• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.11
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• pp.3043-3047
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• 2009

Nitrogen solubility and nitride formation in liquid 304 Stainless steel has been measured by sampling method at various temperatures. Also values of thermodynamic functions are determined. Nitrogen solubility in molten 304 Stainless steel is increased with temperature and under the 1atm nitrogen atmosphere, titanium nitride is formed over 0.03wt%Ti in 304Stainless steel. Produced nitride is identified TiN by EDS analysis.

• Korean Journal of Materials Research
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• v.24 no.2
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• pp.81-86
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• 2014

The nitrogen solubility and nitride capacity of $CaO-SiO_2-Al_2O_3-MgO-CaF_2$ slag systems were measured by using gas-liquid equilibration at 1773K. The nitrogen solubility of this slag system decreased with increasing CO partial pressure, with the linear relationship between nitrogen contents and oxygen partial pressure being -3/4. This system was expected to show two types of nitride solution behavior. First, the nitrogen solubility decreased to a minimum value and then increased with the increase of CaO contents. These mechanisms were explained by considering that nitrogen can dissolve into slags as "free nitride" at high basicities and as "incorporated nitride" within the network at low basicities. Also, the basicity of slag and nitride capacity were explained by using optical basicity. The nitrogen contents exhibited temperature dependence, showing an increase in nitrogen contents with increasing temperature.

• Applied Biological Chemistry
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• v.32 no.4
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• pp.321-326
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• 1989

Nitrogen and phytate solubility of perilla seed flour were influenced by the following factors: pH, centrifugal force, temperature and the presence of salt. The nitrogen solubility of perilla seed flour was minimum$(17.1{\sim}18.0%)$ at the pH range of $(4.0{\sim}5.0)$ and maximum(92.3%) at pH 11.0, while phytate solubility was the highest(48.5%) at pH 4.8 and lowest(8.3%) at pH 11.0. The phytic acid content in the extract decreased with an increase in centrifugal force. However, the nitrogen content was not affected by centrifugal force. The solubility of nitrogen and phytate gradually increased as the temperature was increased from $5^{\circ}C$ to $60^{\circ}C$ The addition of calcium$(0{\sim}50mM)$ at pH 5.0 decreased the phytate solubility, but increased nitrogen solubility. The solubility of nitrogen and phytate of perilla seed protein isolate was gradually increased as pH raised further. The protein and phytate contents of the perilla seed protein isolate were 1.1 and 89.6%, respectively, compared to 5.0 and 60.1% for perilla seed flour.

• Korean Journal of Materials Research
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• v.21 no.12
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• pp.639-643
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• 2011

Zinc oxide as an optoelectronic device material was studied to utilize its wide band gap of 3.37 eV and high exciton biding energy of 60 meV. Using anti-site nitrogen to generate p-type zinc oxide has shown a deep acceptor level and low solubility. To increase the nitrogen solubility in zinc oxide, group 13 elements (aluminum, gallium, and indium) was co-added to nitrogen. The effect of aluminum on nitrogen solubility in a $3{\times}3{\times}2$ zinc oxide super cell containing 72 atoms was investigated using density functional theory with hybrid functionals of Heyd, Scuseria, and Ernzerhof (HSE). Aluminum and nitrogen were substituted for zinc and oxygen sites in the super cell, respectively. The band gap of the undoped super cell was calculated to be 3.36 eV from the density of states, and was in good agreement with the experimentally obtained value. Formation energies of a nitrogen molecule and nitric oxide in the zinc oxide super cell in zinc-rich conditions were lower than those in oxygen-rich conditions. When the number of nitrogen molecules near the aluminum increased from one to four in the super cell, their formation energies decreased to approach the valence band maximum to some degree. However, the acceptor level of nitrogen in zinc oxide with the co-incorporation of aluminum was still deep.

• Journal of Korea Foundry Society
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• v.4 no.4
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• pp.30-33
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• 1984

Nitrogen solubility in liquid Fe and Fe-C alloys has been measured by the levitation melting method under 1 atm $N_2$ pressure. Experiments were carried out at the temperature range of $1774-2097^{\circ}K$ and carbon content of 0-5.06wt%. The nitrogen solubilities measured in pure Fe and Fe-C alloys were $log(wt%N)_{Fe}=-424/T-1.129$ and $log(wt%N)_{Fe-C}=-[424/T+1.129+(%C)/19.14{5447/T-0.612}+(%C)^2/19.14$ 2478/T-1.265].

• Korean Journal of Materials Research
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• v.17 no.12
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• pp.654-659
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• 2007

Austenite precipitation behavior was studied with solidification rates and alloying contents, N and Cr, in duplex stainless steels by directional solidification. Directional solidification experiments were carried out with solidification rates, $1{\sim}100mm/s$, and N and Cr contents, $0{\sim}0.27wt.%,\;25{\sim}28wt.%$ respectively, in a duplex stainless steel, CD4MCU. As the solidification rate increases, the dendrite spacing reduced and the austenite phase in the ferrite matrix became finer. The volume fraction of austenite phase increased and its shape went to be round with increasing nitrogen contents in duplex stainless alloys. The Cr alloying element, even though it is a ferrite former, showed to enhance the nitrogen solubility in the alloy and caused the austenite round and finer. Also, Cr was supposed to decrease the austenite volume fraction, but it increased the austenite slightly due to increasing nitrogen solubility during solidification.

