• Title/Summary/Keyword: nitrogen mode

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A Study of SiC Trench Schottky Diode with Tilt-Implantation for Edge Termination (Edge Termination을 위해 Tilt-Implantation을 이용한 SiC Trench Schottky Diode에 대한 연구)

  • Song, Gil-Yong;Kim, Kwang-Soo
    • Journal of IKEEE
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    • v.18 no.2
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    • pp.214-219
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    • 2014
  • In this paper, the usage of tilt-implanted trench Schottky diode(TITSD) based on silicon carbide is proposed. A tilt-implanted trench termination technique modified for SiC is proposed as a method to keep all the potentials confined in the trench insulator when reverse blocking mode is operated. With the side wall doping concentration of $1{\times}10^{19}cm^{-3}$ nitrogen, the termination area of the TITSD is reduced without any sacrifice in breakdown voltage while potential is confined within insulator. When the trench depth is set to 11um and the width is optimized, a breakdown voltage of 2750V is obtained and termination area is 38.7% smaller than that of other devices which use guard rings for the same breakdown voltage. A Sentaurus device simulator is used to analyze the characteristics of the TITSD. The performance of the TITSD is compared to the conventional trench Schottky diode.

Decomposition Characteristics of PFCs for Various Plasma Discharge Methods in Dielectric Barrier Discharge (DBD 반응기에서 플라즈마 방전형태에 따른 PFCs 가스의 분해 특성)

  • Kim, Kwan-Tae;Kim, Yong-Ho;Cha, Min-Suk;Song, Young-Hoon;Kim, Seock-Joon;Ryu, Jeong-In
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.5
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    • pp.625-632
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    • 2004
  • Perfluorocompounds ($PFC_s$), such as tetrafluoromethane ($CF_4$) and hexafluoroethane ($C_2F_6$), have been widely used as plasma etching and chemical vapor deposition (CVD) gases for semiconductor manufacturing processes. Since these $PFC_s$ are known to cause a greenhouse effect intensively, there has been a growing interest in reducing $PFC_s$ emissions. Among various $CF_4$ decomposing techniques, a dielectric barrier discharge (DBD) is considered as one of a promising candidate because it has been successfully used for generating ozone ($O_3$) and decomposing nitrogen oxide (NO). Firstly, optimal concentration of oxygen for $CF_4$ decomposition was found to figure out how many primary and secondary reactions are associated with DBD process. Secondary, to find effective discharge method for $CF_4$ decomposition, a streamer and a glow mode in DBD are experimentally compared, which includes (i) coaxialcylinder DBD, (ii) DBD reactor packed with glass beads. and (iii) a glow mode operation with a helium gas. The test results showed that optimal concentration of oxygen was ranged 500 ppm~1% for treating 500 ppm of $CF_4$ and helium glow discharge was the most efficient one to decompose $CF_4$.

A Study on characteristics analysis of autotrophic denitrification microbial community using sulfur granule (황입자를 이용한 T. denitrificans에 의한 질소제거 최적화 연구)

  • Yoon, Su Chul;Joo, Jae-Young;Nam, Duck-Hyun;Park, Chul-Hwi
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.2
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    • pp.259-265
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    • 2008
  • Generally speaking, there are two widely used methods of Nitrogen removal from waste water: 1) nitrification using autotrophic microorganisms, and 2) denitrification using heterotrophic microorganisms. The C/N ratio is an important factor of the denitrification process. In this case, if methanol is added to increase the lacking organic matter, a high economic cost is incurred and methanol is left in the processed water. In an effort to fix these issues, autotrophic denitrification through the use of Hydrogen, Iron and Sulfur is being studied, and among those Sulfur is cheaper and carries out denitrification effectively, and therefore is being studied the most. In this study, after cultivating T. denitrificans, the presence of T. denitrificans was determined and the effectiveness of denitirification via T. denitrificans was studied. In order to find out about the inhibition of T. denitrificans from the loading of organic matter, this shows that the greater the loading of organic matter, the more the denitrification ability of T. denitrificans is hindered. In order to research the hindrance of T. denitrificans resulting from the loading of $NO_3{^-}-N$, these results show that concentrations less than 100mg/L per 100mL of gel volume do not hinder T. denitrificans. In order to research the optimization of denitrification resulting from T. denitrificans, three 500mL samples of Sulfur granules were prepared: 1) one with only T. denitrificans attached (Mode I), 2) one with both T. denitrificans and active sludge attached (Mode II), and 3) one with only active sludge attached (Mode III). The results showed that autotrophic denitrification using S from Mode I was the most active.

