• 한국연소학회지
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• 제15권1호
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• pp.22-29
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• 2010

In this study, carbon conversion was measured using an electronic mass balance. In a lab scale furnace, each coal sample was pyrolyzed in a nitrogen environment and became coal char, which was then gasified with steam under isothermal conditions. The reactivity of coal char was investigated at various temperatures and steam concentrations. The VRM(volume reaction model), SCM(shrinking core model), and RPM(random pore model) were used to interpret experimental data. For each model the activation energy(Ea), pre-exponential factor (A), and reaction order(n) of the coal char-steam reaction were determined by applying the Arrhenius equation into the data obtained with thermo-gravimetric analysis(TGA). According to this study, it was found that experimental data agreed better with the VRM and SCM for 1,000 and $1,100^{\circ}C$, and the RPM for 1,200 and $1,300^{\circ}C$. The reactivity of chars increased with the increase of gasification temperature. The structure parameter(${\psi}$) of the surface area for the RPM was obtained.

• 한국환경보건학회:학술대회논문집
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• 한국환경보건학회 2004년도 International Conference Current Challenges and Advances in Environmental Health
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• pp.45-50
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• 2004

Indoor air quality can be affected by indoor sources, ventilation, decay and outdoor levels. Alt hough technologies exist to measure these factors, direct measurements are often difficult. The purpose of this study was to develop an alternative method to characterize indoor environmental factors by multiple indoor and outdoor measurements. Daily indoor and outdoor NO2 concentrations were measured for 30 consecutive days in 28 houses in Brisbane, Australia, and for 21 consecutive days in 37 houses in Seoul, Korea. Using a mass balance model and regression analysis, penetration factor (ventilation rate divided by the sum of ventilation rate and deposition constant) and source strength factor (source strength divided by the sum of ventilation rate and deposition constant) were calculated using multiple indoor and outdoor measurements. Subsequently, the ventilation rate and NO2 source strength were estimated. Geometric means of ventilation rate were 1.44 ACH in Brisbane, assuming a residential NO2 deposition constant of 1.05 hr-1, and 1.36 ACH in Seoul, with the measured residential NO2 deposition constant of 0.94 hr-1. Source strengths of N02 were 15.8 ${\pm}$ 18.2 ${\mu}$g/m3${\cdot}$hr and 44.7 ${\pm}$ 38.1 ${\mu}$g/m3${\cdot}$hr in Brisbane and Seoul, respectively. In conclusion, indoor environmental factors were effectively characterized by this method using multiple indoor and outdoor measurements.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2008년도 추계학술대회 논문집 전기기기 및 에너지변환시스템부문
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• pp.191-193
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• 2008

A fuel cell power system among various alternative power sources has many advantages such as low-polluted, high-efficient, and heat-recyclable, thus it is now able to be up to hundreds MWh-scaled through improving feasibility and longevity of it. During the last few years of the twentieth century, much changed to stimulate new and expanding interest in fuel cell technology. This paper presents optimal design and operational features of stand-alone 500W PEMFC(Proton Exchange Membrane Fuel Cell) system which can be a substitute instead fossil fuel. The stack of PEMFC is composed of 35 laminated graphite, and a unit cell of the stack has electrical characteristics as below; 14W, 0.9V, 15A. The other components of BOP(Balance of Plant) are composed of hydrogen and nitrogen tanks, regulators, 3way 5solenoid valves, mass flow meters, etc.

• 한국연소학회지
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• 제15권2호
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• pp.1-11
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• 2010

Power generation systems based on the oxy-coal combustion with carbon dioxide capture and storage (CCS) capability are being proposed and discussed lately. Although a large number of lab scale studies for oxy-coal power plant have been made, studies of pilot scale or commercial scale power plant are not enough. Only a few demonstration projects for oxy-coal power plant are publicized recently. The proposed systems are evolving and various alternatives are to be comparatively evaluated. This paper presents a proposed approach for performance evaluation of a commercial 100 MWe class power plant, which is currently being considered for 'retrofitting' for the demonstration of the concept. The system is configurated based on design and operating conditions with proper assumptions. System components to be included in the discussion are listed. Evaluation criteria in terms of performance are summarized based on the system heat and mass balance and simple performance parameters, such as the fuel to power efficiency and brief introduction of the second law analysis. Also, gas composition is identified for additional analysis to impurities in the system including the purity of oxygen and unwanted gaseous components of nitrogen, argon and oxygen in air separation unit and $CO_2$ processing unit.

• 전력전자학회:학술대회논문집
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• 전력전자학회 2008년도 하계학술대회 논문집
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• pp.320-322
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• 2008

The international oil price now has been going up every each day, about 120 USD per a gallon April 2008, so that most of countries in the world are concern of the the shortage of petroleum and the development of new and renewable energy resources. This paper presents optimal design and operational features of stand-alone 500W PEMFC(Proton Exchange Membrane Fuel Cell) system which can be a substitute instead fossil fuel. The stack of PEMFC is composed of 35 laminated graphites, and a unit cell of the stack has electrical characteristics as below; 14W, 0.9V, 15A. The other components of BOP(Balance of Plant) are composed of hydrogen and nitrogen tanks, regulators, 3way solenoid valves, mass flow meters, etc.

• 한국물환경학회지
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• 제23권4호
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• pp.543-550
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• 2007

In this study, combined sewer overflows (CSOs) from five independent rainfall events in rural city area were collected and investigated. First flush effect in sewage pumping station located near the WWTP was retarded 30 to 60 minutes from booster pumping station. The ratios between SS, COD and TP concentrations prior to rainfall and peak concentrations during the period of rainfall were highly increased but nitrogen was relatively constant, which indicates that it is not associated with particles washed off from the surface of watershed. Mass balance results show that 30% of CSO was generated from booster pump station and 66.5% of CSO was from the whole runoff area. In the area of newly constructed sewer system, CSO problem was related with pump and sewer capacities, but in other old sewer system equipped area, it was due to the collection efficiency. Finally, Log-Log pollutant rating equations were suggested.

