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Synthesis of Zirconium Oxide Nanoballs Using Colloid-Imprinted Carbon and Their Electrical Properties

  • Kim, Chy Hyung
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.2
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    • pp.86-89
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    • 2015
  • Uniform ZrO2 nanoballs were synthesized at 700℃ using the inverse replication method through a colloid-imprinted carbon (CIC) template. The structural, dielectric, and conducting properties of the ZrO2 nanoballs were investigated and compared with those of ZrO2 film prepared by sol-gel method and powdered ZrO2 chemical. Both the monoclinic and cubic phases were found in the ZrO2 balls and film but the ZrO2 chemical showed a monoclinic phase, where the cubic structure is known to be formed at above 2,300℃. ZrO2 nanoballs showed the lower dielectric property of k = 21.2 at 1 MHz because the 8-coordinated cubic phase in the ZrO2 nanoball produced lower polarization than the polarization of the 7-coordinated monoclinic ZrO2 chemical (k = 23.6). The dielectric stability was maintained in each ZrO2 ball, film, and chemical under the applied forward and reverse voltage range (−5 to +5 V) at 1 MHz. The ionic conductivities were 7.86 × 10−8/Ω·cm for ZrO2 nanoballs, 3.29 × 10−8/Ω·cm for ZrO2 chemical, and 6.70 × 10−5/Ω·cm for the thickness of 1,053 nm ZrO2 film at room temperature with the electronic contribution being less than 0.006%.

Dielectric Characteristics of the ${Ta_2}{O_5}/{Al_2}{O_3}$ Multilayer Thin Films Processed by Reactive Sputtering (반응성 스퍼터링으로 제조한 ${Ta_2}{O_5}/{Al_2}{O_3}$ 다충박막의 유전특성)

  • Choe, Jae-Hun;O, Tae-Seong
    • Korean Journal of Materials Research
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    • v.11 no.12
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    • pp.1080-1085
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    • 2001
  • Dielectric properties and leakage current characteristics of 100 nm-thick $Ta_2O_5/Al_2O_3$multilayer thin films, which were fabricated by reactive sputtering of$Al_2O_3$and$Ta_2O_5$ successively on top of each other for total 9 layers, have been investigated with variation of the$Al_2O_3$content$(i.e,\;Ta_2O_5/Al_2O_3 \;thickness\;ratio)$.$Ta_2O_5/Al_2O_3$films were amorphous regardless of the$Al_2O_3$content. With increasing the$Al_2O_3$content from 0% to 100%, refractive index of the $Ta_2O_5/Al_2O_3$films decreased linearly from 2.03 to 1.56 and dielectric constant was lowered from 23.9 to 7.7 Variation of the dielectric constant with the$Al_2O_3$content was in good agreement with the behavior that was obtained by assuming parallel capacitors of$Al_2O_3$and Ta_2O_5$. Leakage current characteristics of $Ta_2O_5/Al_2O_3$ multilayer films were superior to those of $Ta_2O_5$ and$Al_2O_3$films. $Ta_2O_5/Al_2O_3$ films of 5% and 10%$Al_2O_3$content exhibited excellent leakage current densities which were lower than $10^{-7} A/cm^2$ at 1MV/cm.

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Effects of SNPs in Haptoglobin on Average Daily Gain in Pig (Haptoglobin SNP의 돼지 일당 증체량에 관한 효과)

  • Kim, Myung-Jick;Chung, Ho-Young;Cho, Kyu-Ho;Jeon, Gi-Jun;Kim, Jin-Hyung
    • Journal of Embryo Transfer
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    • v.23 no.3
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    • pp.197-201
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    • 2008
  • In order to provide information of genetic variants for Haptoglobin (Hp) gene, which may be related to weight traits in pig, a total of 235 animals from National Institute of Animal Science (NIAS) were screened with 3 primers. The primer sequences were selected using the porcine cDNA sequences based on NM_214000, and the exon boundaries were estimated. Genetic variants were observed using direct sequencing analysis, and there were 9 SNPs detected at nucleotide positions 503 (A/G), 509 (A/G), 709 (C/T), 734 (C/A), 742 (G/A), 769 (A/G), 840 (C/T), 876 (C/T) and 882 (C/A). All the SNPs were located in coding regions, and mutations caused amino acid changes at nucleotide positions 503, 509, 734, 742 and 769. Allele frequencies of SNPs were estimated for all segments. The SNPs at nucleotide position 509 (p<0.0001) and 734 (p<0.05) were significantly associated with average daily gain, but no significance was observed with other SNPs. From the results, the identified SNPs may be a useful candidate marker for the porcine weight gain traits.