• Journal of Nutrition and Health
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• v.30 no.1
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• pp.40-47
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• 1997

Dietary peptides have recently received attention regarding their beneficial effects on nutrient metabolism since the caseinphosphoptides obtained from casein hydrolysate are generally believed to enhance the intestinal absorption of Ca. The two experiments were conducted to investigate the effects of various hydrolyzed fractions of gluten on Ca bioavailability. The gluten hydrolysate of dietary components was produced by enzymatic hydrolysis of gluten whereas gluten hydrolysate supernationt and its precipiate resulted from centrifugation. In experiment I, the rats were for 4 weeks fed the 4 kinds of diets containing same amount of nitrogen and calories and diffeing only in the forms of nitrogen sources. The diets were gluten (G), gluten hydrolysat(GH), gluten hydrolysate supernatant(GHS) and gluten hydrolysate precipitatie(GHP). Determination was made for the body weight gain, serum Ca concentration, Ca solubility in small intestinal contents, bone weight, length and stength, bone ash and Ca content, and Ca balance, respectively. No significant difference was noticed as regards growth, serum Ca, and bone dimension and Ca content among rat groups. More significant increase was observed with regard to Ca absorption and intestinal solubility in the rats receiving the GH or GHS diet which containe crude gluten peptides, than in those subjected to G or GHP diet. In experiment II, in vitro determination for Ca solubility was made to ascertain the mechanism responsible for the effects of gluten peptides on Ca absorption. The 10mM Ca in potassium phosphate buffer solution(pH 7.0) incubated for 3 hours at 37$^{\circ}C$ by the GHS fraction, was observed to be capable of increasing the Ca solubility at 5-25mg/ml concentration of gluten peptides. These observations suggest that the gluten peptides from gluten hydrolysate may enhance the Ca absorption efficiency by increasing the solubility of Ca in small intestine.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.568-569
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• 2006

The use of the nickel free, high nitrogen stainless steel powder and nitriding during sintering of iron based materials have been shown as an alternative way to the conventional PM stainless steels containing nickel. Nitrogen as an alloying element for iron improves in an effective way the properties of sintered alloyed steels. The powder metallurgy route is a suitable way to introduce nitrogen into these alloys and, in particular, to produce high nitrogen (close to the solubility limit) stainless steels. The paper presents and discusses the nitriding behavior of nickel-free stainless steels produced by powder metallurgy method. Alloyed melt was atomized by nitrogen and in this way nitrogen was introduced into the powder. Further nitriding occurred during sintering in a nitrogen atmosphere. For comparison, compacts having the same composition as an alloyed powder were produced from elemental powders mixture. Sintering-nitriding behaviour of investigated materials has been controlled by dilatometry, chemical and X-Ray phase analysis and metallography. Mechanical properties of sintered compacts were also measured.

• The Korean Journal of Food And Nutrition
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• v.23 no.1
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• pp.114-117
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• 2010

The effects of isolated soy protein(ISP) content on the physicochemical properties of extrudates from rice flour produced by a single-screw extruder were evaluated. The integrity index(II), nitrogen solubility index(NSI), rehydration ratio(RR), and density were measured as indices of the changes of physicochemical properties of rice extrudates. Increased amounts of ISP resulted in increased II but decreased RR and density. There was no change in the NSI value. It was concluded that the addition of ISP to the raw material could be helpful in texturization of rice extrudate.

• Fire Science and Engineering
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• v.16 no.3
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• pp.26-31
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• 2002

Bromotrifluoromethane(halon-1301) and bromochlorodifluoromethane(halon-1211) have been widely used as a clean fire extinguishing agents due to their outstanding properties. However, production and use of halon are currently being phased out under an international agreements Montreal Protocol because of global environmental concerns and HFCs have been considered as promising alter-natives for the replacement of halon since their ozone depletion potentials are low. The vapor-liquid equilibrium data are required as important basic information in evaluating the solubility of clean fire extinguishing agents and determining their optimal compositions. In this work, we chose HFCs such as HFC-22 HFC-125, and HFC-l34a for gaseous fire extinguishing agents and nitrogen as a pressurization gas for a proper jet velocity of these agents. Phase equilibria for binary mixtures of nitrogen/HFC-22, nitrogen/HFC-125, and nitrogen/HFC-l34a were measured in the temperature range from 283.15K to 303.15K. For equilibrium measurement, we used a circulation type apparatus in which both vapor and liquid phases were continuously recirculated. The experimental data were relatively well correlated with the Peng-Robinson equation of state with Wong-Sandier mixing rules.