratios vary from $7.67{\times}10^{-6}$ to $8.38{\times}10^{-6}$ and from 21.32 to 725.7, respectively. On the $^3He/^4He$ versus $^4He/^{20}Ne$ diagram, the noble gas isotope ratios plot in the field of a deep-seated source, such as mantle or magma. We therefore conclude that $CO_2$ gas and noble gas in the Dalki carbonate waters originated from a deep-seated source, rather than an inorganic $CO_2$ origin as suggested in a previous study.

Emission Properties of Electrodeless Sulfur Lamp by Additives (화합물 첨가에 따른 무전극 황램프의 발광특성)

  • Lee, Jong-Chan;Kim, Kwang-Soo;Park, Dae-Hee;Hwang, Myung-Keun;Park, Cheol-Soon
    • Proceedings of the KIEE Conference
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    • 2002.07c
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    • pp.1890-1892
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    • 2002
  • The technology of sulfur lamps that has physical and electrical characteristics comparable to current HID source has been reported. The fundamental principles of the operation of microwave discharges that are used to convert microwave energy to broad spectrum visual light are known. In this paper, emission dependance of microwave discharges in mixture content of sulfur with noble gases was studied. It is shown that the excitation of this gaseous mixture is carried out in two phases: (l) ionization of noble gas atoms by a microwave field and (2) the consequent maintenance of slightly ionized nonequilibrium plasma by the field. These two processes have essentially various thresholds for the microwave pump. The purpose of this work is to investigate spectral properties of the high frequency discharges in a mixture sulfur vapors with noble gases.

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Fabrication and NOx Sensing Characteristics of $WO_{3}$ Based Thick Film Devices Doped with $TiO_{2}$ and Noble Metals ($TiO_{2}$와 귀금속을 첨가한 $WO_{3}$ 후막 센서의 제조 및 NOx 감응 특성)

  • Lee, Dae-Sik;Han, Sang-Do;Son, Young-Mok;Lee, Duk-Dong
    • Journal of Sensor Science and Technology
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    • v.6 no.4
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    • pp.274-279
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    • 1997
  • NOx sensors using tungsten oxide films as a base material were prepared and their electrical and sensing characteristics have been investigated. The $WO_{3}$ thick films doped with $SnO_{2}$ or $TiO_{2}$ showed higher sensitivity and better sorption characteristics to NOx gas than the pure $WO_{3}$ films material in air at operating temperature of $400^{\circ}C$. By addition of noble catalysts, such as Ru or Au, to the $TiO_{2}-WO_{3}$ thick films, their sensitivity, recovery and selectivity to NOx gas were found to be more enhanced.

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Determination of escape rate coefficients of fission products from the defective fuel rod with large defects in PWR

  • Pengtao Fu
    • Nuclear Engineering and Technology
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    • v.55 no.8
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    • pp.2977-2983
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    • 2023
  • During normal operation, some parts of the fission product in the defective fuel rods can release into the primary loops in PWR and the escape rate coefficients are widely used to assess quantitatively the release behaviors of fission products in the industry. The escape rate coefficients have been standardized and have been validated by some drilling experiments before the 1970s. In the paper, the model to determine the escape rate coefficients of fission products has been established and the typical escape rate coefficients of noble gas and iodine have been deduced based on the measured radiochemical data in one operating PWR. The result shows that the apparent escape rate coefficients vary with the release-to-birth and decay constants for different fission products of the same element. In addition, it is found that the escape rate coefficients from the defective rod with large defects are much higher than the standard escape rate coefficients, i.e., averagely 4.4 times and 1.8 times for noble gas and iodine respectively. The enhanced release of fission products from the severe secondary hydriding of several defective fuel rods in one cycle may lead to the potential risk of the temporary shutdown of the operating reactors.

Factors Affecting the Minimum Detectable Activity of Radioactive Noble Gases (방사성 노블가스 측정을 위한 최소검출방사능 산출의 조절인자)

  • Park, Ji-young;Ko, Young Gun;Kim, Hyuncheol;Lim, Jong-Myoung;Lee, Wanno
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.3
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    • pp.301-308
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    • 2018
  • Anthropogenic radioactive noble gases formed by nuclear fission are significant indicators used to monitor the nuclear activity of neighboring countries. In particular, radioactive xenon, owing to its abundant generation and short half-life, can be used to detect nuclear testing, and radioactive krypton has been used as a tracer to monitor the reprocessing of nuclear fuels. Released radioactive noble gases are in the atmosphere at infinitesimal amounts due to their dilution in the air and their short half-life decay. Therefore, to obtain reliable and significant data when performing measurement of noble gases in the atmosphere, the minimum detectable activity (MDA) for noble gases should be defined as low as possible. In this study, the MDA values for radioactive xenon and krypton were theoretically obtained based on the BfS-IAR system by collecting both noble gases simultaneously. In addition, various MDA methods, confidence level and analysis conditions were suggested to reduce and optimize MDA with an assessment of the factors affecting MDA. The current investigation indicated that maximizing the pretreatment efficiency and performance maintenance of the counter were the most important aspects for Xe. In the case of Kr, since sample activities are much higher than those of Xe, it is possible to change the target MDA or to simplification of the analysis system.