A Study on the Characteristics of High Energy Nitrogen ion Implanted CdS Thin Films (고에너지 질소 이온 주입된 CdS 박막 특성에 관한 연구)

  • 이재형;홍석주;양계준
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.7 no.4
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    • pp.712-718
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    • 2003
  • The effects of nitrogen ion implantation on vacuum evaporated cadmium sulphide (CdS) thin films were investigated by X-ray diffraction, optical transmittance spectra, and Raman scattering studies. The as-deposited CdS films have a hexagonal structure with preferential (0 0 2) orientation. Formation of Cd metallic clusters was observed in ion implanted films from the XRD patterns. The band gap of N+ implanted films decreased, whereas the optical absorption coefficient values increased with the increase of implantation dose. The Raman peak position appeared at 299 cm-1 and the FWHM increased with the ion dose. A decrease in the area of Raman peak of CdS Al(LO) mode is seen on implantation.

Raman Spectroscopic Investigations of the Amide-Amide and Amide-Solvent Interactions (아미드-아미드 및 아미드-용매 상호작용에 관한 Raman 분광학적인 연구)

  • Jeong-A Yu;Young-Sang Choi
    • Journal of the Korean Chemical Society
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    • v.27 no.6
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    • pp.399-404
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    • 1983
  • Raman spectra for the carbonyl stretching mode of the amides, and amide-solvent systems have been recorded to investigate the effect of alkyl substitutions at the carbonyl carbon and at the nitrogen on the amide hydrogen-bonding. The data have shown that the interaction affinities are in the order of amide-amide > amide-water > amide-alcohol in formamide system, and amide-water > amide-amide > amide-alcohol in acetamide and propionamide systems. The strength of the proton acceptor of the carbonyl oxygen is increased by the presence of alkyl group to the carbonyl carbon and the proton donorcity of the amide is decreased by the alkyl substitution at the nitrogen. The above results are in good agreement with the ab initio SCF MO calculation.

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Compositional Characterization of Petroleum Heavy Oils Generated from Vacuum Distillation and Catalytic Cracking by Positive-mode APPI FT-ICR Mass Spectrometry

  • Kim, Eun-Kyoung;No, Myoung-Han;Koh, Jae-Suk;Kim, Sung-Whan
    • Mass Spectrometry Letters
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    • v.2 no.2
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    • pp.41-44
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    • 2011
  • Molecular compositions of two types of heavy oil were studied using positive atmospheric pressure photoionization (APPI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). Vacuum gas oil (VGO) was generated from vacuum distillation of atmospheric residual oil (AR), and slurry oil (SLO) was generated from catalytic cracking of AR. These heavy oils have similar boiling point ranges in the range of 210-$650^{\circ}C$, but they showed different mass ranges and double-bond equivalent (DBE) distributions. Using DBE and carbon number distributions, aromatic ring distributions, and the extent of alkyl side chains were estimated. In addition to the main aromatic hydrocarbon compounds, those containing sulfur, nitrogen, and oxygen heteroatoms were identified using simple sample preparation and ultra-high mass resolution FT-ICR MS analysis. VGO is primarily composed of mono- and di-aromatic hydrocarbons as well as sulfur-containing hydrocarbons, whereas SLO contained mainly polyaromatic hydrocarbons and sulfur-containing hydrocarbons. Both heavy oils contain polyaromatic nitrogen components. SLO inludes shorter aromatic alkyl side chains than VGO. This study demonstrates that APPI FT-ICR MS is useful for molecular composition characterization of petroleum heavy oils obtained from different refining processes.

Effects of Two-Stage Injection on Combustion and Exhaust Emission Characteristics in a HCCI Engine (2단분사법에 따른 예혼합압축착화엔진의 연소 및 배기특성)

  • Kook, Sang-Hoon;Park, Cheol-Woong;Choi, Wook;Bae, Choong-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.5
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    • pp.32-39
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    • 2004
  • HCCI (Homogeneous Charge Compression Ignition) combustion has a great advantage in reducing NOx (Nitrogen Oxides) and PM (Particulate Matter) by lowering the combustion temperature due to spontaneous ignitions at multiple sites in a very lean combustible mixture. However, it is difficult to make a diesel-fuelled HCCI possible because of a poor vaporability of the fuel. To resolve this problem, the two-stage injection strategy was introduced to promote the ignition of the extremely early injected fuel. The compression ratio and air-fuel ratio were found to affect not only the ignition, but also control the combustion phase without a need for the intake-heating or EGR (Exhaust Gas Recirculation). The ignition timing could be controlled even at a higher compression ratio with increased IMEP (Indicated Mean Effective Pressure). The NOx (Nitrogen Oxides) emission level could be reduced by more than 90 % compared with that in a conventional DI (Direct Injection) diesel combustion mode, but the increase of PM and HC (Hydrocarbon) emissions due to over-penetration of spray still needs to be resolved.