AB9: A neural processor for inference acceleration

  • Cho, Yong Cheol Peter;Chung, Jaehoon;Yang, Jeongmin;Lyuh, Chun-Gi;Kim, HyunMi;Kim, Chan;Ham, Je-seok;Choi, Minseok;Shin, Kyoungseon;Han, Jinho;Kwon, Youngsu
    • ETRI Journal
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    • v.42 no.4
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    • pp.491-504
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    • 2020
  • We present AB9, a neural processor for inference acceleration. AB9 consists of a systolic tensor core (STC) neural network accelerator designed to accelerate artificial intelligence applications by exploiting the data reuse and parallelism characteristics inherent in neural networks while providing fast access to large on-chip memory. Complementing the hardware is an intuitive and user-friendly development environment that includes a simulator and an implementation flow that provides a high degree of programmability with a short development time. Along with a 40-TFLOP STC that includes 32k arithmetic units and over 36 MB of on-chip SRAM, our baseline implementation of AB9 consists of a 1-GHz quad-core setup with other various industry-standard peripheral intellectual properties. The acceleration performance and power efficiency were evaluated using YOLOv2, and the results show that AB9 has superior performance and power efficiency to that of a general-purpose graphics processing unit implementation. AB9 has been taped out in the TSMC 28-nm process with a chip size of 17 × 23 ㎟. Delivery is expected later this year.

0.11-2.5 GHz All-digital DLL for Mobile Memory Interface with Phase Sampling Window Adaptation to Reduce Jitter Accumulation

  • Chae, Joo-Hyung;Kim, Mino;Hong, Gi-Moon;Park, Jihwan;Ko, Hyeongjun;Shin, Woo-Yeol;Chi, Hankyu;Jeong, Deog-Kyoon;Kim, Suhwan
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.17 no.3
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    • pp.411-424
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    • 2017
  • An all-digital delay-locked loop (DLL) for a mobile memory interface, which runs at 0.11-2.5 GHz with a phase-shift capability of $180^{\circ}$, has two internal DLLs: a global DLL which uses a time-to-digital converter to assist fast locking, and shuts down after locking to save power; and a local DLL which uses a phase detector with an adaptive phase sampling window (WPD) to reduce jitter accumulation. The WPD in the local DLL adjusts the width of its sampling window adaptively to control the loop bandwidth, thus reducing jitter induced by UP/DN dithering, input clock jitter, and supply/ground noise. Implemented in a 65 nm CMOS process, the DLL operates over 0.11-2.5 GHz. It locks within 6 clock cycles at 0.11 GHz, and within 17 clock cycles at 2.5 GHz. At 2.5 GHz, the integrated jitter is $954fs_{rms}$, and the long-term jitter is $2.33ps_{rms}/23.10ps_{pp}$. The ratio of the RMS jitter at the output to that at the input is about 1.17 at 2.5 GHz, when the sampling window of the WPD is being adjusted adaptively. The DLL consumes 1.77 mW/GHz and occupies $0.075mm^2$.

Photoactivities of Nanostructured α-Fe2O3 Anodes Prepared by Pulsed Electrodeposition

  • Lee, Mi Gyoung;Jang, Ho Won
    • Journal of the Korean Ceramic Society
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    • v.53 no.4
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    • pp.400-405
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    • 2016
  • Ferric oxide (${\alpha}-Fe_2O_3$, hematite) is an n-type semiconductor; due to its narrow band gap ($E_g=2.1eV$), it is a highly attractive and desirable material for use in solar hydrogenation by water oxidation. However, the actual conversion efficiency achieved with $Fe_2O_3$ is considerably lower than the theoretical values because the considerably short diffusion length (2-4 nm) of holes in $Fe_2O_3$ induces excessive charge recombination and low absorption. This is a significant hurdle that must be overcome in order to obtain high solar-to-hydrogen conversion efficiency. In consideration of this, it is thought that elemental doping, which may make it possible to enhance the charge transfer at the interface, will have a marked effect in terms of improving the photoactivities of ${\alpha}-Fe_2O_3$ photoanodes. Herein, we report on the synthesis by pulsed electrodeposition of ${\alpha}-Fe_2O_3$-based anodes; we also report on the resulting photoelectrochemical (PEC) properties. We attempted Ti-doping to enhance the PEC properties of ${\alpha}-Fe_2O_3$ anodes. It is revealed that the photocurrent density of a bare ${\alpha}-Fe_2O_3$ anode can be dramatically changed by controlling the condition of the electrodeposition and the concentration of $TiCl_3$. Under optimum conditions, a modified ${\alpha}-Fe_2O_3$ anode exhibits a maximum photocurrent density of $0.4mA/cm^2$ at 1.23 V vs. reversible hydrogen electrode (RHE) under 1.5 G simulated sunlight illumination; this photocurrent density value is about 3 times greater than that of unmodified ${\alpha}-Fe_2O_3$ anodes.