• 한국수자원학회논문집
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• 제37권12호
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• pp.1009-1018
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• 2004

하천을 따라 분포된 비점 오염원을 하천 수질모형의 매개변수들과 동시에 추정하는 체계적인 방법을 제안하였다. 수립된 방법을 QUAL2E 모형과 함께 충주댐 하류의 남한강 구간에 적용하여 모형의 반응계수와 비점 오염 부하량에 대한 최적 추정을 수행하였다. 민감도 분석 결과로부터 선정된 반응계수들에 대한 초기 추정 결과에 따르면 하천 시스템에 대한 질량수지가 만족되기 위해서는 질소와 인의 비점 오염 부하량의 입력이 필요한 것으로 나타났다. 이에 따라 총질소와 총인에 대한 비점 오염 부하를 포함하여 확장된 추정 문제의 해로써 비점 오염 부하량을 추정하였다. 비점 오염 부하량과 동시에 추정된 반응계수들과 비점 오염원을 고려하지 않고 추정된 반응계수의 비친 결과, 그 자체에 대한 추정을 위해서 뿐만 아니라 수질모형의 적절한 보정을 위하여 비점 오염 부하량이 최적 추정 과정에 포함될 필요가 있음을 알 수 있었다. 하천수질 의형에 대한 최적추정 방법의 적용성을 민감도계수 행렬 구조의 관점에서 논하였다.

• 대한토목학회논문집
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• 제14권3호
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• pp.635-644
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• 1994

혐기성 소화에 비해 낮은 시설비 및 공정의 안정성 등의 장점으로 중소규모 하수처리장의 슬리지 처리에 적합한 호기성 소화의 상징액내 영양염류 농도를 예측하기 위하여, 본 연구에서는 질소 및 인의 거동 관찰로 주요반응을 규정하고 물질수지를 고려해서 연립미분방정식 형태로 수학적 모형을 수립하였다. 하수처리장의 폐활성슬러지를 시료로 하여 초기 고형물 농도 수준을 다르게 한 회분식 호기성 소화조를 온도 $20^{\circ}C$, pH $7{\pm}0.5$의 조건에서 운영하였고, 반응계수 추정을 위하여 비선형 회귀분석을 실시하였다. 수립된 모형은, Biomass-N, 용존 유기질소, $NH_4{^-}$-N, $NO_x{^-}$-N과 Biomass-N, 용존 유기인, $PO_4{^-}$-P와 같은 영양염류의 거동 예측이 가능하였다. 모의실험으로 고형상의 영양염류보다 용존상 영양염류가, 질소보다는 인이 상징액에 미치는 영향이 크다는 것을 보였다.

• 한국산학기술학회:학술대회논문집
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• 한국산학기술학회 2007년도 춘계학술발표논문집
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• pp.112-115
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• 2007

Currently an increase in domestic sewage and industrial wastewater causes serious water pollution in Korea. To solve water pollution problems, conventional activated sludge (CAS) system is generally used in wastewater treatment plant but this process is so ineffective in nitrogen and phosphorus. Even if CAS system is the major process, it must be improved instantly so as to remove nitrogen and phosphorus. Otherwise, the serious water pollution problems can't be resolved with CAS system. Therefore this study focused on the comparison of the treatment characteristics between ASA system and CAS system. And also the mass balance of each process of ASA system. The results from operating advanced step aeration (ASA) system indicated that the removal efficiency of BOD, COD, and SS was 89.9%, 74.5%, and 89.0% respectively. In comparison, the removal efficiency of BOD, COD, and SS for CAS system was 89.5%, 71.8%, and 89.5% respectively. In addition to the results, the TN removal efficiency of ASA system was 76.5% comparing to 32.7% of CAS system. It was concluded that the TN removal efficiency of ASA system was 44% higher than CAS system. And the TP removal efficiency was 81.4% in ASA system comparing to 25.2% in CAS system. It also means that over 56% of TP was removed in ASA system comparing to CAS system.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
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• pp.138-141
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• 2004

The environmental tracers tritium/helium-3 (3H/3He) and chlorofluorocarbons (CFCs) were investigated in ground water from Jeju Island, Korea, a basaltic volcanic island. The apparent 3H/3He and CFC-12 ages were in relatively good agreement in samples with low concentrations of terrigenic He. Ground water mixing was evaluated by comparing 3H and CFC-12 concentrations with mixing models, which distinguished old water with negligible 3H and CFC-12, young water with piston flow, and binary mixtures of the two end members. The ground water CFC-12 age is much older in water from wells completed in confined zones of the hydro-volcanic Seoguipo formation in coastal areas than in water from the basaltic aquifer. Comparison of major element concentrations in ground water with the CFC-12 age shows that nitrate contamination processes contribute more solutes in young water than are derived from water-rock interactions in non-contaminated old water. Chemical evolution of ground water resulting from silicate weathering in basaltic rocks reaches the zeolite-smectite phase boundary. The calcite saturation state of ground water increased with the CFC-12 apparent (piston flow) age. In agricultural areas, the temporal trend of nitrate concentration in ground water was consistent with the known history of chemical fertilizer use on Jeju Island, but the response of nitrate concentration in ground water to nitrogen inputs follows an approximate 10-year delay. Based on mass balance calculations, it was estimated that about 40% of the nitrogen applied by fertilizers reached the water table and contaminated ground water resources when the fertilizer use was at the highest level.