Production of Compaction from Penicillium sp. Y-8515 (Penicillium sp. Y-8515에 의한 Compactin 생산)

  • 박주웅;이주경;권태종;박용일;강상모
    • Microbiology and Biotechnology Letters
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    • v.28 no.5
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    • pp.291-297
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    • 2000
  • A strain producing high levels of compaction was isolated from soil and identified as Penicillium sp. Y-8515 based on the morphological characteristics and ribosomal RNA sequence analysis. Optimization of several different carbon and nitrogen sources for the effective production of compaction was performed resulting in the medium compositions containing 5%(w/v) glucose, 1.0 % soybean meal, 0.5% yeast extract, 0.5%(NH$_4$)$_2$$SO_4$, 0.25%,$ NaH_2$$PO_4$, 0.25% $CaCO_3$. The fixed con-centration of glucose(5%, w/v) and relatively lower concentrations(less than 2.5%, w/v) of soybean meal stimu-lated the transformation of the growth morphology from filamentous to pellet form. Comparing to that by filamentous form, the production of compactin by pellet form increased up to 1.5 folds. In a fed-batch fermentation, continuous feeding of the mixture of glucose and nitrogen source at the ratio of 10:1 showed 3.5-fold more produc-tion yield of compaction comparing to the batch mode.

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Postmortem analysis of a failed liquid nitrogen-cooled prepolarization coil for SQUID sensor-based ultra-low field magnetic resonance

  • Hwang, Seong-Min;Kim, Kiwoong;Yu, Kwon Kyu;Lee, Seong-Joo;Shim, Jeong Hyun
    • Progress in Superconductivity and Cryogenics
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    • v.16 no.4
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    • pp.44-48
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    • 2014
  • A liquid nitrogen-cooled prepolarization ($B_p$) coil made for ultra-low field nuclear magnetic resonance and magnetic resonance imaging (ULF-MR) designed to generate 7 mT/A was fabricated. However, with suspected internal insulation failure, the coil was investigated in order to find out the source of the failure. This paper reports detailed build of the failed $B_p$ coil and a number of analysis methods utilized to figure out the source and the mode of failure. The analysis revealed that pyrolytic graphite sheet linings put on either sides of the coil for better thermal conduction acted as an electrical bridge between inner and outer layers of the coil to short out the coil whenever a moderately high voltage was applied across the coil. A simple model circuit simulation corroborated the analysis and further revealed that the failed insulation acted effectively as a damping resistor of $R_{d,eff}=6{\Omega}$ across the coil. This damping resistance produced a 50 ms-long voltage tail after the coil current was ramped down, making the coil not suitable for use in ULF-MR, which requires complete removal of magnetic field from $B_p$ coil within milliseconds.

Nutritional Factors Affecting Efficiency of a Bioremediation Process for Diesel-Contaminated Soil (경유오염 토양의 생물정화공정에 대한 영양인자의 영향 분석)

  • No, Sang-Cheol;Lee, Cheol-Hyo;Jang, Deok-Jin
    • KSBB Journal
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    • v.14 no.4
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    • pp.503-510
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    • 1999
  • In order to analyze nutritional factors affecting in situ bioremediation of diesel degradation and cell viability were studied by varying nutritional conditions. In column experiments packed with diesel-contaminated soil, nitrogen was found to be the major limiting nutrient. When nitrogen was added to soil at four different levels of C : N (100 : 5, 100 : 10, 100 : 15, and 100 : 20 mg N/kg dry soil), the greatest simulation of microbial activity occurred at the lowest, rather than the highest nitrogen addition. However, no significant effects was observed when phosphorus and air were added. No matter how the incubation mode varied, less than 50% of the diesel was remained after 7 days of treatment, presumably because the residual hydrocarbons were adsorbed on soil particles, adsorption

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