박막 표면 결정성에 대한 Nano-Indenter 압입 각도 차이의 nano-electrotribology 특성 변화 연구

  • Lee, Jae-Hun;Kim, Su-In;Kim, Hong-Gi;Kim, Min-Ho;Kim, Min-Jun;Park, Bo-Gyeom;Lee, Seok-Won;Hong, Gi-Taek;Lee, Chang-U
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.176.2-176.2
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    • 2015
  • 기존의 트라이볼로지 분석 기법은 macro 영역에서 시료의 강도 및 탄성 등의 물성을 분석하는 정도였으나 Nano-Indenter 분석 기법은 macro 영역보다 더 미세한 nano 영역에서의 시료 물성 분석을 가능하게 해주었다. 따라서 본 연구에서는 시료들의 결정 배양 방향에 따른 Nano-Indenter 압입 각도 차이에 대한 nano 영역에서의 연구를 진행하였다. Si 기판 외에 본 연구에 사용 된 HfN 및 Zr 박막의 시료들은 rf magnetron sputter를 이용하여 약 100 nm 두께로 증착하였다. 각각 시료들에 대한 결정성 확인을 위해 XRD 분석을 실시하였다. 이후 Nano-Indenter를 이용하여 압입 인가력 대비 압입 깊이를 측정하였다. 이 과정에서 Nano-Indenter 압입 각도를 $0^{\circ}$$90^{\circ}$로 변화함에 따라 압입 인가력 - 압입 깊이 그래프의 차이를 확인하였고 이를 기준점으로 부터 $10{\mu}m$ 이격시켜 16회 반복 측정과 Weilbull distribution을 통해 신뢰도를 향상시켰다. 측정 결과 Zirconium(Zr) 박막의 경우 21.53 GPa과 22.18 GPa 측정되었으나 Si 기판은 17.46 GPa 16.33 GPa으로, 그리고 HfN 박막의 경우 25.18 GPa과 27.75 GPa으로 상대적으로 큰 차이를 확인하였다. Si 기판과 HfN의 측정결과 Weibull distribution는 75.02와 70.23인 반면 Zr 박막은 30.94로 상대적으로 불균일한 특성을 확인하였다. 이 결과들로부터 각각의 박막 결정 배양 방향에 따른 분석의 한가지 방법으로 Nano-Indenter 분석 기법을 사용할 수 있는 가능성을 확인하였다.

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Effect of the low level light irradiation to NTacSam:SD tissue cell culture (NTacSam:SD의 조직세포 배양에 저출력 광원의 효과)

  • Kim, Tae-Gon;Kim, Toung-Pyo;Park, No-Bong;Lee, Ho-Sic;Park, Yong-Pil;Cheon, Min-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.423-423
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    • 2009
  • Currently, lasers are one of the most popular light sources in use for medical treatment. Many studies on low power lasers are being done in cell culture or through animal tests and most report different findings, making it difficult to verify their true effects. There are shifts in trends of studies from laser and LED that are expensive and generate heat problem to LED that are economically effective and safe. Its near infrared rays can penetrate deep into skin or muscle, up to 23 cm, without causing thermal damage or impairing neighboring tissues. This study verified the performance and effectiveness of an LED irradiator that was designed to emit similar wavelengths to that of a laser and thus could be used instead of a low level laser therapy in experiments on animals. And then, each experiment was performed to irradiation group and non-irradiation group for NTacSam:SD tissue cells. MIT assay method was chosen to verify the cell increase of two groups and the effect of irradiation on cell proliferation was examined by measuring 590nm transmittance of ELISA reader. As a result, the cell increase of NTacSam:SD tissue cells was verified in irradiation group as compared to non-irradiation group. The fact that specific wavelength irradiation has an effect on cell vitality and proliferation is known through this study.