Fabrication of catalytic combustible gas sensor for hydrocarbon gas detection (탄화수소계 가스 감지용 접촉연소식 가스센서의 제조)

  • Park, Hyo-Derk;Lee, Jae-Suk;Kim, Kun-Nyun;Park, Jong-Wan;Shin, Sang-Mo
    • Journal of Sensor Science and Technology
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    • v.3 no.3
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    • pp.9-15
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    • 1994
  • Catalytic combustible gas sensors were fabricated by using ${\gamma}-Al_{2}O_{3}$ with large surface area and noble metal catalysts. The optimum conditions for ${\gamma}-Al_{2}O_{3}$ fabrication were investigated by DT/TGA and XRD analyses and it was found that fabricated ${\gamma}-Al_{2}O_{3}$ had superior value as surface area of $215.5m^{2}/g$. Gas sensors were manufactured and tested to inflammable gases by using Pt coil as a heater and temperature sensing part, fine ${\gamma}-Al_{2}O_{3}$ powder as a bead material and Pt, Pd noble metal powder as a catalyst. From the results, fabricated sensor showed good sensitivity to LPG and LNG of 20mV/l000ppm, 6.5mV/l000ppm respectively.

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Study of atmosphere parameters of the IVV-2M reactor hall

  • M.E. Vasyanovich;M.V. Zhukovsky;E.I. Nazarov;I.M. Russkikh
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.3935-3939
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    • 2023
  • The paper presents the results of a study of radioactive noble gases and from decay products in the atmosphere of the reactor hall of the research nuclear reactor IVV-2M. The distribution of short-lived 88Rb and 138Cs activity by sizes of aerosol particles was measured in the range of 0.5-1000 nm. It is shown that radioactive aerosols are characterized by three main modes with AMTD 2-3 nm, 7-15 nm and 400 nm. About 70% of aerosol activity is due to 88Rb. The equilibrium factor between 88Kr and 88Rb is 0.2 ± 0.1. The total concentration of aerosols particles was measured using an aerosol diffusion spectrometer. The value of unattached fraction of radioactive aerosols in the atmosphere of reactor hall IVV2M was f = 0.15-0.25 at the average total aerosol particles concentration from 20,000 cm3 to 53,000 cm3.

Hydrochemistry and Noble Gas Isotopes of Groundwaters around the Fault Zones (단층대 지하수의 수리화학 및 노블가스 동위원소 특성)

  • Jeong, Chan Ho;Choi, Hyeon Young;Lee, Yong Cheon;Lee, Yu Jin;Yang, Jae Ha
    • The Journal of Engineering Geology
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    • v.26 no.4
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    • pp.551-559
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    • 2016
  • The chemical composition and noble gas isotopes of 10 deep groundwater samples were analyzed to know the circulation of groundwaters in the Yangsan fault and the Gampo fault. The chemical types of groundwaters show the $Ca-HCO_3$ type and $Ca-SO_4(Cl)$ type, and show indistinct relationship with geology. Noble gas isotopic data of most groundwaters were plotted along the air-crust mixing line on $^3He/^4He$ vs. $4^He/^{20}Ne$ diagram, and show dominant $^3He$ of air origin except one sample that shows helium mixing of crust origin. This indicates that groundwater actively circulates along fault, and fault could not play an role of upward pathway of a deep-seated helium gas. A comparatively high $^4He$ indicates that groundwater flows in an aquifer assuring relatively enough water-rock interaction.

Humidity Dependence Removal Technology in Oxide Semiconductor Gas Sensors (산화물 반도체 가스 센서의 습도 의존성 제거 기술)

  • Jiho Park;Ji-Wook Yoon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.4
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    • pp.347-357
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    • 2024
  • Oxide semiconductor gas sensors are widely used for detecting toxic, explosive, and flammable gases due to their simple structure, cost-effectiveness, and potential integration into compact devices. However, their reliable gas detection is hindered by a longstanding issue known as humidity dependence, wherein the sensor resistance and gas response change significantly in the presence of moisture. This problem has persisted since the inception of oxide semiconductor gas sensors in the 1960s. This paper explores the root causes of humidity dependence in oxide semiconductor gas sensors and presents strategies to address this challenge. Mitigation strategies include functionalizing the gas-sensing material with noble metal/transition metal oxides and rare-earth/rare-earth oxides, as well as implementing a moisture barrier layer to prevent moisture diffusion into the gas-sensing film. Developing oxide semiconductor gas sensors immune to humidity dependence is expected to yield substantial socioeconomic benefits by enabling medical diagnosis, food quality assessment, environmental monitoring, and sensor network establishment.