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Development of Neuromuscular Stimulus System using Wearable Ultra-miniature Lighting Modules and its Verification of Clinical Effectiveness (의복형 초소형 발광모듈을 이용한 신경근육 자극 시스템 개발 및 임상적 효과 검증)

  • Park, Se-Hyeong;Lee, Jong-Shill;Kim, In-Young;Kim, Sun-I.
    • Journal of Biomedical Engineering Research
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    • v.30 no.1
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    • pp.23-33
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    • 2009
  • It can be used easily to reduce rehabilitation and treatment time if diagnostic and therapeutic devices are attached to cloth or body. Therefore we developed neuromuscular wearable ultra-miniature lighting modules which can improve the neuromuscular function and verified its clinical effectiveness. The system is based on the ultra-miniature lighting treatment module and there are two types of systems. One of them is designed as an attached type and the other type is combined with clothing. The wearable ultra-miniature lighting module is composed of controller (battery, MCU, bidirectional transmitter and receiver), cable, treatment medium generating device and other peripheral devices. To verify the clinical effectiveness of this device, we observed the difference of the strength of a muscle before and after 650nm and 25mW laser irradiation on the reflex point for 1 to 4 seconds. Among 48 patients having the degenerative osteoarthritis, the muscle strength before and after irradiation of laser was $21.8{\pm}7.99$ and $27.3{\pm}8.43$. According to the result, the muscle strength after treatment was significantly increased (p<0.01). To whom having difficulty in visiting to OPD(Out-Patient Department), doctors medically examine the patients and find the therapeutic point, attachment of this wearable ultra-miniature lighting module can function as self treatment (treating instrument) and treatment assist at home. If doctor can remotely control the patient and take part in treatment, the therapeutic device could contribute to prevention and care device.

Antioxidative Materials in Domestic Meju and Doengjang 3. Separation of Hydrophilic Brown Pigment and Their Antioxidant Activity (재래식 메주 및 된장중의 항산화성 물질에 관한 연구 3. 수용성 갈변물질의 항산화력)

  • 이종호;김미혜;임상선;김성희;김경업
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.23 no.4
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    • pp.604-613
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    • 1994
  • Hydrophilic brown pigments(HBPs) produced during fermentation and aging the domestic Meju and Doenjang were separated by dialysis and chromatography , and their antioxidant activity were measured . The chemical properties of HBP were determined by UV and IR spectrophotometry. HBPs contents were found to be 93.1 mg/g and 183.2mg/g in Meju fermentated for 30 days and 80 days , respectively. The ratio of dialysate to diffusate of the HBPs were appeared to be 70 : 30 and 87 :13 in the Meju fermented for 30 days and 80 days, respectively. and the rtio in the Doenjang aged for 60 days was 91 :9 , indicating that dialysate slowly days, respectively, and the ratio in the Doenjang aged for 60 days was 91 : 9, incidatin that dialysate slowly increased by the fermentation . Both portion exhibited strong antioxidant activity, but more stronger antioxidant activity was found in the dialysate. DEAE-celluose column chromatography showed that dialysate contained more materials eluted by 0.01-0.03M HCI solution than 0.01M acetate buffer, but diffusate showed opposite results. The degree of browning reaction and antioxdiant activity found in the fraction eluted by HCI solution was stronger than that of the fraction eluted by acetate buffer. The fraction eluted from DEAE-cellulose column chormatogrphy was further fractionaged by TLC and found that strong antioxidant activity was present in the fractions which did not possess fluorescenece and showed a negative ninhydrin reaction. TLC fractions of HCI eluant in Meju exhibited a strong absorbance at 260-280nm, but most of other fractions did not show any absorbance at UV region. TLC fractions from dialysate and diffusate showed fairly identical IR spectrum with absorbance at 3400cm-1, 2800cm-3000cm -1, 1600cm, -1 1400cm-1 and 1100 cm-1 , however, in addition to these absorbances, the spectrum from HCI eluant of Meju exhibited a strong absorbance at 1750cm , indicating the carbonic acid or carbonate ester.

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